Safety Data Sheet according GB/T
16483-2008
Diresul Black RDT-2KS liq Page 1(12)
Substance key: KS16023 Revision Date: 29.09.2023
Version : 3 - 0 / CHI Date of printing : 10.12.2023
1) Chemical Product and Enterprise Logo
Trade name
Diresul Black RDT-2KS liq
Material number: 102705
Intended use of the product
Industry sector: Textile processing industry
Type of use: textile dye
Identification of the company
Archroma Ibérica, Sociedad Limitada
ZAL - Prat, c/ Cal Coracero, 46-56
8820 El Prat de Llobregat (Barcelona)
Telephone no. : +34 93 479 82 00
Information about the substance/preparation
Product Stewardship +34 93 479 82 00
E-mail:
[email protected] Emergency telephone number: +86 10 5100 3039
2) Hazard Summary
Main physical and chemical hazard information
GHS hazard class(es)
The product is classified and labelled in accordance with GHS regulation and the relevant
national laws.
Skin corrosion/irritation Category 1B
GHS labeling UN
The product is classified and labelled in accordance with GHS regulation and the relevant
national laws.
Symbols
Corrosion
Signal word
Danger
Hazard statements
Causes severe skin burns and eye damage.
Contact with acids liberates toxic gas.
Precautionary statements
Wear protective gloves/eye protection/face protection.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
Safety Data Sheet according GB/T
16483-2008
Diresul Black RDT-2KS liq Page 2(12)
Substance key: KS16023 Revision Date: 29.09.2023
Version : 3 - 0 / CHI Date of printing : 10.12.2023
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Additional information
No additional hazards are known except those derived from the labelling.
3) Ingredient/Composition information
Product type: Mixture
Chemical characterization
sulfur dyestuff
anionic
Hazardous ingredients China:
Chemical name or generic name CAS-number Concentration or
concentration scope
Sodium hydroxide 1310-73-2 2-4%
Sodium sulphide 1313-82-2 3-5%
Hazardous ingredients GHS:
Chemical name or generic name CAS-number Concentration or
concentration scope
Sodium hydroxide 1310-73-2 2-4%
Sodium sulphide 1313-82-2 3-5%
4) First-aid Measures
General information
In case of accident or if you feel unwell, seek medical advice immediately.
After inhalation
Remove the casualty from the affected area to fresh air. Keep casualty warm and still..
In case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible).
After contact with skin
Remove contaminated clothes, under clothes and shoes immediately.
In case of contact with skin wash off immediately with soap and water
Consult a doctor if skin irritation persists.
After contact with eyes
Immediately rinse eyes thoroughly with running water. Take injured quickly to factory medical
center or call an ambulance (code word: eye accident).
After ingestion
If swallowed, wash mouth with plenty of water. Take patient to physician/factory medical
centre or call for an ambulance.
Advice to doctor
Hazards
The possible risks known are those derived from the labelling (see section 2).
Safety Data Sheet according GB/T
16483-2008
Diresul Black RDT-2KS liq Page 3(12)
Substance key: KS16023 Revision Date: 29.09.2023
Version : 3 - 0 / CHI Date of printing : 10.12.2023
Treatment
Treat symptomatically.
5) Fire Safety Measures
Suitable extinguishing media
all
Extinguishing media that must not be used for safety reasons
No restrictions
Special hazards from the substance itself, its combustion products or from its vapours
carbon oxides
nitrogen oxides
sulfur oxides
Special protective equipment for firefighting
Use self-contained breathing apparatus
Further information
This product is not combustible
Closed containers involved in a fire must to be cooled by water spray.
Remove material from the area if can be done without risk.
6) Leak Emergency Treatment
Personal precautions
Wear personal protective equipment. Unprotected persons must be kept away.
Keep people away and stay on the upwind side.
Environmental precautions
Do not allow entry to drains,water courses or soil
Methods for cleaning up/taking up
Take up with absorbent material (eg sand, kieselguhr, universal binder)
Dispose of absorbed material in accordance with the regulations.
Additional information
Information regarding Safe handling, see chapter 7.
Information regarding personal protective measures see, chapter 8.
Information regarding Waste Disposal, see chapter 13.
7) Operation, Disposal and Storage
Advice on safe handling
Keep container tightly closed.
If any hydrogen sulfide (H2S) is detected during use of the product, evacuate the workplace
to a very well-ventilated area and call the Emergency Response Team.
Advice on protection against fire and explosion
Keep away from sources of ignition
Advice on storage compatibility
Store separately from acids and oxidizing products in order to minimize the risk of reaction in
a possible leak.
Safety Data Sheet according GB/T
16483-2008
Diresul Black RDT-2KS liq Page 4(12)
Substance key: KS16023 Revision Date: 29.09.2023
Version : 3 - 0 / CHI Date of printing : 10.12.2023
Further information on storage conditions
Keep container tightly closed
Keep only in the original container in a cool, well ventilated place
8) Exposure Control and Individual Protection
Ingredients with occupational exposure limits to be monitored
Sodium hydroxide
CAS number : 1310-73-2
Occupational exposure limits for hazardous agents in the workplace - Chemical hazardous
agents.
China. Occupational Exposure Limit for Hazardous Agents in the Workplace.
Revision : : 2007-04-27
Maximum allowable concentration
Values: 2 mg/m3
General protective measures
Observe the usual precautions for handling chemicals.
Hygiene measures
Avoid contact with skin and eyes.
Develops in contact with acids very toxic gases.
Always work in a well-ventilated area; ensure that all packages and equipment where the
dyes will be used are clean and free of contamination with undesired substances, particularly
acids.
Hand protection : Gloves (alkali-resistant)
Observe the information of the glove manufacturers on
permeability and breakthrough times and other workplace
requirements
Eye protection : tightly fitting safety goggles
Body protection : Alkali-resistant protective clothing
9) Physical and Chemical Properties
Physical state/shape : aqueous solution
Color : black
Smell : yes
pH value : 12 - 14
Melting point : not applicable
Boiling point : app. 100 °C
Flash point : no flash point up to the boiling point
Lower explosion limit : Not applicable
Upper explosion limit : Not applicable
Vapour pressure : not tested.
Safety Data Sheet according GB/T
16483-2008
Diresul Black RDT-2KS liq Page 5(12)
Substance key: KS16023 Revision Date: 29.09.2023
Version : 3 - 0 / CHI Date of printing : 10.12.2023
Density : 1.4 g/cm3 (20 °C)
Solubility in water : miscible
n-Octanol/water partition This property is not applicable for mixtures.
coefficient (log Pow) :
Self-ignition temperature : There is no information which suggests that the product is
pyrophoric.
Thermal decomposition : not tested.
Viscosity (dynamic) : 50 - 100 mPa.s (20 °C)
Further information
Incompatible substances: Acids.
10) Stability and Reactvity
Chemical stability:
Under normal conditions the product is stable.
Hazardous reactions
With acids, release of hydrogen sulfide (H2S).
Conditions to be avoided
Avoid contact with acids and oxidizing agents.
Incompatible substances
See under section "Conditions to avoid"
Dangerous decomposition products
When used and handled as intended, none.
11) Toxicological Information
Information related to the product itself:
Acute oral toxicity : LD50 > 2,000 mg/kg (rat)
Method : test result of a related preparation.
Skin irritation or corrosion : corrosive
Method : evaluation based on the high pH-value
Eye irritation or corrosion : serious eye damages
Method : evaluation based on the high pH-value
Respiratory or skin allergies : not tested.
Germ cell mutation : not tested.
Reproductive toxicity : not tested.
Specific target organ toxicity Remarks: not tested.
- a one-time exposure (STOT -
single exposure) :
Specific target organ toxicity Remarks: not tested.
- repeated exposure (STOT -
repeated exposure) :
Safety Data Sheet according GB/T
16483-2008
Diresul Black RDT-2KS liq Page 6(12)
Substance key: KS16023 Revision Date: 29.09.2023
Version : 3 - 0 / CHI Date of printing : 10.12.2023
Hazardous ingredients China:
Information related to the component: Sodium sulphide
Acute oral toxicity : LD50 939 - 1,342 mg/kg (rat)
Method : OECD Guide-line 401
Source : European Chemicals Agency (ECHA)
Acute inhalation toxicity : Not applicable
Acute dermal toxicity : Study not performed as the substance is corrosive.
Skin irritation or corrosion : corrosive
Based on pH
Eye irritation or corrosion : corrosive
Based on pH
Respiratory or skin allergies : Study not performed as the substance is corrosive.
Germ cell mutation : It is concluded that the product is not mutagenic based on
evaluation of several mutagenicity tests.
Carcinogenicity : Carcinogenicity classification not possible from current data.
Reproductive toxicity : No teratogenic effects to be expected.
Specific target organ toxicity Remarks: Based on available data, the classification
- a one-time exposure (STOT - criteria are not met.
single exposure) :
Specific target organ toxicity Remarks: Based on available data, the classification
- repeated exposure (STOT - criteria are not met.
repeated exposure) :
Repeated dose toxicity : Repeated Dose Toxicity (subchronic study)
Route of application: Oral
The study is not necessary from a scientific perspective.
Repeated dose toxicity : Repeated Dose Toxicity (subchronic study)
Route of application: inhalation
NOAEL: 14 mg/m3 (90 d, Rats)
Method : other
Information relate to hydrogen sulfide.
Source : literature
Repeated dose toxicity : Repeated Dose Toxicity (subchronic study)
Route of application: dermal
The study is not necessary from a scientific perspective.
Inhalation hazard :
Data for aspiration toxicity are not available.
Remarks
Poisoning affects the central nervous system
Hazardous ingredients GHS:
Information related to the component: Sodium sulphide
Acute oral toxicity : LD50 939 - 1,342 mg/kg (rat)
Method : OECD Guide-line 401
Source : European Chemicals Agency (ECHA)
Safety Data Sheet according GB/T
16483-2008
Diresul Black RDT-2KS liq Page 7(12)
Substance key: KS16023 Revision Date: 29.09.2023
Version : 3 - 0 / CHI Date of printing : 10.12.2023
Acute inhalation toxicity : Not applicable
Acute dermal toxicity : Study not performed as the substance is corrosive.
Skin irritation or corrosion : corrosive
Based on pH
Eye irritation or corrosion : corrosive
Based on pH
Respiratory or skin allergies : Study not performed as the substance is corrosive.
Germ cell mutation : It is concluded that the product is not mutagenic based on
evaluation of several mutagenicity tests.
Carcinogenicity : Carcinogenicity classification not possible from current data.
Reproductive toxicity : No teratogenic effects to be expected.
Specific target organ toxicity Remarks: Based on available data, the classification
- a one-time exposure (STOT - criteria are not met.
single exposure) :
Specific target organ toxicity Remarks: Based on available data, the classification
- repeated exposure (STOT - criteria are not met.
repeated exposure) :
Repeated dose toxicity : Repeated Dose Toxicity (subchronic study)
Route of application: Oral
The study is not necessary from a scientific perspective.
Repeated dose toxicity : Repeated Dose Toxicity (subchronic study)
Route of application: inhalation
NOAEL: 14 mg/m3 (90 d, Rats)
Method : other
Information relate to hydrogen sulfide.
Source : literature
Repeated dose toxicity : Repeated Dose Toxicity (subchronic study)
Route of application: dermal
The study is not necessary from a scientific perspective.
Inhalation hazard :
Data for aspiration toxicity are not available.
Remarks
Poisoning affects the central nervous system
12) Ecological Information
Information related to the product itself:
Fish toxicity : LC50 > 100 mg/l (48 h, rainbow trout (salmo gairdneri,
oncorhynchus mykiss))
Method : test result of a related preparation.
Persistency and degradation app. 100 % (TOC)
(Biodegradability) : Method : OECD 302B * 1981 Mod. Zahn-Wellens (inherent)
By analogy with a similar product.
Safety Data Sheet according GB/T
16483-2008
Diresul Black RDT-2KS liq Page 8(12)
Substance key: KS16023 Revision Date: 29.09.2023
Version : 3 - 0 / CHI Date of printing : 10.12.2023
Potential biological not tested.
accumulation :
Relocation in soil (Transport
between environment
compartiments) :
Chemical oxygen demand 525 mg/g
(COD) :
Biochemical oxygen demand 31 mg/g
(BOD5) : 5d
Bacteria toxicity : IC50 > 100 mg/l (activated sludge)
Method : test result of a related preparation.
Behaviour in environmental compartments
No known data.
Remarks
Product does not contain any organic bound Halogens which could lead to AOX-values.
Hazardous ingredients China:
Information related to the component: Sodium sulphide
Fish toxicity : LC50 0.0027 mg/l (96 h)
Method : OECD 203
Source : literature
Daphnia toxicity : LC50 0.032 - 0.085 mg/l (96 h, Penaeus indicus)
Method : EPA
Source : literature
Algae toxicity : NOEC (growth rate) 0.77 mg/l (4 h, Skeletonema costatum)
Method : OECD 201
Source : literature
LOEC (growth rate) 1.6 mg/l (4 h, Skeletonema costatum)
Method : OECD 201
Source : literature
EC50 (growth rate) 1.5 mg/l (4 h, Skeletonema costatum)
Method : OECD 201
Source : literature
Persistency and degradation not applicable
(Physico-chemical
eliminability) :
Persistency and degradation Inorganic product, cannot be eliminated from the water by
(Biodegradability) : biological purification processes.
Potential biological Accumulation in aquatic organisms is unlikely.
accumulation :
Relocation in soil (Transport Type: adsorption
between environment Not applicable
compartiments) :
Safety Data Sheet according GB/T
16483-2008
Diresul Black RDT-2KS liq Page 9(12)
Substance key: KS16023 Revision Date: 29.09.2023
Version : 3 - 0 / CHI Date of printing : 10.12.2023
Chemical oxygen demand not available
(COD) :
Biochemical oxygen demand not available
(BOD5) :
Bacteria toxicity : EC50 14 mg/l (72 h, Entosiphon sulcatum)
Method : other
Source : literature
Behaviour in environmental compartments
not available
Remarks
Do not allow to enter soil, waterways or waste water
Hazardous ingredients GHS:
Information related to the component: Sodium sulphide
Fish toxicity : LC50 0.0027 mg/l (96 h)
Method : OECD 203
Source : literature
Daphnia toxicity : LC50 0.032 - 0.085 mg/l (96 h, Penaeus indicus)
Method : EPA
Source : literature
Algae toxicity : NOEC (growth rate) 0.77 mg/l (4 h, Skeletonema costatum)
Method : OECD 201
Source : literature
LOEC (growth rate) 1.6 mg/l (4 h, Skeletonema costatum)
Method : OECD 201
Source : literature
EC50 (growth rate) 1.5 mg/l (4 h, Skeletonema costatum)
Method : OECD 201
Source : literature
Persistency and degradation not applicable
(Physico-chemical
eliminability) :
Persistency and degradation Inorganic product, cannot be eliminated from the water by
(Biodegradability) : biological purification processes.
Potential biological Accumulation in aquatic organisms is unlikely.
accumulation :
Relocation in soil (Transport Type: adsorption
between environment Not applicable
compartiments) :
Chemical oxygen demand not available
(COD) :
Biochemical oxygen demand not available
(BOD5) :
Safety Data Sheet according GB/T
16483-2008
Diresul Black RDT-2KS liq Page 10(12)
Substance key: KS16023 Revision Date: 29.09.2023
Version : 3 - 0 / CHI Date of printing : 10.12.2023
Bacteria toxicity : EC50 14 mg/l (72 h, Entosiphon sulcatum)
Method : other
Source : literature
Behaviour in environmental compartments
not available
Remarks
Do not allow to enter soil, waterways or waste water
13) Waste Disposal
Residual wastes
Reuse according to instructions of the plant manager or ask supplier.
Contaminated container and package
Consider recycling.
Packaging that cannot be cleaned should be disposed of as product waste
In case of disposal, the chemical elements contained in the preparation have to be
considered.
For disposal local regulation is binding.
14) Transport Information
Safety Data Sheet according GB/T
16483-2008
Diresul Black RDT-2KS liq Page 11(12)
Substance key: KS16023 Revision Date: 29.09.2023
Version : 3 - 0 / CHI Date of printing : 10.12.2023
IATA
Proper shipping name: Dye, liquid, corrosive, n.o.s., mixture
Class: 8
Packing group: III
UN/ID number: UN 2801
Primary risk: 8
Remarks: Shipment permitted
Hazard inducer(s): Sodium Sulphide
SODIUM HYDROXIDE SOLUTION
IMDG
Proper shipping name: Dye, liquid, corrosive, n.o.s., mixture
Class: 8
Packing group: III
UN no.: UN 2801
Primary risk: 8
Remarks: Shipment permitted
Hazard inducer(s): Sodium Sulphide
SODIUM HYDROXIDE SOLUTION
EmS: F-A S-B
ADR
Proper shipping name: Dye, liquid, corrosive, n.o.s., mixture
Class: 8
Packing group: III
UN no.: UN 2801
Primary risk: 8
Hazard no. : 80
Remarks: Shipment permitted
Hazard inducer(s): Sodium Sulphide
SODIUM HYDROXIDE SOLUTION
RID
Proper shipping name: Dye, liquid, corrosive, n.o.s., mixture
Class: 8
Packing group: III
UN no.: UN 2801
Primary risk: 8
Hazard no. : 80
Remarks: Shipment permitted
Hazard inducer(s): Sodium Sulphide
SODIUM HYDROXIDE SOLUTION
15) Information on Laws and Regulations
Regulatory information China
GB 13690-2009 : General rule for classification and hazard communication of chemicals.
GB 20576 - 20599, GB 20601-20602: Safety rules for classification, precautionary labelling
and precautionary statements of chemicals.
Decree No. 591 of the State Council of the People’s Republic of China: Regulations on the
Control over Safety of Hazardous Chemicals.
GB 6944-2012: Classification and code of dangerous goods.
GB 12268-2012: List of dangerous goods.
GB 190-2009: Packing symbol of dangerous goods.
Safety Data Sheet according GB/T
16483-2008
Diresul Black RDT-2KS liq Page 12(12)
Substance key: KS16023 Revision Date: 29.09.2023
Version : 3 - 0 / CHI Date of printing : 10.12.2023
16) Other information
The data are based on the current state of our knowledge, and are intended to describe the
product with regard to the requirements of safety. The data should not be taken to imply
any guarantee of a particular or general specification. It is the responsibility of the user of
the product to ensure to his satisfaction that the product is suitable for the intended purpose
and method of use. We do not accept responsibility for any harm caused by the use of this
information.In all cases, our general conditions of sale apply.
