[1] Revision Sheet–3 / Chemistry (JEE Main)
JEE MAIN - 2025
Revision Sheet – 3
CHEMISTY
(Metal Complexes, Biomolecules, Practical Organic Chemistry,
Electronic Structure of Atoms, Periodic Properties)
Time : 2 Hrs.
Straight Objective Type Questions
1. Among the following metal carbonyls, the C – O bond length is the smallest in
(A) Mn CO 6 (B) Fe CO 5 (C) Cr CO 6 (D) V CO 6
2. Which of the following complex species is NOT expected to exhibit optical isomerism?
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(A) Co en 3 (B) Co en 2 Cl2
(C) Co NH3 3 Cl3 (D) Co en NH3 2 Cl2
3. Match the metals (Column I) with the coordination compound(s) / enzyme(s) (Column II).
Column I Column II
(A) Co (i) Wilkinson catalyst
(B) Zn (ii) Chlorophyll
(C) Rh (iii) Vitamin
(D) Mg (iv) Carbonic anhydrase
(A) (A) - (i), (B) - (ii), (C) - (iii), (D) - (iv) (B) (A) - (iv), (B) - (iii), (C) - (i), (D) - (ii)
(C) (A) - (iii), (B) - (iv), (C) - (i), (D) - (ii) (D) (A) - (ii), (B) - (i), (C)- (iv), (D) - (iii)
4. The octahedral complex of a metal ion M3+ with four monodentate ligands L1, L 2 , L3 and L 4
absorb wavelengths in the region of red, green, yellow and blue, respectively. The increasing
order of ligand strength of the four ligands is
(A) L 4 < L3 < L2 < L1 (B) L1 < L3 < L 2 < L 4
(C) L3 < L 2 < L4 < L1 (D) L1 < L 2 < L4 < L3
5. A solution containing 2.675 g of CoCl3 6 NH3 (molar mass = 267.5 g mol1 ) is passed through
a cation exchanger. The chloride ions obtained in solution were treated with excess of AgNO3 to
give 4.30 g of AgCl (molar mass 143.5g mol1 ). The formula of the complex is (At. mass of
Ag = 108 u)
(A) [Co(NH3 )6 ]Cl3 (B) [CoCl2 (NH3 )4 ]Cl (C) [CoCl3 (NH3 )3 ] (D) [CoCl(NH3 )5 ]Cl2
6. Geometrical shapes of the complexes formed by the reaction of Ni 2+ with Cl , CN and
H 2O, respectively, are
(A) octahedral, tetrahedral and square planar
(B) tetrahedral, square planar and octahedral
(C) square planar, tetrahedral and octahedral
(D) octahedral, square planar and octahedral
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[2] Revision Sheet–3 / Chemistry (JEE Main)
7. The hybridization of central metal ion and shape of Wilkinson’s catalyst is
(A) dsp 2 , square planar (B) sp3 , tetrahedral
(C) d 2sp3 , octahedral (D) sp3d, trigonal bipyramidal
8. The intense purple colour of MnO4 arises due to the absorption of visible light for
(A) promotion of electron from t 2g to eg orbital
(B) promotion of electron from eg to t 2g orbital
(C) d–d transition
(D) momentary transfer of electron from O 2 to metal Mn(VII) ion
9. Given below are two statements:
3 3 3
Statement-I : Mn CN 6 , Fe CN 6 and Co C2O 4 3 are d 2sp3 hybridized.
3 3
Statement-II : MnCl6 and FeF6 are paramagnetic and have 4 and 5 unpaired electrons,
respectively.
In the light of the above statements, choose the correct answer from the options given below:
(A) Statement-I is correct but statement-II is false.
(B) Both statement-I and statement-II are false.
(C) Statement-I is incorrect but statement-II is true.
(D) Both statement-I and statement-II are true.
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10. Pd F Cl Br I has n number of geometrical isomers. Then, the spin-only magnetic
n 6
moment and crystal field stabilization energy [CFSE] of Fe CN 6 respectively, are
[Note: Ignore the pairing energy]
(A) 1.73 BM and 2.0 0 (B) 2.84 BM and 1.6 0
(C) 0 BM and 2.4 0 (D) 5.92 BM and 0
11. Two complexes [Cr(H 2O)6 ]Cl3 (A) and [Cr(NH3 )6 ]Cl3 (B) are violet and yellow coloured,
respectively. The incorrect statement regarding them is
(A) 0 value of (A) is less than that of (B).
(B) 0 value of (A) and (B) are calculated from the energies of violet and yellow light,
respectively.
(C) Both absorb energies corresponding to their complementary colors.
(D) Both are paramagnetic with three unpaired electrons.
12. Three isomers A, B and C (mol. formula C8H11N ) give the following results:
R Product of A
Azotization i Hydrolysis
A and C P Q
ii Oxidation KMnO4 H
S Product of C
R has lower boiling point than [S]
C H SO Cl
6 5 2 alkali-insoluble product
B
A, B and C, respectively are
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[3] Revision Sheet–3 / Chemistry (JEE Main)
(A)
(B)
(C)
(D)
13. Hydrolysis of an ester gives acid A and alcohol B. The acid reduces Fehling’s solution.
Oxidation of alcohol B gives acid A. The ester is
(A) Methyl formate (B) Ethyl formate (D) Methyl acetate (D) Ethyl acetate
14. A compound 'A' having the molecular formula C5H12O, on oxidation gives a compound 'B' with
molecular formula C5H10O. Compound 'B' gave a 2, 4-dinitrophenylhydrazine derivative but did
not answer haloform test or silver mirror test. The structure of compound 'A' is
(A) CH3 – CH2 – CH2 – CH2 – CH2 – OH (B) CH3 CH 2 CH 2 CH CH3
|
OH
(C) CH 3 CH 2 CH CH 2 CH 3 (D) CH3 CH 2 CH CH 2 OH
| |
OH CH3
15. Compound (X) with molecular formula C3H8O is treated with acidified potassium dichromate to
form a product (Y) with molecular formula C3H6O. (Y) does not form a shining silver mirror on
warming with ammoniacal AgNO3. (Y) when treated with an aqueous solution of
NH2CONHNH2.HCl and sodium acetate, gives a product (Z). The structure of (Z) is
(A) CH3CH2CH = NNHCONH2 (B) (CH3)2C = NNHCONH2
(C) (CH3)2C = NCONHNH2 (D) CH3CH2CH = NCONHNH2
16. A compound (X) with a molecular formula C5H10O gives a positive 2, 4-DNP test but a negative
Tollen's test. On oxidation it gives a carboxylic acid (Y) with a molecular formula C3H6O2.
Potassium salt of (Y) undergoes Kolbe's reaction and gives a hydrocarbon (Z). (X), (Y) and (Z)
respectively are
(A) pentan-3-one, propanoic acid, butane
(B) pentanal, pentanoic acid, octane
(C) 2-methylbutanone, butanoic acid, hexane
(D) 2, 2-dimethylpropanone, propanoic acid, hexane
17. The product of acid hydrolysis of [P] and [Q] can be distinguished by:
(A) Lucas reagent (B) 2,4-DNP (C) Fehling’s solution (D) NaHSO3
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18. Which of the following amine will give the carbylamine test?
(A) (B) (C) (D)
19. Among the following, the incorrect statement is
(A) Cellulose and amylose has 1,4-glycosidic linkage
(B) Lactose contains D galactose and D glucose
(C) Maltose and lactose has 1,4–glycosidic linkage
(D) Sucrose and amylose has 1,2–glycosidic linkage
20. The term anomers of glucose refers to
(A) isomers of glucose that differ in configurations at carbons one and four (C-1 and C-4)
(B) a mixture of (D)-glucose and (L)-glucose
(C) enantiomers of glucose
(D) isomers of glucose that differ in configuration at carbon on (C-1)
21. Consider the following ionization enthalpies of two elements ‘A’ and ‘B’.
Element Ionization enthalpy (kj/mol)
1st 2nd 3rd
A 899 1757 14847
B 737 1450 7731
Which of the following statements is CORRECT?
(A) Both ‘A’ and ‘B’ belong to group-1 where ‘B’ comes below ‘A’.
(B) Both ‘A’ and ‘B’ belong to group-1 where ‘A’ comes below ‘B’.
(C) Both ‘A’ and ‘B’ belong to group-2 where ‘B’ comes below ‘A’.
(D) Both ‘A’ and ‘B’ belong to group-2 where ‘A’ comes below ‘B’.
22. Addition of an electron to a gas-phase Si atom results in the release of more energy than addition
of an electron to a gas-phase P atom. What is the best explanation for their relative electron
affinities?
(A) The electron added to Si experiences less electron-electron repulsion than the electron added
to P.
(B) The electron added to Si enters a lower-energy subshell than the electron added to P.
(C) Si is more electronegative than P.
(D) Si is smaller than P.
23. Which graph best describes the radial wave-function of 2p orbital?
(A) (B)
(C) (D)
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24. Consider the following four elements, which are represented according to long form of periodic
table
Here W, Y and Z are left, up and right elements with respect to the element ‘X’ and ‘X’ belongs
to 16th group and 3rd period. Then according to given information the incorrect statement
regarding given elements is
(A) Maximum electronegativity : Y (B) Lowest Ionisation energy : W
(C) Maximum electron affinity : Z (D) Highest atomic radius : W
25. The successive ionization energies (in kJ / mol) for an element are shown below.
E1 E2 E3 E4 E5
577 1820 2740 11600 14800
What is the electron configuration of this element?
(A) 1s 2 2s 2 2p6 3s1 (B) 1s 2 2s 2 2p6 3s 2 3p1 (C) 1s 2 2s 2 2p6 3s 2 3p3 (D) 1s 2 2s 2 2p6 3s 2 3p6 3d3
26. Consider the following reaction and statements
[Co(NH3 )4 Br2 ] Br [Co(NH3 )3 Br3 ] NH3
(I) Two isomers are produced if the reactant complex ion is a cis-isomer.
(II) Two isomers are produced if the reactant complex ion is a trans-isomer.
(III) Only one isomer is produced if the reactant complex ion is a trans-isomers.
(IV) Only one isomer is produced if the reactant complex ion is a cis-isomer.
The CORRECT statement are
(A) I and II (B) I and III (C) III and IV (D) II and IV
27. Which one of the following complexes is violet in colour?
4 4
(A) Fe CN 6 (B) Fe SCN 6
4
(C) Fe4 Fe CN 6 H 2 O (D) Fe CN 5 NOS
3
28. Match List-I with List-II.
List-I List-II
2
(A) PtCl4 (I) sp3d
(B) BrF5 (II) d 2sp3
(C) PCl5 (III) dsp 2
3
(D) Co NH3 6 (IV) sp3d 2
Choose the most appropriate answer from the options given below:
(A) (A)-(II), (B)-(IV), (C)-(I), (D)-(III) (B) (A)-(III), (B)-(IV), (C)-(I), (D)-(II)
(C) (A)-(III), (B)-(I), (C)-(IV), (D)-(II) (D) (A)-(II), (B)-(I), (C)-(IV), (D)-(III)
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29. The graph between | | 2 and r (radial distance) is shown below. This represents
(A) 1s-orbital (B) 2p-orbital (C) 3s-orbital (D) 2s-orbital
30. The spin only magnetic moments (in BM) for free Ti3 , V 2 and Sc3 ions respectively are
[At.No. Sc = 21, Ti = 22, V = 23]
(A) 3.87, 1.73, 0 (B) 1.73, 3.87, 0 (C) 1.73, 0, 3.87 (D) 0, 3.87, 1.73
31. Element 'E' belongs to the period 4 and group 16 of the periodic table. The valence shell electron
configuration of the element, which is just above 'E' in the group is
(A) 3s 2 , 3p 4 (B) 3d10 , 4s 2 , 4p4 (C) 4d10 , 5s 2 , 5p4 (D) 2s 2 , 2p 4
32. The energy of electron in an excited hydrogen atom is –3.4 eV. Its angular momentum according
to Bohr's theory will be
h h 3h 3
(A) (B) (C) (D)
2 2 2h
33. The CORRECT decreasing order of energy, for the orbitals having, following set of quantum
numbers:
(i) n 3, 0, m 0 (ii) n 4, 0, m 0
(iii) n 3, 1, m 0 (iv) n 3, 2, m 1
(A) (iii) > (ii) > (iv) > (i) (B) (ii) > (iv) > (iii) > (i)
(C) (iv) > (ii) > (iii) > (i) (D) (ii) > (iii) > (iv) > (i)
34. The first and second ionisation enthalpies of a metal are 496 kJ mol1 and 4560 kJ mol1 ,
respectively. How many moles of HCl and H 2 SO 4 , respectively, will be needed to react
completely with 1 mole of the metal hydroxide?
(A) 1 and 0.5 (B) 2 and 0.5 (C) 1 and 1 (D) 1 and 2
35. The electron gain enthalpy (in kJ / mol) of fluorine, chlorine, bromine and iodine, respectively are
(A) –349, –333, –325 and –296 (B) –296, –325, –333 and –349
(C) –333, –325, –349 and –296 (D) –333, –349, –325 and –296
36. What must be the ratio of kinetic energies of a free proton & a free particle for them to have
the same de Broglie wavelength?
(A) 1 : 2 (B) 1 : 4 (C) 2 : 1 (D) 4 : 1
37. Consider the elements Mg, Al, S, P and Si, the CORRECT increasing order of their first
ionization enthalpy is
(A) Mg < Al < Si < S < P (B) Al < Mg < Si < S < P
(C) Mg < Al < Si < P < S (D) Al < Mg < S < Si < P
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38. A polysaccharide 'X' on boiling with dil. H 2SO 4 at 393 K under 2-3 atm pressure yields 'Y'. 'Y'
on treatment with bromine water gives gluconic acid. 'X' contains glycosidic linkages only.
Compound 'X' is
(A) Starch (B) Cellulose (C) Amylose (D) Amylopectin
39. The process that is NOT endothermic in nature is
(A) Ar g e Ar g (B) Na g Na g e
(C) H g e H g (D) O g e O 2 g
40. The atomic number of the element unnilennium is
(A) 108 (B) 109 (C) 102 (D) 119
Non-negative Integer Type Questions
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41. The number of chiral stereoisomers of FeBr NH3 ox 2 is _______ .
42. The coordination number of Th in K 4 [Th(C2O 4 )4 (OH 2 )2 ] is ________. C2O42 = Oxalato
3
43. The absorption spectrum of Ti H 2O 6 shows a single broad peak with a maximum at
20, 000cm 1. The magnitude of crystal field stabilization energy of the complex is __________
kJ / mol. [Use: hc 1250 eV nm, N A 6.0 1023 mol1 ]
44. Incident photons strike a sodium surface having a work function of 2.28 eV, causing a
photoelectric emission. When a stopping potential of 3.92 V is imposed, there is no photocurrent.
The wavelength of the incident photon is ________nm (Take hc = 1240 eV.nm)
45. Among the following, the number of atoms having higher electron affinity than a nitrogen (N)
atom is _______ .
Li Be B C O
F Si P S
46. The number of orbitals in 5th shell that have no radial nodes is _______.
47. Among the following, the number of species exhibiting mutarotation is
glucose fructose maltose lactose sucrose
galactose cellulose amylose amylopectin
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48. Fe CN 6 should be an inner orbital complex. Ignoring the pairing energy, the value of crystal
field stabilization energy for this complex is ______ 0 (round off to the nearest integer).
49. A tetrapeptide has –COOH groups on alanine. This produces glycine (Gly), valine (Val), phenyl
alanine (Phe) and alanine (Ala), on complete hydrolysis. For this tetrapeptide, the number of
possible sequences (primary structures) with NH 2 group attached to a chiral center is_____.
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50. Number of compounds from the following which will not produce orange red precipitate with
Benedict solution is _______.
glucose, maltose, sucrose, ribose, 2-deoxyribose, amylose, lactose.
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Revision Sheet 03 (Answer Key)
(Chemistry)
1. (A) 2. (C) 3. (C) 4. (B) 5. (A) 6. (B) 7. (A) 8. (D) 9. (D) 10. (A)
11. (B) 12. (A) 13. (A) 14. (C) 15. (B) 16. (A) 17. (C) 18. (C) 19. (D) 20. (D)
21. (C) 22. (A) 23. (A) 24. (B) 25. (B) 26. (B) 27. (D) 28. (B) 29. (D) 30. (B)
31. (A) 32. (A) 33. (C) 34. (A) 35. (D) 36. (D) 37. (B) 38. (B) 39. (C) 40. (B)
41. (2) 42. (10) 43. (96) 44. (200) 45. (8) 46. (9) 47. (5) 48. (2) 49. (4) 50. (2)
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