Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.S60_Elite, Target & LIIT-BTs JEE-MAIN(Theory Based Test) Date: 27-12-2024
Time: 09.00Am to 12.00Pm GTM - 10/05 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point Pen
only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on the
Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 75 Questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Mathematics, Physics and Chemistry
having 25 Questions in each subject and subject having two sections.
(I) Section –I contains 20 Multiple Choice Questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
(II) Section-II contains 05 Numerical Value Type Questions.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the Nearest Integer
value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and
less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted Question 21. Bubble on 21 as shown below
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.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________

Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________

27-12-2024_Sr.S60_Elite, Target & LIIT-BTs

Jee-Main-GTM-10/05(Theory Based)_Test Syllabus
MATHEMATICS : Theory Based Test
PHYSICS : Theory Based Test
CHEMISTRY : Theory Based Test

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MATHEMATICS Max Marks: 100

SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which
ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Let f(x) be a real function
Number of correct statements among the following.
Statement I: If f(x) is an odd function on R and is known to be an increasing function for x
> 0 then it is also decreasing function for x < 0
Statement II: If f(x) is an odd function and lim f ( x ) exists then lim f ( x )  0
x0 x0

Statement III: If f(x) is an even function on R and is known to be increasing for

x > 0, then it is decreasing function for x <0
Statement IV: If f(x) is an even function and f (0) exists then lim f ( x )  lim f ( x )
x0 x0
1)1 2)2 3)0 4)3
2. Let f(x) be continuous on [a, b] and differentiable on (a, b)
Number of correct statements among the following.
Statement I: If f(x) is strictly increasing on (a, b) then f 1 (x)  0 for all x  (a, b)
Statement II: If f(x) is strictly decreasing on (a, b) then f 1 (x)  0 for all x  (a, b)
Statement III: f(x) and f 1 (x) have opposite sign, for all x, then f 2 (x) is a decreasing function
Statement IV: f(x) and f 1 (x) have opposite sign, for all x, then f (x) is an increasing function
1)1 2)2 3)3 4)4
3. Which of the following must be the true value of the statements below in that order.
Statement I: arg( z)   arg( z ) for any complex number z

Statement II: If z  z1  z  z2  k where k  z1  z2 , Then the locus of z is a hyperbola

Statement III: z1, z2.....zn be the complex numbers representing the vertices of n – sided
n
regular polygon, and “ zo ” is its centre, then  zi2  nz02
i 1

Statement IV: If z12  z 22  z1 z2  0 , then z1 , z2 and origin form an equilateral triangle.

1) TFFT 2) FFTF 3) FFTT 4) TTTT

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3 2
4. Let the function f : R  R be defined by f  x   x  x   x  1 sin x and let g : R  R be
an arbitrary function.
Let fg : R  R be the product function defined by  fg  x   f  x  g  x  .
Then Number of correct statements among the following.
A) If g is discontinuous at x = 1, then fg can never be differentiable at x = 1
B) If fg is differentiable at x = 1, then g is continuous at x = 1
C) If fg is differentiable at x = 1, then g must be differentiable at x = 1
1)3 2)2 3)1 4)0
5. Which of the following must be the true value of the statements below in that order.
eax
Statement I:  eax .sin bx dx  2 2  a sin bx  b cos bx   c, where a, b  R  0 and c is
a b
arbitrary real number
 n 1

Statement II:  f '( x)n dx 

 f ( x)  where n  1 and f ( x) is a positive differentiable
 f ( x)  n  1
function

Statement III:  e kx  f (kx)  f 1

( kx ) 
dx = ekx f (kx)  c where k,c  R
k
Statement IV: Let F  x  be an indefinite integral of sin 2 x , then the function F  x  satisfies

F  x     F  x  for all real x.

1) TFFT 2) TFTF 3) TFTT 4) TFFF
6. Which of the following must be the true value of the statements below in that order.
  
Statement I: For x  R, let tan 1  x     ,  . Then the minimum value of the function
 2 2
x tan 1 x
e 
t  cos t
f :R  R , defined by f  x    dt is zero
0
1  t 2023

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Statement II: If f(x) is a periodic function with period T, then

b nT b

 f  x  dx a f  x  dx, n  Z,a, b  R

a  nT

b b
Statement III: If   x     x  for a  x  b, then    x  dx     x  dx
a a

1) TTF 2) FTF 3) FTT 4) TTT

7. Consider the given statements
Statement I: If f(x) is bounded for x  a,b , then area bounded by curve y = f(x), x – axis,
b
x = a and x = b is  f  x  dx
a

Statement II: If f(x) is bounded and differentiable for x  a,b , then the area between
b
1
y  f  x  and y  f  x  is equal to the double the value of  f  x   x dx
a

1) Only Statement I is true 2) Only Statement II is true

3) Both Statement I and II are True 4) Both Statement I and II are false
dy
8. Let y  y  x  be the solution of the differential equation  2y  f (x), where
dx
1, x   0, 1
f x    If y  0   0, then y  ln 2  is
0, otherwise
e2  1 e2  1 1 3
1) 2) 3) 4)
4e2 2e2 4 8
9. Let x , M and  2 be respectively the mean, mode and variance of n observations x1, x2.....xn
and di   x i – a, i  1, 2, , n where a is any number
Statement 1: variance of d1 , d2 ,...dn is  2
Statement 2: Mean and mode of d1 , d 2 ,....d n are  x  a and M  a respectively

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1)Statement 1 and Statement 2 are both false

2) Statement 1 and Statement 2 are both true
3)Statement 1 is true and Statement 2 is false
4)Statement 1 is false and Statement 2 is true
10. Number of correct statements among the following.
 x, if x is rational
Statement I: If f, g: R  R defined as f  x    and
0, if x is irrational

0, if xis rational

g  x   , then, f g is one-one and onto
 x, if x is irrational

Statement II: f ( x)  sin x  cos ax is periodic function then a must be rational

Statement III: If f : A  B and g : B  C are functions such that g f : A  C is one -one
then f must be one -one
1)1 2)2 3)0 4)3
11. Which of the following is true?
dy
1) for y  sin 1  cos x  , where x   0,   , is -1
dx
dy
2) for y  sin 1  cos x  , where x   0,2  , is 1
dx
dy  
3) for y  cos 1  sin x  , where x    ,  , is -1
dx  2
dy   3 
4) for y  cos 1  sin x  , where x    ,  , is -1
dx  2 2 

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12. Consider the following Statements

Statement-I: If both functions   x  and g  x  have limits at x  a, then

Lt    g  x      Lt   g  x    [ ] denotes G.I.F
x a  x a 
Statement-2: A function may fail to have a limit at a point in its domain but functional
value at x = a exists (i.e. f(a) exists)
1) Only Statement I is true 2) Only Statement II is true
3) Both Statement I and II are True 4) Both Statement I and II are false
13. Which of the following is always true

1) One root of the equation ax2  bx  c  0, in the form of p  q then other root is

p  q  p  z, q  z  

2) If the equation ax 2  bx  c  0 is satisfied by more than two distinct numbers

(real or complex), then it becomes an identity.
3) If a = 2 and b, c are integers and the roots of the quadratic equation ax 2  bx  c  0 are
rational, then the roots must be integers
4) a, b, c are in A.P and G.P then (a, b, c) can be (k, k, k) for all k  R
14. Two players, P1 and P2 , play a game against each other. In every round of the game,
each player rolls a fair die once, where the six faces of the die have six distinct numbers. Let
x and y denote the readings on the die rolled by P1 and P2 , respectively. If x  y , then P1
scores 5 points and P2 scores 0 point. If x  y , then each player scores 2 points. If x  y ,
then P1 scores 0 point and P2 scores 5 points. Let X i and Yi be the total scores of
th
P1 and P2 , respectively, after playing the i round.

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List – I List – II
I) Probability of  X 2  Y2  is 3
P)
8
II) Probability of  X 2  Y2  is 11
Q)
16
III) Probability of  X 3  Y3  5
R)
16
IV) Probability of  X 3  Y3  355
S)
864
77
T)
432
1) I  Q; II  R; III  T ; IV  S 2) I  Q; II  R; III  T ; IV  T
3) I  P; II  R; III  Q; IV  S 4) I  P; II  R; III  Q; IV  T
15. Which of the following is/are true
Statement I: A variable circle cuts two fixed perpendicular lines so that each intercept is of
different length, then locus of the centre of the circle is hyperbola.
Statement II: If the eccentric angles of the extremities of a focal chord of a Hyperbola
   
cos  1 2 
 2   sin 1   2 
2 2
x y
2
 2  1 are 1 &2 Then eccentricity of the Hyperbola e=
a b      sin 1   sin  2 
cos  1 2 
 2 

1) Only Statement I is true 2) Only Statement II is true

3) Both Statement I and II are True 4) Both Statement I and II are false
16. Consider the following Statements
Statement I: General form ax  by  c  0 (here a, b and c are the parameters and a, b, c  R )
always represents a straight line

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Statement II: A line ax  by  1  0, is such that the algebraic sum of theperpendiculars on it,
from a number of points  xi , yi  , (i  1,2,......., n). is zero, then the line always passes through

a fixed point is  x , y  Where x   i and y  

x yi
n n
1) Only Statement I is true 2) Only Statement II is true
3) Both Statement I and II are True 4) Both Statement I and II are false
17. Which of the following must be the true value of the statements below in that order.
  
Statement I: If a  2i  j  k , and b and c be two nonzero vectors such that
         
a  b  c  a  b  c and b.c  0 then a  c  a for all   R
     
Statement II: If the vectors PQ,QR,RS,ST,TU and UP represent the sides of regular
   

hexagon then PQ  RS  ST  0 
   
Statement III: Four points A,B,C & D with position vectors a, b, c & d respectively, are
    
coplanar, then there exists constants x, y, z and w such that xa  yb  zc  wd  0 where x + y +
z + w = 0 but not all x, y, z and w are zero
1) TFF 2) TFT 3) FFT 4) TTT
18. Which of the following must be the true value of the statements below in that order.
Statement I: For square matrices A and B of same order. (with real entries) (O is null matrix
2 2
and I is Identity matrix of same order as A and B). If AB = O then  det A   det B   0
Statement II: If li , mi , ni (i  1, 2,3) denote the direction cosines of 3 mutual perpendicular
 l1 m1 n1 
vectors then A   l2 m2

n2  is an orthogonal matrix
l m3 n3 
3
Statement III: For two distinct Lines with shortest distance d  0 we can have a point A on
line one and point B on line two such that AB=d then A and B be unique points on them in
all possible cases
1) FFT 2) FFF 3) FTF 4) FTT

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19. Graph of y    x  is given below

 0, 3
2 x
1 3
1

1
Then graph of y  is best represented by
  x
y
y

 1
 1
 0,   0, 
 2  3
2 2 x
0 x 0 1 3
1 3
1 1

1) 2)
y y

2 x y 1
 1 0 1 3  1
 0,  
 3  0, 
y  1  3
0 x
1 2 3
3) 4)

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20. Which of the following must be the true value of the statements below in that order.
Statement I: There are “n”,  n  3 straight lines, drawn in a plane, no two of which are
parallel and no three pass through the same point, and the points of intersection of these lines
n  n  1 n  2  n  3
are joined. Then the number of fresh lines, hence made is
8
Statement II: Vertices of n-sided regular polygon, joined to form a triangle then number of
n 1
obtuse angled triangle, is = n. 2 C2 , if n is even  n  4 

1) TT 2) TF 3) FT 4) FF
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
21. Let P  a1, b1  and Q  a2 , b2  be two distinct points on a circle with center C( 2, 3) . Let O

be the origin and OC be perpendicular to both CP and C Q . If the area of the triangle OCP

is 35 , then a12  a22  b12  b22 is equal to______.

22. Let Q be the cube with the set of vertices  x , x , x   R

1 2 3
3
: x1 , x 2 x 3  0,1. Let F be

the set of all twelve lines containing the diagonals of the six faces of the cube Q. Let S
be the set all four lines containing the main diagonals of the cube Q; for instance, the
line passing through the vertices  0,0,0  and 1,1,1 is in S. For lines l1 and l 2 , let

d  l1 , l 2  denote the shortest distance between them. Then the maximum value of

d  l1 , l2  , as l1 varies over F and l 2 varies over S, is  . Find the value of  2

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23. Number of correct statements among the following is k. Then 2k is ______

Statement I: Chord joining the points P  at12 , 2at1  & Q  at22 , 2at2  of the parabola y 2  4ax passes
2
 1
through focus of the parabola, length of the focal chord PQ  a  t1    4a
 t1 
Statement II: Let P   : sin   cos   2 cos  and Q   :sin   cos   2 sin  be two sets. Then
P=Q
Statement III: If a,b,c,d and p are distinct non zero real numbers such that
 a 2  b2  c2  p 2  2  ab  bc  cd  p   b2  c 2  d 2   0 then a,b,c,d are in G.P
24. Number of correct statements among the following is k. Then 3k is _______
Statement I: For two given events A and B, P  A  B  is not less than P (A) +P (B) -1
Statement II: The number of symmetric relations defined on the set {1,2,3,4} which are not
reflexive is 20
 1 1  1 1  1 1 
 2 
Statement III: lim  a  a 3  a 2  a 5  ....... a 2  a 2 n 1    o , if a>1
n      
    
25. Number of correct statements among the following is k. then 2k is _______
Statement I: Let A  1, 2, 3, 4, 5, 6, 7. Define B  T  A : either 1  T or 2  T and
C={T  A : the sum of all the elements of ‘T’ is a prime number}. Then the number of
elements in the set B  C is 107
Statement II: If sum of n terms of any sequence is a quadratic in ‘n’, then the sequence is an
AP
Statement III: Let x  (8 3 13)13 and y  (7 2  9)9 . If [t] denotes the greatest integer  t ,
then [ x ]  [ y ] is even
1 5 1 5
   
Statement IV: The expression  x   x  1 2    x   x  1 2  is a polynomial of degree 7
3 3

   

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PHYSICS Max Marks: 100

SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which
ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
26. A potential difference is applied across the ends of a metallic wire. If the potential difference
is doubled, then the drift velocity:
1) will be doubled 2) will be halfed
3) will be quadrupled 4) will remain unchanged
27. Consider a neutral conducting sphere. A positive point charge is placed outside the sphere.
The net charge on the sphere is then:
1) negative and distributed uniformly over its surface.
2) negative and appears only at the point on the sphere closest to the point charge
3) negative and distributed non-uniformly over its entire surface of the sphere
4) zero
28. When a proton is released from rest in a room, it starts with an initial acceleration a0
towards west. When it is projected towards north with a speed v0 it moves with an initial
acceleration 3a0 towards west. The electric and magnetic fields in the room are
ma0 3ma0 ma0 2ma0
1) east , down 2) west , up
e ev0 e ev0
ma0 2ma0 ma0 3ma0
3) west , down 4) east , up
e ev0 e ev0
29. A square loop, carrying a steady current I, is placed in a horizontal plane near a long straight
conductor carrying a steady current I1 at a distance d from the conductor as shown in figure.
The loop will experience:

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I1

d
I

I
1) A net attractive force towards the conductor
2) A net repulsive force away from the conductor
3) A net torque acting upward perpendicular to the horizontal plane
4) A net torque acting downward normal to the horizontal plane
30. Two wires A and B of same length and made of same material are hanging from the same
roof. The figure shows the load F versus extension  graph for the two wires then:

FN

40 B

10 A

O   mm 

1) The elasticity of wire A is greater than that of B

2) The cross-sectional area of wire A is equal to that of B
3) The ratio of radii of wires A to B is 1:2
4) The ratio of area of cross-section of wires A to B 4:1
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31. The spring balance A reads 2kg with a block m suspended from it. A balance B reads 5kg
when a beaker with liquid is put on the pan of the balance. The two balances are now so
arranged that the hanging mass is inside the liquid in the beaker as shown in the figure in this
situation:

1) the balance A will read more than 2kg

2) the balance B will read more than 5kg
3) the balance A will read less than 2kg and B will read less than 5kg
4) the balances A and B will read 2kg and 5kg respectively
32. A spherical ball falls through viscous medium with terminal velocity v. If this ball is
replaced by another ball of the same mass but half the radius, then the terminal velocity will
be (neglect the effect of buoyancy):
1) v 2) 2v 3) 4v 4) 8v

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33. The graphs show the variation of current I (y-axis) in two photocells A & B as a function of
the applied voltage V(x-axis) when light of same frequency is incident on the cell. Which of
the following is the correct conclusion drawn from the data?

I A

1) Cathodes of the two cells are made from the same substance, the intensity of light used are
different
2) Cathodes are made from different substances and the intensity of light is the same
3) Cathode substances as well as intensity of light are different
4) no conclusion can be drawn
34. For the position (x) -time (t) graph shown of a particle in one dimensional motion. Choose
the correct alternatives from below
a) Particle was released from rest at t  0
b) At C particle will reverse its direction of motion
c) Average velocity for motion between B and D is positive
d) At E, velocity = 0 and acceleration > 0
x

A C
B

D
t
E
1) a, b 2) a, b, d 3) a, d 4) b, c, d
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35. Assertion: The direction of the frictional force on an object is opposite to the actual motion
(Kinetic friction) or the impending motion (static friction) of the object relative to the surface
with which it is in contact.
Reason: Friction force always opposes the motion
1) Both A and R are true and R is the correct explanation of A
2) Both A and R are true and R is NOT the correct explanation of A
3) A is true but R is false
4) A is false but R is true
36. A plane glass sheet is kept over various coloured pictures. The least raised picture is
1) Green 2) Yellow 3) Violet 4) Red
37. In a reflecting telescope, a secondary mirror is used to
1) remove spherical aberration
2) reduce the problem of mechanical support
3) make chromatic aberration zero
4) move the eyepiece outside the telescope tube
38. One cannot see through fog, more appropriate answer is
1) Fog absorbs all the incident light falling on it
2) Light suffers total reflection at droplets
3) Refractive index of the fog is infinity
4) Light is scattered by the droplets
39. When a body is under pure rolling, the fraction of its total kinetic energy which is purely
2
rotational is . Identify the body.
5
1) Hollow sphere 2) Sphere 3) Ring 4) Disc

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40. Two springs have their force constant as k1 and k 2  k1  k2  . When they are stretched by the
same force up to equilibrium
1) No work is done by this force in case of both the springs
2) Equal work is done by this force in case of both the springs
3) More work is done by this force in case of second spring
4) More work is done by this force in case of first spring
41. A particle (bob) of mass 1kg is performing vertical circular motion. Then:

 4

 3

2
m
1
1) Power delivered by tension at point (4) is negative.
2) Power delivered by tension at point (2) is positive.
3) Power delivered by gravitational force at point (3) is zero
4) Power delivered by gravitational force at point (4) is negative
42. Which of the following statements is true about the magnetic susceptibility x m of
paramagnetic substance?
1) Value of x m is inversely proportional to the absolute temperature of the sample
2) Value of x m is directly proportional to the absolute temperature of the sample
3) xm is negative at all temperatures
4) xm does not depend on the temperature of the sample
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43. Assertion (A): A small metal ball is charged to a potential of +1 V. It is introduced into a
large hollow metal sphere charged to a potential of +10,000V and comes into contact with
the inside surface of the sphere. The ball’s charge passes to the sphere completely.
Reason (R): Positive charge flows from a body at lower potential to another body at higher
potential
1) If both A and R are true and R is correct explanation of A
2) If both A and R are true but R is not the correct explanation of A
3) If A is true but R is false
4) If both A and R are false
44. Statement-I: The fundamental frequency of an open organ pipe increases as the temperature
is increased.
Statement-II: As the temperature increases, the velocity of sound increases more rapidly
than length of the pipe.
1) Statement-I is true, Statement-II is true; Statement-II is correct explanation for
Statement-I.
2) Statement-I is true, Statement-II is true; Statement-II is not a correct explanation for
Statement-I
3) Statement-I is true, Statement-II is false
4) Statement-I is false, Statement-II is true.
45. The potential of electrostatic field is given by   xy, where x & y are coordinate. Which of
the following is correct?
1) Electric field at all points on positive x-axis is in positive y-direction.
2) Electric field at all points of positive y-axis is in negative x-direction.
3) Electric field at  2, 2  is 2 N m.
 y
4) Electric field at x, y makes an angle   tan 1   with x-axis
x
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases

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Note:
From: Question number’s 41 to 45 rules for Answer marking
If your answer is options 2,4 Then you have to fill the OMR sheet as ‘24’
If your answer is options 1,3,4 Then you have to fill the OMR sheet as ‘134’
And if your answer is options 1,2,3,4 then you have to fill the OMR sheet as ‘1234’
46. Hydrogen gas absorbs radiations of wavelength 0 and consequently emit radiations of 6
different wavelengths of which three wavelengths are shorter than 0 . Choose the
CORRECT statement(s).
1) The final energy state of the atom is n  4
2) The initial state of the atom may be n  2
3) There are two transitions in balmer series
4) There are three transitions belonging to Lyman series.
47. Select the CORRECT statement(s) for a particle performing SHM with angular frequency
' '. (in undamped SHM)
1) The displacement is zero in one time period
2) The distance travelled is 2A in one time period
3) Average acceleration is zero in one time period
4) Total energy of system remains constant with time
48. If a satellite orbits as close to the earth’s surface as possible
1) Its speed is maximum
2) Time period of its revolution is minimum
3) The total energy of the ‘earth plus satellite’ system is minimum
4) The total energy of the ‘earth plus satellite’ system is maximum
49. Number of collisions per second of molecules of a gas on the wall of a container per m2
will:
1) Increase if temperature and volume both are doubled.
2) Increase if temperature and volume both are halved.
3) Increase if pressure and temperature both are doubled.
4) Increase if pressure and temperature both are halved.
50. Choose the correct statement(s)
1) The density of nuclear matter is independent of the size of the nucleus.
2) The binding energy of nuclei first increases and then decreases as its mass number
increases
3) A free neutron is stable
4) A free proton is stable
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CHEMISTRY Max Marks: 100

SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which
ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
51. For the following given reaction
CH2

H2

Pd
 X+Y

CH3
[X] & [Y] are-
1) Enantiomer of each other 2) Diastereomer of each other
3) Both are meso compounds 4) Constitutional isomer of each other
52. The major products A and B in the following reactions are:
CN Peroxide
Heat
  A 

 A  B

1)

2)

3)

4)

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53. Choose the correct option [true or false] for the following compounds
I) In C2 molecule only  bonds are present
II) In C2 molecule one  bond and one  bond is present
III) C2 molecule is paramagnetic if s – p mixing is not operative
IV) Correct order of dipolemoment for chloromethanes is
CCl4  CHCl3  CH2Cl2  CH3Cl
1) TFTT 2) FTFF 3) TFTF 4) TFFF
54.
CH =CH2

Br2 KMnO4
A B Compound A and B respectively are :
Fe 

1) o  bromo styrene, benzoic acid 2) p  bromo styrene, benzaldehyde

3) m  bromo styrene, benzaldehyde 4) styrene dibromide, benzoic acid

55. The specific conductance of a saturated solution of silver bromide is k Scm  1 . The limiting
ionic conductivity of Ag  and Br  ions are x and y, respectively. The solubility of silver
bromide in gL 1 is:
(molar mass of AgBr =188)
k  1000 k k  1000  188 x  y 1000
1) 2)  188 3) 4) 
x y x y x y k 188
OH

HO OCH3 1) Pd/C-H2
1) Conc. HNO3 2) dil. HNO2
(A) (B) (C)
2) p-Toulene 3) H3PO2
sulphonyl
CH3 chloride
56.
What is the final product (C)?
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MeO Me MeO O Me
1) 2)

Me O Me MeO O
3) 4)
57. The degree of dissociation   of a weak electrolyte, Ax By is related to Vant’t Hoff factor (i)
by the expression:
i 1 i 1 x  y 1 x  y 1
1)   2)   3)   4)  
 x  y  1  x  y  1 i 1 i 1
58. In Cannizaro reaction, correct order of rate of reaction with respect to substrate

CHO

is
1) p  Me2 N  p  NMe2  p  alkyl  H  p  Cl  m  Cl  m  NO2
2) p  MeO  p  NMe2  p  alkyl  H  m  Cl  m  NO2  p  Cl
3) p  Me2 N  p  MeO  p  alkyl  H  p  Cl  m  Cl  m  NO2
4) p  MeO  p  NMe2  p  alkyl  H  m  NO2  m  Cl  p  Cl

59. The formation of O2  PtF6  is the basis for the formation of xenon fluorides. This is because:

1) O2 and Xe have comparable sizes

2) both O2 and Xe are gases
3) O2 and Xe have comparable ionization energies
4) O2 and Xe have same electron gain enthalpy
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60. Graph between log k and 1/T [k is rate constant  s 1  and T the temperature (K)] is a

straight line OX = 5,   tan 1 1 / 2.303  . Hence Ea will be

log k


O 1/ T
2.303
1) 2.303  2 cal 2) 2 / 2.303 cal 3) 2 cal 4) cal
2
61. Assertion:- Na2Cr2O7 cannot be used as a primary standard in titrations.
Reason: - Na2Cr2O7 is hygroscopic in nature
1) Assertion is True, Reason is true: Reason is the correct explanation for Assertion.
2) Assertion is true Reason is true: Reason is not the correct explanation for Assertion.
3) Assertion is True, Reason is False.
4) Assertion is False, Reason is true.
62. A student added aqueous chlorine to aqueous sodium bromide and the resulting mixture was
shaken with an equal volume of trichloroethane
Which diagram best represents the observation made?

Colourless Colourless

Red
Purple brown
Red
Purple brown
1) 2) 3) 4)

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63. Which of the following is the most soluble in water?

1) Bi2 S3  K SP  1 10 70  2) Ag 2 S  K SP  6  10 51 
3) CuS  K SP  8  10 37  4) MnS  K SP  7  1016 
64. INCORRECT statement for the below sequence is

1) P3 on reaction with Ag gives acetylene

2) P4 on reaction with sodalime gives toluene
3) P4 on reaction with sodalime gives benzene
4) P1 on reaction with 2,4-DNP gives coloured compound
65. Match the Column – I and Column – II
Column – I Column – II
A) Hypophosphoric acid P) All hydrogens are ionizable in water
B) Pyrophosphoric acid Q) Lewis acid
C) Boric acid R) Monobasic acid
D) Hypophosphorous acid S) sp3 hybridized central atom
1) A-PS; B-PS; C-QR; D-RS 2) A-QR; B-PS; C-PQ; D-RS
3) A-PS; B-QR; C-RS; D-S 4) A-QS; B-PR; C-PQ; D-P

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2
66. Which of the following statements are correct with respect to  NiCl4  and  Ni  PPh 3  2 Cl2  ?

1) In both cases Ni undergoes dsp2hybridisation

2)  Ni  PPh 3 2 Cl 2  is tetrahedral

3)  Ni  PPh 3 2 Cl 2  is square planar

4)  NiCl4 2 is square planar

67. Which one of the following order is not in accordance with the property stated against it?
1) F  Cl  Br  I : Electro negativity
2) F2  Cl2  Br2  I 2 : Bond dissociation energy
3) F2  Cl2  Br2  I 2 : Oxidizing power
4) HI  HBr  HCl  HF : Acidic strength
dP
68. For a reversible adiabatic ideal gas expansion is equal to
P

dV dV    dV dV
1)  2)  3)   4)
V V   1  V V

69. Saturated solution of KNO3 with agar-agar is used to make ‘salt bridge’ because:
1) size of K  is greater than that of NO3
2) velocity of NO3 is greater than that of K 
3) velocities of both K  and NO3 are nearly the same
4) both velocities and size of K  and NO3 ions are same

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70. Match the Column – I and Column – II

Column – I Column – II
(Graphs) (Area shown in the graph represents
the magnitude of)
A) P) q

B) Q) w

C) R) (G)T

D) S) ( G ) P

1) A-S, B-P, C-Q,D-R 2) A-S, B-Q, C-P,D-R

3) A-P, B-R, C-Q,D-S 4) A-R, B-P, C-S,D-R

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SECTION-II (NUMERICAL VALUE TYPE)

This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
71. Among the following, the number of aromatic compound(s) is.....
H

, H

72.

The value of (m + n) is
73. The product P obtained through the following sequence of reactions

conc. HNO 3 Br2 ,Fe Sn / HCl i) NaNO , HCl


conc. H 2 SO 4 , warm
L 
heat
 M  N 
ii) Cu Cl
P 2
2 2

According to IUPAC nomenclature, what position will be assign to chlorine atom from 1to
6 in product P
74. Maximum number of atoms present in a plane in diborane is X. Maximum number of atoms
X Y
present in a plane in Borazine is Y. Then, what is the value of ?
2
(Consider those planes which contain maximum number of atoms)
75. What will be the n-factor of the reactant in the following reaction?


Mn  NO3 2   MnO2  NO

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