CHEMISTRY ASSIGNMENT

GENERAL ORGANIC CHEMISTRY

1. The IUPAC name for

a) 1,1-dimethyl-1,2-butanediol
b) 2-methyl-2,4-pentanediol
c) 4-methyl-2,4-pentanediol
d) 1,3,3-dimethyl-1,3-propanediol

2.

a) 1,2,3-trieyanopropane
b) Propane-1,2,3-tricarbonitrile
c) 1,2,3-cyanopropane
d) Propane tricarbylamine

3. Which is wrong IUPAC name?

a) CH! CH" CH" COOCH" CH! (Ethyl butanoate)

b)

c)
d)

4. 3-methyl penta-1,3-diene is :
a) CH" = CH(CH" )" CH!
b) CH" = CHCH(CH! )CH" CH!
c) CH! CH = C(CH! )CH = CH"
d) CH! − CH = CH(CH! )"

5. Give the correct IUPAC name for

CH!
|
CH! . CH" OCH. CH" . CH" . CH" Cl
a) 2-ethoxy-5-chloropentane b) l-chloro-4-ethoxy-4-methylbutane
 c) 1-chloro-4-ethoxypentane d) Ethyl-1-chloropentylether

6. The IUPAC name of the compound,

a) 1,2,3-trihydrosypropane
b) 3-hydroxypentane-1,5-diol
c) 1,2,3-hydroxypropane
d) Propane-1,2,3-triol

7. Which of the following orders is not correct regarding the – 𝐼 effect of the substitutents?
a) −I < −Cl < −Br < −F b)

c) d)

8. The IUPAC name of compound shown below is

a) 2-bromo-6- chlorocyclohex-1-ene b) 6-bromo-2-chlorocyclohexene

c) 3-bromo-1-chlorocyclohexene d) 1-bromo-3-chlorocyclohexene

9.

a) 2-ethyl-3-methylbutanoyl chloride
b) 2,3-dimethylpentanoyl chloride
c) 3,4-dimethylpentanoyl chloride
d) 1-chloro-l-oxo-2,3-dimethylpentane

10.

The IUPAC name of is

a) 2-methyl-3-bromohexanal b) 3-bromo-2-methylbutanal
 c) 2-bromo-3-bromobutanal d) 3-bromo-2-methylpentanal

11. IUPAC name of the following compound is

a) 3, 5-dimethylcyclohexene b) 3, 5-dimethly-1-cyclohexene
c) 1, 5-dimethly-5-cyclohexene d) 1, 3-dimethyl-5-cyclohexene

12. The correct IUPAC name of the compound,

a) 3-(1-ethyl propyl) hex-1-ene

b) 4-Ethyl-3-propyl hex-1-ene
c) 3-Ethyl-4-ethenyl heptane
d) 3-Ethyl-4-propyl hex-5-ene

13. Which of the following is phenyl ethanoate?

a) b)

c) d)

14. IUPAC name of the compound

a) 4-isoprophyl, 6-methyl octane b) 3-methyl, 5-(1-methylethyl) octane

c) 3-methyl, 5-isopropyl octane d) 6-methyl, 4-(1-methylethyl) octane

15. Which nomenclature is not according to IUPAC system?

 a)

b)

c)
d)

16. What is the formula of tertiary butyl alcohol?

a) CH! − CH(CH! ) − CH" − OH b) CH! − (CH" )" OH
c) CH! − CH(OH) − CH" − CH! d) (CH! )! . C − OH

17. The IUPAC name of the compound

a) 3, 3-dimethyl-1-hydroxy cyclohexane b) 1, 1-dimethyl-3- hydroxy cyclohexane

c) 3, 3- dimethy-1- cyclohexanol d) 1,1-dimethyl-3-cyclohexanol

18. The IUPAC name of C" H# − o − CH

is

a) Ethoxy propane b) 1, 1-dimethyl ether 2-ethoxy 𝑖𝑠𝑜- d) 2-ethoxy propane

c)
propane
19. Overlap of which of the following atomic orbitals would be maximum to form the strongest covalent
bond?
a) 1𝑠 − 2𝑠(𝜎) b) 1𝑠 − 2𝑝(𝜎) c) 2𝑝 − 2𝑝(𝜋) d) 2𝑝 − 2𝑝(𝜎)

20. The correct statement about the compounds (A), (B) and (C) is
 a) (A) and (B) are identical b) (A) and (B) are diastereomers
c) (A) and (C) are enantiomers d) (A) and(B) are enantiomers

21. Which one of the following pairs represents stereoisomerism?

a) Geometrical isomerism, position isomerism
b) Geometrical isomerism, conformational isomerism
c) Optical isomerism, geometrical isomerism
d) Optical isomerism, metamerism

SOME BASIC CONCEPTS OF CHEMISTRY

22. 10 g CaCO! on heating gives 5.6 g CaO and …. g CO" .
a) 4.4 b) 5.6 c) 6.5 d) 4.2

23. Which of the following changes with increase in temperature?

a) Molality
b) Weight fraction of solute
c) Fraction of solute present in water
d) Mole fraction

24. On combustion of 4 g of the methane, 10.46 kJ of heat is liberated. Heat of combustion of

methane is
a) 83.68 kJ b) 10.46 kJ c) 41.84 kJ d) 20.93 kJ

25. A signature, written in carbon pencil weights 1 mg. What is the number of carbon atoms
present in the signature?
a) 5.02 × 10"! b) 5.02 × 10"$ c) 6.02 × 10"$ d) 0.502 × 10"$

26. Which of the following is correct?

a) Mole fraction of I + mole fraction of II = 1
(if only two components are present)
Mole fraction of I mole of I
=
b) Mole fraction of II mole of II
(if only two components are present)
 Mole fraction of solute =
c) %&'( &* +&',-(
%&'( &* +&',-(.%&'( &* +&'/(0-
d) All of the above

27. An organic compound containing C and H has 92.3% of carbon, its empirical formula is
a) CH b) CH! c) CH" d) CH1

28. The empirical formula of a compound is CH" O. If its VD is 30, its molecular formula is:
a) CH" O b) C" H1 O" c) C! H2 O! d) CH! OH

29. In a compound C, H, N atoms are present in 9 :1 : 3.5 by weight. Molecular weight of

compound is 108, its molecular formula is:
a) C" H2 N" b) C! H1 N c) C2 H3 N" d) C4 H5" N!

30. The mass of 1 mole of electrons is

a) 9.1 × 106"3 g b) 1.008 mg c) 0.55 mg d) 9.1 × 106"7 g

CHEMICAL BONDING
31. The hybrid state of S in SO! is similar to that of
a) C in C" H" b) C in C" H1 c) C in CH1 d) C in CO"

32. The bond order in NO is 2.5 while that in NO. is 3. Which of the following statements is
true for these two species?
a) Bond length in NO. is greater than in NO
b) Bond length in NO is greater than in NO.
c) Bond length in NO. is equal to than in NO
d) Bond length is unpredictable

33. If H − 𝑋 bond length is 2.00 Å and H − 𝑋 bond has dipole moment 5.12 × 106!$ C − m,
the percentage of ionic character in the molecule will be
a) 10% b) 16% c) 18% d) 20%

34. The element having lowest ionisation energy among the following is:
a) 1𝑠 " , 2𝑠 " 2𝑝! b) 1𝑠 " , 2𝑠 " 2𝑝2 , 3𝑠5 c) 1𝑠 " , 2𝑠 " 2𝑝2 d) 1𝑠 " , 2𝑠 " 2𝑝#

35. Which of the following is not tetrahedral?

 a) BF16 b) NH1. c) CO"6
! d) SO"6
1

36. If the ionic radii of K . and F 6 are about 1.34 Å each, then the expected values of atomic
radii of K and F should be respectively:
a) 1.34 and 1.34 Å b) 2.31 and 0.64 Å c) 0.64 and 2.31 Å d) 2.31 and 1.34 Å

37. Which 𝑝-orbitals overlapping would give the strongest bond?

a) b) c) d)

38. The electronic configuration

can be assigned to
a) O" b) O.
" c) O6
" d) O"6
"

39. Which of the following are isoelectronic and isostructural?

NO6 "6 6
! , CO! , ClO! , SO!
a) NO6 "6
! , CO! b) SO! , NO6
! c) ClO6 "6
! , CO! d) CO"6
! , SO!

40. The incorrect statements regarding bonding molecular orbitals because:

a) Bonding molecular orbitals possess less energy than combining atomic orbitals.
b) Bonding molecular orbitals have low electron density between the two nuclei.
c) Every electron in bonding molecular orbitals contributes to attraction between atoms.
d) They are formed when the lobes of the combining atomic orbitals have same sign.

REDOX REACTIONS
41. Of the following reactions, only one is a redox reaction. Identify this reaction.
a) Ca(OH)" + 2HCl ⟶ CaCl" + 2H" O b) 2S" O"6
7 + 2H" O ⟶ 2SO1 + 4H
"6 .

c) BaCl" + MgSO1 ⟶ BaSO1 + MgCl" d) Cu" S + 2FeO ⟶ 2Cu + 2Fe + SO"

42. MnO6 1 is a good oxidising agent in different medium changing to
MnO6 1 ⟶ Mn
".

⟶ MnO"6 1
⟶ MnO"
⟶ Mn" O!
Changes in oxidation number respectively are
a) 1,3,4,5 b) 5,4,3,2 c) 5,1,3,4 d) 2,6,4,3

43. The coefficients of I 6 , IO6 . 6 6 .

! and H in the redox reaction, I + IO! + H → I" + H" O in
the balanced form respectively are
a) 5, 1, 6 b) 1, 5, 6 c) 6, 1, 5 d) 5, 6, 1

44. Which reaction indicates the oxidising behavior of H" SO1 ?

a) 2PCl# + H" SO1 ⟶ 2POCl! + 2HCl + SO" Cl"
b) 2NaOH + H" SO1 ⟶ Na" SO1 + 2H" O
c) NaCl + H" SO1 ⟶ NaHSO1 + HCl
d) 2HI + H" SO1 ⟶ I" + SO" + 2H" O

45. 𝑎K " Cr" O7 + 𝑏KCl + 𝑐H" SO1 ⟶ 𝑥CrO" Cl" + 𝑦KHSO1 + 𝑧H" O.
The above equation balances when
a) 𝑎 = 2, b = 4, c = 6 and 𝑥 = 2, 𝑦 = 6, 𝑧 = 3
b) 𝑎 = 4, 𝑏 = 2, 𝑐 = 6 and 𝑥 = 6, 𝑦 = 2, 𝑧 = 3
c) 𝑎 = 6, 𝑏 = 4, 𝑐 = 2 and 𝑥 = 6, 𝑦 = 3, 𝑧 = 2
d) 𝑎 = 1, 𝑏 = 4, 𝑐 = 6 and 𝑥 = 2, 𝑦 = 6, 𝑧 = 3

CLASSIFICATION OF ELEMENTS AND PERIODICITY IN

PROPERTIES
46. The size of ionic species is correctly given in the order:
a) Cl7. > Si1. > Mg ". > Na.
b) Na. > Mg ". > Si1. > Cl7.
c) Na. > Mg ". > Cl7. > Si1.
d) Cl7. > Na. > Mg ". > Si1.

47. In which of the following arrangements, the sequence is not strictly according to the
property written against it?
a) CO" < SiO" < SnO" < PbO" : increasing oxidising power
b) HF < HCl < HBr < HI : increasing acid strength
c) NH! > PH! < AsH! < SbH! : increasing basic strength
d) B < C < O < N : increasing first ionisation enthalpy
48. The correct increasing bond angles order is:
a) BF! < NF! < PF! < ClF!
b) ClF! < PF! < NF! < BF!
c) BF! ≈ NF! < PF! < ClF!
d) BF! < NF! < PF! > ClF!

49. Identify the transition element.

a) 1𝑠 " , 2𝑠 " 2𝑝2 , 3𝑠 " 3𝑝2 , 4𝑠 " b) 1𝑠 " , 2𝑠 " 2𝑝2 , 3𝑠 " 3𝑝2 3𝑑 " , 4𝑠 "
c) 1𝑠 " , 2𝑠 " 2𝑝2 , 3𝑠 " 3𝑝2 3𝑑5$ , 4𝑠 " 4𝑝" d) 1𝑠 " , 2𝑠 " 2𝑝2 , 3𝑠 " 3𝑝2 3𝑑5$ , 4𝑠 " 4𝑝5

50. The correct order of decreasing second ionisation enthalpy of Ti (22), V (23), Cr (24)
and Mn (25) is:
a) V > Mn > Cr > Ti b) Mn > Cr > Ti > V c) Ti > V > Cr > Mn d) Cr > Mn > V > Ti