PRINCE SR. SEC.

SCHOOL SET –2
EXAM-P.A.2 ( 2024—25)
CLASS: 11th
SUBJECT: CHEMISTRY

DATE :
M.M : 40 MARKS
DAY :
TIME : 1.5 hours
NAME : __________
ROLL NO. _______
SECTION : ________
EXA. SIGN: ___________
INV. SIGN : ________
GENERAL INSTRUCTION:
1.This question paper contains 22 questions .All questions are
compulsory
2.Question paper is divided into four sections.
Section A,BC and D
3.In section A,Q no 1-7 are multiple choice questions of carrying one
marks each.
4.In section B,Q no 8-14 are Assertion Reason based questions of one
mark each
5. In section C,Q no 15-21 are short question answer type questions of
carrying three marks each.
6.In section D,Q no 22 are case based questions carrying five marks
each.
SECTION –A (1X7=7)
Q1. The shape ofPCL5 molecule is
(a) triagonal bipyramidal (b) square pyramidal (c) pyramidal (d) 1
square bipyramidal
Q2. Relation b/w Kc and Kp is given by
(a)Kp=Kc(RT)n (b) Kc=Kp(RT)n (c)Kc/Kp=RT2(d)Kp=KcR2Tn 1
Q3. The pair of ions having same electronic configuration
(a)Cr+3 ,Fe+3(b) Fe3+,Mn+2 (c)Fe+3,Co+3 (d)Sc+3,Cr+3 1
Q4. The elements in which electrons are progressively filled in 4f orbital
are called 1
 (a)actinoids (b) transition elements (c) lanthanoids (d) halogens
Q5. 16 g of oxygen has same number of molecules as in
(a)16g of CO (b) 28 g of N2 (c) 14 g of N2 (d) 1.0g of H2 1
Q6. If travelleing at the same speed,which of the following matter
waves has the shortest wavelength.
(a)electron (b)alpha particle (c)neutron (d)proton
Q7. Oxidation number of the hydrogen in CaH3 is 1
(a)1(b)-1(c)0(-2)
(SECTION-B)Assertion-Reason 1X7=7
In the following questions are statement of assertion (A) is followed 1
by statement of reason (R) Read the given statements carefully
and choose the correct option :
(a) Both assertion and reason are true and reason is the correct
explanation of assertion.
(b) Both assertion and reason are true and reason is not the
correct explanation of assertion.
(c) Assertion is true but the reason is false.
(d) Assertion is false but the reason is true.
Q8. Assertion(A): Through the central atom of both NH3 and 1
H2O molecule are sp3 hybridised
Reason(R): sp2 hybridistion gives rise to trigonal shapes
Q9. Assertion: Size of the atom increase on going down the 1
group and the added electron would be further from the
nucleus
Reason: electron gain enthalpy becomes less negative as
well as go down a group
Q10 Assertion(A): Combustion of all organic compounds is an 1
. exothermic reaction
Reason(R): The enthaplies of all elements in the standard state are
zero
Q11 Assertion(A):Sodium chloride formed by the action of chlorine gas 1
. on sodium metal is a stable compound.
Reason(R):Sodium and chlorine atoms lose and gain one electron
respectively to complete their octat.
Q12 Assertion(A):For any chemical reaction at a particular
. temperature , the equilibrium constant is if fixed and is a
characterstic property
Reason®: Equilibrium constant is independent of
temperature
Q13 Assertion (A): Spontaneous process is an irrersiveble process and 1
. maybe reversed by an external agency
Reason(R):Decrease in enthalpy is a contributory factor for
spontaneity
Q14 Assertion : removal of the electron from the atom results in 1
. the formation of an anion
Reason : atoms and ions containing different no. of
electrons are called isoelectronic species.
 (SECTION-C )SHORT ANSWER (3X7=21) 1
Q15 (i) Derive a relationship b/w Cp and Cv for an ideal gas
. (ii) prove that ; H=U+ngRT 3
Q16 (i) Draw the shape of s,p and d orbital 3
. (ii) Difference b/w electromagnetic wave theory and
planck’s quantum theory?
Q17 (i)Discuss the lewis definition of acid and base? 3
.
(ii) What is bronsted lowry concept of acid and base?

(iii) What is buffer solution?

Q18 (i) Difference b/w sigma and pi bond? 3
. (ii) Draw the resonance structure of NO-3 and CO-23 ion
Q19 (i) How many moles of NaOH are contained in 27 ml of 0.15M 3
. NaOH?
(ii) H3PO2 H3PO4 +PH3
(ii) Ca+H2O  Ca(OH)2+H2
(iii) Fe2(SO4)3+NH3+H2OFe(OH)3 +(NH4)2SO4
Q20 (i) Explain the term electrongain enthalpy .How does it vary in a 3
. group and in a period?

(ii) Write the general electronic configuration of s,p,d and f block

element?
Q21 (i) Write the oxidation and reduction half reactions for each 3
. redox reactions

(a) Zn+PbCl2 Pb+ZnCl2

(b) 2Fe+3 +2I-I2 +2Fe+2

(ii) Find out the oxidation number of chlorine in the

following compounds

NaClO4,KCLO2
SECTION-D CASE STUDY (1X5=5)
Q22 Read the passage given below and answer the following 5
. questions:

Modern periodic table arranges the elements in the

increasing order of atomic number. It has 18 groups and 7
periods. Atomic numbers are consecutive in a period and
increases in group in a pattern. Elements are divided into
four blocks, s-block, p-block, d-block and f-block based on
their electronic configuration. 78% of elements are metals,
about 20 elements are non-metals and few elements like B,
Si, Ge, As are metalloids. Metallic character increases down
the group but decreases along the period from left to right.
The physical and chemical properties vary periodically with
their atomic numbers. Periodic trends are observed in
atomic size, ionisation enthalpies, electron gain enthalpies,
electronegativity and valence. Oxides of metals are basic,
some are amphoteric. Non-metals form acidic oxides, some
form neutral oxides. s-block elements are soft, highly
reactive, do not show variable oxidation states. p-block
elements are metals, non-metals as well as metalloids,
show variable oxidation states, exist as solids, liquids and
gases. d-block elements are metals, form coloured ions,
show variable oxidation states, have high melting and
boiling points. Lanthanoids and actinoids are f-block
elements, form coloured ions. All actinoids are radioactive.

(a) What are representative elements?

(b) Which of the following belong to d-block but are not

transition elements? Zn, Cd, Hg, Ag.

(c) (i) What is difference between oxidation states of p-

block and d-block elements?

(ii) Which group elements are most electropositive and

most electronegative respectively

(d) Which type of compound is formed by Group 14

elements in 3rd period and what is the formula of its
chloride and its oxide?