T “] CARIBBEAN EXAMINATIONS COUNCIL CARIBBEAN ADVANCED PROFICIENCY EXAMINATION” ira FILL IN ALL THE INFORMATION REQUESTED CLEARLY IN CAPITAL LETTERS. resrcove }o }2]1}1|2]o SUBJECT CHEMISTRY ~ UNIT 1 - Paper 02 PROFICIENCY _ ADVANCED. REGISTRATION NUMBER ‘SCHOOL/CENTRE NUMBER NAME OF SCHOOL/CENTRE, CANDIDATE’S FULL NAME (FIRST, MIDDLE, LAST) DATE OF BIRTH SIGNATURE LL (gei S ‘rest-coe 02112020] FORM TP 2023194 MAY/JUNE 2023 CARIBBEAN EXAMINATIONS COUNCIL CARIBBEAN ADVANCED PROFICIENCY EXAMINATION® (CHEMISTRY UNIT 1 - Paper 02 2 hours 30 minutes READ THE FOLLOWING INSTRUCTIONS CAREFULLY. 1, This paper consists of THREE questions. Answer ALL questions. Write your answers in the spaces provided in this booklet. 3. DoNOT write in the margins. 4, Where appropriate, ALL WORKING MUST BE SHOWN in this booklet. 5, Addata booklet is provided. 6. You may use a silent, non-programmable calculator to answer questions. 7. Ifyou need to rewrite any answer and there is not enough space to do so on the original page, you must use the extra lined page(s) provided atthe back of this booklet, Remember to draw a line through your original answer. 8. Ifyou use the extra page(s) you MUST write the question number clearly in the box provided at the top of the extra page(s) and, where relevant, include the question part beside the answer. DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO. a Copyright © 2022 Caribbean Examinations Council All rights reserved. 02112020/MJ/CAPE 2023 1 |L (@) (b) Answer ALL questions. MODULE 1: FUNDAMENTALS OF CHEMISTRY State EACH of the following laws. (i) Boyle’s law [1 mark] Gi) Charles’ law [1 mark} List FOUR assumptions made about gas molecules in the kinetic molecular theory with reference to ideal gases. GO ON TO THE NEXT PAGE 02112020/MN/CAPE 2023 L ee sng ar “ 7 (©) Afflask has a mass of 47.392 g when empty, and 47.816 g when filled with acetone vapor at 100 °C and 745 mm Hg. If the volume of the flask is 247.3 mL, what is the molar mass of the acetone? R= 0.0821 L atm/mol K, 760 mmHg = 1 atm. {4 marks} @ (i) State Hess” law. [2 marks] Gi) Construct a Born-Haber eycle for the formation of lead (II) fluoride, PbF,(S), showing clearly, using equations, the steps of the enthalpy changes involved. [6 marks} GO ON TO THE NEXT PAGE | 02112020/MJ/CAPE 2023 =r “ 7 Table 1 shows the enthalpy changes associated with the Born—Haber cycle. TABLE 1: ENTHALPY CHANGES ASSOCIATED WITH THE BORN-HABER CYCLE. Enthalpy Change Value (ki/mol) Enthalpy of atomization of Pb 195.20 Ist ionization energy of Pb 716.00 2nd ionization energy of Pb 1450.00 Enthalpy of atomization of F 79.00 Enthalpy of formation of PDF, 664.00 Ist Electron affinity of F 328.16 Gi) Using the data in Table 1, calculate the lattice energy of PbF,(s), [3 marks] (©) State the effect of EACH of the following on the magnitude of the lattice energy. (Tonic charge Tonic radius [1 mark] GO ON TO THE NEXT PAGE, nig _| 02112020/MI/CAPE 2023 LL mTwo (gs) 4 A yellow precipitate is formed when silver nitrate solution, acidified with dilute nitric acid, is added to an aqueous solution containing iodide ions. (Write the simplest ionic equation for the formation of the yellow precipitate. [2 marks} (ii) State the result observed when concentrated ammonia solution is added to this [1 mark] State why the silver nitrate solution is acidified when testing for iodide ions. “TT mark] (iv) Explain why dilute hydrochloric aci in this test for iodide ions. is not used to acidify the silver nitrate solution [1 mark] Describe the result observed when chlorine water is added to a solution of potassium bromide, followed by aqueous silver nitrate. [2 marks] Total 30 marks GO ON TO THE NEXT PAGE 02112020/MJ/CAPE 2023, nn _|-8- 7 MODULE 2: KINETICS AND EQUILIBRIA 2. (@)_Asstudent placed a known quantity of frozen N,O, in a sealed tube and allowed it to warm upto room temperature, As the vessel was warming, a brown gas appeared which indicated that the frozen N,O, had vaporized to form a gas, and then decomposed to form NO.(g) according to the reaction below. The student allowed the reaction to proceed further until equilibrium was reached. @ @ Gi) ww N,0,(@) = 2.NO,(g) 3 AH = 458.0 k mol Colourless Brown Explain the term ‘dynamic equilibrium’, [2 marks} State what is observed when dynamic equilibrium is reached in the reaction above. State Le Chatelier’s Principle, Write the expression for K, for the reaction above. [1 mark} GO ON TO THE NEXT PAGE 02112020/MI/CAPE 2023 L |r * 1 (v) Inthe space provided below, draw a graph to show how the concentrations of N.Oy, and NO,,,, are expected to change as the reaction proceeds towards equilibrium. g E i 8 6 Time ——> [2 marks} (vi) Account for the shape of the graph drawn in (a) (v). [2 marks} (vii) State what is observed when the sealed tube is cooled to 0 °C. Outline the reason for what is observed. GO ON TO THE NEXT PAGE 02112020/MJ/CAPE 2023 L ge _| ooF (b) @ ii) -10- “| State the difference in behaviour between a strong acid and a strong base according to the Bronsted-Lowry Theory. [1 mark] Complete Table 2 below, using the variable x to generate expressions for the equilibrium concentrations of the reaction components for a 0.30 M solution of CH,COOH. TABLE 2: DATA FOR THE DISSOCIATION OF CH, COOH CH,COOH © CH,COO Tnitial 030M oM OM Change Equilibrium 16 marks] GO ON TO THE NEXT PAGE 02112020/MI/CAPE 2023 0 _| Br (aq) + BrO-(aq) + H,0(1) H Use the equation to explain the term ‘disproportionation’ . [3 marks] GO ON T0 THE NEXT PAGE (02112020/MJ/CAPE 2023 gn |r “" 1 (g) Study Table 4 of the electrode potential values and answer the questions ‘TABLE 4: ELECTRODE POTENTIAL VALUES EW ¥0.09 1, + 2e— 2 1054 280," + 10H" + 8e > S,0,? +5H,0 4057 Br, + 2e > 2Br +107 Cl, F2e > 2Cr +136 (i) Which of the halogens bring about the maximum change in oxidation number of sulfur? (ii) Write ONE fall ionic equation to represent this change. [1 mark] GO ON TO THE NEXT PAGE _ 02112020/MJ/CAPE 2023 L sir “ 1 (h) _NaZ.is a sodium halide which gives the following results on testing. + Bubbling Cl, into an aqueous solution of NaZ. gives a brown solution, On addition of starch, a blue-black colour forms. + Addition of AgNO, to NaZ(aq) gives a yellow precipitate which is insoluble in aqueous ammoni @ Identify element Z, [1 mark (i) Explain the reaction taking place in EACH of the tests above. Include balanced equations in your explanation, [4 marks) Total 30 marks END OF TEST IF YOU FINISH BEFORE TIME 18 CALLED, CHECK YOUR WORK ON THIS TEST. (02112020/MI/CAPE 2023 _T -19- | EXTRA SPACE Ifyou use this extra page, you MUST write the question number clearly in the box provided. Question No. 02112020/MJ/CAPE 2023 L ng _|-20- ~] EXTRA SPACE Ifyou use this extra page, you MUST write the question number clearly in the box provided. Question No. 02112020/MJ/CAPE 2023 ng |im -21- 7] EXTRA SPACE Ifyou use this extra page, you MUST write the question number clearly in the box provided. Question No. 02112020/MNCAPE 2023 L 0 A _|r = 1 EXTRA SPACE, If you use this extra page, you MUST write the question number clearly in the box provided. Question No. (02112020/MI/CAPE 2023 L ange _lCANDIDATE’S RECEIPT a INSTRUCTIONS TO CANDIDATE, 1, Fill in all the information requested clearly in capital letters. vesrcope |o}2}1]1}/2}o}]2}0 SUBJECT CHEMISTRY — UNIT | ~ Paper 02 PROFICIENCY ADVANCED REGISTRATION NUMBER FULL NAME, (BLOCK LETTERS) SIGNATURE DATE Ensure that this slip is detached by the Supervisor or Invigilator and given to you when you hand in this booklet. 3. Keep it ina safe place until you have received your results. INSTRUCTION TO SUPERVISOR/INVIGILATOR Sign the declaration below, detach this slip and hand it to the candidate as his/her receipt for this booklet collected by you. Thereby acknowledge receipt of the candidate’s booklet for the examination stated above. Signature Supervisor/invigilator Date