Revision date: 17/01/2022 Revision: 7 Supersedes date: 22/11/2021

SAFETY DATA SHEET

RODEX EXCEL (EU)
According to Regulation (EC) No 1907/2006, Annex II, as amended. Commission Regulation (EU) No 2015/830
of 28 May 2015.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name RODEX EXCEL (EU)

Synonyms; trade names RODEX EXCEL BLOCKS

UFI UFI: 8V10-00V0-D00J-Y2CV

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Ready for use Rodenticide containing 50ppm Bromadiolone.

Uses advised against No specific uses advised against are identified.

1.3. Details of the supplier of the safety data sheet

Supplier PelGar International Ltd
Unit 13
Newman Lane
Alton
Hampshire
GU34 2QR
United Kingdom
+44(0)1420 80744
[email protected]

EU Legal Representative PelGar International Limited 18 rue des Remparts d'Ainay 69002 Lyon, France

1.4. Emergency telephone number

Emergency telephone +44(0)1420 80744 (Monday - Friday 9.00am - 5pm GMT)

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National emergency telephone Austria: +43 1 406 43 43

number Belgium: 070 245 245
Bulgaria: +359 2 9154 233
Croatia: +3851 2348 342
Cyprus: 1401
Czech Republic: +420 224 919 293, +420 224 915 402
Denmark: +45 8212 1212
Estonia: 16662
Finland: 0800 147 111
France: + 33 (0)1 45 42 59 59
Germany: +44 (0)1420 80744 (9am-5pm Monday- Friday GMT)
Greece: (0030) 2107793777
Hungary: +36-80-201-199
Iceland: (+354) 543 1000 / 112
Ireland: Members of Public: +353 (01) 809 2166. (8am-10pm daily)
Ireland: Healthcare Professionals: +353 (01) 809 2566 (24 hour service)
Italy: 0382-24444
Latvia: +371 67042473
Liechtenstein: +44 (0)1420 80744 (9am-5pm Monday- Friday GMT)
Lithuania: +370 (85) 2362052
Luxembourg: 8002 5500
Malta: +44 (0)1420 80744 (9am-5pm Monday- Friday GMT)
Netherlands: +31(0)30 274 8888 Healthcare Professionals only
Norway: 22 59 13 00
Poland: +44 (0)1420 80744 (9am-5pm Monday- Friday GMT)
Portugal: +351 800 250 250
Romania: +40213183606
Slovakia: +421 2 5477 4166
Slovenia: 112
Spain: +34 91 562 04 20
Sweden: 112 – Begär Giftinformation

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Sens. 1 - H317 Repr. 1B - H360D STOT RE 1 - H372

Environmental hazards Not Classified

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H317 May cause an allergic skin reaction.

H360D May damage the unborn child.
H372 Causes damage to organs (Blood) through prolonged or repeated exposure.

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Precautionary statements P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.
P280 Wear protective gloves.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P314 Get medical advice/ attention if you feel unwell.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P405 Store locked up.
P404 Store in a closed container.
P501 Dispose of contents/ container in accordance with national regulations.

Supplemental label EUH 208 Contains 1, 2- Benzisothiazolin-3-one. May produce an allergic reaction.
information Keep / Store away from foodstuffs, beverages and animal feeding stuffs.
EUH 208 Contains 2-octyl-2H-isothiazol-3-one. May produce an allergic reaction.

Contains 2-OCTYL-2H-ISOTHIAZOL-3-ONE

2.3. Other hazards

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Ethyl vanillin <1%

CAS number: 121-32-4 EC number: 204-464-7

Classification
Eye Irrit. 2 - H319

2,2'-Imino Diethanol <0.1%

CAS number: 111-42-2 EC number: 203-868-0

Classification
Acute Tox. 4 - H302
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
STOT RE 2 - H373
Aquatic Chronic 3 - H412

1,2-BENZISOTHIAZOLIN-3-ONE <1%
CAS number: 2634-33-5 EC number: 220-120-9
M factor (Acute) = 1

Classification
Acute Tox. 4 - H302
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
Skin Sens. 1 - H317
Aquatic Acute 1 - H400

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BROMADIOLONE (EU) 0.005%

CAS number: 28772-56-7 EC number: 249-205-9
M factor (Acute) = 1 M factor (Chronic) = 1

Classification
Acute Tox. 1 - H300
Acute Tox. 1 - H310
Acute Tox. 1 - H330
Repr. 1B - H360D
STOT RE 1 - H372
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

2-OCTYL-2H-ISOTHIAZOL-3-ONE <1%
CAS number: 26530-20-1 EC number: 247-761-7
M factor (Acute) = 100 M factor (Chronic) = 100

Classification
Acute Tox. 3 - H301
Acute Tox. 3 - H311
Acute Tox. 2 - H330
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Skin Sens. 1A - H317
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

Denatonium Benzoate <0.1%

CAS number: 3734-33-6 EC number: 223-095-2

Classification
Acute Tox. 4 - H302
Aquatic Chronic 3 - H412

The full text for all hazard statements is displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information In case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible). Advice for Medical Doctors: Bromadiolone is an indirect anti-coagulant.
Phytomenadione, Vitamin K, is antidotal. Determin prothrombin time not less than 18 hours
after consumption. If elevated, administer Vitamin K1 until prothrombin time normalises.
Continue determination of prothrombin time for two weeks after withdrawal of antidote and
resume treatment if elevation occurs in that time.

Inhalation Due to the physical nature of this product, exposure by this route is unlikely. Seek medical
attention if symptoms persist.

Ingestion Rinse mouth. Do not induce vomiting. Get medical attention immediately.

Skin contact May cause irritation to susceptible persons. If skin irritation occurs wash with soap and water.
Remove contaminated clothing. Get medical attention if symptoms are severe or persist.

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Eye contact May cause eye irritation to susceptible persons. Rinse immediately with plenty of water and
seek medical advice.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Ingestion Harmful if swallowed.

Skin contact May cause sensitisation or allergic reactions in sensitive individuals.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Use fire-
extinguishing media suitable for the surrounding fire.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

5.2. Special hazards arising from the substance or mixture

Specific hazards None known.

Hazardous combustion Thermal decomposition or combustion products may include the following substances:
products Harmful gases or vapours.

5.3. Advice for firefighters

Protective actions during Avoid breathing fire gases or vapours. Evacuate area. Cool containers exposed to heat with
firefighting water spray and remove them from the fire area if it can be done without risk. Cool containers
exposed to flames with water until well after the fire is out.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing. Firefighter's clothing conforming to European standard EN469 (including helmets,
protective boots and gloves) will provide a basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions No specific recommendations. For personal protection, see Section 8.

6.2. Environmental precautions

Environmental precautions Avoid discharge to the aquatic environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Reuse or recycle products wherever possible. Collect spillage with a shovel and broom, or
similar and reuse, if possible. Collect and place in suitable waste disposal containers and seal
securely. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a
spillage. Dispose of contents/container in accordance with national regulations.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

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Usage precautions Avoid contact with skin and eyes. Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking. Good personal hygiene is necessary. Wash hands
and contaminated areas with water and soap before leaving the work site. Read label before
use.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in a cool, dry location. Store only in the original receptacle. Keep containers tightly
closed in a well-ventilated place. Take suitable precautions when opening sealed containers,
as pressure can build up during storage.
Keep away from sources of heat. Keep out of the reach of children. Store away from
foodstuffs. Keep away from oxidizing agents.

Storage class Miscellaneous hazardous material storage.

7.3. Specific end use(s)

Usage description Ready to use rodenticide containing 50 ppm Bromadiolone.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
Propane-1,2-diol (Propane-1,2-diol Particulates) WEL 8-Hr limit mg/M3: 10
Propane-1,2-diol (Propane-1,2-diol total vapour and particulates) WEL 8-Hr limit ppm: 150
WEL 8Hr limit mg/M3: 474
Sugar (Sucrose) WEL 8-Hr limit mg/M3: 10 WEL 15 min limit mg/M3: 20
Paraffin Wax WEL 8-Hr limit mg/M3: 2 WEL 15 min limit mg/M3: 6

Paraffin Wax (Paraffin wax fume) WEL 8-Hr limit mg/M3: 2 WEL 15 min limit mg/M3: 6

8.2. Exposure controls

Protective equipment

Appropriate engineering No specific ventilation requirements.

controls

Personal protection Body protection must be chosen depending on activity and possible exposure, for example
apron, protecting boots, chemical-protection suit.

Eye/face protection No specific eye protection required during normal use.

Hand protection Suitable chemical resistant gloves are recommended for professional users.

Other skin and body Handle in accordance with good hygiene and safety practice. Wearing of closed work clothing
protection is recommended. Avoid contact with the skin, eyes and clothing. Store work clothing
separately.

Hygiene measures Wash hands thoroughly after handling. Wash at the end of each work shift and before eating,
smoking and using the toilet. Do not eat, drink or smoke when using this product.

Respiratory protection No specific recommendations. Provide adequate ventilation.

Environmental exposure Not regarded as dangerous for the environment.

controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Wax Block.

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Colour Blue. Red.

Odour Slight.

Odour threshold No information available.

pH No information available.

Melting point approx. 60 °C (for the wax).

Initial boiling point and range No information available.

Flash point No information available.

Evaporation rate Not relevant.

Evaporation factor No information available.

Flammability (solid, gas) combustible

Upper/lower flammability or No information available.

explosive limits

Other flammability No information available.

Vapour pressure Not relevant.

Vapour density Not relevant.

Relative density No information available.

Bulk density No information available.

Solubility(ies) Immiscible with water.

Partition coefficient Not relevant.

Auto-ignition temperature No information available.

Decomposition Temperature No information available.

Viscosity No information available.

Explosive properties Not considered to be explosive.

Oxidising properties Not oxidising.

9.2. Other information

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended. Stable under the
prescribed storage conditions.

10.3. Possibility of hazardous reactions

Possibility of hazardous Keep away from: Oxidising agents.
reactions

10.4. Conditions to avoid

Conditions to avoid Heat, sparks, flames.

10.5. Incompatible materials

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Materials to avoid No specific material or group of materials is likely to react with the product to produce a
hazardous situation.

10.6. Hazardous decomposition products

Hazardous decomposition Does not decompose when used and stored as recommended. Thermal decomposition or
products combustion products may include the following substances: Harmful gases or vapours.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
Notes (oral LD₅₀) >2000 mg/kg

Acute toxicity - dermal

Notes (dermal LD₅₀) >2000 mg/kg

Acute toxicity - inhalation

Notes (inhalation LC₅₀) >5 mg/l (Dust)

Skin corrosion/irritation
Skin corrosion/irritation Not irritating.

Animal data Based on available data the classification criteria are not met.

Serious eye damage/irritation

Serious eye damage/irritation Based on available data the classification criteria are not met.

Respiratory sensitisation
Respiratory sensitisation Based on available data the classification criteria are not met.

Skin sensitisation
Skin sensitisation Based on available data the classification criteria are not met.

Germ cell mutagenicity

Genotoxicity - in vitro Based on available data the classification criteria are not met.

Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.

IARC carcinogenicity None of the ingredients are listed or exempt.

Reproductive toxicity
Reproductive toxicity - fertility Based on available data the classification criteria are not met.

Reproductive toxicity - May damage the unborn child.

development

Specific target organ toxicity - single exposure

STOT - single exposure Not classified as a specific target organ toxicant after a single exposure.

Specific target organ toxicity - repeated exposure

STOT - repeated exposure STOT RE 1 - H372

Aspiration hazard
Aspiration hazard Not relevant. Solid.

General information Avoid contact during pregnancy/while nursing. May damage fertility. The severity of the
symptoms described will vary dependent on the concentration and the length of exposure.

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Inhalation No specific symptoms known.

Ingestion See section 4 - First Aid

Skin contact Prolonged contact may cause dryness of the skin.

Eye contact No specific symptoms known.

Route of exposure Ingestion Inhalation Skin and/or eye contact

Toxicity of ingredients Denatonium Benzoate: LD50 Oral (Rat) = 584 mg/kg LC50 (Rat) 4h: >8.7 mg/l
Bromadiolone Acute Oral ≤5mg/kg Acute Dermal ≤50mg/kg Acute Inhalation ≤0.05mg/kg
(Commission Regulation 2016/1179)

SECTION 12: Ecological information

Ecotoxicity Not regarded as dangerous for the environment.

12.1. Toxicity
Toxicity Based on available data the classification criteria are not met.

12.2. Persistence and degradability

Persistence and degradability The degradability of the product is not known.

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.

Partition coefficient Not relevant.

12.4. Mobility in soil

Mobility No data available.

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects
Other adverse effects Toxic to mammals, including domesticated animals and birds if ingested. Exposure of non-
target animals should be prevented.

Toxicity of ingredients Bromadiolone Daphnia EC50/48Hr = 5.79 mg/l Rainbow trout LC50/96Hr = 2.89 mg/l

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information This material and its container must be disposed of in a safe way.

Disposal methods Dispose of in accordance with applicable regional, national, and local laws and regulations.
Dispose of Contaminated packaging as unused product unless fully cleaned.

Waste class Waste disposal key number from EWC is 20 01 19 (Pesticides)

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).

14.1. UN number
Not applicable.

14.2. UN proper shipping name

Not applicable.

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14.3. Transport hazard class(es)

No transport warning sign required.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations Authorisation number: IE/BPA 70582
Health and Safety at Work etc. Act 1974 (as amended).
EH40/2005 Workplace exposure limits.
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment
Regulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"].

EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Commission Regulation (EU) No 2015/830 of 28 May 2015.
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

Inventories
EU - EINECS/ELINCS
None of the ingredients are listed or exempt.

SECTION 16: Other information

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Abbreviations and acronyms ADR: European Agreement concerning the International Carriage of Dangerous Goods by
used in the safety data sheet Road.
ADN: European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways.
RID: European Agreement concerning the International Carriage of Dangerous Goods by
Rail.
IATA: International Air Transport Association.
ICAO: Technical Instructions for the Safe Transport of Dangerous Goods by Air.
IMDG: International Maritime Dangerous Goods.
CAS: Chemical Abstracts Service.
ATE: Acute Toxicity Estimate.
LC₅₀: Lethal Concentration to 50 % of a test population.
LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose).
EC₅₀: 50% of maximal Effective Concentration.
PBT: Persistent, Bioaccumulative and Toxic substance.
vPvB: Very Persistent and Very Bioaccumulative.

Classification abbreviations Repr. = Reproductive toxicity

and acronyms STOT RE = Specific target organ toxicity-repeated exposure

Classification procedures STOT RE 1 - H372: Calculation method. Repr. 1B - H360D: Calculation method. Skin Sens. 1
according to Regulation (EC) - H317: Calculation method.
1272/2008

Revision date 17/01/2022

Revision 7

Supersedes date 22/11/2021

SDS number 20899

Hazard statements in full H300 Fatal if swallowed.

H301 Toxic if swallowed.
H302 Harmful if swallowed.
H310 Fatal in contact with skin.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H360D May damage the unborn child.
H372 Causes damage to organs (Blood) through prolonged or repeated exposure.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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