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Exercise

Some Basic concept of chemistry

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® Chemistry : Some Basic Concept of Chemistry
Pre-Medical

EXERCISE-I (Conceptual Questions) Build Up Your Understanding

QUESTIONS BASED ON MOLES 10. 4.4 g of an unknown gas occupies 2.24 L of
1. The volume of a gas in discharge tube is volume at STP. The gas may be :-
1.12 × 10–7 mL at STP. Then the number of (1) N2O (2) CO
molecule of gas in the tube is - (3) CO2 (4) 1 & 3 both
4
(1) 3.01 × 10 (2) 3.01 × 1015 MC0019
12 16
(3) 3.01 × 10 (4) 3.01 × 10
MC0025 11. Which contains least no. of molecules :–
(1) 1 g CO2 (2) 1 g N2
2. Vapour density of gas is 11.2, volume occupied
by 2.4 g of this at STP will be - (3) 1 g O2 (4) 1 g H2
(1) 11.2 L (2) 2.24 L (3) 22.4 L (4) 2.4 L MC0020
MC0024
12. If V mL of the vapours of substance at NTP weight
3. Which of the following contains the least number W g. Then molecular weight of substance is:-

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of molecules ?
(1) (W/V) × 22400
(1) 4.4 g CO2 (2) 3.4 g NH3
(3) 1.6 g CH4 (4) 3.2 g SO2 V
(2) × 22.4
MC0015 W
(3) (W - V) × 22400
4. The number of molecule in 4.25 g of NH3 is -
(1) 1.505 × 10
23
(2) 3.01 × 1023 W ×1
(4)
(3) 6.02 × 1023 (4) None of these V × 22400
MC0016 MC0021
5. Vapour density of ammonia is 8.5, then 85 g of
13. Number of oxygen atoms in 8 g of ozone is -
NH3 at NTP will occupy.
(1) 22.4 L (2) 112 L 23 6.02 × 1023
(1) 6.02 × 10 (2)
(3) 224 L (4) 1120 L 2
NMC0202 6.02 × 1023 6.02 × 1023
(3) (4)
3 6
6. Which of the following contains the highest
MC0008
number of molecules -
(1) 2.8 g of CO (2) 3.2 g of CH4
14. 5.6 L of oxygen at STP contains -
(3) 1.7 g of NH3 (4) 3.2 g of SO2 23
(1) 6.02 × 10 atoms
NMC0203 23
(2) 3.01 × 10 atoms
7. 5.6 L of oxygen at NTP is equivalent to – (3)
23
1.505 × 10 atoms
(1) 1 mole (2) 1/2 mole (4)
23
0.7525 × 10 atoms
(3) 1/4 mole (4) 1/8 mole MC0007
MC0018
15. Number of neutrons present in 1.7 g of ammonia
8. A gas is found to have the formula (CO)x. It's VD
is -
is 70 the value of x must be:-
(1) NA (2) NA/10 × 4
(1) 7 (2) 4 (3) 5 (4) 6
(3) (NA/10) × 7 (4) NA × 10 × 7
MC0023
MC0006
9.
23
If 32 g of O2 contains 6.022 × 10 molecules at
NTP then 32 g of S, under the same conditions, 16. Which of the following contains largest number
will contain:- of atoms ?
23 21
(1) 6.022 × 10 S (2) 3.011 × 10 S (1) 4 g of H2 (2) 16 g of O2
23 23
(3) 1 × 10 S (4) 12.044 × 10 S (3) 28 g of N2 (4) 18 g of H2O
NMC0204 MC0005
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Chemistry : Some Basic Concept of Chemistry ®
Pre-Medical
17. The number of atoms present in 16 g of oxygen is 25. What is the mass of a molecule of CH4 :–
(1) 6.02 × 10
11.5
(2) 3.01 × 1023 (1) 16 g
(2) 26.6 × 10 g
22
(3) 3.01 × 1011.5 (4) 6.02 × 1023
MC0001 (3) 2.66 × 10
–23
g
(4) 16 NA g
18. Which of the following contains greatest number MC0013
of oxygen atoms ?
(1) 1 g of O 26. The weight of 1 mole of a gas of density
(2) 1 g of O2 –1
0.1784 g L at NTP is -
(3) 1 g of O3 (1) 0.1784 g
(4) all have the same number of atoms (2) 1 g
MC0003 (3) 4 g
(4) Can not be Calculate
19. A person adds 1.71 gram of sugar (C12H22O11) in
NMC0207
order to sweeten his tea. The number of carbon
atoms added are (mol. mass of sugar = 342) 27. Given that one mole of N2 at NTP occupies

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22
(1) 3.6 × 10 (2) 7.2 × 1021
22.4 litre the density of N2 is -
(3) 0.05 (4) 6.6 × 1022 –1
(1) 1.25 g L (2) 0.80 g L–1
NMC0205 –1
(3) 2.5 g L (4) 1.60 g L–1
20. No. of atoms in 4.25 g. of NH3 is approx :– MC0029
(1) 1 × 1023 (2) 1.5 × 1023 28. Caffeine has a molecular weight of 194. It
(3) 2 × 1023 (4) 6 × 1023 contains 28.9% by mass of nitrogen Number of
MC0002 atoms of nitrogen in one molecule of it -
(1) 2 (2) 3 (3) 4 (4) 5
21. The number of atoms in n mole of gas can be
MC0045
given by :-
n × Av.No. 29. A giant molecule contains 0.25% of a metal
(1) n× Av. No.× atomicity (2)
Atomicity whose atomic weight is 59. Its molecule contains
Av.No. × Atomicity one atom of that metal. Its minimum molecular
(3) (4) None weight is -
n
NMC0206 (1) 5900 (2) 23600
100 × 59
(3) 11800 (4)
22. Sum of number of protons, electrons and neutrons 0.4
12
in 12g of 6 C is :- NMC0208
(1) 1.8
23 30. Insulin contains 3.4% sulphur. The minimum
(2) 12.044 × 10
(3) 1.084 × 10
25 mol. wt. of insulin is –
(4) 10.84 × 10
23 (1) 941.176 (2) 944
MC0010 (3) 945.27 (4) None
MC0043
23. The weight of one atom of Uranium is 238 amu.
Its actual weight is .... g. 31. Modern atomic weight scale is based on -
(1) 1.43 × 10
26
(2) 3.94 × 10–22 (1) H–1 (2) C–12
(3) 6.99 × 10–23 (4) None of these (3) C–14 (4) C–16
MC0011 NMC0209

32.
–1
24. The actual weight of a molecule of water is - Density of a gas STP is 1.43 g L . What is its
(1) 18 g molecular weight ?
–23
(2) 2.99 × 10 g (1) 16 (2) 32
(3) both (1) & (2) are correct
(3) 48 (4) 64
(4) None of these
MC0012 NMC0210

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® Chemistry : Some Basic Concept of Chemistry
Pre-Medical
QUESTIONS BASED ON STOICHIOMETRY 38. The number of litres of air required to burn 8
33. In a gaseous reaction of the type litres of C2H2 is approximately-
aA + bB → cC + dD, (1) 40 (2) 60
which statement is wrong ? (3) 80 (4) 100
(1) a litre of A combines with b litre of B to give
NMC0211
C and D
(2) a mole of A combines with b moles of B to
give C and D QUESTIONS BASED ON LIMITING REAGENT
(3) a g of A combines with b g of B to give 39. If 0.5 mole of BaCl2 is mixed with 0.2 mole of
C and D Na3PO4 the maximum number of moles of
(4) a molecules of A combines with b molecules
Ba3(PO4)2 that can be formed is -
of B to give C and D
MC0046 3BaCl2 + 2Na3 PO4 → Ba3 (PO4)2 + 6NaCl
(1) 0.7 (2) 0.5 (3) 0.3 (4) 0.1
34. 9 g of Al will react, with MC0054
3
2Al + O2 → Al2 O3 40. 4 g of hydrogen are ignited with 4 g of oxygen.

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2
The weight of water formed is -
(1) 6 g O2 (2) 8 g O2 (1) 0.5 g (2) 3.5 g (3) 4.5 g (4) 2.5 g
(3) 9 g O2 (4) 4 g O2 MC0056
MC0048
41. For the reaction A + 2B → C,
35. The equation : 5 mole of A and 8 mole of B will produce
3 (1) 5 mole of C (2) 4 mole of C
2Al(S) + O2(g) → Al2O3(S) shows that :-
2 (3) 8 mole of C (4) 13 mole of C
3 MC0057
(1) 2 mole of Al reacts with mole of O2 to
2
42.
22
7 If 1.6 g of SO2 and 1.5 × 10 molecules of H2S
produce mole of Al2O3 are mixed and allowed to remain in contact in a
2
3 closed vessel until the reaction
(2) 2g of Al reacts with g of O2 to produce
2H2S + SO2 → 3S + 2H2O,
2
one mole of Al2O3 proceeds to completion. Which of the following
3 statement is true ?
(3) 2 g mole of Al reacts with litre of O2 to
2 (1) Only 'S' and 'H2O' remain in the reaction vessel.
produce 1 mole of Al2O3 (2) 'H2S' will remain in excess
3 (3) 'SO2' will remain in excess
(4) 2 mole of Al reacts with mole of O2 to
2 (4) None
produce 1 mole of Al2O3 MC0058
MC0049
43. 12 L of H2 and 11.2 L of Cl2 are mixed and
36. 26 cc of CO2 are passed over red hot coke. The exploded. The composition by volume of mixture is–
volume of CO evolved is :– (1) 24 L of HCl (g)
C(s) + CO2(g) → 2CO(g) (2) 0.8 L Cl2 and 20.8 L HCl (g)
(1) 15 CC (2) 10 CC (3) 0.8 L H2 and 22.4 L HCl (g)
(3) 32 CC (4) None of these
(4) 22.4 L HCl (g)
MC0051
MC0059
37. If 1/2 moles of oxygen combine with Aluminimum
to form Al2O3 then weight of Aluminium metal EMPIRICAL AND MOLECULAR FORMULA
used in the reaction is (Al= 27)– 44. A hydrocarbon contains 75% of carbon. Then its
4Al(s) + 3O2(g) → 2Al2O3(s) molecular formula is -
(1) 27 g (2) 18 g (3) 54 g (4) 40.5 g (1) CH4 (2) C2H4 (3) C2H6 (4) C2H2
MC0052 NMC0212
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Chemistry : Some Basic Concept of Chemistry ®
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45. A compound of X and Y has equal mass of 53. The number of atoms of Cr and O are 4.8 × 1010 and
them. If their atomic weights are 30 and 20 9.6 × 1010 respectively. Its empirical formula is –
respectively. Molecular formula of that compound (1) Cr2O3 (2) CrO2 (3) Cr2O4 (4) None
(its mol. wt. is 120) could be - MC0042
(1) X2Y2 (2) X3Y3 (3) X2Y3 (4) X3Y2 LAWS OF CHEMICAL COMBINATION
MC0031 54. The law of multiple proportion was proposed by:
(1) Lavoisier (2) Dalton
46. An oxide of sulphur contains 50% of sulphur in
(3) Proust (4) Gay lussac
it. Its emperial formula is -
MC0114
(1) SO2 (2) SO3 (3) SO (4) S2O
MC0032 55. Which one of the following pairs of compounds
illustrates the law of multiple proportions ?
47. A hydrocarbon contains 80% of carbon, then the (1) H2O, Na2O (2) MgO, Na2O
hydrocarbon is - (3) Na2O, BaO (4) SnCl2, SnCl4

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(1) CH4 (2) C2H4 (3) C2H6 (4) C2H2 MC0115
MC0033
56. In the reaction N2 + 3H2 → 2 NH3, ratio
48. Emperical formula of glucose is - by volume of N2, H2 and NH3 is 1 : 3 : 2. This
(1) C6H12O6 (2) C3H6O3 illustrates law of -
(3) C2H4O2 (4) CH2O (1) Definite proportion
(2) Multiple proportion
MC0034
(3) Reciprocal proportion
49. A compound is found to contain 80% of carbon (4) Gaseous volumes
and 20% of hydrogen, then the molecular MC0116
formula of the compound is- 57. Different proportions of oxygen in the various
(1) C6H6 (2) C2H5OH (3) C2H6 (4) C2H4 oxides of nitrogen prove the law of -
NMC0213 (1) Equivalent proportion
(2) Multiple proportion
50. The simplest formula of a compound containing (3) Constant proportion
50% of element X(at wt. = 10) and 50% of (4) Conservation of matter
element Y(at wt. = 20) is:- MC0117
(1) XY (2) X2Y (3) XY2 (4) X3Y
58. The law of conservation of mass holds good for
MC0037
all of the following except -
51. Which of the following compounds has same (1) All chemical reactions
empirical formula as that of glucose:- (2) Nuclear reactions
(1) CH3CHO (2) CH3COOH (3) Endothermic reactions
(3) CH3OH (4) C2H6 (4) Exothermic reactions
MC0119
MC0038
59. Number of molecules in 100 mL of each of O2,
52. A gas is found to contain 2.34 g of Nitrogen and
NH3 and CO2 at STP are –
5.34 g of oxygen. Simplest formula of the (1) in the order CO2 < O2 < NH3
compound is - (2) in the order NH3 < O2 < CO2
(1) N2O (2) NO (3) the same
(3) N2O3 (4) NO2 (4) NH3 = CO2 < O2
NMC0214 MC0120
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® Chemistry : Some Basic Concept of Chemistry
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60. Four one litre flasks are seperately filled with the 63. If law of conservation of mass was to hold true,
gases hydrogen, helium, oxygen and ozone at then 20.8 g of BaCl2 on reaction with 9.8 g of
same room temp. and pressure. The ratio of H2SO4 will produce 7.3 g of HCl and BaSO4
total number of atoms of these gases present in equal to :–
the different flasks would be - (1) 11.65 g (2) 23.3 g
(1) 1 : 1 : 1 : 1 (2) 1 : 2 : 2 : 3 (3) 25.5 g (4) 30.6 g
(3) 2 : 1 : 2 : 3 (4) 2 : 1 : 3 : 2 NMC0201
MC0122
64. A chemical equation is balanced according to the
61. A and B are two identical vessels. A contains law of –
15 g ethane at 1 atm and 298 K. The vessel B (1) Multiple proportions
contains 75 g of a gas X2 at same tamperature (2) Constant proportions
and pressure. The vapour density of X2 is – (3) Gaseous volumes
(1) 75 (2) 150 (3) 37.5 (4) 45 (4) Conservation of mass
NMC0200 MC0127

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62. When 100 g of ethylene polymerizes to 65. Two flasks A & B of equal capacity of volume
polythylene according to equation contain NH3 and SO2 gas respectively under similar
nCH2 = CH2 → -(- CH2 - CH2 -)n-. The weight of conditions. Which flask has more no. of moles –
polyethylene produced will be:- (1) A
n (2) B
(1) g (2) 100 g
2 (3) Both have same moles
100 (4) None
(3) g (4) 100n g
n MC0128
MC0125

EXERCISE-I (Conceptual Questions) ANSWER KEY

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 3 4 4 1 2 2 3 3 1 4 1 1 2 2 3
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 1 4 4 1 4 1 3 2 2 3 3 1 3 2 1
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. 2 2 3 2 4 4 2 4 4 3 2 3 3 1 3
Que. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 1 3 4 3 2 2 4 2 2 4 4 2 2 3 3
Que. 61 62 63 64 65
Ans. 1 2 2 4 3

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Chemistry : Some Basic Concept of Chemistry ®
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EXERCISE-II (Previous Year Questions) AIPMT/NEET
AIPMT 2014 7. 20.0 g of a magnesium carbonate sample
1. Equal masses of H2,O2 and methane have been decomposes on heating to give carbon dioxide and
taken in a container of volume V at temeprature 8.0g magnesium oxide. What will be the percentage
27°C in identical conditions. The ratio of the purity of magnesium carbonate in the sample?
volumes of gases H2 : O2 : CH4 would be : (At. Wt. : Mg = 24)
(1) 8 : 16 : 1 (2) 16 : 8 : 1 (1) 60 (2) 84 (3) 75 (4) 96
(3) 16 : 1 : 2 (4) 8 : 1 : 2 MC0143
MC0137
8. What is the mole fraction of the solute in a
2. When 22.4 litres of H2(g) is mixed with 11.2 1.00 m aqueous solution?
litres of Cl2(g), each at S.T.P., the moles of HCl (1) 0.0354 (2) 0.0177 (3) 0.177 (4) 1.770
(g) formed is equal to :- NLS0216
(1) 1 mol of HCl (g) (2) 2 mol of HCl (g)
NEET-II 2016

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(3) 0.5 mol of HCl (g) (4) 1.5 mol of HCl (g)
9. Suppose the elements X and Y combine to form
MC0138
two compounds XY2 and X3Y2. When 0.1 mole
3. 1.0 g of magnesium is burnt with 0.56 g O2 in a of XY2 weighs 10 g and 0.05 mole of X3Y2
closed vessel. Which reactant is left in excess and weighs 9 g, the atomic weights of X and Y are
how much? (1) 20,30 (2) 30,20 (3) 40,30 (4) 60,40
(At. wt. Mg = 24 ; O = 16) MC0144
(1) Mg, 0.16 g (2) O2, 0.16 g NEET(UG) 2018
(3) Mg, 0.44 g (4) O2, 0.28 g 10. A mixture of 2.3 g formic acid and 4.5 g oxalic acid
is treated with conc. H2SO4. The evolved gaseous
MC0139 mixture is passed through KOH pellets. Weight
AIPMT 2015 (in g) of the remaining product at STP will be
(i) HCOOH 
H 2SO 4
→ CO + H2O
4. A mixture of gases contains H2 and O2 gases in
Formic acid (H2O absorbed by H2SO4)
the ratio of 1 : 4 (w/w). What is the molar ratio
of the two gases in the mixture ? (ii) H2C2O4 → CO + CO2 + H2O
H 2SO 4

(1) 4 : 1 (2) 16 : 1 (3) 2 : 1 (4) 1 : 4 Oxalic acid (H2O absorbed by H2SO4)

MC0140 (iii) CO2 is absorbed by KOH

Re-AIPMT 2015 (1) 1.4 (2) 3.0 (3) 2.8 (4) 4.4
MC0146
5. The number of water molecules is maximum in :-
11. In which case the number of molecules of water is
(1) 18 gram of water
(2) 18 moles of water maximum?
(3) 18 molecules of water (1) 18 mL of water
(4) 1.8 gram of water (2) 0.18 g of water
MC0141 (3) 0.00224 L of water vapours at 1 atm and
6. If avogadro number NA, is changed from 273 K
23 –1 20 –1
6.022 × 10 mol to 6.022 × 10 mol , this –3
(4) 10 mol of water
would change :
MC0147
(1) the ratio of chemical species to each other in
a balanced equation NEET (UG) 2019
12. The number of moles of hydrogen molecules
(2) the ratio of elements to each other in a
compound required to produce 20 moles of ammonia
through Haber's process is :-
(3) the definition of mass in units of grams
(1) 10 (2) 20 (3) 30 (4) 40
(4) the mass of one mole of carbon
MC0192
MC0142
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® Chemistry : Some Basic Concept of Chemistry
Pre-Medical
NEET (UG) (Odisha) 2019 19. A sample of phosphorous trichloride (PCl3)
13. The volume occupied by 1.8 g of water vapour contains 1.4 moles of the substance. How many
at 374 °C and 1 bar pressure will be :- atoms are there in the sample?
–1
[Use R = 0.083 bar L K mol ]
–1 (1) 4 (2) 5.6
(1) 96.66 L (2) 55.87 L (3) 8.431 × 1023 (4) 3.372 × 1024
(3) 3.10 L (4) 5.37 L MC0229

MC0193 NEET (UG) 2022

NEET (UG) 2020 20. In one molal solution that contains 0.5 mole
14. Which one of the following has maximum number of a solute, there is
(1) 500 g of solvent
of atoms?
(2) 100 mL of solvent
(1) 1g of Li(s) [Atomic mass of Li = 7]
(3) 1000 g of solvent
(2) 1g of Ag(s) [Atomic mass of Ag = 108]
(4) 500 mL of solvent

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(3) 1g of Mg(s) [Atomic mass of Mg = 24] MC0230
(4) 1g of O2(g) [Atomic mass of O = 16] 21. What mass of 95% pure CaCO3 will be
MC0224
required to neutralise 50 mL of 0.5 M HCl
NEET (UG) 2020 (COVID-19)
solution according to the following reaction ?
15. One mole of carbon atom weighs 12 g, the
CaCO3(s)+2HCl(aq) → CaCl2(aq)+CO2(g)+2H2O(l)
number of atoms in it is equal to, (Mass of
carbon – 12 is 1.9926 × 10–23 g) [Calculate upto second place of decimal
(1) 1.2 × 10
23
(2) 6.022 × 10 22
point]
22 23
(3) 12 × 10 (4) 6.022 × 10 (1) 1.32 g (2) 3.65 g
MC0225
(3) 9.50 g (4) 1.25 g
NEET (UG) 2021
MC0231
16. An organic comopound contains 78% (by wt.)
NEET (UG) 2022 (OVERSEAS)
carbon and remaining percentage of hydrogen.
22. Match List-I with List-II :
The right option for the empirical formula of this
List-I List-II
compound is [Atomic wt. of C is 12, H is 1]
(a) 4.48 litres of (i) 0.2 moles
(1) CH (2) CH2
O2 at STP
(3) CH3 (4) CH4
(b) 12.022 × 1022 (ii) 12.044 × 1023
MC0226
molecules molecules
NEET (UG) 2021 (Paper-2) of H2O
17. An organic compound on analysis gave C = 54.5%, (c) 96 g of O2 (iii) 6.4 g
H = 9.1% by mass. Its empirical formula is (d) 88 g of CO2 (iv) 67.2 litres at STP
(1) CHO2 (2) CH2O (Given : Molar volume of a gas at STP=22.4 L)
(3) C2H4O (4) C3H4O Choose the correct answer from the
MC0227 options given below :
18. If 1 mL of water contains 20 drops then number
(1) (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
of molecules in a drop of water is (2) (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)
(1) 6.023 × 1023 (2) 1.673 × 1021 (3) (a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)
(3) 1.344 × 1018 (4) 4.346 × 1020 (4) (a)-(i), (b)-(iii), (c)-(iv), (d)-(ii)
MC0228 MC0232

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Chemistry : Some Basic Concept of Chemistry ®
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Re-NEET (UG) 2022 NEET (UG) 2023
23. The density of the solution is 2.15 g mL–1, then 24. The right option for the mass of CO2 produced
mass of 2.5 mL solution in correct significant by heating 20 g of 20% pure limestone is
figures is (Atomic mass of Ca = 40)
1200 K
(1) 5375 × 10 g
–3 [CaCO3  → CaO + CO2]

(2) 5.4 g (1) 1.76 g (2) 2.64 g (3) 1.32 g (4) 1.12 g
MC0234
(3) 5.38 g
(4) 53.75 g
MC0233

EXERCISE-II (Previous Year Questions) ANSWER KEY

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 3 1 1 1 2 4 2 2 3 3 1 3 4 1 4
Que. 16 17 18 19 20 21 22 23 24
Ans. 3 3 2 4 1 1 1 2 1

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® Chemistry : Some Basic Concept of Chemistry
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EXERCISE-III (Analytical Questions) Master Your Understanding

1. Air contains nearly 20% oxygen by volume. The 7. 10 mL of gaseous hydrocarbon on combustion
volume of air needed for complete combustion of give 40 mL of CO2(g) and 50 mL of H2O (vap.).
100 mL of acetylene will be : The hydrocarbon is -
(1) 500 mL (2) 100 mL (1) C4H5 (2) C8H10
(3) 250 mL (4) 1250 mL (3) C4H8 (4) C4H10
NMC0217 MC0060

2. Elements A and B form two compounds B2A3 8. 500 mL of a gaseous hydrocarbon when burnt in
and B2A. 0.05 moles of B2A3 weigh 9.0 g and excess of O2 gave 2.5 L of CO2 and 3.0 L of
0.10 mole of B2A weigh 10 g. Atomic weight of water vapours under same conditions. Molecular
A and B are- formula of the hydrocarbon is -
(1) 20 and 30 (2) 30 and 40 (1) C4H8 (2) C4H10

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(3) 40 and 30 (4) 30 and 20 (3) C5H10 (4) C5H12
MC0017 NMC0219

3. If 3.01 × 1020 molecules are removed from 9. 1 L of a hydrocarbon weighs as much as one
98 mg of H2SO4, then the number of moles of litre of CO2 Under similar conditions. Then the
H2SO4 left are :– molecular formula of the hydrocarbon is -
(1) 0.1 × 10
–3 (1) C3H8 (2) C2H6
(3) C2H4 (4) C3H6
(2) 0.5 × 10–3
MC0171
(3) 1.66 × 10–3
(4) 9.95 × 10–2 10. 0.01 mole of iodoform (CHI3) reacts with Ag to

MC0022 produce a gas whose volume at NTP is

2CHI3 + 6Ag → C2H2 + 6Ag I(s)
4. Which of the following has the highest mass ?
(1) 224 mL (2) 112 mL
(1) 1 g atom of C
(3) 336 mL (4) None of these
(2) 1/2 mole of CH4
MC0159
(3) 10 mL of water
23
(4) 3.011 × 10 atoms of oxygen 11. CaCO3 is 90% pure. Volume of CO2 collected at
NMC0218 STP when 10 g of CaCO3 is decomposed is -
(1) 2.016 litres
5. An oxide of metal M has 40% by mass of
(2) 1.008 litres
oxygen. Metal M has atomic mass of 24. The
(3) 10.08 litres
empirical formula of the oxide is
(4) 20.16 litres
(1) M2O (2) M2O3
MC0166
(3) MO (4) M3O4
MC0035 12. How many mole of magnesium phosphate,
Mg3(PO4)2 will contain 0.25 mole of oxygen atoms?
6. A compound contains 38.8% C, 16.0% H and –2
(1) 2.5 × 10
45.2% N. The formula of the compound would be
(2) 0.02
(1) CH3NH2 (2) CH3CN –2
(3) 3.125 × 10
(3) C2H5CN (4) CH2(NH)2 (4) 1.25 × 10–2
MC0036 MC0156

34

Chemistry : Some Basic Concept of Chemistry ®
Pre-Medical
13. Perecentage composition of an organic compound 19. 2.2 g of a compound of phosphorous and sulphur
is as follows : has 1.24 g of 'P' in it. Its empirical formula is -
C=10.06, H=0.84 , Cl=89.10 (1) P2S3 (2) P3S2 (3) P3S4 (4) P4S3
Which of the following corresponds to its MC0040
molecular formula if the vapour density is 60.0
20. On analysis, a certain compound was found to
(1) CH2 Cl2 (2) CHCl3
contain iodine and oxygen in the ratio of
(3) CH3Cl (4) None 254 : 80. The formula of the compound is :
MC0175 (At mass I = 127, O = 16)
(1) IO (2) I2O (3) I5O2 (4) I2O5
14. The ratio of masses of oxygen and nitrogen in a
MC0041
particular gaseous mixture is 1 : 4. The ratio of
number of their molecule is 21. What volume of oxygen gas (O2) measured at
(1) 1 : 8 (2) 3 : 16 0°C and 1 atm, is needed to burn completely 1L,

®
(3) 1 : 4 (4) 7 : 32 of propane gas (C3H8) measured under the same
MC0176 conditions:-
(1) 5 L (2) 10 L
15. 23 g sodium metal reacts with water. Calculate the
(3) 7 L (4) 6L
(a) volume of H2 liberated at NTP (b) moles of H2
liberated (c) weight of H2 liberated. MC0129
2Na + 2H2O → 2NaOH + H2
22. Volume occupied by one molecule of water
(1) 22.4 L, 1 mol, 2g (density =1 gcm–3) is :-
(2) 11.2 L, 1/2 mol, 1g (1) 3.0 × 10
–23
cm3
(3) 44.8 L, 2 mol, 4g (2) 5.5 ×10
–23
cm3
(4) None of the above (3 9.0 × 10–23 cm3
NMC0220 –23 3
(4) 6.023 × 10 cm
16. Which of the following is a compound MC0130
(1) graphite (2) steel
(3) cement (4) marble 23. How many moles of lead (II) chloride will be
NMC0221 formed from a reaction between 6.5 g of PbO
and 3.2 g of HCl ? (Atomic wt. of Pb=207)
17. Calculate the number of atoms of chlorine in PbO + 2HCl → PbCl2 + H2O
2.08 gm of BaCl2. (Atomic weight of Ba = 137,
(1) 0.011 (2) 0.029
Cl = 35.5)
–1 (3) 0.044 (4) 0.333
(1) 2 × 10 NA (2) 2 NA
(3) 2 × 10–2 NA (4) 2 × 10–3 NA MC0131
NMC0222
24. An organic compound contains carbon, hydrogen
18. A container of volume V, contains 0.28 g of N2 and oxygen. Its elemental analysis gives C,
gas. If same volume of an unknown gas under 38.71% and H, 9.67%. The empirical formula of
similar condition of temperature and pressure the compound would be :-
weighs, 0.44 g, the molecular mass of the gas is (1) CHO (2) CH4O
(1) 22 (2) 44 (3) CH3O (4) CH2O
(3) 66 (4) 88
NMC0223 NMC0215

35 35

® Chemistry : Some Basic Concept of Chemistry
Pre-Medical
25. 10g of hydrogen and 64 g of oxygen were filled 27. Which has the maximum number of molecules
in a steel vessel and exploded. Amount of water among the following?
produced in this reaction will be :- (1) 64 g SO2 (2) 44 g CO2
(1) 1 mol (2) 2 mol (3) 48 g O3 (4) 8 g H2
(3) 3 mol (4) 4 mol MC0135

MC0133

26. The number of atoms in 0.1 mol of a triatomic

gas is :- (NA = 6.02 × 1023 mol–1)
22
(1) 1.800 × 10 (2) 6.026 × 1022
23 23
(3) 1.806 × 10 (4) 3.600 × 10

MC0134

EXERCISE-III (Analytical Questions) ANSWER KEY

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 4 3 2 1 3 1 4 4 1 2 1 3 2 4 2
Que. 16 17 18 19 20 21 22 23 24 25 26 27
Ans. 4 3 2 4 4 1 1 2 3 4 3 4
36