[l=] MARANDA HIGH SCHOOL LX The Kenya Certificate of Secondary Education MOCK FORM 4 233/3 Chemistry (PRACTICAL) Paper 3 JUNE, 2024 Time: 2 Hours 15 Minutes Stream: Adm No: 23323 Ch PP3- Practical Wed, 28 June, 2024 Morning Time: 7.00-9.15am Instructions to Candidates a) Write your name and Admission number in the spaces provided above. b) Sign and write the date of examination in the spaces provided above ©) Answer ALL the questions in the spaces provided below each question. @ You are NOT allowed to start working with the apparatus for the first 15 minutes of the 2% hours allowed for this paper. This time is to enable you to read the question paper and make sure you have all the apparatus and chemicals that you may need. ©) All working MUST be clearly shown where necessary ) Mathematical tables and silent non-programmed electronic calculators may be used. For Examiner's Use Only ‘QUESTION MAXIMUM SCORE, CANDIDATES SCORE i 20 2 08 3 2 “TOTAL SCORE 40 ~ 23/3: Chemistry PP3—Theory ©The Maranda High School Mock ~ 20241. You are provided with: © Solid A, 0.3g, Magnesium metal Solution B, Hydrochloric acid * Solution C, 0.15M sodium carbonate © Methyl orange indicator ‘You are required to determine the: « Enthalpy change,AH per mole, of the reaction between magnesium metal and excess hydrochloric aci * Concentration in moles per litre of hydrochloric acid, solution B Procedure I i) Using a burette, measure 50.0cm* of solution B and place it in a 100m! plastic beaker. ii) Measure the temperature of solution B in the beaker after every 30 seconds and record it in table I below. iii) At the 90 * second, add all the solid A provided into the beaker, stir with the thermometer and continues measuring and recording the temperature after every 30 seconds and complete table I. Retain the mixture in the beaker for use in procedure II. Table I Time(seconds) 0 30 | 60 90 120 150 180 | 210 | 240 | 270 Temperature °C) (3marks) cr-\ (©The Maranda High Schoo! Mock ~2024 23/3: Chemistry PP3- Theory3 a) Plot a graph of temperature (vertical axis) against time on the grid provided (marks) b) Determine the change in temperature,AT, for the reaction. (Imark) Loedh.Reain | : c)Calculate the heat change, in Joules, for the reaction. (Assume that for the solution, specific heat capacity is 4.2J/g/K and density is 1.0 gem?) (1 mark) d)The relative atomic mass of magnesium is 24.0. Calculate the enthalpy change,AH,of the reaction per mole of magnesium. a. / Moles = ee O-o1z5 males (1 mark) \“ — Ans Ars n@ mit wkd 233/3: Chemistry PP3— Theory ©The Maranda High School Mock — 2024 cv ve “oy and g kal mol )Procedure II (Fill the burette with 0.1 5M sodium carbonate, solution C aker from procedure | into 250 ml volumetric flask. Add more ske thoroughly. Label the mixture solution D (ii) Place all the mixture in the b distilled water to the mark and sl j) Pipette 2Sem* of solution D into a 250 ml conical flask and add 2 drops of methyl orange indicator. (iv) Titrate solution D in the conical flask with the sodium carbonate, solution C and record the reading in table II below (v) Repeat steps(iii) and(iv) and complete table IT Table I i) u | i | | \ | ° =a -\ °- { Final burette reading (cm*) Initial burette reading (cm>) | | | nDprg - "= Volume of solution C used (em*) 7 L - || adel (4 markyOD_ (a)Determine the average volume of solution C, used. (1 mark) (b)Calculate the number of ‘moles of: (i) Sodium carbonate used, solution C (1 mark) QISA/ VE (ii) Hydrochloric acid in the 25.0cm? of solution D . (1 mark) = Ans in. Peoedue, TE bit Corrar.... Ans.va—.. 23/3: Chemistry PP3- Theory ©The Maranda High School Mock ~ 20245 (iii) Hydrochloric acid in the 250cm} of solution D (1 mark) 25K Ams we b6d.09...10.%.Ans ws nn bi 25 =. Coned.. Ans vs. = Conve ns (©) Calculate the total number of moles of hydrochloric in the 50.0em? of solution B_ (1 mark) A (a) Determine the concentration of hydrochlori in moles per {jre, in solution B_ (1 mark) = CorrentAas in (C) above i 5o Casseck. Ana is ; seer -orannits: 5 3. You are provided withgolid B. Carry out the following tests and record your ‘observation and inferences in the spaces provided. Divide solid E into four portions. (i) Place the first portion of solid E ina spatula and Ignite it. Tnferences Observations Bums with a elles ys) bee \ Sloe (mark) (mark) (ii) Place the second portion of solid E in test tube. Add about 2cm? of aqueous sodium hydroxide and shake. Observations inferences Disselve4o Serna ColoulesA LC mpc | Solu R-COOH | a _ (mark) | (mark) | 233/3: Chemistry PP3 - Theory ©The Maranda High Schoo! Mock ~ 20246 (iii) Place the third portion of solid E in a test tube, Add about 2em? of distilled water, Heat the mixture and add three drops of acidified potassium manganate (VI), servations Racgle de al 0 Jassivn ra anule Vif) remains oS not Gren fo Cloull (iv) Place the fourth por mixture and add all the 3.You are provided with solic inferences in the spaces provided. (a)Place all the sold F in a boiling tube, Add about 10cm? of distilled wat (mark) Ein a test tube. Add about 2cm! of distilled water. Heat the m hydrogen carbonate provided. Inferences: \ Cat -CEC \ fy 4 a ent (mark) | ! ie Inferences | R-coon paint V1 _(marky your observations and following tests and v Shake well and filter. Divide the filtrate into three portions and keep the residue for use in part (b). (a) (i) To the fir: (ii) To the second portion add three drops of lg nitric(V) acid. 23/3: Chemistry PP3— Theory ©The Maranda I st portion add aqueous sodium hydroxide deop [ Observati Nike presi insoluble wy @Xless ake °§ “he Oud” __(imark) : until in excess. a wie for FllON aaa eontadld itty dom? of dilute Jn School Mock = 20247 (iii)_To the third portion add ammonia solution dropwise until excess, Observations Inferences [White pacipitede wseluble Ma* past VM! in Q@xcess. - | Q enllcpie Jgrlk Gre ay Corded fm marry | 4 Su Aral (make (b) Place the residue in (a) above in a boiling tube and add BEN caine nitric (V) acid. Retain the mixture for the tests below: (i)To 2cm’ of the solution, add sodium hydroxide solution dropwise until in excess. Inferences _ Zt Al pu Present Bins Ge Ale a (mark) Qums ee yl (male a — Om (ii)To 2cm} of the solution, add three drops of sulphuric (V1) a dank [F< pee Cubed ame £ mak “4 Observations Tnferences No white Peripeke re Zant ee t No bubbles 6s & yas ve *, $03 ~ abide Zz _ (1 mark) re ot, a ~__(Imark) i)To Jem? of the solution, add ammonia solution dropwise until 2 excess. Observations - Inferences ke pv My v0 ( 4 ore uf saa Zn pest” | (i mark) a =: THIS IS THE LAST PRINTED PAGE 233/3: Chemistry PP3— Theory ©The Maranda High School Mock ~ 2024