2.chemistry Ms
2.chemistry Ms
b)
25. a) any one difference (The chemical composition of nucleotide consists of a phosphate group, a 1
sugar and a nitrogenous base. A nucleoside has a chemical composition that consists of a sugar
and a base without the phosphate group)
b) due to solubility in water, it will intake regularly.
( Water soluble vitamins must be supplied regularly in diet because they are readily excreted in
urine and cannot be stored (except vitamin B12) in our body) 1
26 a) henry law expression or statement- Henry’s law is a gas law which states that at the amount of 1
gas that is dissolved in a liquid is directly proportional to the partial pressure of that gas above
the liquid when the temperature is kept constant
b) P10 = 0.850 bar; p = 0.845 bar; M1 = 78 g mol–1; w2 = 0.5 g; w1 = 39 g
P10 -P1/ P10 = W2 X M1 / M2 X W1 1
0.850 bar – 0.845 bar /0.850 bar
0.5 g × 78 g mol /M 2× 39 g ½
M2 = 170 g mol–1 ½
Outer electronic configuration of nickel (Z = 28) in ground state is 3d84s2. Nickel in this 1
complex is in + 2 oxidation state. It achieves + 2 oxidation state by the loss of the two 4s-
electrons. The resulting Ni2+ ion has outer electronic configuration of 3d8. Since CN– ion is a
strong field, under its attacking influence, two unpaired electrons in the 3d orbitals pair up.
b) When FeSO4 and (NH4)2SO4 solutions are mixed in 1 : 1 molar ratio, a double
salt known as Mohr’s salt is formed. It has the formula FeSO4.(NH4)2SO4.6H2O.
But in CuSO4, the Cu is part of coordination entity and cannot be ionized
28. a) C6H5 CH2Cl will undergo SN1reaction faster. 1
The carbocation formed by C6 H5 CH2Cl gets stabilized through resonance. 1
Greater the stability of carbocation, greater will be its ease of formation from the respective halide
b) chloro benzene converts into phenol (with reaction 1
31. . a) solution that follow Raoult’s law at all concentrations, is ideal solution. 1
b) positive deviation
C) The various quantities known to us are as follows: Π = 2.57 × 10–3 bar, 1
V = 200 cm3 = 0.200 litre
T = 300 K 1
R = 0.083 L bar mol-1 K-1
Substituting these values in equation we get
M2= w2RT/ Π V 1
M2 =1 .26 g × 0.083 L bar K-1 mol -1 × 300 K/ 2.57×10 -3 bar × 0.200 L
= 61,022 g mol-1
OR
Correct Reasons
Sample Question Paper
32 a) sucrose do not have free aldehyde group.
b) Sucrose is dextrorotatory but after hydrolysis gives dextrorotatory glucose and laevorotatory
fructose. Since the laevorotation of fructose (–92.4°) is more than dextrorotation of glucose (+
52.5°), the mixture is laevorotatory. Thus, hydrolysis of sucrose brings about a change in the sign
of rotation, from dextro (+) to laevo (–) and the product is named as invert sugar
c) When a protein in its native form, is subjected to physical change like change in temperature
or chemical change like change in pH, the hydrogen bonds are disturbed. Due to this, globules
unfold and helix get uncoiled and protein loses its biological activity. This is called denaturation
of protein.
OR
The D-L system corresponds to the configuration of the molecule: spatial arrangement of its
atoms around the chirality center. Plus, minus indicate dextro and laevo.
OR 1
a) Complex formation. 1
b) (425.9 + 91.0 – 126.4 ) S cm2 mol –1 = 390.5 S cm2 mol–1 .
c) Anode: Pb(s) + SO4 2–(aq) → PbSO4 (s) + 2e– 1
Cathode: PbO2 (s) + SO4 2–(aq) + 4H+ (aq) + 2e– → PbSO4 (s) + 2H2O (l )
Overall reaction 2
Pb(s) + PbO2 (s) + 2H2 SO4 (aq) → 2PbSO4 (s) + 2H2O(l)
2
34 . (i) Cu2+(aq) is much more stable than Cu+(aq). This is because although second ionization
enthalpy of copper is large but Δhyd (hydration enthalpy) for Cu2+(aq) is much more negative than
that for Cu+(aq) and hence it more than compensates for the second ionization enthalpy of
copper. Therefore, many copper (I) compounds are unstable in aqueous solution and undergo
disproportionation as follows: 2Cu+ → Cu2+ + Cu
(ii) Because of very small energy gap between 5f, 6d and 7s subshells all their electrons can take
part in bonding and shows variable oxidation states.
(iii) Cr2+ has the configuration 3d4 which easily changes to d3 due to stable half-filled t2g orbitals.
Therefore Cr2+ is reducing agent. While Mn2+ has stable half-filled d5 configuration. Hence Mn3+
easily changes to Mn2+ and acts as oxidising agent.
OR
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