Unique Set. 02
Unique Set. 02
= π × 2rh + πr = π × 2rh + πr
= + = +
r = 6 cm, = 1 cm /s r = 6 cm, = 1 cm /s
∴ h = 3r + 3 = 21 cm ∴ h = 3r + 3 = 21 cm
Avevi, Again,
× × × × × ×
1= + ×3× 1= + ×3×
dr
⇒ 1 = 120π ⇒ 1 = 120π
dt
𝑑𝑟 1 𝑑𝑟 1
∴ = = 2.65 × 10 𝑐𝑚𝑠 ∴ = = 2.65 × 10 𝑐𝑚𝑠
𝑑𝑡 120𝜋 𝑑𝑡 120𝜋
b¤^i eÈbt Marks Distribution:
h = ar + b ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, h = ar + b
= + ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, = +
= 𝑐𝑚𝑠 A_ev, = 2.65 × 10 𝑐𝑚𝑠 ; wbY©q Kivi Rb¨ 05 marks for determining,
05 b¤^i| = 𝑐𝑚𝑠 𝑜𝑟 = 2.65 × 10 𝑐𝑚𝑠
[we:`ª: GKK bv wjL‡j ev fzj GKK wjL‡j 01 b¤^র KZ©b Kiv n‡e|] [N. B: 01 mark will be deducted if unit is not written or
wrong unit is written.]
h-h′ h-h′
x x
h′ h′
r r
awi, †Kvb‡Ki D”PZv I e¨vmva© h_vµ‡g ℎ I 𝑟 Ges wmwjÛv‡ii D”PZv I e¨vmva© Let, the height of cone and radius are respectively h & r
h_vµ‡g ℎ′ I 𝑥| and the height of cylinder and radius are ℎ′ & x
wmwjÛv‡ii eµZ‡ji †ÿÎdj = 2πxh respectively.
GLb, xh′ Gi gvb hZ †ewk n‡e ZZ eµZj e„nËg n‡e| Area of curved surface = 2πxh
ΔABC I ΔADE m`„k| Now, Area of curved surface will increase as xh′
increases
= ⇒ =1− ⇒ = ⇒ ℎ = (𝑟 − 𝑥) ΔABC & ΔADE similar
∴ eµZ‡ji †ÿÎdj = 2𝜋 × 𝑥 × (𝑟 − 𝑥) = ⇒ =1− ⇒ = ⇒ ℎ = (𝑟 − 𝑥)
A = 2πhx − ⇒ = 2πh − . 2x = 0 ∴ Area of curved surface = 2𝜋 × 𝑥 × (𝑟 − 𝑥)
⇒ 2x = r ⇒ x = A = 2πhx − ⇒ = 2πh − . 2x = 0
b¤^i eÈbt ⇒ 2x = r ⇒ x =
¯úk©‡Ki mgxKiY, 𝑦 = ±2; wbY©q Kivi Rb¨ 04 b¤^i| 03 marks for determining, x 3x√1 − x − 4 = 0
04 marks for determining, equation of tangent, 𝑦 = ±2
and 𝑦 = 2.
y y
y=2 y=2
A (0,1) A (0,1)
𝑥 = 0 n‡j, 𝑦 = 𝑒° = 1 If 𝑥 = 0, then 𝑦 = 𝑒° = 1
∴ 𝐴 we›`yi ¯’vbv¼ (0,1) ∴ co-ordinate of the point ‘𝐴’, (0,1)
𝑦 = 𝑒 | | ⇒ 𝑥 = ln 𝑦 (𝑥 > 0) 𝑦 = 𝑒 | | ⇒ 𝑥 = ln 𝑦 (𝑥 > 0)
∴ wb‡Y©q †ÿÎdj = 2 ∫ ln 𝑦 𝑑𝑦 [∵ Ave× AskwU 𝑦-A‡ÿi mv‡c‡ÿ ∴ Required area = 2 ∫ ln 𝑦 𝑑𝑦 [∵ the region enclosed is
cÖwZmg] symmetric with respect to y-axis]
= 2 [𝑦 ln 𝑦 − 𝑦] = 2[(2 ln 2 − 2) − (0 − 1)] = 2(2 ln 2 − = 2 [𝑦 ln 𝑦 − 𝑦] = 2[(2 ln 2 − 2) − (0 − 1)] =
1) = 0.7725 eM© GKK 2(2 ln 2 − 1) = 0.7725 sq. unit
c`v_©weÁvb Phy
01 [Medium] 10
Bqs Gi wØ-wPo cixÿvq, Pig Gi ZxeªZv 10 Wm | 30° ‡KŠwYK In Young’s double-slit experiment, intensity at maxima is
e¨eav‡b _vKv †Kv‡bv we›`yi ZxeªZv KZ ? [wPo؇qi e¨eavb, a = 100λ] 10 Wm . What is the intensity of any point situated at
an angular distance of 30°? [distance between slits, a =
100λ]
c`v_©weÁvb Phy
02 [Advanced] 10
Bqs Gi wØwPo cixÿvq 6500Å I 5200Å Zi½‰`‡N©¨i Av‡jv e¨envi In Young's double-slit experiment, light with wavelengths
Kiv n‡q‡Q| wPo؇qi `~iZ¡ 2mm I wPo n‡Z c`©vi `~iZ¡ 1.2m| †K›`ªxq of 6500Å & 5200Å are used. The distance between the
Pig †_‡K me©wb¤œ KZ `~i‡Z¡ Dfq Zi½‰`‡N©¨i D¾¡j †Wviv wgwjZ n‡e? slits is 2 mm, and the screen is 1.2 m away from the slits.
What is the minimum distance from the central maximum
at which bright fringes of both wavelengths coincide?
m × 6500 = n × 5200 ⇒ = m × 6500 = n × 5200 ⇒ =
m Gi me©wb¤œ gvb 4 minimum value of m is 4
× × × . × × × .
y= = 0.156 cm y= = 0.156 cm
× ×
c`v_©weÁvb Phy
03 [Easy] 10
`ywU Zi‡½i mgxKiY n‡jv 𝐸 = 𝑎 sin 𝜔𝑡 Ges 𝐸 = 𝑎 sin(𝜔𝑡 − 𝛿) The equations of two waves are 𝐸 = 𝑎 sin 𝜔𝑡 and 𝐸 =
†hLv‡b 𝛿 n‡jv `kv cv_©K¨| hw` Zv‡`i‡K DcwicvZb Kiv nq Z‡e jwä 𝑎 sin(𝜔𝑡 − 𝛿) , where δ is the phase difference. If they are
Zi‡½i mv‡_ cÖ_g Zi‡½i `kv cv_©K¨ wbY©q Ki| superimposed, find the phase difference of the resultant
wave relative to the first wave.
𝐸 = 𝐸 + 𝐸 = 𝑎 sin 𝜔𝑡 + 𝑎 sin(𝜔𝑡 − 𝛿) 𝐸 = 𝐸 + 𝐸 = 𝑎 sin 𝜔𝑡 + 𝑎 sin(𝜔𝑡 − 𝛿)
= 2𝑎 sin cos = 2𝑎 sin cos
= 2𝑎 cos sin 𝜔𝑡 − = 2𝑎 cos sin 𝜔𝑡 −
2𝑎 cos n‡jv we¯Ívi| myZivs `kv cv_©K¨ _vK‡e| 2𝑎 cos is the amplitude. So, phase difference will be
c`v_©weÁvb Phy
04 [Medium] 10
1 mm cÖ¯’‡”Q‡`i cwievnx Zv‡ii cÖwZ GKK AvqZ‡b e msL¨v A conductive wire with a cross-sectional area of 1 mm has
4.5 × 10 wU| ZviwU GKwU d‡UvZwor †Kv‡l hy³ hv‡Z 300 nm Gi electron number of 4.5 × 10 per unit volume. It is
Av‡jv AvcwZZ nq| hw` cwievnx e Gi †eM d‡Uv B‡jKUª‡bi †e‡Mi connected to a photo-electric cell with incident light of
0.0005% nq Z‡e Zwor cÖevn KZ? [λ = 350 nm Ges meKwU 300nm wavelength. If the velocity of conduction electrons
cwievnx e Zwor cwien‡b Ask †bq] is 0.0005% of the velocity of the photoelectrons, what is the
current flow? [λ = 350 nm; assume all conduction
electrons contribute to the current.]
= + mv = + mv
⇒ 𝑣 × 5 × 10 = 2 × 10 1− ∴ 𝑣 = 2.4 × ⇒ 𝑣 × 5 × 10 = 2 × 10 1− ∴ 𝑣 = 2.4 ×
10 𝑚𝑠 10 𝑚𝑠
GLb, m = = = 1000 kg Now, m = = = 1000 kg
. .
c`v_©weÁvb Phy
06 [Easy] 10
240 m w¯’i ˆ`‡N©¨i GKwU Mvwo I GKRb e¨w³ ci¯úi‡K 3.5 μs G A rest length of 240 m long car and an observer pass each
(e¨w³i wnmv‡e) AwZµg K‡i| Zv‡`i ga¨Kvi Av‡cwÿK †eM KZ? other in
3.5 μs, according to the observer’s perspective. What is
their relative velocity?
awi, Av‡cwÿK †eM v (Mvwoi mv‡c‡ÿ e¨w³i) Let, relative velocity is v (of the observer with respect to
car)
GLb, v = ⇒v= ⇒ (vt ) = L −
Now, v = ⇒v= ⇒ (vt ) = L −
⇒v = = 4.47 × 10 ms
⇒v = = 4.47 × 10 ms
∴ v = 66.847 × 10 ms
∴ v = 66.847 × 10 ms
b¤^i eÈbt
Marks Distribution:
v= ; ‡jLvi Rb¨ 03 b¤^i|
03 marks for writing, v =
v = ; wbY©q Kivi Rb¨ 03 b¤^i|
03 marks for determining, v =
v = 66.847 × 10 ms ; wbY©q Kivi Rb¨ 04 b¤^i|
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|]
04 marks for determining, v = 66.847 × 10 ms
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written.]
Eng. Admission Program-2024
Weekly Exam Chemistry-11 (Physical) Written ‰Re †hŠM (A¨vjwWnvBW - A¨vwgb)
Set-B
imvqb Chem
01 10
‘𝐴’ †hŠMwU cUvwkqvg mvqvbvB‡Wi mv‡_ wewµqvq ‘𝐵’ †hŠM Drcbœ K‡i| Compound ‘B’ is produced from the reaction between
‘𝐵’ †hŠMwU kw³kvjx weRviK Øviv weRvwiZ n‡q ‘𝐶’ †hŠM Drcbœ K‡i I compound ‘A’ and Potassium cyanide. Compound ‘B’ will
A¤øxq `ªe‡Y Av`ª©we‡køwlZ n‡q ‘𝐷’ †hŠM Drcbœ K‡i| Ô𝐷Õ †hŠMwU be reduced by strong reagent and produces compound
wf‡bMv‡ii cÖavb Dcv`vb| 𝐴, 𝐵, 𝐶 I 𝐷 †hŠMmg~n Dchy³ wewµqvmn ‘C’and compound B’ also will be hydrolyzed in acidic
kbv³ Ki| [𝐴 Gi AvYweK fi 50.5] solution to produce compound ‘D’. Compound ‘D’ is the
main ingredient of vinegar. Identify compounds A, B, C
and D with the help of suitable reactions. [Molecular mass
of A is 50.5]
CH Cl + KCN ⎯⎯ KCl + CH CN CH Cl + KCN ⎯⎯ KCl + CH CN
imvqb Chem
02 10
‘𝐴’ †hŠMwU NaOH Gi mv‡_ wewµqv K‡i GKwU M¨vm I GKwU †hŠM ‘𝐵’ Compound ‘A’ reacts with NaOH and produces a gas and a
Drcbœ nq| ‘𝐵’ †hŠMwU‡K cybivq †mvWvjvBg mn DËß Ki‡j ‘𝐶’ †hŠM compound ‘B’. When compound ‘B’ is reheated with soda
Drcbœ nq| ‘𝐶’ me©wb¤œ AvYweK fiwewkó ˆRe †hŠM| Dchy³ wewµqvmn lime, compound ‘C’ is produced. Compound ‘C’ is an
𝐴, 𝐵 I 𝐶 †hŠMmg~n kbv³ Ki| organic compound having the least molecular mass.
Identify compounds A,B and C with suitable reactions.
†h‡nZz 𝐶 Gi AvYweK fi me©wb¤œ| myZivs 𝐶 → wg‡_b| Since the molecular mass of C is the least. Therefore 𝐶 →
∆ Methane.
CH CONH + NaOH ⎯⎯⎯⎯ CH COONa + NH ∆
CH CONH + NaOH ⎯⎯⎯⎯ CH COONa + NH
CH COONa + NaOH ⎯⎯⎯⎯ CH + Na CO
A ⎯⎯⎯⎯ CH CONH CH COONa + NaOH ⎯⎯⎯⎯ CH + Na CO
imvqb Chem
03 10
Dchy³ wewµqvi mvnv‡h¨ wb‡¤œv³ iƒcvšÍi m¤úbœ Ki: Complete the following conversion with the help of
B_vbj †_‡K †cÖvcvb¨vj| suitable reaction:
Ethanol to propanal
CH CH OH ⎯ → 𝐶𝐻 𝐶𝐻 𝐶𝑙 ⎯ 𝐶𝐻 𝐶𝐻 𝐶𝑁 ⎯⎯⎯ CH CH OH ⎯ 𝐶𝐻 𝐶𝐻 𝐶𝑙 ⎯ 𝐶𝐻 𝐶𝐻 𝐶𝑁 ⎯⎯⎯
∆, ∆,
imvqb Chem
04 10
wb‡Pi wewµqv¸‡jv m¤ú~Y© Ki: Complete the following reactions:
|| || ,
(i) CH − C − CH + NH − (i) CH − C − CH + NH − NH ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ +
∆
,
NH ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ +
∆
N2Cl N2Cl
. .
(ii) ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ (ii) ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯
NH2 NH2
, ,
(iii) ⎯⎯⎯⎯⎯⎯⎯⎯ +H O (iii) ⎯⎯⎯⎯⎯⎯⎯⎯ +H O
∆ ∆
(iv) R − CONH (iv) R − CONH
(i) CH − CH − CH + N (i) CH − CH − CH + N
NH2 NH2
(ii) (ii)
N2Cl N2Cl
(iii) (iii)
(iv) R − CN (iv) R − CN
(v) NO (v) NO
b¤^i eÈbt Mark distribution:
5 wU wewµqvi Rb¨ (02 × 05) = 10 b¤^i| (02 × 05) = 10 marks for five reactions.
imvqb Chem
05 10
†Kv‡bv GKwU bgybv †hŠM eªvwWi weKvi‡Ki mv‡_ wewµqvq njy` Aat‡¶c †`q| A sample compound gives yellow precipitate in reaction with
GwU n¨v‡jvdig wewµqv I U‡jb weKvi‡Ki mv‡_ Kvw•ÿZ wewµqv †`q bv| Brady’s reagent. It does not give haloform reaction and does
†hŠMwU wK¬‡gbmb weRviY wewµqvq n-‡n‡·b Drcbœ K‡i| bgybv †hŠMwUi not give the desired reaction with Tollen’s reagent. The
IUPAC c×wZ‡Z bvg, ms‡KZ Ges Zxeª Rvi‡Y cÖvß cÖavb Drcv`mg~n wjL| compound produces n-hexane in Clemmensen reduction
reaction. Write down the name in IUPAC method, the
formula and the major products obtained from the strong
oxidation of the sample compound.
†h‡nZy eªvwWi weKvi‡K njy` Aat‡¶c → A¨vjwWnvBW/wK‡Uvb Since yellow precipitate with Brady’s reagent →
†h‡nZy, U‡jb weKvi‡K wewµqv †`q bv → wK‡Uvb aldehyde/ketone
wK¬‡gbmb wewµqvq n-hexane, → 6-C hy³ wK‡Uvb As, it does not give reaction with Tollen reagent → ketone
n-hexane in Clemmensen reaction → 6-C ketone
m¤¢ve¨, Probable,
wØZxqwU n¨v‡jvdig wewµqv †`q bv| The second one does not give haloform reaction.
b¤^i eÈbt
U‡jb weKvi‡K wewµqv †`q bv → wK‡Uvb ‡jLvi Rb¨ 01 b¤^i| Mark distribution:
wK¬‡gbmb wewµqvq n-hexane, → 6-C hy³ wK‡Uvb 01 mark for writing it does not give reaction with Tollen
‡jLvi Rb¨ 01 b¤^i| reagent → ketone.
01 mark for writing n-hexane in Clemenson reaction, → 6-C
ketone.
†hŠMwU n¨v‡jvdig wewµqv †`q
bv, ‡jLvi Rb¨ 02 b¤^i| 02 marks for writing it
†hЇMi ms‡KZ ‡jLvi Rb¨ 02 b¤^i| does not give haloform reaction.
†hЇMi IUPAC bvg ‡jLvi Rb¨ 02 b¤^i| 02 marks for writing the structure of the compound.
02 marks for writing the name of compound in IUPAC
bgybv †hŠMwUi Zxeª Rvi‡Y cÖvß cÖavb Drcv` 2𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 ‡jLvi
method.
Rb¨ 02 b¤^i| 02 marks for writing the major products obtained
2𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 from the strong oxidation of the sample
compound.
imvqb Chem
06 10
B_v‡bvwqK GwmW I wg_v‡bvwqK Gwm‡Wi cvi¯cwiK iƒcvšÍi †`LvI| Show the inter conversion between ethanoic acid & methanoic
acid.
B_v‡bvwqK GwmW †_‡K wg_v‡bvwqK GwmW: Ae‡ivn c×wZ- Ethanoic acid to methanoic acid: Descending method:
, ,
CH COOH ⎯⎯⎯⎯⎯ CH CONH ⎯⎯⎯⎯ CH NH CH COOH ⎯⎯⎯⎯⎯ CH CONH ⎯⎯⎯⎯ CH NH
∆ ∆ ∆ ∆
[ ] [ ] [ ] [ ]
⎯⎯ CH OH ⎯⎯⎯⎯ HCHO ⎯⎯⎯⎯ HCOOH. ⎯⎯ CH OH ⎯⎯⎯⎯ HCHO ⎯⎯⎯⎯ HCOOH.
wg_v‡bvwqK GwmW †_‡K B_v‡bvwqK GwmW: Av‡ivn c×wZ- Methanoic acid to ethanoic acid: Ascending method: