Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60_STERLING BT JEE-MAIN Date: 26-10-2024
Time: 09:00AM to 12:00PM WTM-16 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball
Point Pen only.
2. The candidates should not write their Admission Number anywhere (except in the specified space)
on the Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Physics, Chemistry and
Mathematics having 30 questions in each subject and subject having two sections.
(I) Section –I contains 20 multiple choice questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

(II) Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only, if
more than 5 questions attempted, First 5 attempted questions will be considered.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and if answer is from
10.5 and less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted question 21. Bubble on 21 as shown below

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use
of pencil is strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone
any electron device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in
the Hall. However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet

Name of the Candidate (in Capital): ________________________________________________

Admission Number:

Candidate’s Signature: __________________ Invigilator’s Signature: ____________________

 Sri Chaitanya IIT Academy, India 26-10-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-16_Q.P
26-10-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-16_Test Syllabus

PHYSICS : FLUID STATICS: Archimedes' Principle, Principle of Buoyancy, Buoyancy (Including

effective 'g'), Laws of floatation, Basic Ideas of stable Equilibrium of floating Body,
Problems in fluid Statics, FLUID STATICS: Basic
Ideas of stable Equilibrium of floating Body, Problems in fluid Statics, Fluid Dynamics:
General Characteristics of liquid flow, types of Fluid flow (Stream line and turbulent
flow), Equation of Continuity, Bernoulli's theorem, Applications of Bernoulli's theorem:
Velocity of efflux, horizontal range of the escaping liquid time of emptying of the vessel,
Impact force of liquid, Venturimeter, Sprayer (or) atomizer, Narrowing water jet,
Siphon, Pitot tube, Dynamic lift, Thrust on a rocket, Magnus effect.

CHEMISTRY : ORGANIC CHEMISTRY: Allotropes of carbon, Hybridisation of carbon; Sigma and

pi-bonds; Shapes of simple organic molecules, Purification and charecterisation of
organic compounds:Methods of purification, Detection of nitrogen, sulphur, phosphorus
and halogens, Estimation of carbon, hydrogen, nitrogen, halogens, sulphur, phosphorus.,
IUPAC NOMENCLATURE : Nomenclature of Hydrocarbons.

MATHEMATICS : Applications of vectors to Geometry, Product of four vectors (Deleted

pertaining to JEE Main but still in JEE ADV Syllabus & BIEAP), 3D-
Geometry: Distance Formula, Section formula, Direction Ratios &
Cosines of a line, Angle between two lines by using D.Cs and D.Rs

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PHYSICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Water flows out of a big tank along a horizontal tube AB of length L and radius R and
bends at right angle at the other end as shown in the figure. Find moment of force exerted
by water on the tube about the end A at the instant shown (Assume that the radius of the
tube is small.)

H ρ
3H
2

H 2ρ
A B H 4

1) 5 R 2 gHL 2) 10  R 2 gHL 3) 15  R 2 gHL 4) none of the above

2. There are two identical small holes of area of cross-section ‘a’ on the opposite sides of
a tank containing a liquid of density  . The difference in height between the holes is h.
The tank is resting on a smooth horizontal surface. Horizontal force required to keep the
tank in equilibrium is (at the shown instant)

h2
h1
h

2gh  gh
1) 2) 3) 2  agh 4) gh a
Q a
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3. A container containing a liquid is moving down an incline plane with constant
acceleration ‘a’. The angle made by the water surface with the inclined plane is
(take a = 2gsinθ)

 ?

a

1) 2θ 2) 0.5θ 3) θ 4) cannot say anything
4. A solid cone of uniform density and height 2R and base radius R has a conical portion
scooped out from its base with the same base radius but height R as shown in the figure.
The solid cone is floating in a liquid of density  with vertex A touching the fluid
surface. If atmospheric pressure is P0, the buoyant force on the cone is

A
ρ
C
2R
R
B D

 R3  g  3P0   R3  g  3P0 
1) 2  R g  2) 5  R  g 
3   3  

 R3  g  R3  g  3P0 
3) 4)  4  Rpg 
3 3  

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5. The ratio of masses of a cubical block of wood and a chunk of concrete is 3/5 so that the
combination just floats with entire volume submerged under water. If the specific gravity
of wood is 0.5, then specific gravity of concrete will be
1) 2.5 2) 25 3) 15 4) 3
6. In the figure shown, water flows into the open vessel through pipe A at a constant rate.
The water can flow out of the vessel by pipe B. The maximum flow-rate of the water in
pipe B is always more than that in pipe A. Final height of the water level in the vessel
would be

h0
hf

1) h0
2) hf
3) Somewhere in-between h0 and hf
4) The water level will keep oscillating in the vessel
7. A target object is placed at the bottom of a tank of depth 20 m, and filled with a liquid of
density 500 gm/cc. Another object of density 100 gm/cc is dropped onto it, from a height
of 45 m from the upper surface of the liquid. (Take g=10 m/s2).
Choose incorrect statement.

45 m

20 m

1) The second object does not collide with the target.

2) The second object does collide with the target.
3) The least separation between object and target is 8.75 m.
4) The retardation of the object in the liquid is 40 ms-2.
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8. A small body of density 𝜌 is dropped from rest at a height h (from surface) on to a lake of
density  ' where 𝜌 < 𝜌′. Which of the following statement or statements is or are correct
if all dissipative effects are neglected? (Neglect viscosity)
1) The speed of the body just before entering the lake is 2gh
2) The body in the lake experiences downward acceleration equal to   /  '  1 g
3) The maximum depth to which the body sinks in the lake is ℎ𝜌/(−𝜌 + 𝜌′)
4) The body does not come back to the surface of the lake
9. A wooden ball of mass m (density  ) is kept inside water (density    ) by the help of a
massless string shown in the figure. One end of the string is fixed at the bottom of vessel.
When the vessel containing the water is accelerated upwards with acceleration a as
shown in the figure.

1) Tension in the string will increase 2) tension in the string will decrease
3) Force of buoyancy will decrease 4) None
10. Along a streamline
1) The velocity of fluid particle remain constant
2) The velocity of all fluid particles crossing a given position is constant
3) The velocity of all fluid particles at a given instant is constant
4) The speed of a fluid particle remains constant.
11. In the following figure is showing the flow of an ideal liquid through a horizontal pipe.
Three tubs A, B, and C are connected to the pipe. The radii of the tubes A, B and C at the
junction are respectively 2 cm, 1 cm and 2cm. It can be said that the :
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A B C

1) Height of the liquid in the tubes B and C is same

2) Height of the liquid in the tubes A and B is the same
3) Height of the liquid in all the three tubes is the same
4) Height of the liquid in the tubes A and C is the same
12. Which one of the following cannot be explained on the basis of Bernoulli’s theorem?
1) Blowing off of light roofs when strong winds blow
2) Curved path followed by a spinning ball
3) Working of an atomizer/ perfume bottle
4) None
13. The rate of flow of glycerin of density  through conical section of a pipe, if the area of
cross-sectional of its ends are A1 and A2 and pressure drop across its length be p , is
given by (A1>A2)
P 2 P
1) A1 A2 2) A1 A2
  A12  A22    A12  A22 

2P 2 P
3) 4) A1 A2
  A12  A22  3  A12  A22 

14. A body floats in a liquid contained in a beaker. The whole system shown in figure is
falling under gravity. The up thrust on the body due to liquid is:

1) Zero 2) equal to weight of liquid displaced

3) Equal to weight of the body in air 4) equal to weight of the immersed body
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15. In container having liquid

Column-I Column-II
A. Pressure difference between two points is P Container is stationary
 gh  where h is vertical separation

B. Pressure difference between two points at Q Container is accelerating along

the same horizontal level is zero horizontal direction
C. Pressure difference between two points at R Container is falling freely.
the same horizontal level is non-zero
D. Pressure difference between two points S Container is accelerating in vertical
separated by same vertical distance is zero direction with an acceleration < g.

1) A-PQ ; B-PRS ; C-Q ; D-R 2) A-P ; B-PRS ; C-R ; D-R

2) A-Q ; B-P ; C-R ; D-P 4) A-RS ; B-PRS ; C-R ; D-Q
16. An arrangement of the pipes is shown in the Fig. The flow of water (incompressible and
non-viscous through the pipes is steady in nature. Three sections of the pipe are marked
in which section (1) and section (2) are at same horizontal level, while being at a greater
height than section (3). Correctly match order of the different physical parameter. R1, R2
and R3 are radii of cross sections with R3=R2

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Column-I Column- II
(A) Order of volume flow rate (P) 1> 2 > 3
(B) Order of kinetic energy of a mass element (Q) 1 = 2 = 3
(C) Order of pressure in the sections (R) 1 > 2 = 3
(D) Order of flow speed in sections (S) 3 > 2 > 1
1) A-Q B-R C-S D-R 2) A-P B-S C-Q D-R
3) A-R B-P C-Q D-S 4) A-S B-Q C-P D-P
17. Statement -1: Cross-sectional area of the water stream pouring out of a tap decreases as
the height from the ground decreases. (in steady state)
Statement -2: Work done by gravity is equal to increase in the kinetic energy of the fluid
and thus reduces the cross-sectional area.
1) Statement–1 is True, Statement–2 is True; Statement–2 is a Correct explanation for
Statement–1
2) Statement–1 is True, Statement–2 is True; Statement–2 is not a Correct explanation for
Statement–1
3) Statement–1 is True, Statement–2 is False
4) Statement–1 is False, Statement–2 is True
18. Statement –I: A barometer tube reads 76 cm of Hg. If the tube is gradually inclined at an
angle of 60o with the vertical keeping the open end immersed in the mercury reservoir the
length of the mercury column along the tube in the barometer will not change.
Statement – II: Barometer is a device used to measure atmospheric pressure.
1) Statement–1 is True, Statement–2 is True; Statement–2 is a Correct Explanation For
Statement–1
2) Statement–1 is True, Statement–2 is True ; Statement–2 is not a Correct explanation
for Statement–1
3) Statement–1 is True, Statement–2 is False
4) Statement–1 is False, Statement–2 is True
19. Statement – 1: A solid body of density b floats in a liquid (density L where b   L )
kept in a beaker. When the beaker is accelerated vertically upward with an acceleration a,
then the fraction of the submerged volume of the solid within the liquid increases.
Statement – 2: When accelerated upward, the net force on the body with respect to the
beaker remains unchanged.
1) Statement–1 is True, Statement–2 is True; Statement–2 is a Correct Explanation For
Statement–1
2) Statement–1 is True, Statement–2 is True; Statement–2 is Not a Correct Explanation
For Statement–1
3) Statement–1 is True, Statement–2 is False
4) Statement–1 is False, Statement–2 is True

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 Sri Chaitanya IIT Academy, India 26-10-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-16_Q.P
20. Statement - I: It is difficult to stop bleeding from a cut in the body at high altitude
Statement II: The atmospheric pressure at high altitude is lesser than the blood pressure.
1) Statement–1 is True, Statement–2 is True; Statement–2 is a Correct Explanation For
Statement–1
2) Statement–1 is True, Statement–2 is True; Statement–2 is not a Correct Explanation
For Statement–1
3) Statement–1 is True, Statement–2 is False
4) Statement–1 is False, Statement–2 is True
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. If more than 5 questions attempted, First 5
Attempted questions will be considered. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and if answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. A small block of wood of relative density 0.5 is placed 10 m inside a vessel containing
water. The vessel is accelerated upward with an acceleration of 10 m/s2. If the block is
released at some instant then the time taken by the block to reach the surface of water
from that instant is (consider g=10 m/s2).
22. In the figure shown density of lower liquid is three times of density of upper liquid. The
cross- sectional areas of openings shown are same and very small compared to the
container cross section. The ratio of mass flow rate from upper opening to lower opening
1
at initial moment is . Find N
N 3

h
1

2 h

8
23. In the figure shown, the heavy cylinder (radius m ) kept on a smooth surface separates
3
two liquids of densities 2  and 3  . The height h (in meter) for the translational
equilibrium of the cylinder must be.

h 2
R 3 R

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24. Water is filled in a uniform container of area of cross section A. A hole of cross section
area a is made in the container and a block is placed at some distance from container.
With what approximate integral speed (in ms-1) the block should be moved such that
a 1
water stream always hits the block. (Given  ). (Take g=10 ms-2)
A 20
(hole is at a height of 200m)
A

a
200 m

25. A small cube of negligible mass is floating on the surface of lake. The side of the cube is
30 cm and depth of lake is 2m. The cube is pushed very slowly under the water, down to
the bottom of the lake. The density of water is 103 kg/m3 and acceleration due to gravity
is 10 m/s2. Find the work done (in multiples of 100 joule) by external pushing force in the
process. (to the nearest integer)
26. A sealed vessel contains water (   1000 kg/m3) upto height h=3.5 m. The space above
the water contains compressed air at pressure 4.2 P0  P0  atmospheric pressure  1  105 Pa  .
The vessel is connected to a hose at the bottom as shown in the figure. Assuming the area
of cross section of hose to be uniform and small as compared to the area of the vessel.The
end of the hose is open to atmosphere. Initial speed of efflux of water is (20+x) m/s. Then
x is (closest integer)

4.0 m h

P 1m

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27. Air is blown through a pipe AB at a rate of 15 liters per minute. The cross-sectional area
of the narrow portion is 0.5 cm2. The cross-sectional area of the broad portion is 2 cm2.
The difference in water level h is (N+0.546) mm   air  1.32 kg / m3 
(g = 10m/s2 density of water = 1000kg/m3) then N is (closest integer)
A
B

h water

28. A sphere is just immersed in a liquid. Find the ratio of hydrostatic force acting on the
lower half and upper half of the sphere. (Neglect atmospheric pressure).

29. A homogeneous solid cylinder of length L  L  H / 2  , cross sectional area A/5 is immersed
such that it floats with its axis vertical at the liquid-liquid interface with length L / 4 in the
denser liquid as shown in the figure. The lower density liquid is open to atmosphere
having pressure P0 . If the density of solid is given by kd then find the value of 4k

30. A cube of wood supporting 200 gm mass (on top of the cube with mass not in water) just
floats (completely immersed with top face in line with water surface) in water. When the
mass is removed, the cube rises by 2cm. What is the side of cube  in 10 m 
1

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CHEMISTRY Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

CH3
H3C  CH  CH 2  C  CH3
CH3 CH3
31. In the structure, the number of carbons are:
1) One primary, two secondary and one tertiary
2) Four primary, two tertiary and one secondary
3) One primary, one secondary, one tertiary and one quaternary
4) Five primary, one secondary, one tertiary and one quaternary
32. The correct IUPAC name of  C2 H5 4 C is
1) Tetraethyl methane 2) 2- Ethylpentane
3) 3, 3-Diethylpentane 4) 2, 2- Diethyl pentane
33. How many sp 3 hybridised carbon atoms are there in the given anti-cancer compound
(podophyllotoxin) ?
OH

O
O
O
O

MeO OMe

OMe

the anti-cancer compound podophyllotoxin

1) 6 2) 7 3) 9 4) 8

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34. Match the following
Column I Column II
compound IUPAC Nomenclature
P) 3-Ethyl-2-methylpentane

A)
Q) 3-Methylhexane

B)
R) 2,3-Dimethylbutane

C)
S) 2,3-Dimethylpentane

D)
1) A-S; B-Q; C-P; D-R 2) A-Q; B-S; C-P; D-R
3) A-S; B-Q; C-R; D-P 4) A-P; B-Q; C-S; D-R
35. 3-methyl penta-1, 3-diene is
1) CH 2  CH  CH 2 2 CH 3 2) CH 2  CHCH  CH 3  CH 2CH 3
3) CH 3CH  C  CH 3  CH  CH 2 4) H 2C  C  C  CH 3 2
36. A mixture of two organic compounds A ( b. p. 800 C ) and B ( b. p.1100 C ) can be
separated by
1) Sublimation 2) steam distillation
3) Fractional distillation 4) fractional crystallization
37. For the detection of phosphorus, the organic compound after fusion with Na2O2 , boiled
with HNO3 solution and then ammonium molybdate is added to it. A yellow ppt. is
obtained which is due to the formation of
1) Ammonium phosphate 2) Ammonium phosphomolybdate
3) Ferric phosphate 4) Disodium ammonium phosphate
38. 0.5 g of an organic compound on Kjeldahl’s analysis gave enough ammonia to just
neutralize 10 cm3 of 1M H 2 SO4 .The percentage of nitrogen in the compound is
1) 56 2) 28 3) 42 4) 14
39. In an experiment 0.22 g of magnesium pyrophosphate was produced from 0.1 g of an
organic compound. The percentage of phosphorus in it is:(Gram atomic weight =31g)
1) 14.64% 2) 64.14% 3) 62% 4) 44.16%
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40. Lassaigne’s test for the detection of N fails in:
O

NH  C  NH  NH
1) 2 2
2) NH 2  NH 2 3) CH 3CH 2 NH 2 4) C6 H 5  NH  NH 2
41. given below are two statements; one is labelled as Assertion (A) and the other is labelled
as Reason(R).
Assertion: In Duma's method the mixture of gases which is produced for estimation of
Nitrogen is collected over aqueous solution of potassium hydroxide.
Reason: In duma's method compound is heated with copper oxide in an atmosphere of
carbondioxide and potassium hydroxide absorbs CO2 .
In the light of the above statements, choose the most appropriate answer from the options
given below :
1) Both (A) and (R) are correct and (R) is the correct explanation of (A).
2) Both (A) and (R) are correct but (R) is not the correct explanation of (A).
3) (A) is correct but (R) is not correct.
4) (A) is not correct but (R) is correct.
42. For which of the following compounds Kjeldahl method is not used for estimation of
nitrogen
NO 2

N=N CH3
A) B)

NH 2

NH 2 N
C) D) E)
1) A, B, D and E 2) A, B and D 3) A and D 4) D and E

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43. Match the column :
Column I Column II
Test product for element detection Colour
A)  Fe  CN 5 NOS 
4
P) Prussian blue
B)  Fe  SCN  
2
Q) Blood red
C)  NH 4 3 PO 4 12MoO3 R) Violet
D) Fe4  Fe  CN 6   xH 2 O S) Yellow
3

1) A = Q, B = S, C = R, D = P 2) A = P, B = Q, C = R, D = S
3) A = Q, B = R, C = S, D = P 4) A = R, B = Q, C = S, D = P
44. Match the column :
Column I Column II
Compound Hybridisation of carbon
A) P) sp3 : sp 2 : sp  1

B) Q) sp
1
sp 2
C)  CH 3 2 CO R) sp 2
2
sp3
D) H 2C  C  C  CH 2 S) sp3
2
sp 2
1) A = P, B = R, C = Q, D = S 2) A = R, B = P, C = S, D = Q
3) A = S, B = P, C = R, D = P 4) A = S, B = P, C = R, D = Q
45. Which of the following molecules represents the order of hybridisation sp 2 , sp 2 , sp, sp
From left to right atoms?
1) HC  C – C  CH 2) CH 2 = CH – C  CH
3) CH 2 = CH – CH = CH 2 4) CH3 – CH = CH – CH 3

46. The IUPAC name of is :

1) 2–Ethyl–3–methyl–1–penten–4–yne 2) 2–Ethyl–3–methyl–4–pentyne–1–ene
3) 4–Ethyl–3–methyl–1–pentyn–4–ene 4) 4–Ethyl–3–methyl–4–penten–1–yne
47. The catalyst used in Kjeldahl’s method for the estimation of nitrogen is:
1) Copper 2) Magnesium 3) Mercury 4) Sodium

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48. In Dumas method for the estimation of nitrogen in an organic compound, nitrogen is
determined in the form of:
1) Gaseous nitrogen 2) Sodium cyanide
3) Ammonium sulphate 4) Gaseous ammonia
49. Each of the following statements of Assertion (A) is followed by a corresponding
statement of Reason (R) just below it. Mark the correct answers:
Assertion (A): Hydroxylamine  NH 2OH  contains N, and hence gives Prussian blue
colour in Lassaigne's test.
Reason (R): Hydroxylamine does not contain C, so with Na metal, CN ion is not
formed.
1) If both (A) and (R) are correct and (R) is the correct explanation for (A).
2) If both (A) and (R) are correct and (R) is not the correct explanation for (A).
3) If (A) is correct and (R) is incorrect
4) If (A) is incorrect and (R) is correct.
50. Each of the following statements of Assertion (A) is followed by a corresponding
statement of Reason (R) just below it. Mark the correct answers:
Assertion (A): Benzene (boiling point 353 K) and methanol (boiling point 338 K) are
separated by simple distillation.
Reason (R): Fractional distillation is used to separate two liquids from their mixture when
their boiling points differ by 200
1) If both (A) and (R) are correct and (R) is the correct explanation for (A).
2) If both (A) and (R) are correct and (R) is not the correct explanation for (A).
3) If (A) is correct and (R) is incorrect
4) If (A) is incorrect and (R) is correct.
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. If more than 5 questions attempted, First 5
Attempted questions will be considered. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and if answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
51. What is the ratio of 20 and 30 hydrogen atoms in the given structure.

52. a, b, c, d, e are the successive members of homologous series in the increasing order of
their Molecular weight. Atomic weight of b is 30 amu, what is the molecular
weight of e in amu?
53. In Carius method of estimation of halogens, 250mg of an organic compound
gave 141 mg of AgBr. The percentage of bromine in the compound is
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54. In Sulphur estimation. 0.471 g of an organic compound gave 1.4439 g of barium
sulphate. The percentage of Sulphur in the compound is ______
55. An organic compound is estimated through Dumas method and was found to evolve 4
mole of CO2, 3 mole H2O and 1 mole N2 gas the formula of compound is Cx Hy Nz . The
value of x  y  z _________ .
56. Following chromatogram was developed by adsorption of compound ‘A’ on a 9cm TLC
glass plate retardation factor of the compound A is……… 101
0.5cm

A Solvent font
Compound
4.5 cm

0.5cm

57. Amongst the following compounds the total number of compounds which give Beilstein
test.
I. Urea II. Thiourea III. Pyridine IV. CH 3 F
V. CH 3Cl VI. CH 3 Br VII. CH 3 I VIII. Benzamide
IX. Benzaldehyde X. Aniline
58. How many of the following Incorrect IUPAC names
1) 1- pentene 2) 2- pentene 3) 3- pentene 4) 1- methyl pentene-2
5) 2 - methyl pentene-1 6) 3 - methyl pentene-2
7) 2,4 – di Methyl butane
59. For the estimation of nitrogen, 1.4 g of organic compound was digested by Kjeldahl
M
method and the evolved ammonia was absorbed in 60 mL of sulphuric acid. The
10
M
unreacted acid required 20 ml of sodium hydroxide for complete neutralization. The
10
percentage of nitrogen in the compound is:
60. The number of   and   bonds in but- 1-en-3-yne is x,y respectively then x-y is

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MATHEMATICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

61. If the point  x1  t  x2  x1  , y1  t ( y2  y1), z1  t ( z2  z1 )  divides internally the line

segment joining  x1, y1, z1  and  x2 , y2 , z2  then
1) t  0 2) 0  t  1 3) t  1 4) t  1
62. Let A(5, 4,6), B(1, 1,3) and C (4,3,2) form ABC . If the internal bisector of angle A
meets BC in D, then the length of AD is
1 3 5 7
1) 170 2) 170 3) 170 4) 170
8 8 8 8
63. ˆ
If iˆ  3 ˆj  5k bisects the angle between â and iˆ  2 ˆj  2k , where â is a unit vector, then
ˆ

1) aˆ 
1
105

41iˆ  88 ˆj  40kˆ  2) aˆ 
1
105

41iˆ  88 ˆj  40kˆ 
3) aˆ 
1
105

41iˆ  88 ˆj  40kˆ  4) aˆ 
1
105

41iˆ  88 ˆj  40kˆ 
64. In the following figure, AB, DE, and GF are parallel to each other and AD, BG and EF
are parallel to each other. If DC  2 CE and CG  2BC , then the value of
area AEG : area ABD is equal to
G F

D
C E

A B
1) 7/2 2) 3 3) 4 4) 9/2 
65. The angles of a triangle , two of whose sides are represented by the vectors 3(aˆ  b)
  
and b  (a  b) a ; where b is a non – zero vector and a is a unit vector in the

direction of a are
 32   1 
1) tan 1   , tan 1   , tan 1  2) tan 1  3  , tan 1 
1 1 1
  , cot (0)
 3 2 1 2 3   3 

 32 
3) tan 1  3  , tan 1  2  , tan 1   4) tan 1 (1), tan 1 (1),cot 1 (0)
 2 3 1 

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66. Match the following
Column I Column II
 2
A) The angle between any two diagonals P) cos 1  
 3
of a cube is
 1 
B) The angle between one diagonal of unit Q) sin 1  
 3
Cube and a diagonal of its face is
 1 
C) The angle between a diagonal of a cube R) cot 1  
 3
and the diagonal of a face intersecting it.
1
D) The angle between the diagonal of the S) cos 1  
3
Faces of the cube through the same vertex is
1) A  S , B  P, C  Q, D  R 2) A  P, B  S , C  R, D  Q
3) A  R, B  Q, C  S , D  P 4) A  Q, B  S , C  R, D  Q
67. If ABCDEF be a regular hexagon in the xy-plane and AB  4i then CD 
1) 6i  2 3 j 2) 2i  2 3 j 3) 2(i  3 j) 4) 2(i  3 j)
68. A vector a has components a1, a 2 , a 3 in a right-handed rectangular Cartesian coordinate

system OXYZ. The coordinate system is rotated about Y-axis through an angle . The
2
component of a in the new system are
1) (a 3 ,a 2 ,a1 ) 2) (a 3 ,a 2 , a1 ) 3) (a 3 ,a 2 , a1 ) 4) (a 3 ,a 2 ,a1)
69. Statement-I: A line makes the same angle  with each of the x and z-axis. If the angle 
3
which it makes with y-axis, is such that sin 2   3 sin 2  , then cos 2   .
5
Statement-II: If a line with direction ratios l , m, n make angles  ,  , respectively with
l m n
x, y and z-axis, then cos  , cos   , cos  
l m n
2 2 2
l m n
2 2 2
l  m2  n2
2

1) Statement-I is true, Statement-II is true, and Statement-II is correct explanation for

Statement-I
2) Statement-I is true, Statement-II is true , but Statement-II is not correct explanation for
Statement-I
3) Statement-I is true, and Statement-II is false
4) Statement-I is false, Statement-II is true
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70. A straight line cuts the sides AB, AC and AD of a parallelogram ABCD at points B1, C1
     3 
And D1 respectively. If AB1  1 AB, AD1  2 AD and AC1  AC , where 1,2 and 3 are
2
positive real numbers, then:
1) 1, 3 and 2 are in AP 2) 1, 3 and 2 are in GP
3) 1, 3 and 2 are in HP 4) 1  2  3  0
71. Let PQ and QR be diagonals of adjacent faces of a rectangular box, with its Centre at O.
If QOR, ROP and POQ are   and  respectively then the value
of 'cos  cos   cos ' is :
1) -2 2)  3 3) -1 4) 0
   
72. If O (origin) is a point inside the triangle PQR such that OP  k1 OQ  k2 OR  0 , where k1 , k2
Area  PQR 
are constants such that  4 , then the value of k1  k2 is:
Area  OQR 
1) 2 2) 3 3) 4 4) 5
73. Let ABC be a triangle and let p   sin A i   sin B  j, q   cos B  i   cos A j be two
vectors such that p.q  sin 2C . If sin A, sin C, sin B are in A.P, and

AC. BA  CA   32 , then which of the following is false
1) BCA     2) ABC is equilateral  .
4 8
3) In-radius of ABC is 3 4) circumradius of ABC is .
3 3
74. If D, E and F are the mid points of the sides BC, CA, AB respectively of a
 2  1  
triangle ABC AD  BE  CF  K AC , then 2K is equal to
3 3
1) 1 2) 3 3) 2 4) 5
75. L1 and L2 are two lines whose vector equations are r   ai  bj  ck and  
  
r    cos   3 i 
  
2 sin  j  cos   3  
k  , where  and  are scalars

and ‘  ’ is the acute angle between L1 and L2 . If the angle ‘  ’ is independent
of  , then the value of  is
   
1) 2) 3) 4)
3 4 2 6

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76. The position vector of A, B are a,b respectively and the position vector
a b
of C is  . Then
2 3
1) C is inside the OAB 2) C is outside the but inside the angle AOB
3) cannot be said 4) C is outside the but inside the angle OAB
77. If the vectors a  3i  j  2k , b  i  3 j  4k , and c  4i  2 j  6k constitute the
sides of a ABC , then the length of the median bisecting the vector c is
1) 2 2) 14 3) 74 4) 6
78. If the vector 6i  3 j  6k is decomposed into vectors parallel and perpendicular
to the vector i  j  k then the vectors are respectively
1)   i  j  k  & 7i  2 j  5k 2) 2  i  j  k  &8i  j  4k
3) 2  i  j  k  & 4i  5 j  8k 4) 3  i  j  k  & i  j  k
79. Statement-I : If S is the circumcenter, G is the centroid, and O is the orthocenter
of a ABC then SA  SB  SC  SO
Statement-II : In ABC, let O and H denote circumcenter and orthocenter respectively.
Then OA  OB  OC  3OG Where G is centroid of the ABC,
1) Statement-I is true, and Statement-II is false
2) Statement-I is false, Statement-II is true
3) Both Statement-I and Statement-II are true
4) Neither Statement-I nor Statement-II are true
80. The vectors a  i  2 j  3k , b  2i  j  k , and c  3i  j  4k are so placed that the end
point of one vector is the starting point of the next vector. Then the vectors are
1) Not coplanar 2) coplanar but cannot form a triangle
3) coplanar but can form a triangle 4) coplanar and form a right-angled triangle.
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. If more than 5 questions attempted, First 5
Attempted questions will be considered. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and if answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
81. If origin is the orthocenter of a triangle formed by the points  cos , sin  , 0  ,

 cos  , sin  , 0  ,  cos  , sin  , 0  then  cos(2     )  ____

82. P(1,2, 2) Q(8,10,11) R (1,2,3) S (3,5,7) . If  denotes the length of projection of PQ

on RS then 29 2  29 is _____

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83. If V be the volume of a tetrahedron and V' be the volume of another tetrahedron formed
by the centroids of faces of the previous tetrahedron and V = KV', then K is equal to
   
84. Let O be an interior point of  ABC such that OA  2OB  3OC  0 , then the ratio of area
of  ABC to the area of  AOC is______.
85. The distance between Two points P and Q is d and the length of their projections of PQ

on the coordinate planes are d1, d2 , d3. Such that d12  d 22  d32  Kd 2 , then K
86. If the angle between the lines whose direction cosines are connected by relations
l  m  n  0 and 2lm  2 nl  mn  0 is  , then the value of 4sin 2  is___

87. If the straight line r   i  3 j  k   s  i   j   k  and r   j  2k   t  i  2 j  2k 

with parameters s and t respectively, are coplanar, then the value of  is_____.

88. If two straight lines whose direction cosines are connected by relations l  m  n  0
3
and l 2  m 2   n 2 are parallel, then the value of

89. If (p, q, r) is the image of point i  2 j  3k in the line r   6i  7 j  7k   t  3i  2 j  2k  , then

the value of  p  q  r  is_____.

90. The perpendicular distance of a corner of a unit cube from a diagonal not passing through
it is d, then the value of 3d 2 is _____.

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