ALLEN CAREER INSTITUTE
ASHOKNAGAR_CHENNAI.
Section: Jr IIT DPP-4 Date: 19-10-2023
GOC
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1. For the following reactions :
Cl Cl , H10
Cl Cl , H02
CH2 Cl , H03
Cl
Cl Cl , H04
The correct decreasing order of enthalpies of dissociation is
(A) H04 H02 H30 H10 (B) H04 H10 H20 H30
(C) H03 H02 H10 H04 (D) H02 H10 H04 H03
2. Which of the following is the strongest nucleophilic site in the following species ?
( 4) O O
( 1) O ( 3)
S
O O
O
( 2)
(A) 1 (B) 2 (C) 3 (D) 4
3. Which of the following phenols will show highest acidity?
CH3 CH3
OH H3C OH OH
H3C OH
CH3 O 2N H3C
(A) NO 2 (B) CH3 (C) H3 C NO 2 (D) NO 2
4. Which of the given species is not aromatic?
(A) (B)
N
O H
H3C O CH3
B B
(C) O O (D) None of these is ‘not–aromatic’
B
CH3
5. In which of the following cases, the hydrogenation reaction is most exothermic?
(A) (B)
(C) (D)
6. In which of the following cases, protonation of nitrogen will change its hybridization
N N N N
(A) H (B) H (C) H (D) H
7. Which has the least dipole moment?
CH3 H3Si
Me N H Me N H N SiH 3 N SiH 3
(A) H (B) Me (C) H3Si (D) H3Si
8. Which of the following is most acidic (Bronsted)?
H
H H
H C H CH3 C C 2 H5
Me C H
(A) H (B) (C) (D) CH3
9. Which of the following compounds has a C–H bond with the lowest bond dissociation energy
(A) C2H6 (B) C6H6 (C) C2H2 (D) CH3–CH=CH2
10. Cross conjugation occurs in
(I) C6H5CH2CONH2 (II) C6H5CONH2
(III) Quinone (IV) C6H5OCOCH=CH2
(A) I, II and III (B) I, II and IV (C) II, III and IV (D) I, III and IV
11. Hyperconjugation may involve the following overlap(s)
(A) (B) (C) (D) p(empty) (E) n
12.
(A) (B)
S–I : Structure B is more stable than structure A.
S–II : The most stable resonating structure for a polycyclic aromatic hydrocarbon is the one
which has the greatest number of rings that corresponds to Kekule formulation of
Benzene.
(A) S-I and S-II are correct and S-II is the correct explanation of S-I.
(B) S-I and S-II are correct and S-II is not the correct explanation of S-I.
(C) S-I is correct and S-II is incorrect (D) S-I is incorrect and S-II is correct
13. Correct statement(s) regarding the following equilibrium is/are
OH OH
H OH H H
H H H H
H OH
(A) Intra molecular hydrogen bonding is more important than steric crowding
(B) Equilibrium constant for the reaction is < 1
(C) Steric crowding dominates over Intra molecular hydrogen bonding in deciding the
equilibrium amounts of both.
(D) Intra molecular H–bonding and steric crowding are equally important
14. Which of the following carbocation would you expect to rearrange?
CH2 CH3 CH3 CH3
(a) (b) (c) (d)
(A) All (B) a, b (C) a, c (D) a, b, d
15. Which of the following species is highly acidic?
CF3 CF3
F 3C CF3
(A) (B) CF3
CF 3 CF 3
CF 3 CF 3
CF 3 CF 3
(C) CF3 (D) F3C CF 3
16. Arrange the following in decreasing order of basicity
Aniline P nitroaniline
I II
N,N dim ethyl aniline N,N,2,6 tetra methyl aniline
III IV
(A) I > II > IV > III (B) III >IV > I > II
(C) III > I > IV > II (D) IV > III > I > II
17. Among
NH2 O S
strongest base is
, ,
N N
NH2 O S
(A) (B) N (C) N (D) all are equally basic
18. Which of the following on treatment with CHCH produce gas(es)?
(I) NH2 (II) C H3 (III) OH (IV) Na in liq NH3
(A) II, III and IV (B) I, II and III (C) I, II and IV (D) I, III and IV
19. Which of the following is the most stable resonance structure?
CH2 CH C OH
CH CH2 CH C OH
(A) CHNH2 (B) CH CHNH2
CH2 CH C OH CH2 CH C OH
(C) CH CHNH2 (D) HC CH NH2
20. Which of the following statement/s is/are incorrect?
(A) Ka1 of phthalic acid is less than that of isophthalic acid
(B) Ka2 of phthalic acid is more than that of isophthalic acid
(C) salicylic acid is stronger acid than ortho methoxy benzoic acid
(D) phenol is stronger acid than thio phenol
21. The Increasing order of the acidity of Hydrogen among the following is
H HI
H H
H H II III
(A) III < II < I (B) II < I < III (C) I < II < III (D) II < III < I
22. The most stable conformation of 1,4-di-t-butylcyclcohexane is
(A) trans: chair (B) trans: boat (C) cis - twist boat (D) cis: half chair
23. The compound with highest enthalpy of combustion is
(A) but-1-ene (B) but-2-ene
(C) 2-methylprop-1-ene (D) All have the same
