l'rinll•tl ra1:c: I of 2

Ill IIIII IIIII PAPER Ill IIIIIIIII IIIIII IIIII Ill

II IIIII II I10-311236 Suhjcct Code: IJASI02
Roll No: [ l 1 l ~! J l 1 r ,r r JJ
BTECII
(SEl\11) TIIEORY EXAi\llNATION 2023-2-4
ENGINEERING CHEMISTRY
Tli\lE: JIIRS i\1.MARl(S: 70

Note: I. Attempt all Sections. If require any missing data; then choose suitnbly.
SECTION A
I. Attempt nil questions in hril'f.
Q no. Question Marks
a. Explain moleculnr self-assembly method for preparing the nanonmterials. 2
b. A solution shows a transmittance of 20%, when kept in a cell of 2.5 cm lhickness. 2
Calculate its conce.!:itration if_!_he molar ~bsorptivity coefficient is 12Q.90dm1mor 1cnf 1.
C. Analyze the effect of polnr solvent on n - n • transition in acetone. 2
t-<l-.--+-C_a_l_c1_il_a_tc the emf of the c~II. if the st.1~1<l;<l emf of the cell 1s 1.54 V. Wnte ce(j";.enc1io11 2
also.

Z11(s1z,,:• (0.2M ~Ag. (0.002M~Ag(.t )at 25° C

e. What is role of Gypsu m in cement manufaeruring? 2

f. A sample of coal con rains 60% C~rbon. 33% Oxygen, 6.0% Hydrogen, 0.5% Sulphur, 2
0.2% NitrOl!Cll and 0. 3!o Ash. Ca!£~~c i.:..:ts'...:G=Cc..:V..:.·•L--,,-------------t-=---':r--'.-1
g. What do you underst,rnd by Polyn~Jlcnds'!._ _.:..'.;..\________ ____ 2 ( '\
SECTION B ' ,; -
,
<,// 0.\
K)•
2. Attempt any three of the following: __.,_,...,....::-.....,
.) , . - - -
r a. --Dra\;molccular orb11al ~iagr:1111 01 (~~id NO. Calculate rhci~ bond order and ~.)111ent 7
on their mai.:nct1c behaviors •·
r;-- Illustrate the shielding nnd Dnl11~ldinc ~fR:i.:1 invo~edi-;;-NMR spcctro-;cojry,~:- 7
j In the P-NMR specmun reco1ded at 293 K. an Organic compound (Cil-1~.J.f
exhibited signals at Ii 7.8 ( 111. singlet). Ii 2.8 (JI I. singlet) and o 2:6 ~ . singlet). Find
_!!!_~ru~re of compound. _ ~'-------t--- __
c. Illustrate the various steps 1n-volved Jui 111g mnnufacturing of1Por1land cement with the 7
help of a labelled d1aor;m1
,____ _ _h_a_rd_1:_•n_i_n_i:_o_f_c_cm_e_n_1._
:,
- - - - -
.
1nv~lved during setting and
G1w the chcm1~nl renctions ,·.___
----------+----1
d. Compare merits and demerits ofZe~c andIon Exc~angc inethod. 7
e. Discuss the preparation of Grignnrd Reagent. Pmlicl the final product obtained when 7
C1 HsMgBr reacts wilh ix
~HCHO _ _(._ii) CH,CIIO (ii,) (01,JzCO _ (iv) C O ! - - - - - - - - ~ - - ~
SECTION C
J. Attempt any one part of the following:
-------------------,----~
Illustrate any live principles ofGn:cn Chemisrry and the give green synthesis method for 7
,_l_ _-+.,.1-'-reJ1--'a-'-ra_t_io_n of Pai acctamol.
b. Classify Liqui~-ystal; on-the ba;is of temperature an<l give their applications in various 7
L_ fields.
4. ,\!tempi any one part of thr following:
a. Asym111elrically subs1itu1e<l cnmpoun<ls hnv1ng even number of cumulative double bonds 7

fb:'
Iexhibit optic.ii isomerism whereas compounds having odd number of cumulative double
. bon<ls cxhibir ~1~ctrical isomerism. Explain_~~ proper rc11sons.
- I Write shorr notes on (any TWO)
1---
7
_ iJ1J UV Shift (iil_J~1li£a~•~oflR s111:c1ros~_py 1iii)Molecular vibration
s. ,\ttcmpt nny one part of the fnllo11 ing:

1 I P ., e ,.
 Printed l'agl': 2 or 2
Ill IIIII IIIII II IIIIIII IIll I1111111111111111111 Ill Suhjcct Code: llAS I02
PAPER 10-311236 Roll No: L. [_ l~~'- I [ r l_L lJ
BTECl-1
(SEMI) THEORY EXAMINATION 2023-24
ENGINEERING CHEMISTRY
Tli\lE: JIIRS M.MARKS: 70
-
a. Illustrate the working, dingrnmnrntic representation nnd cell reaction of Lead Acid 7
storal.!e battery durini.: chnrgini.: nnd dischari.:inl.!.
b. Briefly explain wet corrosion. How corrosion can be prevented by Metallic coaling nnd 7
usinl.! corrosion inhibitors? - -- --
- ---
6. Attempt nny 011e part of the following:
a.
- -r---·-
7
With the help of a neat diagram, explain the working of Bomb calo1imctcr. A
sample of coal contain C=89%, H=8% and ash=)¾.

The following data were obtained when the above coal was tested in bomb
calorimeter: Weight of coal burnt= 0.85 g; Weight of water taken= 850 g; Water
equivalent of bomb and calorimeter- 3500 g; Rise in temperature= 2.5'C; Fuse
wire correction= I0.0 cal ; Acid correction= 50.0 cal; Cooling correction= 0.03 ·c.
Assuming that lhe latent heat of condcnsntion of steam as 580 cal/gm,
Calculate gross and net calorific values of the coal.
b. Illustrate the principle of lime soda process. 7
2
Analysis of m~ water gives t!1e following data:~= 20 ppm, Mg ' = ~5 ppm, CO2~
2
30 ppm, HCOi = 150 ppm, K = IO ppm. Ana~@~ treated water: C03 = 45ppm, OH \J\)
= 68 ppm. Calculate the Lime (87% pure) an cla (91% pure) required to soften 101'
litre of samnle water. " , r
7. Attempt any one part or the followin!Q (;' / i ,'
,,, ,
I a. Classify conducting polymers and in<-:1Jlion their important applications ( 7 .
r b. 1
Wri1e the prepara1ion (structur<;~\monomer and polymer), properties & applications or I 7
1hc any THREE polymers:~
CJ- (iii) Polvestcr ().,.
- , (i) Buna -S (ii) Nylon 6,6 (iv) Kevlar (v) Bakclifc

2 I f' ,l .~ L'