Course Curriculam

Course Code: CHM101 Credit Units L T P/S SW AS/DS FW No. of PSDA Total Credit Unit
Course Level UG 3 0 4 2 0 0 0 6
Fundamentals of Chemistry and Quantitative
Course Title
Analysis

Course This course will give the students a basic concept of organic and inorganic chemistry. It covers bonding theories of molecules and periodic
Description : properties of atoms. The mechanism of organic reactions and stereochemistry.

Course Objectives :

SN. Objectives
1 • Get a good foundation about some of the basic topics of Inorganic and Organic chemistry.
2 • Develop an understanding of how molecules are formed and the properties of atoms.
3 • Recapitulate the basics of organic chemistry and apply it to mechanisms of organic reactions and stereochemistry
4 • Grasp experimental skills for analysis of water and other constituents
5 • Build on their basic knowledge of Computer software and apply it in chemistry

Pre-Requisites : General

SN. Course Code Course Name

Course Contents / Syllabus :

SN. Module Descriptors / Topics Weightage

Resonance and resonance energy, formal charge, Van der Waals forces, ion-dipole forces, dipoledipole
Molecular
interactions, induced dipole interaction, dipole moment and molecular Structure (Diatomic and polyatomic
polarity and
1 molecules), Percentage ionic character from dipole moment, polarizing power and polarizability. Fajan’s rules and 15.00
Weak Chemical
consequences of polarization. Hydrogen bonding, van der Waals forces, ion-dipole forces, dipole-dipole
Forces
interactions, induced dipole interaction.
Atomic orbitals, Aufbau principle, multiple bonding (s and p bond approach) and bond lengths, the valence bond
theory (VBT), Concept of hybridization, hybrid orbitals and molecular geometry, Bent’s rule, Valence shell electron
Simple Bonding
pair repulsion theory (VSEPR), shapes of the following simple molecules and ions containing lone pairs and bond
2 theories of 20.00
pairs of electrons: H2O, NH3, PCl5, SF6, SF4, ClF3, I3¯, and H3O+. Molecular orbital theory (MOT). Molecular
Molecules
orbital diagrams bond orders of homonuclear and heteronuclear diatomic molecules and ions (N2, O2, C2, B2,
F2, CO, NO, and their ions)
Periodic
properties of Brief discussion, factors affecting and variation trends of following properties in groups and periods. Effective
3 Atoms (with nuclear charge, shielding or screening effect, Slater rules, Atomic and ionic radii, Electronegativity, Pauling’s/ 15.00
reference to s & Allred Rochow’s scales, Ionization enthalpy, Electron gain enthalpy.
p-block)
Recapitulation
Hybridization, bond lengths and bond angles, bond energy, localized and delocalized chemical bonding, Van der
of basics of
4 Waals interactions, inclusion compounds, Clatherates, Charge transfer complexes, hyperconjugation, Dipole 15.00
Organic
moment; Electronic Displacements: Inductive, electromeric, resonance mesomeric effects and their applications
Chemistry
Curved arrow notation, drawing electron movements with allows, half-headed and double-headed arrows,
Mechanism of
homolytic and heterolytic bond fission, Types of reagents – electrophiles and nucleophiles, Types of organic
5 Organic 15.00
reactions, Energy considerations. Reactive intermediates – Carbocations, carbanions, free radicals, carbenes,
Reactions
arynes and nitrenes (with examples).
Concept of isomerism, Types of isomerism; Optical isomerism – elements of symmetry, molecular chirality,
enantiomers, stereogenic center, optical activity, properties of enantiomers, chiral and achiral molecules with two
6 Stereochemistry stereogenic centers, disasteromers, threo and rythron diastereomers, meso compounds, resolution of 20.00
enantionmer, inversion, retention and recemization. Relative and absolute configuration, sequence rules, D & L
 and R & S systems of nomenclature. Geometric isomerism – determination of configuration of geometric isomers,
E & Z system of nomenclature, geometric isomerism in oximes and alicyclic compounds. Conformational
isomerism – conformational analysis of ethane and n-butane; conformations of cyclohexane, axial 10 12 and
equatorial bonds, conformation of mono substituted cyclohexane derivatives, Newman projection and Sawhorse
formulae, Fischer and flying wedge formulae, Difference between configuration and conformation.

Course Learning Outcomes :

SN. Course Learning Outcomes

1 Recall the atomic structure and various bonding models.
2 Demonstrate the variation in atomic properties with position in the periodic table
3 Identify Molecular geometries, physical and chemical properties of the molecules.
4 Analyze the current bonding models for simple inorganic and organic molecules in order to predict structures and important bonding parameters.
5 Prove the mechanism of reaction with using stereochemistry
6 Estimate by experiments the various water parameters, amount of acid base present, metal ions and hydrated salts

Pedagogy for Course Delivery :

SN. Pedagogy Methods

The course pedagogy will include lectures, discussion, applications, presentations, reading review papers and individual. E content will be provided
1
to learners with a four-quadrant approach.

Theory /VAC / Architecture Assessment (L,T & Self Work): 66.70 Max : 100

Attendance+CE+EE : 5+35+60

SN. Type Component Name Marks

1 Attendance 5.00
2 End Term Examination (OMR) 60.00
3 Internal CLASS TEST 10.00
4 Internal HOME ASSIGNMENT 7.00
5 Internal Viva 3.00
6 Internal CLASS QUIZ 5.00
7 Internal GROUP PRESENTATION 5.00
8 Internal GROUP DISCUSSION 5.00

Lab/ Practical/ Studio/Arch. Studio/ Field Work Assessment : 33.30 Max : 100

Attendance+CE+EE : 5+35+60

SN. Type Component Name Marks

1 Attendance 5.00
2 External EXPERIMENT 30.00
3 External VIVA VOCE 30.00
4 Internal PRACTICAL / LAB RECORDS 10.00
5 Internal PERFORMANCE 10.00
6 Internal VIVA VOCE 15.00

Lab/ Practical details, if applicable :

SN
Lab / Practical Details
.
a) Estimation of hardness of water by EDTA. b) Determination of chemical oxygen demand (COD). c) 3. Determination of Biological oxygen demand
1
(BOD).
2 a) Estimation of ferrous and ferric by dichromate method. b) Estimation of copper using thiosulphate.
a) Determination of acetic acid in commercial vinegar using NaOH. b) Determination of alkali content – antacid tablet using HCl. c) Estimation of
3
oxalic acid by titrating it with KmnO4.
a) Estimation of sodium carbonate and sodium hydrogen carbonate present in a mixture. b) Estimation of calcium content in chalk as calcium oxalate
4
by permanganometry. c) Estimation of water of crystallization in Mohr’s salt by titrating with KmnO4
5 Application of Software Products (Office, chemsketch, scilab, matlab, hyperchem, etc.)

List of Professional skill development activities :

No.of PSDA : 0
SN. PSDA Point

Text & References :

SN. Type Title/Name Description ISBN/ URL

• Lee, J.D. Concise Inorganic Chemistry,
1 Book
Pearson Education 2010
• Huheey, J.E., Keiter, E.A., Keiter, R. L.,
2 Book Medhi, O.K. Inorganic Chemistry, Principles
of Structur
• Shriver, D.D. & P. Atkins, Inorganic
3 Book Chemistry 2nd Ed., Oxford University
Press, 1994.
• Singh J.,Yadav L.D.S., Advanced Organic
4 Book
Chemistry, Pragati Edition
• Morrison, R. N. & Boyd, R. N. Organic
5 Book Chemistry, Dorling Kindersley (India) Pvt.
Ltd. (Pearson Edu
• Carey, F. A., Guiliano, R. M.Organic
6 Book Chemistry, Eighth edition, McGraw Hill
Education, 2012.
• Loudon, G. M. Organic Chemistry, Fourth
7 Book
edition, Oxford University Press, 2008.
• Clayden, J., Greeves, N. &Warren, S.
8 Book Organic Chemistry, 2nd edition, Oxford
University Press, 2012
• Graham Solomons, T.W., Fryhle, C. B.
9 Book
Organic Chemistry, John Wiley & Sons, Inc.
• Sykes, P. A guidebook to Mechanism in
10 Book Organic Chemistry, Pearson Education,
2003
• Francis, P. G. Mathematics for Chemists,
11 Book
Springer, 1984.
• Mendham, J. Vogel’s Quantitative
12 Book
Chemical Analysis, Pearson, 2009.
• Harris, D. C. Quantitative Chemical
13 Book Analysis. 6th Ed., Freeman (2007)
Chapters 3-5.
• Harris, D.C.Exploring Chemical Analysis,
14 Book
9th Ed. New York, W.H. Freeman, 2016.
 • Khopkar, S.M. Basic Concepts of
15 Book Analytical Chemistry. New Age International
Publisher, 2009.
• Skoog, D.A. Holler F.J. and Nieman, T.A.
16 Book Principles of Instrumental Analysis,
Cengage Learning Ind
• Day, M.C. and Selbin, J. Theoretical
17 Book Inorganic Chemistry, ACS Publications
1962. (Referred in UPHE
• Douglas, B.E. and Mc Daniel, D.H.,
18 Book Concepts & Models of Inorganic Chemistry,
Oxford, 1970 (Referre