CLASS (11th JEE)

City Test-03 Phase-4

DURATION: 180 Minutes DATE: 16/10/2023 M.MARKS: 300

Topic Covered
Physics : Newton Law of Motion, Friction Work, Power & Energy
Chemistry : Chemical Bonding & Molecular Structure, Chemical Thermodynamics & Energetics,
Equilibrium
Math : Trigonometric Equations, Linear Inequalities, Quadratic Equations

GENERAL INSTRUCTION
1. Immediately fill in the particulars on this page of the test booklet.
2. The test is of 3 hours duration.
3. The test booklet consists of 90 questions. The maximum marks are 300.
4. There are Three Sections in the question paper, Section I, II & III consisting of Section-I (Physics), Section-II
(Chemistry), Section-III (Mathematics) and having 30 questions in each part in which first 20 questions are
compulsory and are of Objective Type and Last 10 questions are integers type in which you have to attempt 5
questions only.
5. There is only one correct response for each question.
6. Each correct answer will give 4 marks while 1 Mark will be deducted for a wrong MCQ response.
7. No student is allowed to carry any textual material, printed or written, bits of papers, pager, mobile phone, any
electronic device, etc. inside the examination room/hall.
8. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
11th JEE__________________________________________________________________________________Phase - 4_Test - 03
SECTION-I (PHYSICS)
SECTION – A 4. A boy whose mass is 30 kg climbs, with a constant
1. Each of the two blocks shown in the figure has a speed, a vertical rope of 6 m long in 10 s. The
mass m. The coefficient of friction for all surfaces power of the boy during the climb is:
in contact is μ. A horizontal force P is applied to (Take g = 10 ms–2)
move the bottom block. The value of P, for which (a) 60 W (b) 3000 W
acceleration of block A is same in both cases is (c) 180 W (d) 5 W
5. An object of mass m is tied to string of length L
and a variable horizontal force is applied on it
which starts at zero and gradually increases (it is
pulled extremely slowly so that equilibrium exists
(a) 2μ mg (b) μ mg at all times) until the string makes an angle θ with
the vertical. Work done by the force F is:
2
(c) 3μ mg (d)  mg
3
2. A particle of mass m = 50 g slides with zero initial
velocity down an inclined plane set at an angle θ =
30° to the horizontal, having traversed the distance
s = 50 cm along the horizontal plane, the disc stop.
The length (l) of the inclined plane is (assuming (a) mgL (1– cosθ) (b) FL sinθ
the friction coefficient for both inclined and (c) mgL (d) FL (1 + tanθ)
horizontal plane is μ = 0.15)
6. A block of mass 1 kg slides down a curved track from
rest that is one quadrant of a circle of radius 1 m. Its
speed at the bottom is 2 m/s. The work done by
frictional force is :

(a) 0.10 m (b) 0.20 m

(a) 8 J (b) – 8 J
(c) 0.15 m (d) 0.30 m
(c) 4 J (d) – 4 J
3. A motor is to be used to lift water from a depth of
7. A small block of mass m is kept on a rough inclined
10 m & discharging it on ground level at a speed
surface of inclination θ fixed in a elevator. The elevator
10 m/s. If 2 kg of water is lifted per second & the
goes up with a uniform velocity v and the block does
efficiency of motor is 40%. The minimum power
not slide on the wedge. The work done by the force of
of the motor should be nearly :
friction on the block in time t will be:
(a) 1.5 HP (b) 1 HP (a) Zero (b) mgvt cos2θ
(c) 0.67 HP (d) 2 HP (c) mgvt sin2θ (d) mgvt sin 2θ
Use space for rough work

[2]
11th JEE__________________________________________________________________________________Phase - 4_Test - 03
8. A ball of mass 2 kg is thrown with speed 10 m/s from 12. A bead of mass 5 kg is free to slide on the
top of a tower of height 40 m at an angle 30° with horizontal rod AB. They are connected to two
horizontal. It strikes the ground with speed 25 m/s. identical springs of natural length h m. as shown. If
Work done by air-resistance on the ball is (g = 10 m/s²) initially bead was at O & M is vertically below L
(a) 275 J (b) – 275 J then, velocity of bead at point N will be:
(c) Zero (d) – 300 J
9. In the figure shown, the wedge is fixed and the
masses are released from rest. The coefficient of
friction between 4 kg and wedge is 0.8 and
between 2 kg and wedge is 0.6. Which of the
following statement is/are correct?

(a) 5h m/s (b) 40 h/3 m/s

(a) a of blocks must be same (c) 8h m/s (d) None of these
(b) Friction force on 4 kg is 24 N
13. The displacement of a body of mass 2 kg varies
(c) Friction force on 2 kg is 12 N with time tas S = t2 + 2t, where S is in meters and t
(d) Normal reaction between block is non-zero is in seconds. The work done by all the forces
acting on the body during the time interval t = 2s to
10. Power supplied to a particle of mass 2 kg varies
t = 4s is:
3t 2
with time as P = watt. Here t is in second. If (a) 36 J (b) 64 J
2
velocity of particle at t = 0 is v = 0. The velocity of (c) 100 J (d) 120 J
particle at time t = 2 s will be:
14. The work done by a force F = (–6x3 iˆ ) N in
(a) 1 m/s (b) 4 m/s displacing a particle from x = 4 m to x = – 2m is:
(c) 2 m/s (d) 2 2 m/s (a) –240 J
11. Velocity-time graph of a particle of mass 2 kg moving (b) 360 J
in a straight line is as shown in figure. Work done by all (c) 420 J
the forces on the particle is: (d) will depend upon the path
15. An ideal spring with spring-constant k is hung
from the ceiling and a block of mass M is attached
to its lower end. The mass is released with the
spring initially unstretched. Then the maximum
extension in the spring is:

(a) 400 J (b) – 400 J (a) 4 Mg/k (b) 2 Mg/k

(c) – 200 J (d) 200 J (c) Mg/k (d) Mg/2k
Use space for rough work

[3]
11th JEE__________________________________________________________________________________Phase - 4_Test - 03
16. In the shown arrangement, If the block starts 19. A chain of mass per unit length  and length 1.5 m
sliding from top of the track, maximum 2
rests on a fixed smooth sphere of radius. R = m
compression in the spring is (Horizontal track have 
a rough part of length 10 m and μ = 0.5) such that A end of chain is at the top of sphere
while the other end is hanging freely. Chain is held
stationary by a horizontal thread PA. The tension
in the thread is

(a) 1 m (b) 2m
(c) 2m (d) Zero
1 2  2
17. A motor drives a body along a straight line with a (a) g  +  (b) g  + 
constant force. The power P developed by the  2   2 
motor must vary with time t as: 2
(c) g   (d) None of these
 

20. Two blocks of masses 0.2 kg and 0.5 kg, are placed
(a) (b)
d distance apart on a rough horizontal surface (μ =
0.5) and are acted upon by two forces of magnitude
3 N each as shown in figure at time t = 0. They
collide each other at t = 2 s. The value of d is
(c) (d)

18. A body is moved along a straight line by a machine

(a) 5m
delivering constant power. The distance moved by
the body in time t is proportional to: (b) 22 m
(c) 17 m
(a) t1/2 (b) t3/4
(d) 12 m
(c) t3/2 (d) t2
Use space for rough work

[4]
11th JEE__________________________________________________________________________________Phase - 4_Test - 03
SECTION – B 25. Force acting on a particle is (2 iˆ + 3 ĵ )N. Work
21. A body with mass 2 kg moves in one direction in the
done by this force is zero, when a particle is moved
presence of a force which is described by the potential
on the line 3y + kx = 5. Here value of k is:
energy graph. If the body is released from rest at x = 2
m, then its speed when it crosses x = 5 m is: 26. A block of mass m = (2 kg) is placed on a rough
horizontal surface and is being acted upon by a
time dependant force F (N) = 2t (where t is in
second). The coefficient of static friction between
the block and the horizontal surface is μs = 0.20.
The frictional force f developed between the block
and the surface versus force F (N) plot is as shown.

22. Two blocks of 4 kg and 6 kg are attached by

springs, they are hanging in vertical position, lower
spring breaks due to excessive force. Acceleration
of 4 kg block just after breaking (Take g = 10 m/s2) The velocity of the block at t = 4 s will be

27. Two blocks of mass 4 kg and 6 kg are attached by a

spring of spring constant k = 200 N/m, both blocks
are moving with same acceleration. Find
elongation in spring.(in cm)

28. A 15 gm ball is shot from a spring gun whose

23. In the arrangement shown, frictional force acting spring has a force constant of 600 N/m. The spring
between the block and wall is (g = 10 m/s2) is compressed by 5 cm. The greatest possible
horizontal range of the ball for this compression is:
(Take g = 10 m/s²) write answer in SI unit.

29. A particle of mass 0.1 kg is subjected to a force

which varies with distance as shown in figure. If it
starts its journey from rest at x = 0, its velocity at x
= 12 m is:

24. In the arrangement shown, the minimum value of F

for which block of mass m does not slip relative to
the bigger block is nmg then n will be (string and
pulley are idal)

30. A block of mass 2 kg is tied to one end of a heavy

uniform rope of length 4 m and mass 4 kg. A horizontal
force of 18 N is applied on the other end of the rope.
The whole arrangement is placed on a smooth surface.
Tension (in N) at a point of the rope at a distance 3 m
from the end at which force is applied is…
Use space for rough

[5]
11th JEE__________________________________________________________________________________Phase - 4_Test - 03
(CHEMISTRY)
SECTION – A 36. Which one of the following statements is
31. Ratio between longest wavelengths of H atom in incorrect?
Lyman series to the shortest wavelength in Balmer (a) Greater is the nuclear charge, greater is the
series of He+ is electron affinity
4 36 (b) Neon has zero electron affinity
(a) (b)
3 5 (c) Electron affinity decreases form fluorine to
1 5 iodine in the group
(c) (d) (d) Electron affinity decreases in going down a
4 9
group and increases across period form left
32. Among V (Z = 23), Cr (Z = 24), Mn (Z = 25) the right
which will have highest magnetic moment. 37. 25 mL of 3.0 M HNO3 are mixed with 75 mL of
(a) V 4.0 M HNO3. If the volumes are additive, the
(b) Cr molarity of the final mixture would be:
(c) Mn (a) 3.25 M (b) 4.0 M
(d) all of them will have equal magnetic moment (c) 3.75 M (d) 3.50 M
33. Which one of the following elements has the 38. If the radii of first orbits of H, He+, Li+2 and Be+3
highest ionization energy? are r1, r2, r3 and r4 respectively, then their correct
(a) [Ne] 3s23p1 (b) [Ne] 3s23p3 decreasing order will be:
(c) [Ne] 3s2 3p2 (d) [Ar] 3d10 4s24p2 (a) r1 > r2 > r3 > r4
(b) r3 < r2 > r4 < r1
34. The correct order of hydration energy:
(c) r1 < r2 < r3 > r4
(a) Al+3 < Na+ < Mg+2
(d) Radius of all are equal
(b) Al+3 > Na+ > Mg+2
39. The ionization energy of the ground state
(c) Al+3 > Na+ < Mg+2
hydrogen atom is 2.18 × 10–18 J. The energy of
(d) Al+3 < Na+ > Mg+2 that orbit
35. The ratio of the angular node to the total number (a) –1.09 × 10–18 J
of nodes for 4s orbital: (b) –4.36 × 10–18 J
(a) 0 (b) 3 (c) 2.18 × 10–18 J
(c) 4 (d) Infinity (d) –2.18 × 10–18 J
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[6]
11th JEE__________________________________________________________________________________Phase - 4_Test - 03
40. Calculate the amount of lime (CaO) produced by 46. The correct order of C—O bond order among CO,
heating 100 g of 90% pure limestone. CO32– , CO2 is
(a) 56 g (b) 0.98 mol
(a) CO < CO32– < CO2
(c) 0.90 mol (d) 52.0 g
(b) CO32– < CO2 < CO
41. The correct order for the ionic mobility
(a) Li+1 > Na+1 > K+1 > Rb+1 > Cs+1 (c) CO < CO2 < CO32–
(b) Li+1 < Na+1 < K+1 < Rb+1 < Cs+1 (d) CO2 < CO32– < CO
(c) Li+1 < Be+2 < K+1 < Rb+1 < Cs+1
47. In a regular octahedral molecule, MX6 the number
(d) Li+1 > Be+2 > K+1 > Rb+1 > Cs+1 of X – M – X bonds at 180º is
42. The correct order of bond angle is: (a) Three (b) Two
(a) CH4 < NH3 < H2O < BH3 (c) Six (d) Four
(b) CH4 > NH3 > H2O > BH3 48. Which one of the following has the strongest O –
(c) BH3 > CH4 > NH3 > H2O O bond?
(d) CH4 > BH3 >NH3 > H2O (a) O+2 (b) O2
43. Which of the following pairs are isostructural? (c) O−2 (d) O22−
−
(a) XeF2 IF 2 (b) NH3, BF3
49. Incorrect statement regarding hybridization is
–2 –2
(c) CO , SO
3 3 (d) PCl5, ICl5 (a) It is not possible for isolated atoms
44. The correct order regarding the electronegativity (b) Number of hybrid orbital formed is same as
of hybrid orbitals of carbon is the number of orbitals combining
(a) sp < sp2 < sp3 (c) Only the half filled orbitals and fully filled
(b) sp > sp2 < sp3 orbitals can participate not the Empty orbital
(c) sp > sp2 > sp3 (d) It is not a real physical process
(d) sp < sp2 > sp3 50. If 0.5 mol of BaCl2 is mixed with 0.2 mol of
Na3PO4, the maximum number of mol of
45. In which of the following molecules all the bonds
Ba3(PO4)2 that can be formed is
are not equal?
(a) 0.7 (b) 0.5
(a) NF3 (b) CIF3
(c) 0.2 (d) 0.1
(c) BF3 (d) PF3
Use space for rough work

[7]
11th JEE__________________________________________________________________________________Phase - 4_Test - 03
SECTION – B 56. The number of molecules that have the zero dipole
moment CH3Cl, CCl4, PCl5, BCl3, CO2, NH3,
51. The number of diamagnetic species are NO, O2 ,
ClF3, XeF2, BeF2, PF5
C2, B2, CO, Cu2+, Mn+7, KO2, H2, NO+
57. 2.8 gm of iron displaces 3.2 gm of copper from a
52. In an organic compound of molar mass 108 gm
solution of copper sulphate solution. If the
mol–1 C, H and N atoms are present in 9 : 1 : 3.5
equivalent mass of iron is 28, then equivalent
by weight. Molecular formula can be – CxHyNz
mass of copper will be y then Y/32 will be:
then the sum of (x + y + z)/4 will be:
58. An atom of an element weighs 6.644 × 10–23 g. the
53. 6.02 × 1020 molecules of urea are present in
number of gram atoms of element in 40 kg is 10x
100 ml of its solution. The concentration of urea
gm atoms then the x will be:
solution is 100x then the value of 100x will be:
59. The total number of representative elements will be Na,
54. The number of orbitals have the electron density
Mn, Be, He, C, As, Se, Rb, Ne, Pt, Au, U, Ce
along the axis Px Py Pz dx2-y2 dz2 dxy dyz dxz, s
60. The number of hydrogen bonds formed by one
55. The number of total nodes in the 4p subshell are:
water molecule
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[8]
11th JEE__________________________________________________________________________________Phase - 4_Test - 03

(MATHEMATICS)
SECTION – A
65. The set of values of x for which
61. sin 3θ = 4 sinθ. Sin 2θ. sin 4θ in 0 ≤ θ ≤ π has tan3x − tan 2 x
= 1 is
(a) 2 real solutions (b) 4 real solutions 1 + tan3x tan 2 x
(c) 6 real solutions (d) 8 real solutions (a) 
(b) (π/4)
62. General solution of the equation, cot 3θ –cot θ = 0 is
(c) {nπ + π/4|n = 1, 2, 3…..}

(a)  = (2n − 1) , n  I (d) {2n + π/4|n = 1, 2, 3…..}
2
 66. The number of all possible triplets (a1, a2, a3) such
(b)  = (2n − 1) , n  I
4 that a1 + a2 cos 2x + a3 sin2x = 0 for all x is
 (a) 0 (b) 1
(c)  = (2n − 1) , n  I
3 (c) 2 (d) Infinite
(d) None of these
67. Which of the following is/are the examples of
63. If sinθ + 7 cos θ = 5, then tan (θ/2) is a root of the numerical inequalities?
equation I. 3 < 5 II. 7 > 5
(a) x2 – 6x + 1 = 0 (b) 6x2 – x – 1 = 0 III. x < 5 IV. y > 2
(c) 6x2 + x + 1 = 0 (d) x2 – x + 6 = 0 V. x ≥ 3
(a) I, II (b) III, IV
sin3 1
64. = if (c) IV (d) All of these
2cos2 + 1 2
 68. The solution of |cos x| = cos x – 2sin x is
(a)  = n + , n  I
6 (a) x = n π, n  I
 
(b)  = 2n − , n  I (b) x = nπ + ,nI
6 4
 
(c)  = n + (−1)n ,n I (c) x = n π + (–1)n ,nI
6 4
 
(d)  = n − , n  I (d) (2n + 1)π + ,nI
6 4
Use space for rough work
11th JEE__________________________________________________________________________________Phase - 4_Test - 03
1 73. Which of the following is the solution set of
69. If sin x + cos x = y+ , x  (0, π), then
y 3x – 7 > 5x – 1 x  R?
 (a) (– ∞, –3) (b) (– ∞, –3]
(a) x = , y =1 (b) y = 0
4 (c) (–3, ∞) (d) (–3, 3)
3 2 2
(c) y = 2 (d) x= 74. The equation x − =1− has
4 x −1 x −1
70. The solution set of the inequality (a) No root
4x + 3 < 5x + 7  x  R is (b) One root
(a) (–4, ∞) (b) [–4, ∞) (c) Two equal root
(c) (4, ∞) (d) [4, ∞) (d) Infinitely many roots
71. If α, β are the roots of the equation ax + bx + c = 0
2
75. The solution set of the inequality
then the equation whose roots are and 3(x –1) ≤ 2 (x – 3) is “A”. Here, A refers to
1 1 (a) (–∞, 3) (b) (–∞, –3)
 + and  + , is
 
(c) (–∞, 3] (d) (–∞, –3]
(a) acx2 + (a + c)bx + (a + c)2 = 0
76. The solution set of the inequality
(b) abx2 + (a + c)bx + (a + c)2 = 0
3(2 – x) ≥ 2 (1 – x) is “B” Here, B refers to
(c) acx2 + (a + b)cx + (a + c)2 = 0
(a) (–∞, 4) (b) (–∞, 4]
(d) acx3 + (a + c)bx + (a + c)3
(c) (–∞, –4) (d) (–∞, –4]
72. If α, β are the roots of the equation ax2 + bx + c = 0,
77. If a < b < c < d and K > 0, then the quadratic
 
then + = equation (x –a) (x –b) (x – c) (x –d) = 0 has
a + b a + b
(a) All roots real and distinct
2 2
(a) (b) (b) All roots real but not necessarily distinct
a b
2 2 (c) All root real and negative
(c) (d) −
c a (d) May be imaginary
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[10]
11th JEE__________________________________________________________________________________Phase - 4_Test - 03
78. The solution set of the inequality 2(2x + 3) – 10 < 83. The set of real x satisfying the inequality
6 (x – 2) is 5 − 2x x
 − 5 is [a, ∞), then a is euqal to…
(a) x ≥ 4 (b) x ≤ 4 3 6
(c) x > 4 (d) x < 4
84. The number of pairs of consecutive odd natural
79. Which of the following is/are double inequalities? numbers both of which are larger than 10, such
(a) 3 < 5 < 7 (b) 3 ≤ x < 5 that their sum is less than 40, is
(c) 2 < y ≤ 4 (d) All of these 85. The number of values of x for which sin 2x + cos 2x = 2 is
80. If graph of the quadratic y = ax2 + bx + c is given 86. If the roots of x2 + x + a = 0 exceed a, if a < –m,
below then |m| = ?

87. The number of quadratic equations which are

unchanged by squaring their roots

88. For what value of the curve y = x2 + ax + 25

touches the x-axis
(a) a > 0, b > 0, c > 0 (b) a < 0, b > 0, c < 0
(c) a < 0, b < 0, c > 0 (d) None of these 89. The number of integers satisfying the inequality
x 1
Integer Type Questions  is:
SECTION – B x+6 x
1
81. The value ‘a’ for which the equation 4cosec2 (π(a 90. If The value of m4 + =119, then the value of
m4
+ x)) + a2 – 4a = 0 has a real solution is:
1
m3 − 3 =
82. The solution set of the inequality 4x + 3 < 6x + 7 is m
(–α, ∞), then α is equal to…
Use space for rough work
11th JEE__________________________________________________________________________________Phase - 4_Test - 03
Answer key
Physics Chemistry Math
1. (A) 31. (B) 61. (D)
2. (B) 32. (B) 62. (A)
3. (B) 33. (B) 63. (B)
4. (C) 34. (B) 64. (C)
5. (A) 35. (D) 65. (A)
6. (B) 36. (B) 66. (D)
7. (C) 37. (D) 67. (A)
8. (B) 38. (B) 68. (D)
9. (B) 39. (A) 69. (A)
10. (C) 40. (D) 70. (A)
11. (B) 41. (B) 71. (A)
12. (A) 42. (C) 72. (D)
13. (B) 43. (C) 73. (A)
14. (B) 44. (B) 74. (A)
15. (B) 45. (A) 75. (D)
16. (C) 46. (D) 76. (B)
17. (A) 47. (A) 77. (A)
18. (C) 48. (B) 78. (C)
19. (A) 49. (B) 79. (D)
20. (B) 50. (B) 80. (C)
21. (2) 51. (4) 81. (2)
22. (15) 52. (7) 82. (2)
23. (50) 53. (5) 83. (8)
24. (8) 54. (9) 84. (4)
25. (2) 55. (7) 85. (0)
26. (3) 56. (8) 86. (2)
27. (4) 57. (6) 87. (4)
28. (10) 58. (2) 88. (10)
29. (40) 59. (12) 89. (9)
30. (9) 60. (4) 90. (36)

[12]
5 -

mgM=ma -> T ma+mgM

=

P-ma-myM-3mgM ma
=

p-4mgM ama
=

& 2mgi
- m/a
=

p -3mgM m/a
=

-
-

mgM
o
1
- --

D 2
=

mg
0
↑,
19
-

"
-

R Em=
R
· -**
*

tr
I am

I, d T
(dm)g(058
=

=XRd&

asdmfo
e
&T xRY
= COTOd&
T */2

fdT xRg
=

/cotode
Eg
x*t 0

T
1y= Ry
-

=9 t 19
x842 I)
41
6kg
0
27
Newer -
CON

e
20 kn 8
=

2000 8
=

20 10a
=

a =
2m/s x 4 (m =
 11/12 1 / /

Erdo 100 -

615
40 44
=

Ei
a =

=
K 100 Nm a 15m/s2
=

IOM/S

-
⑧ ----. 30

20x40 kf yxx(625 1007

-
+ =

800
(1 525
+ -
-

If 525-400
=

-
-

275.
↑
⑬ 45s fins 150x0.4
=

5kg =60N

bon f) 50N
=

Em
- >
a
a
24
=

3mm
-
qfms
- >N
fins=mg
ma!
N NM my
=
=

ma
mg
mat: my

mn:mg
F
=
8my

⑲ 4ky will not move.

Friction on 4ky=40x2=24N
⑳ 4kg
-> 18N
&Ky
3m

a
1 3m/s
=

118 T 3 Kg
>L 18N
24
- >

T 3 x3
=
9N
=
 0
80
↓(4 12)
10
=

⑲
x

=
+

29 2
80 Ix*
=

h 158
= 6
=

1600 22
=

v 40m/5
=

6 2
=
+

1x2v2
2x10x10 1x2x100
*
+

3
v2 4 =
=

v 2 =
m// Pout= 300

ut 0.4
=

300
-
-Yo
Din

IHP
Pin 750
=
=

5
t 0.6m)s
4
V = =

( mg((1
=
-

(050)
T300N
=
6m

potte
P 300x0.6
=

Wg+(fric 5x1x2x2
:180 Id 6
=

2
300N
1x10x1 +

'fric=
85
"friz=
-

7 aV-t
Is mysino
=

4V 90-8
- mgsino
->
85 |a mgsinaut
=

(05(90-8) ~ ·
-

-......
-O
I mgsinart
=

-....
↓
- -
0
2. 5 600
x

=* v
↑ 2-4100x1000
15x 10000

= 150x100x1000
-

10000
15 x

v 10m/5
=

Rmax: :": Iom

⑰ y =

5x 5 +
10

k
m =

mc =

23 x = -

k 2 =

11 W.D 0
=
-

1x2 20x20
x

-
-
4005

12
1t h *5x2
x1000 22x2
=

x
=

I v
2x10 52m/5
=

=
13 v 2t
=
2
+

1.D 1 2(40)2
=
x -

623
=100 -
36:
645

-
2

14 10 =
-6(xdn
--
-2
R

916
= -

2563
-

=
35 240
-

-- 360]

15
2,99
1

⑩-

⑰-
⑩ P mav
=

⑳ bis 2040.2
=
4N
=

I
mvt
=

2 t 4
=

V
t A 2 Dec

I
=

!
VdV= dt
fk =3N
0

x
3

=Int
a
=

at*
v =

E 4 K

=
*
t 2 2

!
+*dt (z)*
N

Jan 2 4.-2)
=
v =

-
x

0
2
3/2
x x A v
=

6 -

v 3 m/5
=

0.2kg 0.5kg
20 3N
>
->
a, < - 3N

S -Frz

I
fK, 0.2x10x0.5 fk 0805-
= = x

2.5N
=IN

a
= a (m/s2
=

22
s,-Four
x
1 1 x
=

-2m

-2Om

Stotal 22
=
m
JEE__________________________________________________________________________________________Test - 02
SECTION-II (CHEMISTRY)
SECTION – A
Ionic compound rare soluble only in polar
31. (b) solvents.

H = 13.7 – 3.7 = 10 kcal 43. (c)

32. (b) V1
W = – 2.303 nRT log
V2
2HgO(s) → 2Hg(l) + O2(g)
 It is endothermic and spontaneous process [∵ n > 0] 50
= – 2.303 × 2 × 2 × 300 log
15
∴  H > 0 and  S > 0
= –2763.6 (log 10 – log 3)
33. (b) = –2763.6 (1 – 0.4771)
–2763.6 × 0.5229
Among these has maximum dipole moment
= –1445 cal
34. (b)
44. (b)
H – bond. strength  E.N. (difference between In isothermal process
hydrogen & other element.) q = –w
35. (d) q is +ve
Bond order Unpaired Nature so, gas will do negative work.
N2 3 0 Diamagnetic
45. (a)
N+2 2.5 1 Paramagnetic
O2 2 2 Paramagnetic T1V1( – 1) = T2V2( –1)
O+2 2.5 1 Paramagnetic ( −1)
T V 
or 1 =  2  … (i)
36. (b) T2  V1 
In an antibonding M.O., electron density is According to ideal gas eq for 1 mole
minimum between the two nuclei of the molecule.
PV = RT
37. (d)
(A) O+2 = 2.5 V2  T2  P1 
=    …. (ii)
V1  T1  P2 
(B) O2– = 1.4
(C)NO = 2.5 From equation (1) & (2)
−1 −1
38. (b) T1  T2   P1 
=   
NH3 , NH+4 and NH2– have sp3 hybridization and. T2  T1   P2 
lone pairs 1, 0 and 2 respectively so bond angle  (1− )
 T1   P2 
NH+4  NH3  NH2–   = 
 T2   P1 
39. (a)
46. (d)
Both have pyramidal structure.
H = E + ngRT
40. (d)
 2  2  300 
19 = E +   kcal
 1000 
41. (b) 19 = E + 1.2

Only symmetrical overlap leads to bonding E = 19 – 1.2 kcal = 17.8 kcal

42. (c)

[4]
47. (a) Tata [H+] = [H]acid + [H+] water
C2H4 + H2 C2H6 H = – 32.7 K Cal = 10–7 + 10–7
n = Pmole – Rmole = 1 – 2 = .– 1
2 × 10–7
1
H = – ve Exothermic reaction x 
T Ph = – log[H+] = 7 – log 2
Temperature increases Reaction goes toward
51. (4)
reactant.
Thus, concentration of C2H4 increases.

48. (b)

PCl5 PCl3 + Cl2 [Moleular weight 126 gm]

6.3 1000
PCl5 PCl3 + Cl2 N=
126
1 1 1  250
2
D–d Product mole
= n= N = 0.4
d(n–1) Reactant mole
Oxalic acid = NaOH
80
= = 0.8
100 N1V1 N2V2

2 0.4 × 10 = 0.1 × (V)

n= =2
1 V = 40 ml
104.25 − d
0.8 = (D = 104.25) Hence V/10 is 4
d
52. (7)
0.8 d = 104.25 – d
53. (5)
1.8 d = 104.25
p1
W= – 2.303 nRT log
D = 57.9 p2

49. (b) or – 8180 = – 2.303 n × 2 × 273 log 20/1

or n = 5
Applying Henderson’s equation
Salt 54. (9)
pH = pKa + log
Acid u will be same as u is a state function.
1
pH = – log Ka + log 55. (7)
1
1 TS = H
pH = – log 10–5 + log
1
2.8  103
pH = 5 log 10 S = =7
400
pH = 5
56. (8)
1
log = 0 57. (6)
1
58. (2)
log 10 = 1
59. (12)
50. (b) 60. (4)
10–7 M HCl

HCl → H+ + Cl–1

10–7 0 0

0 10–7 10–7

[5]
 Section-III (MATHEMATICS)
SECTION – A Infinite triplats
61. (d) 67. (a)
sin 3θ = 4 sin θ  sin 2θ  sin 4θ 3 < 5 and 7 > 5
in 0 ≤ θ ≤ π has & solution between 0 ≤ θ ≤ π are numerical Inequalities
62. (a) 68. (d)
cot 3θ = cot θ
|cos x| = cos x – 2sinx
So, for n  I
 
θ = (2n – 1) x = 2xπ + +x
2 4

63. (b) 
= (2x + 1) π +
4
Sin θ + 7 cos θ = 5
69. (a)
  
2tan 7 1 − tan 2 
2 +  2
=5 Sin x + cos x  y +
1
2  2  y
1 + tan 1 + tan
2 2

 Then x = , y=1
tan = π 4
2
70. (a)
2x 7 (1 − x 2
) =5
+ 5x – 4x > 3 – 7
1+ x 2
1 + x2
x>–4
2x + 7 × 7x2 = 5 + 5x2
x  (–4, ∞)
12x2 – 2x – 2 = 0
71. (a)
6x2 –x – 1 = 0
 1  b a
64. (c) sum of roots = ( + ) 1 +  = − 1 + 
   a c 
sin3 1
=
2cos2 + 1 2  1  1
product of roots =   +   + 
   
2 sin3 θ = 2 cos2θ + 1

 1 1 c a
θ = nπ + (–1)n  + 1 + 1 + = 2 +  + = 2+ +
6   a c

65. (c) On putting

tan3x − tan 2 x ac2x + (a + c) x + (a + c)2 = 0

=1
1 + tan3x + tan 2 x 72. (d)
tan(3x – 2x) = 1   −2
+ =
tanx = 1  + b a + b a

 73. (a)
n + ; n 1,2
4 3x – 7 > 5x + 1
66. (d) x  (–∞, –3)
a1 + a2 cosx + θ3sin2x = 0
74. (a) 2x > – 4

2 2 x > –2
x− =1−
x −1 x −1
a=2
Has no roots
83. (8)
75. (d)
5 − 2x x
 −5
3(x – 1) ≤ 2 (x – 3) 3 6
3x – 3 ≤ 2x – 6 x − 30
5 – 2x ≤
2
x  [– ∞, –3] 10 – 4x ≤ x – 30
76. (d) 5x ≥ 40
x≥8
3(2 – x) ≥ 2(1 – x)
a=8
6 –3x ≥ 2 – 2x
84. (4)
4≥x
(11, 13), (13, 15), (15, 17), (17, 19) Four pairs
x  (– ∞, 4)
85. (1)
77. (a)
86. (2)
a<b<c<d&k>0
 < –2
then (x – a) (x – b) (x – c) (x – d) = 0
|–2| = |m| = 2
So, all roots are distinct and real.
87. (4)
78. (c)
88. (10)
4x + 6 – 10 < 6x – 12
y = (x  5)2 = x2  10 x + 25
2x > 8
89. (9)
x>4
x 1
0
x  (4, ∞) x+6 x
79. (d) x2 − x + 6
0
All are double Inequality x ( x + 6)

80. (c) x2 − x + 6
0
a<0 b2 – 4ac > 0 x ( x + 6)

a < 0, b > 0, c < 0 90. (36)

81. (2)

82. (2)

[2]