JR IIT *CO-SC(MODEL-B) Date: 30-06-2024

Time: 3 Hrs CTM-2 Max. Marks: 300

PHYSICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and
(4) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

1. A small block of mass ‘m’ is placed on a rough rotating table. Find maximum angular
velocity 0  that can be given to the table so that the particle does not slip on the
table. It is given that the coefficient of friction between the block and the table is
.

2 g 3 g g g
1) 2) 3) 4) 2
d d d d
2. In uniform circular motion
1) Both velocity and acceleration are constant
2) Acceleration and speed are constant but velocity changes
 3) Both acceleration and velocity change
4) Both acceleration and speed are constant
3. Mark the correct statements regarding circular motion of a particle
1) Particle is in equilibrium 2) Speed of particle is constant
3) Velocity of particle must change 4) Acceleration of particle may be constant
4. A particle is moving along a circular path. The angular velocity, linear velocity,
angular acceleration and centripetal acceleration of the particle at any instant are
   
 , v , and ac respectively. Which of the following relations is/not correct?
       
1)   v 2)    3)   ac 4) v  ac
5. In a non-uniform circular motion (horizontal), a ball is tied with string. The net
acceleration at any time is directed.
1) Radially towards centre 2) Tangential
3) Along the velocity 4) None of these
6. A body is moving in a circle with a speed of 1 m/s. This speed increases at a constant
rate of 2 m/s every second. Assume that the radius of the circle described is 25m. The
total acceleration of the body after 2s is.
1) 2m s 2 2) 25m s 2 3) 5 m s2 4) 7 m s2
7. A particle describes a horizontal circle of radius r on the smooth surface of an
inverted cone. The height of the plane of the circle above the vertex is h. The speed of
the particle is

1) rg 2) 2rg 3) gh 4) 2gh

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8. Small blocks A and B connected with a string are rotated with angular velocity 
about point O as shown in the figure. Breaking strength of both the strings is 75N.
The maximum angular velocity by which system can be rotated on a horizontal
smooth plane

4
1) 4 rad/sec 2) 5 rad/sec 3) 6 rad/sec 4) rad/sec
3
9. A solid body rotates with constant angular velocity 0 = 0.5 rad/s about a horizontal
axis AB. At time t = 0 the axis AB starts turning about vertical with constant angular
acceleration   0.1 rad s 2 . Find the angular acceleration of the body after t = 3.5sec

1) 0.2 rad s 2 2) 0.5rad s 2 3) 0.6 rad s 2 4) 1rad s 2

10. On particle moving on a circular path with a constant speed v, light is thrown from a
projector placed at the centre of the circular path as shown in figure. The shadow of
the particle is formed on the wall. The velocity of shadow up the wall is

1) v sec2  2) v cos2  3) v cos  4) none

11. A 20mg bug sits on the smooth edge of a 25-cm radius phonograph record as the
record is brought up to its normal rotational speed of 45 rev/min. How large must the
coefficient of friction between the bug and record be if the bug is not to slip off?
1) 0.3 2) 0.256 3) 0.566 4) 0.287

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12. A particle is moving in a circle of radius R in such a way that at any instant the
normal and tangential components of its acceleration are equal. If its speed at t = 0 is
v0 . The time taken by the particle to complete the first revolutions is
R R R 2 2 R
1)
v0
2)
v0
1  e2  3)
v0
e 4)
v0
13. Two particles A and B are moving with uniform velocities of 20 m/sec and 10 m/sec
as shown in the figure. The magnitude of angular velocity of A with respect to B
when their separation (AB) becomes 10 metre is:

 1  1
1)  3   rad sec 2)  3   rad sec
 2  2

3) 1 radian / sec 4)  
3  1 rad sec

14. A block of mass m is kept on rough horizontal turn table at a distance r from centre of
table. Coefficient of friction between turn table and block is  . Now turn table starts
rotating with uniform angular acceleration  .
Find the time after which slipping occurs between block and turn table
14 13
  2 g 2   2r 2    2 g 2   2r 2 
1) t    2) t   
  4r 2    4r 2 
12
  2 g 2   2r 2    2 g 2   2r 2 
3) t    4) t   
  4r 2    4r 2 
15. A particle of mass m is fixed to one end of a light spring of force constant k and
unstretched length  . The system is rotated about the other end of the spring with an
angular velocity  in gravity free space. The increase in length of the spring is:

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 m 2 m 2  m 2
1) 2) 3) 4) None of these
k k  m 2 k  m 2
16. Wheel A of radius rA  10cm is coupled by a belt C to another wheel of radius
rB  25cm as in the figure. The wheels are free to rotate and the belt does not slip. At
time t = 0 wheel A increases it’s angular speed from rest at a uniform rate of  2

rad sec2 . Find the time in which wheel B attains a speed of 100 rpm.

50
1) 50 sec 2) 30 sec 3) sec 4) 25 sec
3
17. A small block of mass m slides on a frictionless horizontal table. It is constrained to
move inside a ring of radius l which is fixed to the table. At t = 0, the block has a
tangential velocity V0 . The coefficient of friction between the block and the ring is  .
The velocity of the block at time t is:

V0 V0 V0 V0
1) 2) 3) 4)
V t 2 V0t  V t   V0t 
1 0 1 1  0   
l l  l   l 

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18. A round cone with half-angle   30 and the radius of the base R = 5.0 cm rolls
uniformly and without slipping over a horizontal plane as shown in figure the cone
apex is hinged at the point O which is on the same level with the point C, the cone
base centre. The velocity of point C is v = 10.0 cm/s. Find the moduli of vector of the
angular velocity of the cone about a vertical axis passing through O.

1) 2.7 rad s 2) 3.3rad s 3) 6.3rad s 4) 1.2 rad s

19. Statement – I: A cyclist moving on an unbanked road with a speed of 7kmh 1 and
takes a sharp circular turn along a path of radius of 2m without reducing the speed.
The static friction coefficient is 0.2. The cyclist will not slip and pass the curve.
(g = 9.8 m s 2 )
Statement – II: If the road is banked at an angle of 45° cyclist can cross the curve of
2m radius with the speed of 18.5 kmh 1 without slipping.
In the light of the above statements, choose the correct answer from the options given
below.
1) Statement – I is incorrect and Statement -II is correct
2) Both Statement -I and Statement -II are true
3) Statement -I is correct and Statement – II are false
4) Both Statement – I and Statement – II are false
20. A disc with a flat small bottom beaker placed on it at a distance R from its center is
revolving about an axis passing through the center and perpendicular to its plane with
an angular velocity  . The coefficient of static friction between the bottom of the
beaker and the surface of the disc is  . The beaker will revolve with the disc if:
g g g g
1) R  2) R  3) R  4) R 
2 2 2 2 2 2

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 SECTION-II
(Numerical Value Answer Type)
This section contains 10 questions. The answer to each question is a Numerical value. If the
Answer in the decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10
questions and question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

21. A projectile is fired at speed v0 and angle  . If the radius of curvature at the top

equals half the maximum height. Find the value of sec 2  .

22. A particle moves along the plane trajectory y(x) with constant speed v. The trajectory
has the form of a parabola y  ax 2 where ‘a’ is a positive constant = 6/m. Then the
radius of curvature of the trajectory at the point x = 0 is
23. A curved level road has a radius 75m. The maximum speed of a car turning this
curved road can be 30m/s without skidding. If radius of curved road is changed to
48m and the coefficient of friction between the tyres and the road remains same, then
maximum allowed speed would be ______ m/s.
24. A stone tied to 180 cm long string at its end is making 28 revolutions in horizontal
1936 2
circle in every minute. The magnitude of acceleration of stone is ms . The
x
 22 
value of x _____  Take   
 7 
25. Two particles A and B are projected from top of two towers of height 300 m and 600
m with velocity 50 m/s and 250 m/s respectively. The angular velocity of B w.r.t. A is
 rad min . Find the value of  .

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26. A spot light S rotates in a horizontal plane with constant angular velocity of 1.0
rad/sec. The spot of light P moves along the wall at a distance of 3m. The velocity of
the spot P when line joining S & P makes an angle of 45° with the wall?
27. A ceiling fan rotating at a speed of 2700 rpm is switched off and the resulting
variation in its speed with time is shown in the graph. The total number of revolutions
made by the fan before it comes to rest is

28. A particle undergoes uniform circular motion. The velocity and angular velocity of

the particle at an instant of time is v  3iˆ  4 ˆj m/s and   xiˆ  6 ˆj rad / sec
The value of x in rad/s is
29. The angular frequency of a fan increases from 30 rpm to 60 rpm in  S . A dust
particle is present on the blades at a distance of 20cm from axis of rotation. The net
acceleration of dust particle at the end of  S is. ( m s 2 )
30. A particle is in curvilinear motion as shown, if at any instant particle is at point A and
its velocity is 4 m/s and radius of curvature is 2 m then find the magnitude of
centripetal acceleration (radial acceleration) at point A. ( m s 2 )

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CHEMISTRY Max.Marks:100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and
(4) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

d  A
31. In the reaction, A  2 B 
 6C  2 D , if the initial rate  at t  0 is 2.6  10 2 M sec 1 ,
dt
d  B
what will be the vale of  at t  0 ?
dt
1) 8.5 102 M sec1 2) 2.5 10 2 M sec 1 3) 5.2  10 2 M sec 1 4) 7.2 10 2 M sec 1
32. The rate constant of a reaction depends on
1) temperature 2) pressure
3) extent of reaction 4) initial concentration of the reactant
33. Which of the following statements is incorrect?
1) A second order reaction must be a bimolecular elementary reaction
2) A bimolecular elementary reaction must be a second order reaction
3) Zero order reaction must be a complex reaction
4) First order may be complex or elementary reaction
34. Consider the plots for the types of reaction

The plots respectively correspond to the reaction orders:

1) 0, 2, 1 2) 0, 1, 2 3) 1, 1, 2 4) 1, 0, 2

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35.  B , for which graph between half life  t1/ 2  and initial
For the reaction A 

concentration (a) of the reactant is as given below

d  A
Hence graph between  and time will be:
dt

1) 2)

3) 4)

36. The following data pertain to reaction between A and B

S.no [A] [B] Rate

molL-1 molL-1 Mol L-1 sec-1
I 1 102 2  10 2 2  104

II 2  10 2 2  10 2 4  104

III 2  10 2 4  10 2 8  104

Which of the following inference(s) can be drawn from the above data
a) Rate constant of the reaction 10-4
b) Rate law of the reaction is K  A B 
c) Rate of reaction increases four times on doubling the concentration of both the
reactant, select codes
1) a, b and c 2) a and b 3) b and c 4) c alone

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37.
Column-I Column-II
P. Zero order reaction 1. t1/2 
1
 A0
Q. First order reaction 2. t100%   A0 / k

R. Second order reactions 3. Involves at least

two reactants
S. Pseudo unimolecular reaction 4.  A   A0 e kt
Code:
P Q R S P Q R S
1) 2 1 4 2 2) 2 4 1 3
3) 2 1 3 4 4) 3 2 1 4
38. Consider the following first order competing reactions:
k1 k2
X   A  B and Y  C  D

If 50% of the reaction of X was completed when 96% of the reaction of Y was
completed, the ratio of their rate constants  k2 / k1  is:
1) 4.06 2) 0.215 3) 1.1 4) 4.65
39. For a first order homogeneous gaseous reaction A 
 3 B , if pressure after time t

was PT and after completion of reaction, pressure was P then select correct relation

1  P  1  2P 
1) k  ln  
 2) k  ln  

t  3  P  Pt   t   P  PT  

1  3P  1  2P 
3) k  ln   4) k  ln  

t  2 P  Pt  t  3  P  PT  

40. A decomposes as

The rate of appearance of B, taking 2M concentration of A, is equal to:

1) 2 103 M s 1 2) 4 103 M s 1 3) 8 103 M s 1 4) None of these
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41. The plot of ln k versus 1/T is linear with slope of:
1)  Ea / R 2) Ea / R 3) Ea / 2.303 R 4)  Ea / 2.303 R
k
42. For a complex reaction A   products

Ea1  180 kJ / mol ; Ea2  80 kJ / mol ; Ea3  50 kJ / mol

Overall rate constant k is related to individual rate constant by the equation

2/3
 k .k 
k   1 2  . Activation energy  kJ / mol  for the overall reaction is:
 k3 

1) 100 2) 43.44 3) 150 4) 140

43. Which of the following is a buffer solution?
1) 500 mL of 0.1 N CH 3COOH + 500 mL of 0.1 N NaOH
2) 500 mL of 0.1 N CH 3COOH + 500 mL of 0.1 N HCl
3) 500 mL of 0.1 N CH 3COOH + 500 mL of 0.2 N NaOH
4) 500 mL of 0.2 N CH 3COOH + 500 mL of 0.1 N NaOH
44. What is the hydronium ion concentration of a 0.02 M solution of Cu 2  solution of
copper (II) perchlorate? The acidity constant of the following reaction is 5  109 .
 Cu  OH   aq.  H 3O   aq.
Cu 2   aq.  2 H 2 O  l  


1) 1 105 2) 7  104 3) 5  104 4) 1 104

45. An acid-base indicator has K H ln  3.0  10 5 . The acid form of the indicator is red and

the basic form is blue. The change in  H   required to change the indicator from

75% red to 75% blue is:

1) 8  105 M 2) 9  10 5 M 3) 1 10 5 M 4) 3  104 M
46. A 20.0 mL sample of a 0.20 M solution of the weak diprotic acid H 2 A is titrated with
0.250 M NaOH. The concentration of solution at the second equivalent point is:
1) 0.10 M NaHA 2) 0.153 M Na2 A 3) 0.10 M Na2 A 4) 0.0769 M Na2 A

47. What is the molar solubility of Mn  OH 2  K sp  4.5 1014  in a buffer solution

containing equal amounts of NH 4 and NH 3  K b  1.8  105  ?

1) 3.0  104 2) 1.38  10 4 3) 1.38  10 3 4) 7.3  10 4

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48. Find moles of NH 4Cl required to prevent Mg  OH 2 from precipitating in a litre of

solution which contains 0.02 mole of NH3 and 0.001 mole of Mg 2 ions.
Given: Kb  NH 3   105 ; K sp  Mg  OH 2   1011

1) 10-4 2) 2  103 3) 0.02 4) 0.1

49. Silver ions are added to a solution with  Br    Cl    CO32    AsO43   0.1M . Which

compound will precipitate with lowest  Ag   ?

1) AgBr  K sp  5 1013  2) AgCl  K sp  1.8 1010 

3) Ag 2CO3  K sp  8.1 10 12  4) Ag 3 AsO4  K sp  11022 

3
50. The solubility product of a AgCl is 10 10 M 2 . The minimum volume (in m ) of
water required to dissolve 14.35 mg of AgCl is approximately:
1) 0.01 2) 0.1 3) 100 4) 10
SECTION-II
(Numerical Value Answer Type)
This section contains 10 questions. The answer to each question is a Numerical value. If the
Answer in the decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10
questions and question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

51. A solution is saturated in SrCO3 and SrF2 . The CO32 was found to be 103 mol / L . If the
concentration of F  in solution is represented as y  10 2 M then what is the value of
y?
52. pH of 0.01 M aq. Solution of HA is 4. Find the value of pKa of HA at 25oC
53. Calculate pH of a resultant solution of 0.1 M HA  K a  106  and 0.45 M HB

K a  2  10 6  at 25oC.

54. Calculate the ratio of sodium formate and formic acid K a  2  10 4  in a buffer

solution of pH = 4.3
55. 10 mL of H 2 A (weak diprotic acid) solution is titrated against 0.1 M NaOH. pH of the
solution is plotted against volume of strong base added and following observation is
made.
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 If pH of the solution at first equivalence point is pH1 and at second equivalence point
is pH 2. Calculate the value of  pH 2  pH1  at 25oC

Given: For H 2 A , pK a  4.6 and pK a  8 , log 25 = 1.4

1 2

56. 5 A 
 Product

In above reaction, half-life period is directly proportional to initial concentration of

reactant. The initial rate of reaction is 400 mol lit-1min-1.
Calculate the half-life period (in sec) when initial concentration of reactant is 200
mol lit-1.
57. In an elementary reaction A  g   2 B  g  
 C  g  the initial pressure of A and B are

PA  0.40 atm and PB  0.60 atm respectively. After time T, if pressure of C is observed

ri  initial rate of reaction 

0.1 atm, then find the value of .
rt  rate of reaction after time t 

58. Half-life zero order reaction A  g  

 B  g   C  g  and half-life for the first order

reaction X  g  
 Y  g   Z  g  are equal. If completion time for the zero order

reaction is 13.86 min, then calculate the rate constant (in hr-1) for the reaction
X  g  
Y  g   Z  g 

59. The reaction that occurs in a breath analyser, a device used to determine the alcohol
level in a person’s blood stream is
 2Cr2  SO4 3  3C2 H 4O2  2K 2 SO4  11H 2O If the rate of
2 K 2Cr2O7  8H 2 SO4  3C2 H 6O 

appearance of Cr2  SO4 3 is 2.67 mol min-1 at a particular time, the rate of
disappearance C2 H 6 O at the same time is ________ mol min-1.
60. The following data were obtained during the first order thermal decomposition of
SO2 Cl2 at a constant volume.

SO2Cl2  g  
 SO2  g   Cl2  g 
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 Exp. No. Time (sec) Total pressure
(atm)
1 0 0.5
2 100 0.6
The rate of reaction is ______  10 4 atm / sec when total pressure is 0.65 atm.
(Given: log2=0.3, ln x  2.3log x )
MATHS Max Marks: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and
(4) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
 
61. The maximum value of 3cos  5sin     for any real value of  is:
 6
79
1) 34 2) 31 3) 19 4)
2
1
62. The maximum value of the expression is
sin   3sin  cos  5cos 2 
2

1) 1 2) 2 3) 3 4) 0

63. If u  a 2 cos 2   b2 sin 2   a 2 sin 2   b 2 cos 2  then the difference between

the maximum and minimum of u 2 is given by
2 2

1) 2 a 2  b 2  2)  a  b  3)  a  b  4) 2 a 2  b 2

64. The period of the function f  x    sin 3 x   cos 6 x is.....

2   
1) 2) 3) 4)
3 3 6 2
3 x x
65. The period of the function sin  cos 2 is
2 5
1) 2 2) 10 3) 8 4) 5

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 x x x x x
66. Find the period of f  x   sin x  tan  sin 2  tan 3  ...  sin n1  tan n
2 2 2 2 2
is___

n  
1) 2  2) 3) 4) None of these
3 6
2   2
67. The maximum value of cos   x    sin x  cos x  is......
4 
1) 1 2) 3 3) 2 4) 0
sin x
68. The minimum value of 2  2 cos x is
1
1
2 1 2 1 2 1 2
1) 2 2) 2 3) 2 4) 2

69.    
Let   max 82sin 3 x.4 4cos3 x and   min 82sin 3 x.44cos3 x . If 8 x 2  bx  c  0 is a
xR xR

15
quadratic equation whose roots are  1 5 and  , then the value of c  b is equal to
1) 43 2) 42 3) 50 4) 47
70. The range of the function,

  3       3 
f  x   log 5  3  cos   x   cos   x   cos   x   cos   x
  4  4  4   4 
is

 1 
1) 
 5
, 5

2)  0, 2  
3) 0, 5  4)  2, 2 

cos 20   8sin 70  sin 50  sin10 

71. is equal to
sin 2 80 
1) 1 2) 2 3) 3 4 4) None of these

 2 3 4 5 6
72. cos0  cos  cos  cos  cos  cos  cos 
7 7 7 7 7 7
1) 1 2 2) 1 2 3) 0 4) 1

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   sin   sin 2
73. For    , lies in the interval
2 2 1  cos   cos 2
1)  ,   2)  2, 2  3)  0,  4) None

21
74. Let  ,  be such that       3 . If sin   sin    and
65
21  
cos   cos    , then the value of cos is
65 2
3 3 6 6
1)  2) 3) 4) 
130 130 65 65
1
75. If the maximum value of the expression is equal to
5sec   tan   4cosec 2 
2 2

p
(where, p and q are coprime), then the value of  p  q  is
q
1) 14 2) 15 3) 16 4) 18
sin   sin 3  sin 5  ....  sin  2n  1
76. Let f n  a   . Then the value of
cos   cos3  cos5  ....  cos  2n  1

 
f 4   is equal to
 32 
1) 2 1 2) 2 1 3) 2  3 4) 2  3
cos x  sin x
77. The minimum value of sin x  cos x  is
cos 4 x  sin 4 x
3
1) 2 2) 3) 2 4) 1
2
78. The value of the product

                  
sin  2009  cos  2009  cos  2008  cos  2007  cos  2006  ...cos  3  cos  2 
2  2  2  2  2  2  2 
, is
1 1 1 1
1) 2) 3) 4)
22007 22008 22009 22010
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 A B C
79. In a ABC , the minimum value of sec 2  sec 2  sec 2 is equal to
2 2 2
1) 3 2) 4 3) 5 4) 6

     
80. The maximum value of sin  x    cos  x   in the interval  0,  is attained
 6  6  2
at
   
1) 2) 3) 4)
12 6 3 2

SECTION-II
(Numerical Value Answer Type)
This section contains 10 questions. The answer to each question is a Numerical value. If the
Answer in the decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10
questions and question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

81. The range of f  x   9sin 2 x  30sin x  25  10 is  a, b  then a  b 

82. The number of integral values of ‘ k ’ for which the equation
3sin x  4cos x  k  1 has a solution, k  R is____________
83. 3tan 6 100  27 tan 4 100  33tan 2 100 
84. If cos 40.cos80.cos120.cos160........cos880  2  n then n is equal to
3 20 N 
85. Let N  tan
11
 4sin
11
. The value of  3  is equal to (Where . denotes the

greatest integer function)

86. If the value of tan10 tan 20  tan 20 tan 30.....  tan 880 tan 890 is equal to

cot 2 10  n , where n is a natural number, then the value of n  80 is equal to

44

 cos n
n 1
87. Let x  44
, find the greatest integer that does not exceed

 sin n
n1

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 sin 2 A  sin 2 B  sin 2C A B C
88. If A  B  C  180 0 ,  k sin sin sin then the
sin A  sin B  sin C 2 2 2
3 2
value of 3k  2k  k  1is equal to
   3  5  7 
89. 16  cos  cos  cos  cos  cos  cos  cos  cos    cos 4 ,
 8  8  8  8 
then the value of  is
1 1 0 4 2
90. If 0
  2 k cos 40 , then 18 k  162 k  369 is equal to
sin 20 3 cos 200

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