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Imp Org Boards

Important Organic Questions

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15 views4 pages

Imp Org Boards

Important Organic Questions

Uploaded by

smarttv4027
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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“WISH YOU ALL A VERY HAPPY DIWALI AND A

SUCCESSFUL NEW YEAR”


DIWALI HOMEWORK

Some important questions to be done without fail for boards


CH : 10 HALOGEN CONTAINING ORGANIC COMPOUNDS
1. Explain B-elimination reaction.
2. Explain SN1 reaction.
3. Explain SN2 reaction.

R
4. Explain classification of halides.

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5. Explain Finkelstein and swarts reaction.
6. Explain sandmeyer reaction.

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7. Haloalkanes react with KCN to form alkyl cyanides as main product
while AgCN forms isocyanides as the chief product. Explain.
8.

A K
P
9.

E E
D
10. Explain (a) Wurtz reaction (b) Wurtz Fittig reaction (c) Fittig reaction.
11. Explain optical activity.
12. Explain enantiomers.
13. Aryl halides are extremely less reactive towards nucleophilic
substitution reactions. Why ?
14. Although chlorine is an electron withdrawing group, yet it is ortho-,
para- directing in electrophilic aromatic substitution reactions. Why?
15.

16.
CH : 11 ALCOHOLS, PHENOLS AND ETHERS

1. Explain oxidation of alcohol.

I R
S
2. Explain dehydration of alcohol.
3. Explain Lucas test.
4. Explain Reimer Tiemann reaction.

K
5. Explain Kolbe’s reaction.
6. Explain nitration of phenol.

A
7. Explain bromination of phenol.
8. Explain cumene process.

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9. Explain Dow’s process.
10. Explain Williamson synthesis.

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11. Explain preparation of alcohol by hydroboration oxidation.
12. Arrange the following compounds in increasing order of their acid strength:

E
Propan-1-ol, 2,4,6-trinitrophenol, 3-nitrophenol, 3,5-dinitrophenol,
phenol, 4-methylphenol.

D
13. Explain esterification reaction.
14. Explain bromination and Friedel Craft reactions of anisole.
15. Explain preparation of ether by dehydration reaction.
16. Give the major products that are formed by heating each of the following
ethers with HI.
17.

18.

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CH : 12 CARBONYL COMPOUNDS
A K
1.
2.

E P
Explain Rosenmund reaction and Stephen’s reaction.
Explain Etard reaction.

E
3. Explain Aldol and cross aldol reaction.
4. Explain Cannizaro reaction.

D
5. Explain Clemmensen and Wolff Kishner reduction reaction.
6. Explain Tollen’s reaction and Fehling’s reaction.
7. Explain addition reaction of aldehyde and ketone with HCN and NaHSO3.
8. Explain addition elimination reaction of aldehyde and ketone with
(a) NH3 (b) NH2OH (c) NH2NH2 (d) 2,4-DNP (d) Semicarbazide
9. Explain Hell-Volhard Zelinsky reaction.
10. Explain Gatterman Koch reaction.
11. Write the structures of products of the following reactions;
12. Give names of the reagents to bring about the following
transformations:
Cyclohexanol to
(i) Hexan-1-ol to hexanal (ii)
cyclohexanone
(iii) p-Fluorotoluene to p-fluorobenzaldehyde (iv) Ethanenitrile to ethanal
(vi) But-2-ene to ethanal
(v) Allyl alcohol to propenal

13. Would you expect benzaldehyde to be more reactive or less reactive in


nucleophilic addition reactions than propanal? Explain your answer.
14. Explain Haloform reaction.
15. Arrange the following compounds in increasing order of their reactivity in
nucleophilic addition reactions.
(i) Ethanal, Propanal, Propanone, Butanone.

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(ii) Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.

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16.

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A K
E P
D E
17. Write chemical reactions to affect the following transformations:
(i) Butan-1-ol to butanoic acid
(ii) Benzyl alcohol to phenylethanoic acid
(iii) 3-Nitrobromobenzene to 3-nitrobenzoic acid
(iv) 4-Methylacetophenone to benzene-1,4-dicarboxylic acid
(v) Cyclohexene to hexane-1,6-dioic acid
(vi) Butanal to butanoic acid.

DONT PANIC JUST WORK SMARTLY WITH PROPER TIME MANAGEMENT

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