MOCK TEST -1

JEE MAIN

Time: 3 Hrs Date: -01/04/-2024 M.M.: 300

Physics : Full syllabus
Chemistry : Full syllabus
Mathematics : Full syllabus
Physics Chemistry Mathematics
Questions Answers Questions Answers Questions Answers
1 b 31 a 61 d
2 b 32 b 62 a
3 d 33 d 63 c
4 a 34 a 64 c
5 c 35 c 65 a
6 d 36 b 66 d
7 c 37 b 67 c
8 b 38 d 68 c
9 b 39 d 69 a
10 d 40 c 70 a
11 c 41 b 71 b
12 b 42 d 72 b
13 d 43 b 73 b
14 c 44 b 74 b
15 a 45 c 75 a
16 a 46 d 76 b
17 c 47 b 77 c
18 c 48 c 78 c
19 c 49 b 79 c
20 a 50 a 80 a
21 5 51 5 81 5
22 5 52 7 82 0
23 5 53 3 83 3
24 2 54 1 84 4
25 8 55 2 85 0
26 1 56 2 86 2
27 5 57 5 87 6
28 1 58 3 88 3
29 8 59 3 89 1
30 2 60 5 90 7

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 HINTS AND SOLUTIONS
Physics mv
r … (i)
1. (b) Bq

i1  2A The perpendicular component of velocity results

in circular motion, while the parallel component
i 2  2A results in linear motion. Hence, the path of the
charged particle is helical in nature, the axis of
which lies along the direction of the magnetic
field.
7. (c)
Minimum stopping distance = s
Force of friction =  m g
Work done against the friction W   mgs
i  i13  i 22  2 2A Initial kinetic energy of the toy cart = p 2
/ 2m 
2. (b)   mgs   p 2 / 2m 
v v 2
  2 1  v s1  m2 
3 3  
  2  3
s2  m1 
The correct option is (c)
3. (d)
2GM
We know that frequency of orbital motion 8. (b) v e   11.2 km / s
R
1 1 2GM
f 3
and given f1  f2 ve   2  11.2  22.4 km / s
n 27 R/4
1/3 9. (b)
n 3  f n  1  1
 2   1  2    P2  a  L  P1  P2  a  L
 n1  f 2 n1  27  3
aL
h1  h2 
4. (a) g
d    The correct option is (b)
L  WL 10. (d)
dt
Slope of H vs  graphs give ‘heat capacity’.
 3kˆ  3iˆ  4ˆj
heat capacity
 Specific heat capacity 
 12iˆ  9jˆ mass
tan 45 
5. (c)  kJ / kg / C
2
F  F cos   ma1  0.5kJ / kg / C

F 11. (c)
1  cos   a1 q' q
m  0
F r1 r2
 a2
m The correct options is
F 12. (b)
Relative acceleration a 1  a 2  2  cos 
M 1
Average power  Pav  v2 A 2 average rate of
6. (d) 2
transport potential energy
The formula to calculate the radius of the path
 dU  Pav 1
followed by the charged particle under an external    v2 A 2  256 W
 dt  2 4
magnetic field can be written as
13. (d)
Let the potential of the junction be V. then

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 6 V 4 V 8 V 20. (a)
  0
2 4 4 x   2  10 2  cos t
12  2V  4  V  8  V  0
Here, a  2 102 m  2cm
24  4V
V  6N At t  0, x  2 cm, ie the object is at positive
Potential drop across capacitor extreme, so to acquire maximum speed (i.e, to
 6  ( 10) reach mean postion) it takes

=16 V 1
the of time period.
Charge on capacitor  16  C 4

The correct option is (d) T

 required time =
4
14. (c)
Here path difference will be: 2
Where      T  2s
2 T
x    2   1  t      2  1  t
 T 2
So, required time    0.5s
15. (a) 4 4
B 2 L2 V 2 B 2 L2 V 2 t 2 21. (5)
w  p.t.  t  Let moment of inertia I  kmR 2
R tR
2
B2 L2  vt  B 2 L4
 
tR tR
16. (a)
mc 2  8  1.008982  931MeV

17. (c)
a  Ra........................  I 
x2  1  t 2

  mg sin R   k  1 mR ........  II 
2
dx dx t R
2 x  2t  
dt dt x g sin 
a
d 2 x x  t dx / dt 1 t 2 k 1
    3
dt 2 x2 x x t
2x
The correct option is (c) a
2
18. (c) t1 a k 1
 2  1  3 1 
10
t2 a1 k2  1 1
2 1 3
q1 4 106  0.2 10 3 
q  1  e
2 2  4 101  25 
22. (5)
q  12 1  e 2
 C Initial pressure of gas 0 Let final pressure of air
in ' and x
 e2  1  0 25   ' x..............(I)
 12  2  C  10.37C.
 e 
100  x  ,g....
19 (c)
0   '  II 
100
v2 0   ' 100  x 103
tan    r  v2
rg
 0  100  x 10  x
3
0  25  
2
r2  v 2  x  50
  23. (5)
v1  v1 
After explosion radius of brilliant sphere at t  t;
2
r  1.1v  (assuming explosion to occur at t = 0) R = Vt; v =
or 2     r2  24.2 m speed of all particles at the time e of C.M of
20  v 
particles

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 .
1 From Gauss's law,
R  gt 2  160
2 q
R  80m  E d Scos 0  0
1 2 Here, q = volume charge density  volume of
gt  80
2 imaginary cylinder.
T  4sec  x 2 h
V  20m / s  E  2 xh  
0
24. (2)
x
1 q Q  9  E
F 2 0
40 r2
 2 0
For maximum repulsion force  E  1
2 0 
dF
 Q  2q  0 Thus, electric field is 1 V m 1.
dq
29. (8)
Q 2
 2 Let R1 and R 2 be the resistances of the coils, V
a 1
25. (8) the supply voltage, H the heat required to boil the
water For first coil , H
M  K L 1L 2 V 2 t1
H .............  i 
Here, K  1 R1
M  4  16  8H   a  V2 t 2
For second coil , H  ........  ii 
R2
26. (1)
Equating Eqs. (i) and (ii) , we get
P  Q  23 t1 t
PQ 7
 2
R1 R 2
 2P  30 R 2 t 2 40
i.e.,   4
 P  15 R 1 t1 10
 Q  23  15  0  R 2  4R1........ iii 
  When the two heating coils are in parallel,
If p  Q, R  P 2  Q 2  225  64  17
R1R 2 R  4R 1 4R 1
R  1 
27. (5) R 1  R 2 R 1  4R 1 5
2
Let a be the size of each side of the cude. V
and H  t ......  iv 
R
200  g   2    a 2   1  g
Comparing Eps. (i) and (iv) we get
 a  10 cm V 2 t1 V 2 t R 4
 t  t 1   10
R1 R R1 5
28. (1)
 8min.
Given here, Volume charge density   Cm 3 .
30. (2)
Consider a Gaussian cylindrical surface of height 3/2
Baxis  R 2 
h and radius x. 
Bcentre  R 2  X2 
Let q charge is enclosed by the cylinder of radius
x

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 CHEMISTRY
31. (a)
Theory based
32. (b)
10
x  0.529  10 10 
100
 0.529 10 11 m
h
x.V 
4 m
6.63  10 34 36. (b)
V  HB HA
4  3.14  9.1  1031  0.529  1011  2H   H 2
H 2  2H  
1 atm x y 1 atm
V  107 m / s 10 7 10  5

5
33. (d) K a  10

Let, % of C be 7.5  % and H be  %  H    K a .C

 7.5   x  32  100  H    105.1

 x 8 H    107.1
HB
 % of C  60%,H  8%and O  32%
0.0591 10 5
E 0 log 7 V
 E.F.  C 60 H 8 O 32  C5 H 8O 2 2 10
12 1 16
E  0.059V
34. (a) 37. (b)
T2  527 C  800 k; k1  2.5  10 4 The salt weakest acid will produce highest PH
with strong base.
T1  327C  600k; k 2  1 38. (d)
Complex having maximum number of unpaired
According to Arrhenius Equation: electrons will exhibit maximum attraction to
Cast iron is used to manufacture wrought iron.
k2 E 1 1
In  a   applied magnetic field.
k1 R  T2 T1 
2
 Zn  H 2 O 6   d10 system, t 62g eg 2 ,0 unpaired
 104  Ea  1 1 
ln     
 2.5  R  600 800  electrons
2
Ea  1  Co  H 2 O 6   d7 system, t 52g eg 2 ,3 unpaired
ln  4000  
8.314  2400  electrons
3
Ea  165.431 kJ, Ea  166 kJ / mol Co  en 3   d6 system, t 62g eg 0 ,0 unpaired
electrons
35. (c)
In first step of the reaction H+ will attack on he  Ni  H 2O 6  
2
 d8 system, t 62g eg 2 , 2 unpaired
lone pairs of electrons of the oxygen atom. Will
electrons.
get dehydrated forming carbocation intermidiate.
On this carbocation pibond will attack forming a So, option d is correct.
five membered cyclie ring. In last step Br– will
39. (d)
combine with carbocation forming final porduct
accordign to the following reacitons. K  sp PbCl
2
 3.2  108  32  109


PbCl 2  Pb s2  2 2s
Cl

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 Ksp  Pb2  Cl 
2 42. (d)
N 2 (g)  3H 2 (g)  2 NH 3 (g)
K sp  4s 3  32  10 9 2

KC 
 NH3   64
3
s 3  8  10 9  N 2  H 2 
s  2  103 M For the reaction

1 3
w

1
 2  10 3 NH 3 (g)  N 2 (g)  H 2 (g)
M.W. VL 2 2
1/2 3/2
0.1 1  N  H2 
K 'C  2 
1

1

1
  2  10 3
278 VL  NH 3  KC 64 8

0.1 1000 43. (b)

VL   0.18 L
278  2

40. (c)
Molar mass of octane =114 g/mol.
From the lowering of vapour pressure, we have,
W2
AP M2

P W2 W1

M 2 M1 44. (b)
Where W2 and M2 are mass and molar mass of XeF6  sp 3d 3  Distorted octahedral
solute and W1 and M1 are mass and molar mass of
octane.
W2
75 50 g / mol

100 W 2 144g

50g / mol 114g / mol 45. (c)
 

W2 Ph  I  C2 H 5 O N a 
 No SN 2, Partial double
bond character.
0.75  50
W2 46. (d)
1
50
W2 W2 (a)
1 
50 50  0.75
W 2  150g

41. (b)
The brown ring test is a typical nitrate test that i B2 H 2 / ether
involves adding iron (II) sulphate to a nitrate
solution, then slowly adding strong sulfuric acid (b) ii CH3COOH
until the acid forms a layer below the aqueous (c)
solution. The existence of the nitrate ion will be
shown by the formation of a brown ring at the
junction of the two layers. Dark brown ring is
formed in the confirmatory test of NO 3  ions.
Deep red precipitate with FeCl3 is formed in the
presence of CH 3COO  ions.

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 51. (5)
(d)
NaCN  aq  HCI  NaCI  aq   HCN  aq 
60  0.2
m moles 12 80  0.1
8
47. (b)
4 
 8
Acidic buffer solution
52. (7)
Electronic configuration of Gd = [Xe]4f45d16s2

Due to more statbel exactly half-filled 4f4 shell,

48. (c) electron filling occur in a little higher energy 5d-
D-glucose and D-Mannose are C2 epimers and orbital. So configuration of Gd2+ = [Xe ]4f7 5d1
form the same osazone.
53. (3)
49. (b) Ptotal  PB X B  PT X T
Oxidation of this substituted ketone will give a
ketone and a carboxylic acid. This reaction takes 1 2
 100   50 
place by the cleavage of carbon atoms near the 3 3
carbonyl carbon and the nearby carbons. This 200
cleavage can be from both the sides of carbonyl  torr
3
carbon thus producing two different carboxylic
acids and ketones. The ketone formed converts to PB X B
yB 
hydrocarbon in the presence hydrazine in alkaline PTotal
medium. The overall reaction is shown below. 1
100 
 31
200 2
3
1
6  3
2
54. (1)
Given balanced equation is

10
 10 gKClO3  molKCO3 in obtained
122.6
50. (a)
Alcohol forms carbocation inthe presence of  from the above reaction, it is concluded that by
acidic medium. The carbocation formed from
6F charge 1 mol KClO 3 is obtained.
given alcohol undergo rearranegement to get
stability. Final it loses proton to get an alkene.  By the passage of 6F charge = 1 mol KClO 3

x 10  60  60
 By the passage of F charge
96500

1 x 10  60  60 10
  
6 6  96500 122.6

x  10  60  60 10
Now, 
6  96500 122.6

10  965 965
 x   1.311  1
60 122.6 735.6

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 OR

E
W  I t
F

122.6
10   x 10  3600
96500  6

X  1.311
55. (2)
No reaction with strong base or acid indicates
presence of strong neutrality or non-reactive
functional group with a single oxygen. No
positive 2,4-DNP test indicates absence of
carbonyl compound. Same compound formation
upon hydrogenation indicates single double bond.
Thus, it is an ether. As per the language of given
question, the best possible isomeric structure is
Ph  CH  CH  O  CH 3 (c is and trans). So,
the answer is 2.) 59. (3)
56. (2) In Faintly alkaline medium potassium
Using formula permanganate changes to manganese dioxide in
its oxidising action.
 r G 0   RT ln K p
MnO 4  2H 2O  3e   MnO 2  4OH 
25200  2.3  8.3  400 log(K p )
The oxidation state of manganese in MnO 4 is +7
K p  10 3.3  10 3  0.501 and in MnO2 is + 4.

Hence, it transfers 3 electrons during the oxidising

 5.01  10  4 Bar 1
action in alkaline medium.
KC 60. (5)

8.3  400

K C  1.66  10  5 m 3 / mole

 1.66  10 2 L / mol

2
Gibbs free energy can be visualized as the amount
of useful energy present in a thermodynamic
system that can be utilized to perform some useful
work.

57. (5)
The orbitals oriented along axis have electron MATHEMATICS
density along the axis.
61. (d)
Orientation of 2p orbitals are as follows:
p x , p y, p z ,d z & d x  y are oriented between the axis. The given conditions can be expressed as
2 2 2

58. (3)
n  M  P  C   50, n  M   37, n  P   24,
n  C   43, n  M  P   19,

n  M  C   29 and n  P  C   20,
n  M  P  C   n  M   n  P   n C   n  M  P 

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 n  M  C   n  P  C   n  M  P  C  65. (a)
Using R1  R3 , write
 50  37  24  43  n  M  P   n  P  C 
x  10 3 4
n  M  C   n  M  P  C 
P x   2 x  10 5
 n  M  P  C   n  M  P  n  M  C  7 6 x  10

 n  P  C   54. Observe P(x) is of the form

P( x)  ( x  10)3  a  x  10   b
Therefore, the number of students that could have
passed all three exams is at most. Where a, b are some real numbers.
19  29  20  54  14. sum of zero of P(x)
62. (a) coefficiento of x 2
  30
Period | sin(4 x ) | is    and period of | cos 2 x | is coefficient of x 3
   66. (d)
period of f ( x ) | sin 4 x |  | cos(2 x) | is  cos(  ) sin(  )   0 1 
Let B  
  1 1     sin(   cos(     1 0 
 l cos  2 , 4     2  1 3  1  1 3 
  
and A   , A  0 1 
63. (c)  0 1  
x =1.x so (x, x)  R1. If (x, y)  R1 then x = ay or Note that B is an orthogonal matrix.
y =ax for some integer a  1 3   0 1  1 3 
C  A1 BA     
 y  ax or x  ay  ( y, x)  R1  0 1   1 0  0 1 
If y  ay or y  ax and z  by or y  bz  3 10 
 
For some integer a and b then x  abz or  1 3 
z  abx , so  x, z   R1. Thus R is an equivalence Note that C is neither symmetric, nor skew –
relation. symmetric and nor-orthogonal.
Since (2, 2)  R2 so R2 is not reflexive. Thus R2 67. (c)
is not an equivalence relation. We have
64. (c) n
Cr 1 36 n! r ! n  r  ! 3
n
  
As the roots are real and distinct Cr 84  r  1! n  r  1! n ! 7
2
 a  1  4  a  a  8  0
2
r 3
   10r  3n  3
3a 2  2a  33  0 n  r 1 7
n
11 Cr 84 r 1 2
  3a  11 a  3   0    a  3 ….(1) Similarly, n
  
3 Cr 1 126 nr 3
 5r  3  2n  5r  3  2n
Solving we obtain r =3.
68. (c)
Letters appearing in the word COCHIN are
C,C,H,I, N, O
2 2
Also, for 2  2  a  1  a  a  8  0 Words appearing before COCHIN are of the form
C X -------
 a 2  a  6  0   a  3 a  2   0
Where X is one of the letters C,H, I, N and the
 2  a  3 ……..(2) four remaining places can be filled by the
From (1) and (2), we get -2<a<3. remaining four letters.

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 Thus, the number of words before COCHIN is (4)      
(4!) = 96   2  2 
 
   iˆ  3   ˆj   4   kˆ  . 2iˆ  ˆj  kˆ  3  0
69. (a)
   
We have 24  16  17  1 Hence, the position vector of Q is
4 500
2 2000
 2   17  1
500
   
iˆ  3 ˆj  4 kˆ  2 2iˆ  ˆj  kˆ , i.e.  3iˆ  5 ˆj  2 kˆ.

 500 C0 17 500 500 C117 499  500 C 217 498  71. (b)
2
500
C317 497  .... 500 C499 17    1
500
e x  1  1  cos x  e x 2  1 2sin 2 x / 2 
lim  lim  2  2

x 0 x2 x0 
 x 4  x / 2  
 17m  1
Where m is some positive integer.
Thus, the required remainder is 1.
1 3
 1 
70. (a)
2 2
72. (b)

Let the given point be P iˆ  3 ˆj  4 kˆ and Q be  dx
 2cos t  2 cos 2t  2  2sin  3t / 2  sin t / 2 

the image of P in the plane rˆ. 2iˆ  ˆj  kˆ  3  0  dt
and
as shown in the Figure.
dy  3t t
 2sin t  2 sin 2t  2 sin cos 
dt  2 2
dy
Hence  cot  t / 2  and
dx
 d2y  1 2 dt
 2    cos ec  t / 2  
 dx  2 dx
Therefore,
d2y 1 1
  cos ec 2  t / 2  x 
dx 2 2 4 sin  3t / 2  sin  t / 2 
Then PQ is the normal to the plane. Since PQ and
passes through P and is normal to the given plane,
d2y  1
 2   4  11/ 2    12
2
so the equation of PQ is given by   
2
 dx t    2 
  
r  iˆ  3 ˆj  4 kˆ   2iˆ  ˆj  kˆ  73. (b)
Since Q lies on the line PQ, the position vector of Since f has local minimum at x =2
Q can be expressed as
So f  2   f  x  for x in an open interval around
iˆ  3 ˆj  4kˆ     2iˆ  ˆj  kˆ  , i.e., 2.
1  2  iˆ   3    ˆj   4    kˆ  f  2   lim f  x 
x2 
Since R is the mid point of PQ, the position vector
of R is Thus,  f  2   lim 4 x 2  3 x  1  21
x 2
1  2  iˆ   3    ˆj   4    kˆ   iˆ  3 ˆj  4kˆ  74. (b)
   
2 Since degree of numerator is greater than the
 ˆ   degree of denominator, we divide them
i.e.,     iˆ   3   j   4   kˆ
 2  2 x4 1
2
 x2  1  2
Again, since R lies on the plane x 1 x 1
 ˆ ˆ ˆ
 
r . 2i  j  k  3  0 , we have
So
x4
dx 
x3 1
 x2  1 3  x  tan x  C

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75. (a) 2
 5k   5h 
1 90 1 99    4 
 x 1  x  dx   1  x  1  1  x   dx is  2   2 
0 0

(Property 9)  5k 2  8h
2
1  Locus of P is 5 y  8 x.
1
99 x100 x101
100 1
  ( x  x ) dx    . 79. (c)
0 100 101 0 10100
76. (b) AB   2  3 i   1  4  j  1  4  k
The given curve is a cubic curve and cuts x-axis at   i  3 j  5k
–1,0 and 1. BC  i  2 j  6k , CA  2i  j  k
Since AB  BC  CA  0; A,B,C are the vertices
of a triangle.
AB.CA  0  BCA  900
So the triangle ABC is right angled.
80. (a)
Required area We have
0
  x  x 2  1 dx 
1 P  A  B '   P  A   P  B '   P  A  B '
 xx  1 dx
2
1 0
 [1  P ( A ')]  [1  P ( B )]  [ P ( A)  P ( A  B )]
2 0 2 1
1 x  1 x   1  0.3  1  0.5  1  0.3  0.5
  x4     x4  
4 2  1  4 2 0
Now, P  B / A  B '
1 1 1
   P  B   A  B '   P  ( B  A)  ( B  B ') 
4 4 2  
77. (c) P  A  B ' P  A  B '
The given equation can be written as P  A  B  0.3
   0.6
dy y  sin x  y  1 dy 1 P  A  B '  0.5
   tan x   sec x
dx cos x y 2 dx y 81. (5)
1 Since Tr 1  n C r a n  r x r in expansion of
Put   z, we have
y n
a  x ,
dz
 tan x  z   sec x …….(1) 7
2n 7 7
dx x
Therefore, T8  n C7 (2) n 7    n C7 x
3 37
I .F .  e 
tan x
dx  e log sec x  sec x
8
d n n 8  x n 2 n 8 8
(1) reduces to  z sec x    sec2 x And T9  C8 (2)    C8 x
dx 3 38
 z sec x   tan x  c1 n 2 n 7 n 2 n 8
Therefore, C7  C8 (since it is given
37 38
 sec x   c  tan x  y, c  c1
that coefficient of x7 = coefficient x8)
78. (c)
n 8 n  8 2 n 8 37
Let P be (h, k)    8 . n 7
7 n 7 n 3 2
2x 2y
Then h  , k 8 1
5 5    11n  55
n7 6
As (x, y) lies on the parabola y 2  4 x. 82. (0)
If z  R and z  0 , then
arg( z )  arg( z )  

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  arg ( z )  arg( z )  2  
As log5 2, log5 2 x  5 , log5 2x  7 / 2 are in 
Suppose z  C , z  0 and z is not a negative real A.P., we get
number,
2 log 5  2 x  5  log5 2  log5  2 x  7 / 2 
Let are ( z )    where   so that
arg (z) + arg ( z )  0  (2 x  5)2  2  2 x  7 / 2 
83. (3) 2
4 8 2   2 x   12  2 x   32  0
As       , we get
n n   2 x  4  2 x  8  0
1     1   2 
2 n n  2 x  22 , 23  x  2,3
        Clearly, x  2. Therefore x =3
 n 1 89. (1)
n3 x
Let f ( x)   cos t 2 dt and g  x   x. Then
84. (4) 0

We have  sin x  3 2sin x  1  0 f  0   g  0   0.

 sin x  3 which is not possible f  x f '( x)
 lim  lim
Or x 0 g  x x0 g '( x)
sin x  1 / 2  x           x

as x   0,3   cos t 2dt cos x 2 .1  cos 0.0

0
 lim  lim
85. (0) x0 x x 0 1
2
Let a  AR p 1
, b  AR q 1
and c  AR r 1 cos x
 lim  cos 0  1.
 log a            q  1 
x 0 1
90. (7)
and log c     r )  Let r be the length of the line segment which
Where   log a,   log R. makes angles      respectively with x,y and z-
1 p    )  axes, then
r cos ga  2, r cos    r cos   
Now,   1 q   (q  1) 

1 r     
r 2 (cos 2   cos 2   cos 2  )  22  32  62  49
Using C3  C3      C1   C3 , we get
 r  7 as cos2   cos 2   cos2  

86. (2)
The system of equations will have a non-zero
solution if and only if
4 k 2
k 4 1 0
2 2 1
4 1 k 1 k 4
4 k 2 0
2 1 2 1 2 2
 4(2)  k ( k  2)  2(2k  8)  0
 k 2  6k  8  0  k  2, 4
87. (6)
Clearly, the locus of the point of intersection of
lines is
( x  5)( x  3)  ( y  2)( y  4)  0
Or x 2  y 2  8 x  2 y  7  0
Hence, | f  g || 2  ( 8) | 6
88. (3)

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