11th Chemistry

Solution of MCQ Test

Chapter – 5 & 6
(25/10/2024) Mark:50

1. Study the given figure and label X, Y, and Z.

X Y Z
(a) Backword reaction Forward reaction Products
(b) Forward reaction Backword reaction Equilibrium
(c) Reversible reaction Irreversible reaction Equilibrium
(d) Forward reaction Forward reaction Backword reaction

Ans: (b) The concentration of reactants decreases and that of products increases with time.
Rate of reaction increases with time. At equilibrium, Rf = Rb

2. From the following which statement is not correct?

(a) At equilibrium the concentration of each reactants and product remains same.
(b) At equilibrium the rates of forward and backward reactions are equal
(c) If Kc > 103, reaction proceeds nearly to completion.
(d) If Qc < Kc, net reaction goes from left to right.
Ans: (a)At equilibrium the concentration of each reactants and product remains constant.

3. In which of the following reaction 𝐾𝑝 > 𝐾𝑐

(a) 𝑁2(𝑔) + 3𝐻2(𝑔) ⇌ 2𝑁𝐻3(𝑔) (b)𝐻2(𝑔) + 𝐼2(𝑔) ⇌2𝐻𝐼(g)
(c) 𝑃𝐶𝑙3(𝑔) + 𝐶𝑙2(𝑔) ⇌ 𝑃𝐶𝑙5(𝑔) (d)2𝑆𝑂3(𝑔) ⇌𝑂2(𝑔) + 2𝑆𝑂2(𝑔)
Ans: (d)For reaction 2𝑆𝑂3(𝑔) ⇌𝑂2(𝑔) + 2𝑆𝑂2(𝑔)
𝛥𝑛 is + ve so 𝐾𝑝 is more than 𝐾𝑐 .
By𝐾𝑝 = 𝐾𝑐 (𝑅𝑇)𝛥𝑛
 4. For the reaction 𝑃𝐶𝑙3 (𝑔) + 𝐶𝑙2 (𝑔) ⇌ 𝑃𝐶𝑙5 (𝑔) at 250𝑜 𝐶 , the value of 𝐾𝑐 is 26, then the value
of 𝐾𝑝 on the same temperature will be ( R = 0.0821 atm L/mole K )
(a) 0.61 (b) 0.57 (c) 0.83 (d) 0.46
Ans: (a)𝐾𝑝 = 𝐾𝑐 (𝑅𝑇)𝛥𝑛 = 26(0.0821 × 523)−1 = 0.61. (𝛥𝑛𝑔 = 1 − 2 = −1)

5. On a given condition, the equilibrium concentration of 𝐻𝐼, 𝐻2 and 𝐼2 are 0.80, 0.10 and
0.10 mole/litre. The equilibrium constant for the reaction 𝐻2 + 𝐼2 ⇌ 2𝐻𝐼 will be
(a) 64 (b) 6.4
(c) 8 (d) 0.8
Ans: (a) 𝐻2 + 𝐼2 ⇌ 2HI; [HI] = 0.80, [𝐻2 ] = 0.10, [𝐼2 ] = 0.10
[𝐻𝐼]2 0.80×0.80
𝐾𝑐 = = = 64
[𝐻2 ][𝐼2 ] 0.10×0.10

6. Partial pressures of A, B, C and D on the basis of gaseous system 𝐴 + 2𝐵 ⇌ 𝐶 + 3𝐷 are A =

0.20; B = 0.10; C = 0.30 and D = 0.50 atm. The numerical value of equilibrium constant
(Kp) is
(a) 11.25 (b) 18.75
(c) 5 (d) 3.75
Ans: (b) A + 2B ⇌C + 3D
[𝑝𝐶][𝑝𝐷]3 0.30×0.50×0.50×0.50
𝐾= = = 18.75
[𝑝𝐴][𝑝𝐵]2 0.20×0.10×0.10

7. For the equilibrium 𝑁2 + 3𝐻2 ⇌ 2𝑁𝐻3 , 𝐾𝑐 at 1000K is 2.37 × 10−3 . If at equilibrium [𝑁2 ] =
2𝑀, [𝐻2 ] = 3𝑀, the concentration of 𝑁𝐻3 is
(a) 0.00358 M (b) 0.0358 M
(c) 0.358 M (d) 3.58 M
[𝑁𝐻3 ]2
Ans: (c) 𝐾𝑐 =
[𝑁2 ][𝐻2 ]3
𝑥2
2.37 × 10−3 = = 𝑥 2 = 0.12798
[2][3]3
x = 0.358 M.

8. For reaction 𝐴𝑔2 𝑂(𝑠) → 2𝐴𝑔(𝑠) + (1/2)𝑂2 (𝑔) the value of 𝛥𝐻 = 30.56𝑘𝐽𝑚𝑜𝑙−1 and 𝛥𝑆 = 0.066𝑘 ⥂
⥂ 𝐽𝐾 −1 𝑚𝑜𝑙 −1 . Temperature at which free energy change for reaction will be zero, is
(a) 373 K (b) 413 K
(c) 463 K (d) 493 K
Ans: (c) 𝛥𝐺 = 𝛥𝐻 − 𝑇𝛥𝑆
𝛥𝐺 = 0at equilibrium
∴ 𝛥𝐻 = 𝑇𝛥𝑆 or 30.56 = 𝑇 × 0.066
𝑇 = 463𝐾.
 9. For 𝐶𝑎𝐶𝑂3 (𝑠) ⇌𝐶𝑎𝑂(𝑠) + 𝐶𝑂2 (𝑔) at 727𝑜 𝐶 ; 𝛥𝐻 = 17.6kJ mol, then 𝛥𝑈 is ( R= 8.314 Joule
/mole K)
(a) 92.8 kJ (b) 9.28 kJ
(c) 0.928 kJ (d) 928 kJ
Ans: (b) 𝛥𝑛𝑔 = 1 − 0 = 1
𝛥𝐻 = 𝛥𝑈 + 𝛥𝑛𝑅𝑇
8.314
𝛥𝑈 = +17.6 − 1 × × 1000 = 9.28𝑘𝐽.
1000
10.Work done during isothermal reversible expansion of one mole of an ideal gas from 0.5
L to 5 L at 300 K is (Gas constant R = 2 Cal /mole K)
(a) 138.18 cal. (b) 1138.8 cal.
(c) 1381.8 cal. (d) 113.88 cal.
𝑣2
Ans: (c)−𝑊 = 2.303𝑛𝑅𝑇log
𝑣1
5
−𝑊 = 2.303 × 1 × 2 × 300log = 1381.8𝑐𝑎𝑙.
0.5
11.Values of 𝛥𝐻 and 𝛥𝑆 for five different reactions are given below.
Reaction 𝛥𝐻(𝑘𝐽𝑚𝑜𝑙 −1 )𝛥𝑆(𝐽𝐾 −1 𝑚𝑜𝑙 −1 )
I +98.0 +14.8
II – 55.5 –84.6
III +28.3 –17.0
IV – 40.5 +24.6
V + 34.7 0.0
On the basis of these values predict which one of these will be spontaneous at all
tempeature
(a) Reaction I (b) Reaction II
(c) Reaction III (d) Reaction IV
Ans: (d)A spontaneous process is accompanied by decrease in enthalpy and increase in
entropy means 𝛥𝐻 is negative and 𝛥𝑆 is positive.

12.What is the equilibrium concentration of I2 at equilibrium when the initial concentration

of ICl was 0.78 M?
2ICl(g) ⇌ I2(g)+Cl2(g) ; Kc =0.14
(a) 0.167 M (b)0.253 M
(c) 0.338 M (d)0.456 M
Ans: (a) 0.167 M
 13.Which of the following conditions will always lead to a non-spontaneous change
(a) Positive 𝛥𝐻 and positive 𝛥𝑆
(b) Negative 𝛥𝐻 and negative 𝛥𝑆
(c) Positive 𝛥𝐻 and negative 𝛥𝑆
(d) Negative 𝛥𝐻 and positive 𝛥𝑆
Ans: (c)When 𝛥𝐻 = +𝑣𝑒 and 𝛥𝑆 = −𝑣𝑒 reaction is non-spontaneous.

14.If 𝛥𝐻𝑓𝑜 ( standard enthalpy of formation) for 𝐻2 𝑂2 and 𝐻2 𝑂 are −188𝑘𝐽/𝑚𝑜𝑙𝑒 and
−286𝑘𝐽/𝑚𝑜𝑙𝑒. What will be the enthalpy change of the reaction 2𝐻2 𝑂2 (𝑙) →
2𝐻2 𝑂(𝑙) + 𝑂2 (𝑔)
(a) −196𝑘𝐽/𝑚𝑜𝑙𝑒 (b) 146𝑘𝐽/𝑚𝑜𝑙𝑒
(c) −494𝑘𝐽/𝑚𝑜𝑙𝑒 (d) −98𝑘𝐽/𝑚𝑜𝑙𝑒
𝑜
Ans: (a) 𝛥𝐻𝑓 = HP - HR = (2 x – 286) – ( 2 x -188) = -196 kJ/mole.
 15.One mole of 𝑆𝑂3 was placed in a litre reaction vessel at a certain temperature. The
following equilibrium was established 2𝑆𝑂3 ⇌ 2𝑆𝑂2 + 𝑂2
At equilibrium 0.6 moles of 𝑆𝑂2 were formed. The equilibrium constant of the reaction
will be
(a) 0.36 (b) 0.45
(c) 0.54 (d) 0.675
(d) 2𝑆𝑂3 ⇌ 2𝑆𝑂2 + 𝑂2
(1−0.6) (0.6) (0.3)
[𝑆𝑂2 ]2 [𝑂2 ] 0.6×0.6×0.3
𝐾𝑐 = = = 0.675.
[𝑆𝑂3 ] 0.4×0.4

16.Maximum entropy will be in which of the following

(a) Ice (b) Liquid water
(c) Snow (d) Water vapours
Ans: (d)Entropy is the measure of randomness in the molecules. Randomness is maximum in
case of gases. Hence, entropy is maximum for water vapours.

17.The equilibrium constant (Kc)for a reaction is 10-2. What will be the value of ΔG° at 300
K ? [ R = 2 cal / K mole]
(a) - 1382 cal/mol (b) - 2764 cal/mol
(c) + 1382 cal/mol (d) + 2764 cal/mol
Ans: (d) ΔG = -2.303 RTlogK
= -2.303 x 2 x 300 x log10-2 = 2764 cal/mol. ( log10-2 = -2)

18.The work done by a system is 80 joule, when 4 Kjoule heat is supplied to it. What is the
increase in internal energy of system
(a) -76 J (b) +76 J
(c) 3.92 KJ (d)-3.92 J
Ans: (c)𝑞 = 4000 𝐽

𝑤 = −80 𝐽 (work done by the system)

𝛥𝐸 = 𝑞 + 𝑤 = 4000 − 80 = 3920 𝐽.

19.In a closed insulated container, a liquid is stirred with a paddle to increase its
temperature. In this process, which of the following is true
(a) 𝛥𝑈 = 𝑊 = 𝑄 = 0 (b) 𝛥𝑈 ≠ 0, 𝑄 = 𝑊 = 0
(c) 𝛥𝑈 = 𝑊 ≠ 0, 𝑄 = 0 (d) 𝛥𝑈 = 𝑄 ≠ 0, 𝑊 = 0
(c) As the system is closed and insulated no heat enter or leave the system, i.e. 𝑞 = 0 ;
∴ 𝛥𝑈 = 𝑄 + 𝑊 = 𝑊.
 20.Given the bond energies 𝑁 ≡ 𝑁, 𝐻 − 𝐻 and 𝑁 − 𝐻 bonds are 945, 436 and
391𝑘𝐽𝑚𝑜𝑙𝑒 −1 respectively, the enthalpy of the following reaction 𝑁2 (𝑔) + 3𝐻2 (𝑔) →
2𝑁𝐻3 (𝑔) is
(a) −93𝑘𝐽 (b) 102𝑘𝐽
(c) 90𝑘𝐽 (d) 105𝑘𝐽

𝐻
|
(a) 𝑁 ≡ 𝑁 + 3𝐻 − 𝐻 → 2𝑁 − 𝐻
945+3×436 |
⬚ 𝐻
Energy absorbed 2×(3×391)=2346
⬚
Energy released
Net. energy released = 2346 – 2253 = 93 kJ
i.e. ΔH = – 93 kJ .
21.Considering entropy (S) as a thermodynamic parameter, the criterion for the
spontaneity of any process is
(a) 𝛥𝑆𝑠𝑦𝑠𝑡𝑒𝑚 > 0 only
(b) 𝛥𝑆𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠 > 0 only
(c) 𝛥𝑆𝑠𝑦𝑠𝑡𝑒𝑚 + 𝛥𝑆𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠 > 0
(d) 𝛥𝑆𝑠𝑦𝑠𝑡𝑒𝑚 − 𝛥𝑆𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠 > 0
Ans: (c)𝛥𝑆𝑠𝑦𝑠𝑡𝑒𝑚 + 𝛥𝑆𝑠𝑢𝑟𝑟𝑜𝑢𝑛𝑑𝑖𝑛𝑔𝑠 > 𝑂 (for spontaneity)

𝑜
22.For which one of the following equations is 𝛥𝐻react equal to 𝛥𝐻𝑓𝑜 for the product
(a)2𝐶𝑂(𝑔) + 𝑂2 (𝑔) → 2𝐶𝑂2 (𝑔)
(b)𝑁2 (𝑔) + 𝑂3 (𝑔) → 𝑁2 𝑂3 (𝑔)
(c)𝐶𝐻4 (𝑔) + 2𝐶𝑙2 (𝑔) → 𝐶𝐻2 𝐶𝑙2 (𝑙) + 2𝐻𝐶𝑙(𝑔)
(d)𝑋𝑒(𝑔) + 2𝐹2 (𝑔) → 𝑋𝑒𝐹4 (𝑔)
Ans: (d)Both 𝑋𝑒 and 𝐹2 are gaseous elements at 25𝑜 𝐶 and in their standard states and
∘ ∘
form 𝑋𝑒𝐹4(𝑔) hence 𝛥𝐻(𝑓) = 𝛥𝐻react .

23.Which of the following statement is correct

(a) ΔH is positive for exothermic reaction
(b) ΔH is negative for endothermic reaction
(c) The enthalpy of combustion is positive
(d) The enthalpy of fusion is Positive
Ans: (d) H = −ve for exothermic reaction.
H = + ve for endothermic reaction
Enthalpy of fusion is + ve. ( solid converted into liquid is endothermic process)
 24.Following reaction occurring in an automobile
2C 8 H 18 ( g ) + 25O 2 ( g ) → 16CO 2 ( g ) + 18 H 2 O( g ).
The sign of ΔH, ΔS and ΔG would be
(a) +, –, + (b) –, +, –
(c) –, +, + (d) +, +, –
Ans : (b) For Combustion reaction, ΔH is negative,
Δn(g)= (16+18) – (25 + 2)= +7 , so ΔS is +ve,
reaction is spontaneous, hence ΔG is –ve.

25.Match the column I with Column II and mark the appropriate choice.
Column I Column II
(p) State function (i) At constant pressure
(q) ΔH=q (ii) Specific heat
(r) ΔU=q (iii) Entropy
(s) Intensive property (iv) At constant volume

(a)(p)-(iii), (q)-(i), (r)-(iv), (s)-(ii)

(b)(p)-(ii), (q)-(iv), (r)-(i), (s)-(iii)
(c)(p)-(ii), (q)-(iv), (r)-(iii), (s)-(i)
(d)(p)-(iii), (q)-(ii), (r)-(i), (s)-(iv)

Ans: (a)(p)-(iii), (q)-(i), (r)-(iv), (s)-(ii)