Electrical Analysis of Graphene
Electrical Analysis of Graphene
Abstract The project investigates the identification of graphene through electroanalysis using results from the work
of Sir Andre Geim. The research uses Geim's technology to extract graphene from graphite and focuses on further
testing of the resulting structure. This method involves fine processing to separate the graphene layers, ensuring
that its unique electrical properties are preserved. Measurement applications include measurements of paper work
and work in order to establish a relationship between these parameters and the presence of graphene. The main
aim is to verify the effectiveness of the Geim method to ensure the electronic properties of graphene. These studies
aim to shed light on cost effective and scalable graphene production methods that can be used in electronics and
nanotechnology. The results from this research could have a significant impact on the industry, which relies on
products with excellent electrical properties and making the graphene process easier and more efficient. Finally,
this research aims to bridge the gap between laboratory experiments and practical applications and contribute to
high-level data studies.
Graphene, a single sheet of carbon atoms arranged in a hexagonal lattice, is widely regarded as a
revolutionary material due to its exceptional properties.
Focus on Graphene highlights its high electrical and thermal conductivity, mechanical strength,
and promising applications in fields like electronics, energy storage, and biomedicine【3】. In
industrial contexts, graphene's potential as an electromagnetic shielding material is noted for its
electrical conductivity and radiation absorption capabilities, positioning it as a candidate for
advanced shielding solutions in electronics and telecommunications【4】. The aromaticity of
graphene, rooted in π-electron delocalization, underpins its stability and conductivity, which are
crucial for designing new materials【5】.
Transmission electron microscopy (TEM) has been pivotal in characterizing graphene’s structure,
clarifying its atomic arrangement, and identifying defects through advanced imaging techniques【
6】. Research on graphene's intrinsic diamagnetism under varying field and temperature
conditions provides insights into magnetic sensing and levitation applications【7】. Furthermore,
graphene’s optical transparency, influenced by the fine structure constant, is explored for
applications in transparent conductive films and photonic devices【8】【9】.
The mechanical properties of graphene, including its strength and elasticity, are crucial for
structural materials, composites, and flexible electronics【10】【11】. Surface studies focus on
the adsorption behavior of thin carbon foils, aiding understanding of graphene's surface
characteristics【12】. Historical works like Brodie's atomic weight study of graphite and Debije
and Scherrer’s diffraction patterns laid the groundwork for graphene research【22】【23】.
The development of X-ray crystallography by Friedrich and Hull provided critical insights into
graphite’s atomic structure, furthering the understanding of carbon-based materials【24】【25】
. Kohlschütter and Haenni’s studies on graphitic carbon and graphitic acid advanced early
investigations into carbon allotropes, paving the way for graphene research【26】.
Geim and Novoselov’s Nobel Prize recognition underscores the revolutionary significance of their
work【15】【14】. Their discovery catalyzed market interest in graphene's commercial
production【16】. The IUPAC's standardized graphene definition ensures scientific coherence【
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18】. Future directions emphasize graphene's role in electronics, photonics, and energy storage,
with scalable production methods like silicon carbide synthesis gaining attention【20】【21】.
Comprehensive resources, such as Focus on Graphene, compile critical data for researchers and
engineers, while foundational studies, from X-ray interference phenomena to chemical
investigations of graphitic derivatives, continue to underpin the exploration of graphene's
remarkable properties【3】【17】【24】【26】.
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Procedure for Graphene Extraction and Conductivity
Analysis
Preparation of Substrate
A clean, smooth substrate such as glass slides, silicon wafers, or polymer sheets is prepared to
ensure uniform graphite deposition.
A 2V battery is connected to the graphene sample via leads. The multimeter probes are
positioned across the patch to measure electrical resistance. Multiple readings are taken for
accuracy.
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This process provides insights into graphene’s structural and electrical properties while
identifying areas for improvement in the methodology.
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Result
Graphene, a single layer of carbon atoms in a honeycomb lattice, exhibits extraordinary electrical
conductivity (~4000 Wm−1 K−1), surpassing conventional materials like graphite (~600 Wm−1
K−1). This unique property makes graphene promising for applications in electronics and energy
storage.
In this experiment, a 2V battery was used to apply a potential across graphene patches, and
conductivity was measured using a multimeter. However, the results showed no significant
variations in conductivity, likely due to the small size of the monolayer graphene patches produced
via the cello tape method.
Size Limitations: Small patches may not exhibit graphene's intrinsic conductivity due to defects,
impurities, and boundary effects.
Measurement Sensitivity: The battery and multimeter setup may lack the precision to detect subtle
changes at the atomic level.
Contaminants: Adhesive residue or impurities on the graphene surface could introduce resistance,
masking true conductivity.
These findings highlight the need for improved extraction and characterization techniques.
Advanced methods are essential for accurately exploring graphene's electrical properties and
leveraging its potential in practical applications.
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References
1. "graphene definition, meaning – what is graphene in the British English Dictionary &
Thesaurus – Cambridge Dictionaries Online". cambridge.org.
2. Geim, A. K.; Novoselov, K. S. (26 February 2007). "The rise of graphene". Nature
Materials. 6 (3): 183–191. arXiv:cond-mat/0702595. Bibcode:2007NatMa...6..183G.
doi:10.1038/nmat1849. PMID 17330084. S2CID 14647602.
3. Peres, N. M. R.; Ribeiro, R. M. (2009). "Focus on Graphene". New Journal of Physics. 11
(9): 095002. Bibcode:2009NJPh...11i5002P. doi:10.1088/1367-2630/11/9/095002.
4. [1] "Carbon nanostructures for electromagnetic shielding applications", Mohammed Arif
Poothanari, Sabu Thomas, et al., Industrial Applications of Nanomaterials, 2019. "Carbon
nanostructures include various low-dimensional allotropes of carbon including carbon black
(CB), carbon fiber, carbon nanotubes (CNTs), fullerene, and graphene."
5. Zdetsis, Aristides D.; Economou, E. N. (23 July 2015). "A Pedestrian Approach to the
Aromaticity of Graphene and Nanographene: Significance of Huckel's (4 n +2)π Electron Rule".
The Journal of Physical Chemistry C. 119 (29): 16991–17003. doi:10.1021/acs.jpcc.5b04311.
6. Harris, Peter (12 January 2018). "Transmission Electron Microscopy of Carbon: A Brief
History". C. 4 (1): 4. doi:10.3390/c4010004.
7. Li, Zhilin; Chen, Lianlian; Meng, Sheng; Guo, Liwei; Huang, Jiao; Liu, Yu; Wang,
Wenjun; Chen, Xiaolong (2015). "Field and temperature dependence of intrinsic diamagnetism in
graphene: Theory and experiment". Phys. Rev. B. 91 (9): 094429.
Bibcode:2015PhRvB..91i4429L. doi:10.1103/PhysRevB.91.094429. S2CID 55246344.
8. Nair, R. R.; Blake, P.; Grigorenko, A. N.; Novoselov, K. S.; Booth, T. J.; Stauber, T.;
Peres, N. M. R.; Geim, A. K. (6 June 2008). "Fine Structure Constant Defines Visual
Transparency of Graphene". Science. 320 (5881): 1308. arXiv:0803.3718.
Bibcode:2008Sci...320.1308N. doi:10.1126/science.1156965. PMID 18388259. S2CID 3024573.
9. Zhu, Shou-En; Yuan, Shengjun; Janssen, G. C. A. M. (1 October 2014). "Optical
transmittance of multilayer graphene". EPL. 108 (1): 17007. arXiv:1409.4664.
Bibcode:2014EL....10817007Z. doi:10.1209/0295-5075/108/17007. S2CID 73626659.
6
10. Lee, Changgu (2008). "Measurement of the Elastic Properties and Intrinsic Strength of
Monolayer Graphene". Science. 321 (385): 385–388. Bibcode:2008Sci...321..385L.
doi:10.1126/science.1157996. PMID 18635798. S2CID 206512830.
11. Cao, K. (2020). "Elastic straining of free-standing monolayer graphene". Nature
Communications. 11 (284): 284. Bibcode:2020NatCo..11..284C. doi:10.1038/s41467-019-
14130-0. PMC 6962388. PMID 31941941.
12. Boehm, H. P.; Clauss, A.; Fischer, G. O.; Hofmann, U. (July 1962). "Das
Adsorptionsverhalten sehr dünner Kohlenstoff-Folien" [The adsorption behavior of very thin
carbon foils]. Zeitschrift für anorganische und allgemeine Chemie (in German). 316 (3–4): 119–
127. doi:10.1002/zaac.19623160303.
13. Novoselov, K. S.; Geim, AK; Morozov, SV; Jiang, D; Zhang, Y; Dubonos, SV;
Grigorieva, IV; Firsov, AA (22 October 2004). "Electric Field Effect in Atomically Thin Carbon
Films". Science. 306 (5696): 666–669. arXiv:cond-mat/0410550. Bibcode:2004Sci...306..666N.
doi:10.1126/science.1102896. PMID 15499015. S2CID 5729649.
14. "This Month in Physics History: October 22, 2004: Discovery of Graphene". APS News.
Series II. 18 (9): 2. 2009.
15. "The Nobel Prize in Physics 2010". Nobel Foundation. Retrieved 1 September 2021.
16. "Global Demand for Graphene after Commercial Production to be Enormous, says
Report". AZONANO.com. 28 February 2014. Retrieved 24 July 2014.
17. Mrmak, Nebojsa (28 November 2014). "Graphene properties (A Complete Reference)".
Graphene-Battery.net. Retrieved 10 November 2019.
18. "graphene layer". IUPAC Compendium of Chemical Terminology. International Union of
Pure and Applied Chemistry. 2009. doi:10.1351/goldbook.G02683. ISBN 978-0-9678550-9-7.
Retrieved 31 March 2012.
19. Geim, A. (2009). "Graphene: Status and Prospects". Science. 324 (5934): 1530–4.
arXiv:0906.3799. Bibcode:2009Sci...324.1530G. doi:10.1126/science.1158877. PMID
19541989. S2CID 206513254.
20. Riedl, C.; Coletti, C.; Iwasaki, T.; Zakharov, A.A.; Starke, U. (2009). "Quasi-Free-
Standing Epitaxial Graphene on SiC Obtained by Hydrogen Intercalation". Physical Review
Letters. 103 (24): 246804. arXiv:0911.1953. Bibcode:2009PhRvL.103x6804R.
doi:10.1103/PhysRevLett.103.246804. PMID 20366220. S2CID 33832203.
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21. Geim, A. K. (2012). "Graphene Prehistory". Physica Scripta. T146: 014003.
Bibcode:2012PhST..146a4003G. doi:10.1088/0031-8949/2012/T146/014003.
22. Brodie, B. C. (1859). "On the Atomic Weight of Graphite". Philosophical Transactions of
the Royal Society of London. 149: 249–259. Bibcode:1859RSPT..149..249B.
doi:10.1098/rstl.1859.0013. JSTOR 108699.
23. Debije, P; Scherrer, P (1916). "Interferenz an regellos orientierten Teilchen im
Röntgenlicht I". Physikalische Zeitschrift (in German). 17: 277.
24. Friedrich, W (1913). "Eine neue Interferenzerscheinung bei Röntgenstrahlen" [A new
interference phenomenon in X-rays]. Physikalische Zeitschrift (in German). 14: 317–319.
25. Hull, AW (1917). "A New Method of X-ray Crystal Analysis". Phys. Rev. 10 (6): 661–
696. Bibcode:1917PhRv...10..661H. doi:10.1103/PhysRev.10.661.
Kohlschütter, V.; Haenni, P. (1919). "Zur Kenntnis des Graphitischen Kohlenstoffs und der
Graphitsäure" [To the knowledge of graphitic carbon and graphitic acid]. Zeitschrift für
anorganische und allgemeine Chemie (in German). 105 (1): 121–144.
doi:10.1002/zaac.19191050109.