Deadline 5 DEC 2022 as indicated in VTop
TH
and also that you should upload the pdf document of the
same in the vtop
1. Compute the entropy change when 108 g of water (l)
evaporates at 100°C (ΔH = 40.63 kJ mol ). -1
2. Calculate the maximum work obtained when 9.0 mol of an
ideal gas expands isothermally and reversibly at 30 °C from
a volume of 30 L to 45 L.
3. Compute the maximum work done when 6.0 mol of an
ideal gas expands from 35 L to 50 L isothermally and
reversibly at 37 °C.
4. Calculate the temperature for the reaction N2(g) + 3H2(g)
= 2NH3(g) [ΔH = -95.4 kJ and ΔS = -198.3 JK-1] where
Gibb's energy change, G, is zero
5. Calculate ΔH, ΔS and ΔG when 1 mole of water is
vaporized at 100 C and 1 atm pressure. The latent heat of
o
vaporisation of water is 540 cal/g
6. The heat of formation of methane at constant pressure and
25 C is -74.85KJ/mol. What will be the heat of formation at
o
constant volume? Given: R = 8.314J/K/mol
7. The free energy change (ΔG) accompanying a given
process is -85.77KJ at 25 C and -83.68 KJ at 35 C.
o o
Calculate the change in enthalpy (ΔH) for the process at
30 C.
o
8. ΔG for a reaction at 300K is 16kcal, ΔH for the reaction is
-10kcal. What is the entropy of the reaction? What will be
its ΔG at 330 K?
9. A sample consisting of 2 mol of perfect gas molecules, for
which C = 5/2R, initially at P = 111 kPa and T = 277 K,
V,m 1 1
is heated reversibly to 356 K at constant volume. Calculate
the final pressure, ΔU, q, and w.
10. 0.1642 mol of argon occupies 18.5 dm at 305 K. (a)
3
Calculate the work done when the gas expands isothermally
against a constant external pressure of 7.7 kPa until its
volume has increased by 2.5 dm . (b) Calculate the work
3
that would be done if the same expansion occurred
reversibly.
11. Calculate w and ∆𝑈 for the conversion of 2 moles of
ethanol at 78 ℃ to steam at 1 atm pressure. Heat of
vaporisation of ethanol at 78 ℃ is 38560 Jmol .-1
12. 2 moles of an ideal gas is compressed by external pressure
of 5 atm, the volume of the gas changes from 50 dm to a 3
volume of 20 dm . Calculate the work done in Joules.
3
13. If ko 5.7 x10 mol-1dm s , calculate the rate for a reaction
-4 3 -1
which is first order in both A and B when [A]= 5x10-2 mol
dm and [B]=2x10 mol dm .
3 -2 3
14. Use the Arrhenius equation to calculate the rate constants
for the reaction at 300K. The activation energy for the
reaction is 30kJmol and A factor is 5 x 10 mol-1dm s .
-1 10 3 -1
15. A certain gas expands in volume from 2.0L to 6.0 L at
constant temperature. Calculate the work done by the gas if
it expands (a) against a vacuum and (b) against a constant
pressure of 1.2 atm.
