Paper No 3
Paper No 3
Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
Important Instructions:
1. The test is of 3 hours duration.
2. This test paper consists of 90 questions. Each subject (PCM) has 30 questions. The
maximum marks are 300.
3. This question paper contains Three Parts. Part-A is Physics, Part-B is Chemistry and
Part-C is Mathematics. Each part has only two sections: Section-A and Section-B.
4. Section – A : Attempt all questions.
6. Section-A (01 – 20) contains 20 multiple choice questions which have only one correct
answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
7. Section-B (1 – 10) contains 10 Numerical based questions. The answer to each question
is rounded off to the nearest integer value. Each question carries +4 marks for correct
answer and –1 mark for wrong answer.
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JEE-MAIN-2023 (25th January-First Shift)-PCM-2
Q1. T is the time period of simple pendulum on the earth’s surface. Its time period becomes x T when
taken to a height R (equal to earth’s radius) above the earth’s surface. Then, the value of x will
be:
1 1
(A) (B)
4 2
(C) 4 (D) 2
Q2. A car travels a distance of ‘x’ with speed v 1 and the same distance ‘x’ with speed v 2 in the same
direction. The average speed of the car is :
2x 2v1v 2
(A) (B)
v1 v 2 v1 v 2
v 1v 2 v1 v2
(C) (D)
2 v1 v 2 2
16 4
Q3. The ratio of the density of oxygen nucleus O and helium nucleus He is
8 2
(A) 8 : 1 (B) 1 : 1
(C) 4 : 1 (D) 2 : 1
Q4. An electromagnetic wave is transporting energy in the negative z direction. At a certain point and
certain time the direction of electric field of the wave is along positive y direction. What will be the
direction of the magnetic field of the wave at that point and instant?
(A) Positive direction of z (B) Negative direction of x
(C) Negative direction of y (D) Positive direction of x
Q5. A uniform metallic wire carries a current 2A, when 3.4V battery is connected across it. The mass
of uniform metallic wire is 8.92 10 3 kg / m3 density is 8.92 103 kg / m3 and resistivity is
8
1.7 10 m. The length of wire is :
(A) 100m (B) 5m
(C) 10m (D) 6.8m
Q6. A solenoid of 1200 turns is wound uniformly in a single layer on a glass tube 2m long and 0.2m in
diameter. The magnetic intensity at the centre of the solenoid when a current of 2 A flows through
it is :
(A) 1 A m 1 (B) 1.2 103 A m 1
(C) 2.4 103 A m 1
(D) 2.4 10 3 A m 1
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JEE-MAIN-2023 (25th January-First Shift)-PCM-3
Q7. Electron beam used in an electron microscope, when eccelerated by a voltage of 20kV. Has a de-
Broglie wavelength of 0 . If the voltage is increased to 40kV, then the de-Broglie wavelength
associated with the electron beam would be :
0 0
(A) (B)
2 2
(C) 9 0 (D) 3 0
th
Q8. In Young’s double slits experiment, the position of 5 bright fringe from the central maximum is 5
cm. The distance between slits and screen is 1m and wavelength of used monochromatic light is
600nm. The separation between the slits is :
(A) 48 m (B) 36 m
(C) 12 m (D) 60 m
1
(C) Inversely proportional to square root of temperature
T
(D) Proportional to square root of temperature T
Q10. Given below are two statements : one is labelled as Assertion A and the other is labeled as
Reason R
Assertion A : Photodiodes are used in forward bias usually for measuring the light intensity.
Reason R : For a p-n junction diode, at applied voltage V the current in the forward bias is more
than the current in the reverse bias for Vz V V0 where V0 is the threshold voltage and Vz is
the breakdown voltage.
In the light of the above statements, choose the correct answer from the options given below
(A) A is true but R is false
(B) Both A and R are true and R is correct explanation A
(C) Both A and R are true but R is NOT the correct explanation A.
(D) A is false but R is true
Q11. A message signal of frequency 5 kHz is used to modulate a carrier single of frequency 2 MHz.
The bandwidth for amplitude modulation is :
(A) 2.5 kHz (B) 5 kHz
(C) 20 kHz (D) 10 kHz
Q12. In an LC oscillator, if values of inductance and capacitance become twice and eight times,
respectively, then the resonant frequency of oscillator becomes x times its initial resonant
frequency 0 . The value of x is :
(A) 1/16 (B) 4
(C) 1/4 (D) 16
Q13. Assume that the earth is a solid sphere of uniform density and a tunnel is dug along its diameter
throughout the earth. It is found that when a particle is released in this tunnel. it executes a simple
harmonic motion. The mass of the particle is 100g. The time period of the motion of the particle
will be (approximately)
(Take g 10 ms 2 , radius of earth = 6400 km)
(A) 12 hours (B) 1 hours 24 minutes
(C) 1 hours 40 minutes (D) 24 hours
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JEE-MAIN-2023 (25th January-First Shift)-PCM-4
Q14. A Carnot engine with efficiency 50% takes heat from a source at 600K. In order to increase the
efficiency to 70%, keeping the temperature of sink same, the new temperature of the source will
be :
(A) 900 K (B) 300 K
(C) 1000 K (D) 360 K
Q15. A bowl filled with very hot soup cools from 98 C to 86 C in 2 minutes when the room temperature
is 22 C. How long it will take to cool from 75 C to 69 C?
(A) 2 minutes (B) 1 minutes
(C) 0.5 minutes (D) 1.4 minutes
O 0I
C. III. B0 1
r 2 r
I
1
I
D. 1 r IV. B0 0
1
4 r
Choose the correct answer from the options below :
(A) A – III, B – IV, C – I, D – II (B) A – II, B – I, C – IV, D – III
(C) A – I, B – III, C – IV, D – II (D) A – III, B – I, C – IV, D – II
Q18. A car is moving with a constant speed of 20 m/s in a circular horizontal track of radius 40 m. A
bob is suspended from the roof of the car by a massless string. The angle made by the string with
2
the vertical will be : (Take g = 10 m/s )
(A) (B)
4 6
(C) (D)
2 3
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JEE-MAIN-2023 (25th January-First Shift)-PCM-5
Q20. A parallel plate capacitor has plate area 40 cm2 and plates separation 2mm. The space between
the plates is filled with a dielectric medium of a thickness 1mm and dielectric constant 5. The
capacitance of the system is :
3
(A) 0F (B) 10 0 F
10
10
(C) 0F (D) 24 0 F
3
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JEE-MAIN-2023 (25th January-First Shift)-PCM-6
Q1. In the given circuit, the equivalent resistance between the terminal 3 2 4
A and B is __________ .
2 2
6 4
Q6. A ray of light is incident from air on a glass plate having thickness 3 cm and refractive
index 2 . The angle of incidence of a ray is equal to the critical angle for glass-air interface. The
lateral displacement of the ray when it passes through the plate is ______ 10 2 cm. (given
sin15 0.26 )
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JEE-MAIN-2023 (25th January-First Shift)-PCM-7
Q7. The wavelength of the radiation emitted is 0 when an electron jumps from the second excited
state to the first excited state of hydrogen atom. If the electron jumps from the third excited state
to the second orbit of the hydrogen atom, the wavelength of the radiation emitted will
20
be 0 . The value of x is _________.
x
Q8. An LCR series circuit of capacitance 62.5nF and resistance of 50 , is connected to an A.C.
source of frequency 2.0 kHz. For maximum value of amplitude of current in circuit, the value of
inductance is __________ mH.
(Take 2 10 )
Q9. If P 3iˆ 3ˆj 2kˆ and Q 4iˆ 3ˆj 2.5kˆ then, The unit vector in the direction of P Q is
1
3iˆ ˆj 2 3 kˆ . The value if x is
x
Q10. The distance between two consecutive points with phase difference of 60 in a wave of frequency
500Hz is 6.0 m. The velocity with which wave is traveling is_______km/s
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JEE-MAIN-2023 (25th January-First Shift)-PCM-8
(A) (B)
NO 2
NO 2
Cl Cl
NO 2 NO 2
(C) (D)
NO 2
(A) (B)
O O H
O CH3
(C) (D)
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JEE-MAIN-2023 (25th January-First Shift)-PCM-9
B
Identify A, B, X and Y
1
(A) X = N2O, Y= [O], A = O3, B= NO (B) X O2 , Y = NO2, A = O3, B = O2
2
(C) X = NO, Y= [O], A = O2, B=N2O3 (D) X= [O], Y= NO, A = O2, B = O3
Q9. The correct order in aqueous medium of basic strength in case of methyl substituted amines is:
(A) Me2NH>MeNH2>Me3N>NH3 (B) Me2NH>Me3N>MeNH2>NH3
(C) NH3>Me3N>MeNH2>Me2NH (D) Me3N>Me2NH>MeNH2>NH3
Q10. Reaction of thionyl chloride with white phosphorus forms a compound [A], which on hydrolysis
gives [B], a diabasic acid. [A] and [B] are respectively.
(A) P4O6 and H3PO3 (B) POCl3 and H3PO4
(C) PCl3 and H3PO3 (D) PCl5 and H3PO4
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JEE-MAIN-2023 (25th January-First Shift)-PCM-10
Q13. Inert gases have positive electron gain enthalpy. Its correct order is
(A) He < Ne < Kr < Xe (B) He < Xe < Kr < Ne
(C) Xe < Kr < Ne < He (D) He < Kr < Xe < Ne
Q14. Given below are two statements: One is labelled as Assertion A and the other is labelled as
Reason R:
Assertion A: Acetal / Ketal is stable in basic medium.
Reason R: The light leaving tendency of alkoxide ion gives the stability to acetal / ketal in
basic medium.
In the high of the above statements, choose the correct answer from the options given below:
(A) A is true but R is false
(B) A is false but R is true
(C) Both A and R are true but R is NOT the correct explanation of A
(D) Both A and R are true and R is the correct explanation of A
Q15. A cubic solid is made up of two elements X and Y. Atoms of X are present on every alternate
1
corner and one at the center of cube. Y is at rd of the total faces. The empirical formula of the
3
compound is.
(A) X2Y1.5 (B) XY2.5
(C) X2.5Y (D) X1.5Y2
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JEE-MAIN-2023 (25th January-First Shift)-PCM-11
Q16. The variation of the rate of an enzyme catalyzed reaction with substrate concentration is
correctly represented by graph
A. B.
O O
Substrate Concentration Substrate Concentration
C. D.
O O
Substrate Concentration Substrate Concentration
(A) C (B) D
(C) B (D) A
Q17. Compound A reacts with NH4Cl and forms a compound B. Compound B reacts with H2O and
excess of CO2 to form compound C which on passing through or reaction with saturated NaCl
solution forms sodium hydrogen carbonate. Compound A, B and C, are respectively.
(A) Ca(OH)2, NH3, NH4HCO3 (B) CaCl2, NH3, NH4HCO3
(C) Ca(OH)2, NH4 , (NH4)2CO3 (D) CaCl2, NH4 , (NH4)2CO3
NO 2
Me COOH Me COOH
Br Br Br Br
(A) A = ,E= (B) A = ,E=
Br Br
NO2 NO2
Me COOH Me Me
Br Br Br Br
(C) A = ,E= (D) A = ,E=
NO2 OH NO2
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JEE-MAIN-2023 (25th January-First Shift)-PCM-12
Q19.
?
PhCOOH + PhCH2OH
P Q R
The correct sequence of reagent for the preparation of Q and R is
(A) (i) KMnO4 ,OH ; (ii) Mo2O3 , ; (iii) NaOH ; (iv) H3O
(B) (i) CrO 2Cl2 ,H3 O ; (ii) Cr2O3 ,770K , 20 atm (iii) NaOH ; (iv) H3O
(C) (i) Cr2O3 ,770K , 20 atm; (ii) CrO 2Cl2 ,H3 O ; (iii) NaOH ; (iv) H3 O
(D) (i) Mo2O3 , ;(ii) CrO2Cl2 , H3 O ; (iii) NaOH ; (iv) H3O
Q20. Which one of the following reaction does not occur during extraction of copper?
(A) FeO + SiO2 FeSiO3 (B) 2FeS + 3O2 2FeO + 2SO2
(C) 2Cu2S+3O2 2Cu2O+2SO2 (D) CaO+SiO2 CaSiO3
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JEE-MAIN-2023 (25th January-First Shift)-PCM-13
Q3. The osmotic pressure of solutions of PVC in cyclohexanone at 300K are plotted on the graph.
1
The molar mass of PVC is ____________ g mol (Nearest integer)
C
4
atm / gL 1 Slope = 6 10
1
C(gL )
1 1
(Given: R = 0.083L atm K mol )
Q4. A litre of buffer solution contains 0.1 mole of each of NH3 and NH4Cl. On the addition of 0.02 mole
3
of HCl by dissolving gaseous HCl, the pH of the solution is found to be_______ 10 (Nearest
integer)
[Given: pKb(NH3) = 4.745
log2 = 0.301
log3 = 0.477
T = 298 KJ
Q5. An athlete is given 100g of glucose (C6H12O6) for energy. This is equivalent to 1800 kJ of energy.
The 50% of this energy gained is utilized by the athlete for sports activities at the event. In order
to avoid storage of energy, the weight of extra water be would need to perspire is______ g
(Nearest integer)
Assume that there is no other way of consuming stored energy.
1
Given: The enthalpy of evaporation of water is 45 kJ mol
1
Molar mass of C, H & O are 12, 1 and 16 g mol .
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JEE-MAIN-2023 (25th January-First Shift)-PCM-14
Q6. For the first order reaction A B, the half life is 30 min. The time taken for 75% completion of the
reaction is__________ min. (Nearest integer)
Given: log2 = 0.3010
log 3= 0.4771
log5 = 0.6989
Q7. The density of a monobasic strong acid (Molar mass 24.2 g/mol) is 1.21 gk/L. The volume of its
solution required for the complete neutralization of
2
25mL of 0.24 NaOH is_____________ 10 mL (Nearest integer)
Q8. The total number of lone pairs of electrons on oxygen atoms of ozone is ___________.
Q9. In sulphur estimation, 0.471 g of an organic compound gave 1.4439 g of barium sulphate. The
percentage of sulphur in the compound is _____________ ((Nearest integer)
(Given: Atomic mass Ba; 137u, S; 32u, O;16u)
Q10. How many of the following metal ions have similar value of spin magnetic moment in gaseous
state? _______________ .
(Given: Atomic number : V:23; Cr:24; Fe: 26; Ni:28)
3+ 3+ 2+ 3+
V , Cr ,Fe , Ni
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JEE-MAIN-2023 (25th January-First Shift)-PCM-15
b c
Q1. Let a, b and c be three non zero vectors such that b c 0 and a b c . If d be a
2
vector such that b d a b , then a b c d is equal to
3 1
(A) (B)
4 4
1 1
(C) (D)
2 4
Q2. The mean and variance of the marks obtained by the students in a test are 10 and 4 respectively.
Later, the marks of one of the students is increased from 8 to 12. If the new mean of the marks is
10.2, then their new variance is equal to :
(A) 4.08 (B) 4.04
(C) 3.92 (D) 3.96
1 2 3 4 5 6 .... 3n 2 3n 1 3n
Q3. The value of lim is :
n 4 4
2n 4n 3 n 5n 4
3 3
(A) 2 1 (B)
2 2 2
2 1
(C) (D) 3 2 1
2
Q5. The vector a ˆi 2ˆj kˆ is rotated through a right angle, passing through the y-axis in its way
and the resulting vector is b . Then the projection of 3a 2b on c 5iˆ 4ˆj 3kˆ is :
(A) 2 3 (B) 6
(C) 3 2 (D) 1
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JEE-MAIN-2023 (25th January-First Shift)-PCM-16
1
Q6. Let f : 0,1 R be a function defined by f x x
and g x f x f x . Consider two
1 e
statements
(I) g is an increasing function in 0,1
(II) g is one-one in 0,1
Then,
(A) Neither (I) nor (II) is true (B) Both (I) and (II) are true
(C) Only (II) is true (D) Only (I) is true
2 2 2
Q7. Let z1 2 3i and z2 3 4i . The set S z C : z z1 z z2 z1 z 2 represents a
(A) straight line with the sum of its intercepts on the coordinate axes equals -18
(B) hyperbola with the length of the transverse axis 7
(C) hyperbola with eccentricity 2
(D) straight line with the sum of its intercepts on the coordinate axes equals 14
1 logx y logx z
Q8. Let x,y,z 1 and A logy x 2 logy z . Then adj adj A 2 is equal to
logz x logz y 3
8
(A) 4 (B) 24
(C) 64 (D) 28
Q9. Let M be the maximum value of the product of two positive integers when their sum is 66. Let the
5
sample space S x Z : x 66 x M and the event A x S : x is a multiple of 3 . Then
9
P A is equal to
15 1
(A) (B)
44 3
1 7
(C) (D)
5 22
2x 1
Q10. Let f x dx . If f 3 loge 5 loge 6 , then f 4 is equal to
x 2
1 x 2
3 2
1
(A) loge 19 loge 20 (B) loge 19 loge 17
2
1
(C) loge 17 loge 18 (D) loge 17 loge 19
2
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JEE-MAIN-2023 (25th January-First Shift)-PCM-17
Q13. The points of intersection of the line ax by 0, a b and the circle x 2 y2 2x 0 are
A ,0 and B 1, . The image of the circle with AB as a diameter in the line x y 2 0 is :
2 2 2 2
(A) x y 3x 3y 4 0 (B) x y 3x 5y 8 0
2 2 2 2
(C) x y 5x 5y 12 0 (D) x y 5x 5y 12 0
Q14. Let S1 and S2 be respectively the sets of all a R 0 for which the system of linear equations
ax 2ay 3az 1
2a 1 x 2a 3 y a 1z 2
3a 5 x a 5 y a 2 z 3
has unique solution and infinitely many solutions. Then
(A) S1 is an infinite set and n S2 2 (B) S1 and S2 R 0
(C) S1 R 0 and S2 (D) n S1 2 and S2 is an infinite set
2
10 r 10
10
3 ar
Q15. If ar is the coefficient of x in the Binomial expansion of 1 x , then r is equal to
r 1 ar 1
(A) 5445 (B) 3025
(C) 4895 (D) 1210
Q16. The distance of the point P 4, 6, 2 from the line passing through the point 3, 2, 3 and parallel
to a line with direction ratios 3,3, 1is equal to :
(A) 2 3 (B) 3
(C) 14 (D) 6
Q17. The distance of the point 6, 2 2 from the common tangent y mx c, m 0 of the curve
x 2y 2 and x 1 y 2 is:
1
(A) (B) 5
3
14
(C) 5 3 (D)
3
2
x t
Q18. The minimum value of the function f x e dt is :
0
(A) 2 e 1 (B) e e 1
(C) 2e 1 (D) 2
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JEE-MAIN-2023 (25th January-First Shift)-PCM-18
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JEE-MAIN-2023 (25th January-First Shift)-PCM-19
1 2x 1 1 x2 4
Q1. If the sum of all the solutions of tan cot , 1 x 1, x 0 , is ,
1 x2 2x 3 3
then is equal to……
Q2. Let S 1,2,3,5,7,10,11 . The number of non-empty subsets of S that have the sum of all
elements a multiple of 3, is………
Q3. Let the equation of the plane passing through the line
x 2y z 5 0 x y 3z 5 and parallel to the line
x y 2z 7 0 2x 3y z 2 be ax by cz 65 . Then the distance of the point
a,b,c from the plane 2x 2y z 16 0 is…….
Q4. Let A1,A 2 ,A 3 be the three A.P. with the same common difference d and having their first terms as
th th th
A,A 1, A 2 , respectively. Let a,b,c be the 7 , 9 , 17 terms of A1,A 2 ,A 3 , respectively such that
a 7 1
2b 17 1 70 0 .
c 17 1
If a = 29, then the sum of first 20 terms of an AP whose first term is c–a–b and common
d
difference is , is equal to………..
12
5 2
Q5. Let S : log2 92 4
13 log2 ,3 4
1 2 . Then the maximum value of for which the
2
2
2
equation x 2 2 x 1 0 has real roots, is…….
s a s
1/ 3
1 x 7
Q6. For some a,b,c N , let f x ax 3 and g x xb c, x R . If fog x , then
2
fog ac gof b is equal to…..
5
1 2
Q7. The constant term in the expansion of 2x 3x is……
x7
Q8. It the area enclosed by the parabola P1 : 2y 5x 2 and P2 : x 2 y 6 0 is equal to the area
3
enclosed by P1 and y x, 0 , then is equal to…..
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JEE-MAIN-2023 (25th January-First Shift)-PCM-20
5
Q9. The vertices of a hyperbola H are 6, 0 and its eccentricity is
. Let N be the normal to H at a
2
point in the first quadrant and parallel to the line 2x y 2 2 . If d is the length of the line
2
segment of N between H and the y-axis then d is equal to……….
Q10. Let x and y be distinct integers where 1 x 25 and 1 y 25 . Then, the number of ways of
choosing x and y, such that x y is divisible by 5, is………..
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JEE-MAIN-2023 (25th January-First Shift)-PCM-21
1. D 2. B 3. B 4. D
5. C 6. B 7. A 8. D
9. D 10. D 11. D 12. C
13. B 14. C 15. D 16. D
17. D 18. A 19. A 20. C
SECTION – B
1. 10 2. 5 3. 2 4. 45
5. 17 6. 52 7. 27 8. 100
9. 4 10. 18
PART – B (CHEMISTRY)
SECTION - A
1. C 2. B 3. D 4. D
5. B 6. D 7. D 8. C
9. A 10. C 11. C 12. A
13. B 14. A 15. C 16. A
17. A 18 B 19. C 20. D
SECTION - B
1. 4 2. 10 3. 41500 4. 9079
5. 360 6. 60 7. 12 8. 6
9. 42 10. 2
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JEE-MAIN-2023 (25th January-First Shift)-PCM-22
ART – C (MATHEMATICS)
SECTION - A
1. B 2. D 3. A 4. B
5. C 6. B 7. D 8. D
9. B 10. D 11. C 12. C
13. D 14. C 15. D 16. C
17. B 18 A 19. A 20. D
SECTION - B
1. 2 2. 43 3. 9 4. 495
5. 25 6. 2039 7. 1080 8. 600
9. 216 10. 120
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JEE-MAIN-2023 (25th January-First Shift)-PCM-23
g g
Sol1. g h R 2
R 4
1
R
As we know that TP 2
gP
TP 2 2 2T
g
x x 2 2v1 v 2
Sol2. v av v av v av
x x 1 1 v1 v 2
v1 v2 v1 v2
16 4
Sol3. 8 O & 2 He .
Sol4. v̂ kˆ and Eˆ ˆj
v̂ Eˆ Bˆ ˆj Bˆ kˆ Bˆ ˆi
B 1200
Sol6. H nI 2 1.2 103 A / m
0 2
h h
Sol7. 1 and 2
2me 20 2me 40
1 40 1
2
2 20 2
5 600 10 9 x 1 2 5 600 10 9 x 1
Sol8. x 5 5 10 d 60 m
d 5 10 2
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JEE-MAIN-2023 (25th January-First Shift)-PCM-24
3RT
Sol9. vr m s
M
1 1 0
Sol12.
2 8LC 4 LC 4
Sol13. When we release the particle in tunnel it will perform SHM whose time period will be
R 6400 103 2 800
T 2 2 2 800 sec sec 84 min
g 10 60
T 1 hour 24 min
1 T2 1 1 T2
Sol14. T2 300 K
T1 2 2 600
T2 7 3 300
1 T1' 1000
T1' 10 10 T1'
dQ 12 6
Sol15. K T S K 92 22 6 K 70 K
dt 2 70
6 6 70
72 22 . t 1.4min
70 t 50
Sol17.
r
o
I I 0I
B0 1
2 r
I
I O
r I
0
B0 2
4 r
O
r
I I
B0 0
1
4 r
1 r 1
0 I
B0
4 r
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JEE-MAIN-2023 (25th January-First Shift)-PCM-25
Sol18.
tan
400
1 mv 2
40 10 4 r
20m/s
40m
mg
T
80 10 2
Sol19. 80 100 60
26
T T
20 50 80 100 60 9000 60 T 300N
2 2
Sol20.
0 Ak 0 40 10 4 1cm
C
1 2 1
d t 1 10 2 1 1
k 5
4
0 40 10 0 40 10 4 5 10 0
C F k=5
4 10 2 6 3
10 3 2
5
2cm
SECTION – B
Sol1.
R eq 10 3 2
F 62.8 106
Sol2. 1 Y 5 104 N / m2
F A A 100 3.14 2 2
1 2K
Sol4. mv 2 K v t
2 m v
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JEE-MAIN-2023 (25th January-First Shift)-PCM-26
vy
eE vP
Vy t
m ++++++++++++++++++++ +
eEt eE v P v
vy m m v E
tan -- - - - - - - - - - - - - - - -
vx v v 10cm
eE eE E 10 0.1
tan 1 45o
2 2k 2 0.5 1
mv
2
mR2 mR3 2 1 4 17
Sol5. Icm and IAB m R mR2 mR2
2 2 3 2 9 18
IAB 17 17
Icm 18 9
1
2
1
Sol6. 1 sin 45o 2 sinr sinr r 300 B
2
3 t 2t 2 300 150 M
cos 30o AB 3 2cm
2 AB 3 3 A
Lateral displacement BM AB sin15o 2 0.26 0.52cm 450
2
BM 50 10 cm
1 1 1 5RH
Sol7. RH ……..( 1) , and
0 22 32 36
1 1 1 3RH
RH 2 2
…………( 2)
2 4 16
Divide equation ( 1) by ( 2), we have
5RH 16 20 20
0
0 36 3RH 27 27
ˆi ˆj kˆ
3ˆ 1ˆ
Sol9. P Q 3 ˆi 3 ˆj 2kˆ 4iˆ 3 ˆj 2.5kˆ 3 3 2 i j 3 kˆ
2 2
4 3 2.5
3 ˆ 1ˆ 3ˆ 1ˆ
i j 3 kˆ i j 3 kˆ
2 2 2 2 1
Unit vector along P Q 3iˆ ˆj 2 3 kˆ
3 1 2 4
3
4 4
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JEE-MAIN-2023 (25th January-First Shift)-PCM-27
2 x 2 6
Sol10. 36m
3
v f 36 500 m / s 18 km / s
PART – B (CHEMISTRY)
SECTION – A
Sol1. Antibiotics is a antimicrobial substance, it inhibits the growth of microbes. It should not promote
growth or survival of microorganism. Low concentration of antibiotics is enough to increase
antimicrobial resistance.
Sol2. When electron withdrawing group present at meta position it will have lowest rate of
nuclophilic aromatic substitution.
Cl
NO 2
Cl
Cl Nu Nu
NO 2 NO 2
NO 2
Nu
(Stability increases)
When electron withdrawing group present at ortho & para position it increases the rate of
nucleophilic aromatic substitution.
Sol3.
O O H
O2
air / h
Sol4. 2H2 O 2 H2 O O 2
25 ‘V’ means
1 volume of H2O2 gives 25 volume H2O2
V.S
M
11.2
25
11.2
25
g/L 34 75.89 76
11.2
Or
Strength in g/L N Eq. wt
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JEE-MAIN-2023 (25th January-First Shift)-PCM-28
V.S 25
Eq.wt 17 75.89
5.6 5.6
O 2(A)
O3
B
X = [O] , Y = NO, A = O2, B = O3
Sol11.
CH2OH
H O H
H -(D) (-) Glucopyranose
OH H
OH OH
H OH
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JEE-MAIN-2023 (25th January-First Shift)-PCM-29
CH2OH
H O OH
H -(D) (-)Glucopyranose
OH H
OH H
H OH
CH2OH
O CH2OH
-(D) (-) Fructofuranose
H OH
H OH
OH H
CH2OH
O OH
-(D) (-) Fructofuranose
H OH
H CH2OH
OH H
+2
Sol12. For Li
x2 22 4 r1 H 3x
r2 x r1 r1 , r1
H
z2 H
3 3 H
4
+3
For Be
32 9
r3 r1 H
r1 H
4 4
3x 9 27
x
4 4 16
Sol13. (+ve) electron gain enthalpy of inert gases because octet is complete. When size increase (+ve)
electron gain enthalpy decreases
He (+48 kJ/mole)
Xe (+77 kJ/mole)
Kr(+96 kJ/mole)
Ne(+116 kJ/mole)
-
He has smallest size therefore highest tendency to accept e
Thus correct order is He < Xe < Kr < Ne.
Sol14.
R
OH
C Acetal
H OR
R
OR
C Ketal
R OR
Acetals and ketals are stable in basic medium because R-O group not a good leaving group
1
Sol15. Atom of X 4 alternate corner 1 1(centre) 3/2
8
1 1
Atoms of Y 6 At face 1
3 2
Formula X3/2 Y1 X3 Y2
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JEE-MAIN-2023 (25th January-First Shift)-PCM-30
O
Substrate Concentration
H2O
NH4 Cl NaCl
Sol17. A (B) excess CO2
(C) NaHCO3
Ca OH 2
NH4 Cl CaCl2 NH3 H2O
(A) (B)
NH3 H2 O CO 2 NH4HCO3
(B) (excess) (C)
Sol18.
Me Me Me
Br Br
Br2 Sn / HCl
NO 2 NO 2 NH2
(A) (B)
NaNO2 / HCl
(-273 - 278 K)
COOH Me
Me
Br Br
Br
(i) KMnO4 / KOH
H3PO2 / H2O
(ii) H3O+
(E) (D)
N2 Cl
(C)
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JEE-MAIN-2023 (25th January-First Shift)-PCM-31
Sol19.
CH3
NaOH
+
Cannizaro's reaction
H3O
COOH CH2OH
(Q) (R)
Cu 2 S O2 Cu2 O SO 2
FeS O2 FeO SO 2
FeO SiO 2 FeSiO3
CaO SiO2 CaSiO3 (Not found)
SECTION – B
2
2
Sol1. (a) Ni CN 4
Ni 4s0 3d8
In the effect of strong filed effect.
Changes to
8
3d
-
No unpaired e
(b) Ni CO 4 Nio 4s 2 3d8 In the effect of strong filed effect.
No unpaired e
2 2
(c) NiCl4 Ni 4s0 3d8 In the effect of weak filed ligand.
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JEE-MAIN-2023 (25th January-First Shift)-PCM-32
Unpaired e present
4 2
(d) Fe CN 6
Fe 4s0 3d6 In the effect of strong filed ligand.
changes to
-
No unpaired e
2 2
(e) Cu NH3 4
Cu 4s0 3d9 In the effect of strong filed ligand.
one unpaired e-
3 3
(f) Fe CN 6
Fe 4s0 3d5 In the effect of strong filed ligand.
changes to
one unpaired e
2
2
(g) Fe H2 O 6
Fe 4s0 8d6 In the effect of weak filed ligand.
Unpaired e present
1 3 2
Sol2. H2 (g) Fe(aq) Haq Fe(aq)
2
0 0.059 Fe 2
E E log
n Fe 3 PH2
0.059 Fe 2
0.712 0.771 0 log
1 Fe 3 1
2
Fe
0.059log 3
0.771 0.712 0.059
Fe
2
Fe 0.059
log 1 log(10)
Fe 3
0.059
2
Fe
3
10
Fe
Sol3. MRT
n w
RT RT
v M v (gL 1) Intercept 6 10 4
C
v RT
w M
RT
c M 1
C(gL )
Slope = 0
Given graph is incorrect and correct
graph is given like above.
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JEE-MAIN-2023 (25th January-First Shift)-PCM-33
RT 4
Intercept = 6 10
M
RT 0.083 300
M 4
41500
6 10 6 10 4
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JEE-MAIN-2023 (25th January-First Shift)-PCM-34
2.303 30 100
log
0.693 25
2.303 30
log 4
2.303 log2
30
2log2
log2
30 2 60min
= O O
O O O O
Total number of lone-pairs = 6
32 wt. of BaSO 4
Sol9. %of S 100
233 wt. of organic compound
32 1.4439
100
233 0.471
32 144.39
233 0.471
4620.48
42.10
109.743
42
Sol10. s n n 2 B.M
Here n = number of unpaired electrons.
V3 Ar 4s0 3d2 number of u.e = 2
3
Cr Ar 4s0 3d3 number of u.e = 3
2 0 6
Fe Ar 4s 3d number of u.e = 4
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JEE-MAIN-2023 (25th January-First Shift)-PCM-35
3
Ni Ar 4s0 3d7 number of u.e = 3
3 3
Cr & Ni have same spin only magnetic moment.
PART – C (MATHEMATICS)
SECTION – A
b c
Sol1. Given b c 0 and a b c
2
b c 1 1
a b c a c b a b c b c
2 2 2
1 1
a c and a b
2 2
a b c d a c b d a d b c
1 1
a d 0 b d a b
2 2
1
4
1 2 3 4 5 6 ..... 3n 2 3n 1 3n
Sol3. lim
n
2n4 4n 3 n4 5n 4
n
3 r 1 2n4 4n 3 n4 5n 4
r 1
lim
n
n4 n 1
n n 1
3 n2 2 1
Lt 2
n 1 1
n4 1
n3 n4
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JEE-MAIN-2023 (25th January-First Shift)-PCM-36
3 2 1
2
b 3
a b
6 3
2
b 5i 4ˆj 5kˆ
ˆ
c 25 16 15 6 3 2
3a 2b
c 50 5 2 5
or b ˆi 8ˆj kˆ
c 5 32 3 30
3a 2b 3 2
c 50 5 2
1 ex
Sol6. f x x
1 e ex 1
x x
e e 1 ex ex e2x ex e2x
f' x 2 2
ex 1 ex 1
ex
0
ex 1
f' x 0 . Hence f x decreasing in 0,1 .
1 ex 1 ex
g x
1 ex e x 1 1 e x 1 ex
2ex
g' x f' x f' x 2
0
ex 1
g' x 0 . Hence g x is increasing function. Hence it is also one-one function.
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JEE-MAIN-2023 (25th January-First Shift)-PCM-37
2
Sol7. z z1 z z1 z z2 z z2 2 3i 3 4i
1 i z 1 i z 14
x y 7
sum of intercepts on axes = 14
Sol9. a b 66
p ab a 66 a 66a a2
dp
66 2a
da
dp
0, a 33
da
M a 66 a 6 33 33 332
S x2 66x 605 0
S x 11, 55 n S 45
A x : x is multiple of 3
n A 15
15 1
P A
45 3
2x dx
Sol10. f x 2
x 1 x2 3
dt
, where x 2 t 2xdx dt
t 1 t 3
1 1 1
dt
2 t 1 t 3
1 c
f x n t 1 n t 3
2 2
1 c
f x n x2 1 n x2 3
2 2
1 c
f 3 n10 n12
2 2
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JEE-MAIN-2023 (25th January-First Shift)-PCM-38
1 1 c
n5 n6 n10 n12
2 2 2
10
n c
12
c 0
1
f x n x2 1 n x2 3
2
1
f 4 n17 n19
2
Sol11. f x 2x 4 18x 2 8x 12
3
f' x 8x 36x 8
2 6 2 6
For maximum/minimum, f ' x 0, x 2, ,
2 2
+ +
2 6 2 6 2
2 2
33 2 6
fmax 12 6 at x
2 2
dy y
Sol12. 1 xy 2 1 nx , x 0
dx x
1 dy 1
1 nx
y dx xy 2
3
1 2 dy dt
put t
y2 y 3 dx dx
1 dy 1 1 dt t
1 nx, 1 nx
y 3 dx xy 2 2dx x
I.F = x 2
tx 2 2 x2 1 nx dx
x2 2x3 2x 3 2 3
nx x c
y2 3 3 9
5
Put x = 1, y = 1, we get c
3
y2 x2
9 5 2x 2 3
nx 3
Sol13. x 2 y2 2x 0
2 2
x 1 y 1
A lies on circle,
2
2 0
0, 2
2
B lies on the circle, 1 2 0
1
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JEE-MAIN-2023 (25th January-First Shift)-PCM-39
ax by 0
B 1,
A ,0
A 0, 0 and B 1, 1
Equation of circle as AB diameter is x 2 y2 x y 0 …………(i)
1 1 1 5 5
centre of (i) , and radius = , image of centre of this circle is , .
2 2 2 2 2
2 2
equation of required circle is x y 5x 5y 12 0
a 2a 3a
Sol14. for 2a 1 2a 3 a 1
3a 5 a 5 a 2
a 15a2 31a 37 for infinite solution, 0
a 0,
S1 R 0
Hence system has infinite solution but a R 0
S2
10
Sol15. Tr 1 Cr x r 10
C10 r x10 r
10 10
ar C10 r Cr
10
ar 1 Cr 1
2 2
10
10
ar 10
Cr
r3 r3 10
r 1 ar 1 r 1 Cr 1
2
10
11 r 10
2
r3 r 1 r
r 1 r r 1
10 10
r r2 22r 121 r3 22r 2 121r
r 1 r 1
1210
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JEE-MAIN-2023 (25th January-First Shift)-PCM-40
2 x t
Sol18. f x e dt
0
Case I :
x 0,
2 2
f x e t x dt e x
e t dt e x
e2 1
0 0
fmin e 2 1
Case II :
0 x 2,
2 x 2
f x e x t dt e x t dt et x dt
0 0 x
exe2 x 2
fmin 2e e 2 2 e 1
Case III :
x 2
2
2
f x e x t dt ex e t
ex e 2
1
0
0
fmin e2 1
Sol19. f x 1 x 1 x 2 1 x 4 1 x8 1 x16
1 x32
f x
1 x
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JEE-MAIN-2023 (25th January-First Shift)-PCM-41
31 2 1 1 4 32 0
f" 1 32
4 16
32 61 30
8
4
488 8 480
f ' 1 f " 1 16 480 496
Sol20.
p q p q p q p q p q p q
T T F F F F T
T F F T T T T
F T T F F T T
F F T T F T T
Hence it is tautology.
SECTION – B
Sol1. Case-1
1 x 0
1 2x 1 1 x2
tan cot , 1 x 1, x 0
1 x2 2x 3
1 2x 1 2x
tan tan
1 x2 1 x2 3
1 2x 2
tan
1 x2 3
2 tan 1 x
3
1
x tan
6 3
Case-2
0 x 1
2x 2x
tan 1 tan 1
1 x2 1 x2 3
tan 1 x
12
x 2 3
1 4
Sum = 2 3 2
3 3
2
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JEE-MAIN-2023 (25th January-First Shift)-PCM-42
S 1, 2, 3, 5, 7, 10, 11
Sol2.
No. of element of 3k type = 1
No. of elements of 3k + 1 = 3
No. of elements of 3k + 2 type = 3
No. of subset of 1 element = 1
No. of subset of 2 elements = 1 of (3k + 1) type and 1 of (3k + 2) type = 9
No. of subset of 3 elements = 9 + 1 +1 = 11
No. of subset of 4 elements = 1 + 1 + 9 = 11
No. of subset of 5 elements = 9
No. of subset of 6 elements = 1
No. of subset of itself = 1
5iˆ 3ˆj kˆ
5 1 3 2 1 1 3 0
12
From (iv) 13x 10y 35z 65
26 20 35 16
9
Distance = 9
A1 A n 1d a A 6d b a 2d 1
Sol4.
A2 A 1 m 1d b A 1 8d c b 8d 1
A3 A 2 1 1d c A 2 16d c a 10d 2
a 0 7 c 2b 1 34b 17c 70 0
20b 10c 70 0
2b c 7 0 c 2b 7
2b a c 6d
2b 6d a c
c 7 6d a c
a 6d 7 29 7 6d d 6
a 29, b 42, c 91
20 1
s 2 20 19 495
2 2
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JEE-MAIN-2023 (25th January-First Shift)-PCM-43
log2 92 4
13 92 4 13
2
5 2 4 5 32 4
2
3 1
Sol5. 2
92 4
13 5 32 4
2
2 4
Put 3 t
t 2 13 10t 4
t 2 10t 9 0 t 1, 9
2 4 0
t 1 3 3 2
2 4 2
t 9 3 3 3
x 2 50x 25 0 2500 4 25 0
25 25
f x ax 3 g x xb c, x R
Sol6. and
1/ 3
1 x 7
fog x
2
f g x a xb c 3
1/ b 1/3
1 x 3 ac x 7
f g x
a 2
a 2, b 3, c 5
f x 2x 3, g x x3 5
fog ac gof b 2007 32 2039
5 5 r
1 1 r
2x 3x 2 Tr 1
5
Cr 2x 3x 2
x7 x7
Sol7. , general term
m
5 5 r 5 r m 1
Cr Cm 2x 3r x 2r
x7
5 5 r
Cr Cm 25 r m
3r x5 r m 2r 7m
5 r
5 r 8m 0 m
8
r 3, m 1
5 2
C3 C1 2 33 10 2 2 27 1080
constant term =
2
2y 5x 2 x2 y
Sol8. 5 …………..(i)
x2 y 6 0 x2 y 6
……….(ii)
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JEE-MAIN-2023 (25th January-First Shift)-PCM-44
2,10 2,10
2a 2a 2
,
5 5
2
5 2
x2 6 x dx
2
Area = 2
2 2
3 2 3 x3
2 6 x dx 2 6x
0
2 2 3 0
8
2 12 2 8 16
2
2a/5 2a/5
5 2 ax 2 5 x3
ax x dx
2 2 2 3
Area = 0 0
2a3
75
2a3
16 a3 600
A/q, 75
x2 y2
H: 1
Sol9. Let a2 b2
5
e
2
x y
sec tan 1
Equation of tangent at P is a b
x tan y sec a sec tan b tan sec
Equation of normal at P is b a b a
a2 b2 sec tan
ab
ax cos by cot a2 b2
acos b 1 1
2 sin 2 2
bcot a 2 2
4
x2 y2
1
equation of hyperbola is 36 9
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JEE-MAIN-2023 (25th January-First Shift)-PCM-45
equation of normal is
2x y 15
Q 0,15 P 6 2, 3
and
d2 72 144 216
x 1,2,3,....25 , y 1,2,3,.....25
Sol10.
types 5k 5k + 1 5k + 2 5k + 3 5k + 4
0 1 2 3 4
10 6 7 8 9
15 11 12 13 14
20 16 17 18 19
25 21 22 23 24
5 5 5 5 5
2 5 C1 5
C1 5
C1 5
C1 5
C1 4
C1 100 20 120
Total number =
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