06/09/2024 A

Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.011-47623456

MM : 440 Practice Test Ionic Equilibrium Time : 60 Min.

CHEMISTRY

1. What is the pH of the resulting solution when 100 mL 0.1 6. Generally on increasing the temperature, a saturated
M CH3COOH is mixed with 50 mL of 0.1 M NaOH solution
solution? (pKa of CH3COOH = 4.74) (A) Becomes unsaturated
(A) 4.74 (B) Becomes supersaturated
(B) 5.04 (C) Remains saturated
(C) 4.44 (D) Becomes suspension
(D) 9.37 7. A : CH3COOH is a strong acid.
2. R : pH of 0.1 M CH3COOH is equal to one.
A : Number of H+ ions in one ml solution of pH = 13, is
6.02 × 1023. (A)
Both Assertion & Reason are true and the reason is
the correct explanation of the assertion
R : One molar aqueous solution contains 6.02 × 1023 H+
ions Both Assertion & Reason are true but the reason is
(B)
not the correct explanation of the assertion
Both Assertion & Reason are true and the reason is
(A)
the correct explanation of the assertion (C) Assertion is true statement but Reason is false
Both Assertion & Reason are true but the reason is (D) Both Assertion and Reason are false statements
(B)
not the correct explanation of the assertion
8. Acidic buffer cannot be obtained by
(C) Assertion is true statement but Reason is false
(A) 50 ml, 0.1M KOH + 100 ml, 0.1M C6H5COOH
(D) Both Assertion and Reason are false statements
(B) 100 ml, 0.2M NaOH + 50 ml, 1M CH3COOH
3. How much water should be added to 100 mL of HCl
solution to increase its pH from 3 to 4? (C) 500 ml, 1M KOH + 500 ml, 1M C6H5COOH
(A) 100 ml
(D) 500 ml, 0.1M NaOH + 500 ml, 0.5M CH3COOH
(B) 200 ml
9. For a weak base, pKb is 4.8. If pOH of the solution of
(C) 900 ml weak base and its salt with a strong acid is 5.8, the ratio
(D) 1000 ml of concentration of base to its salt with a strong acid will
be
4. Equimolar aqueous solution of which compound will
(A) 1 : 10
have highest pH?
(B) 3 : 1
(A) NaNO3
(C) 1 : 5
(B) NH4Cl
(D) 10 : 1
(C) CaCl2
10. Pair of solutions which cannot form basic buffer, is
(D) Na3PO4
(A) NH4OH and KOH
5. What is the pH of a 10–6 M aqueous solution of NaOH at (B) NH4OH and HCI
25°C?
(C) NH4OH and (NH4)2SO4
(A) 12
(B) 6 (D) NH4OH and H2SO4

(C) 8
(D) 7

1
Practice Test Ionic Equilibrium

11. The pH of resulting solution when equal volume of 0.01 M 17. pH of a saturated solution of Ba(OH)2 is 12. The value of
NaOH and 0.1 M CH3COOH are mixed (given pKa solubility product (Ksp) of Ba(OH)2 is
(CH3COOH) = 4.74 and log3 = 0.477) is
(A) 3.3 × 10–7
(A) 3.79
(B) 5.0 × 10–7
(B) 6.5
(C) 5.79 (C) 4.0 × 10–6
(D) 4.74 (D) 5.0 × 10–6
12. 23 × 10–6 kg of sodium is added to 0.1 L of water. The pH
18. pH of 0.05 M aqueous solution of weak acid HA (Ka = 4 ×
of solution is
10–4) is
(A) 2
(A) 4.70
(B) 8
(B) 2.35
(C) 10
(C) 3.39
(D) 12
(D) 1.30
13. Maximum buffer capacity of a basic buffer is achieved
when 19. Strongest acid is
HF
(A) pOH = pKb + 1 (A)

(B) pOH = pKb – 1 HCl

(B)
(C) pOH = pKb
HBr
(D) pH = pKb + 1 (C)

14. If the solubility of Al2(SO4)3 is s mol/L then its solubility HI

product will be
(D)
(A) s2

(B) 108 s5
20. Acidic salt(s) among the following is/are
(C) 4 s3
(A) NaH2PO2
(D) 27 s4
(B) Na2HPO3
15. A : H2S is a weak acid.
(C) Na2HPO4
R : Ionisation of H2S increases in the presence HCl.
(D) All of these
Both Assertion & Reason are true and the reason is
(A) 21. Precipitation of a salt will occur when
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is (A) Ionic product = Solubility product
(B)
not the correct explanation of the assertion (B) Ionic product > Solubility product
(C) Assertion is true statement but Reason is false (C) Ionic product < Solubility product
(D) Both Assertion and Reason are false statements
(D) Ionic product = Solubility product
1

16. Aqueous solution of which among the following has

22. The change in pH (initial–final) when 90 ml, 0.01 M HCl is
highest [H+] ion concentration?
added to 10 ml, 0.01 M NaHCO3 solution is (
(A) 0.1 M HCl Ka1 = 10
−7
, Ka2 = 10
−11
for H2 C O3 )
(B) 0.1 M NaOH
(A) 6 – log2
(C) 0.01 M H2SO4 (B) 6 + 2 log3
(D) 0.01 M Ca(OH)2 (C) 6 – 3 log2
(D) 6 + 3 log2

2
Practice Test Ionic Equilibrium

23. A 0.2 M solution of monoprotic acid is 40% ionised. The 29. Molar solubility of AgCl at 25°C is 1 × 10
–5
/
mol ℓ . Its
ionization constant of this acid is solubility in 0.05 M NaCl solution is
(A) 5.33 × 10–2 (A) 10–5 M

(B) 4.7 × 10–4 (B) 2 × 10–5 M

(C) 2 × 10–1 (C) 2 × 10–9 M

(D) 3.23 × 10–2 (D) 2 × 10–3 M

24. A : Degree of hydrolysis for NH4CN depends on 30. The molar solubility of AgCl in 0.1 M solution of NaCl is
concentration of salt.
(Ksp of AgCl = 1.8 × 10–10)
R : NH4CN is a salt of weak base and strong acid.
(A) 1.8 × 10–8 M
Both Assertion & Reason are true and the reason is
(A)
the correct explanation of the assertion
(B) 1.8 × 10–9 M
Both Assertion & Reason are true but the reason is
(B) (C) 1.34 × 10–5 M
not the correct explanation of the assertion
(C) Assertion is true statement but Reason is false (D) 1.8 × 10–5 M
(D) Both Assertion and Reason are false statements
31. Which of the following statements is incorrect?
25. Which one of the following pairs is not an acidic buffer? Weaker is the acid, greater is the hydrolysis constant
(A)
(A) NaHCO3 and H2CO3 of its salt with strong base
As temperature increases, pH of pure water
(B) NaHSO4 and H2SO4 (B)
decreases
(C) HCOONa and HCOOH (C) pH is an extensive property
(D) NaCN and HCN (D) On adding NaOH in basic buffer its pOH decreases
26. The pH of a neutral water sample is 7.5. It implies the
32. The minimum volume of water required to dissolve 4.08
temperature of water gram of Calcium Sulphate at 298 K is [Given Ksp of
(A) Is more than 298 K
Calcium Sulphate is 9 × 10–6]
(B) Is less than 298 K
(A) 2.5 L
(C) Is equal to 298 K (B) 5.0 L
(D) May be either more than 298 K or less than 298 K (C) 10.0 L
27. If dissociation constant of a substituted benzoic acid is 1.0 (D) 12 L
× 10–5 then the pH of 10–2 M solution of sodium salt of
this acid will be 33. An aqueous solution of weak acid HX with 0.005 M
concentration shows a pH of 5. The ionization constant of
(A) 7 HX is
(B) 8.5 (A) 1 × 10–5
(C) 9.4
(B) 2 × 10–8
(D) 10
(C) 2 × 10–3
28. A : H O+ and OH– is not conjugate acid base pair.
3
R : Water is non-electrolyte. (D) 5 × 10–7

Both Assertion & Reason are true and the reason is 34. The ionization constant of an acid (HA) is 1.0 × 10–4. The
(A)
the correct explanation of the assertion concentration of HA in 0.01 M solution of its sodium salt is
Both Assertion & Reason are true but the reason is
(B) (A) 1 × 10–3 M
not the correct explanation of the assertion
(C) Assertion is true statement but Reason is false (B) 1 × 10–6 M

(D) Both Assertion and Reason are false statements (C) 2.5 × 10–5 M

(D) 5 × 10–8 M

3
Practice Test Ionic Equilibrium

35. Two moles of ammonia were added to one litre solution 41. Ratio of volume of acetic acid to sodium acetate (each of
each of molarity 0.1 M) required to get a buffer solution of pH of
A. 2 M H2SO4 5.76 will be (pKa of acetic acid is 4.76)
B. 2 M HCl
C. 2 M HCOOH (A) 10 : 1
The increasing order of the pH of the resulting solutions is (B) 1 : 10
(pKb of NH3 = 4.7, pKa of HCOOH = 3.7)
(C) 1 : 1
(A) C < B < A
(D) 100 : 1
(B) B < A < C
42. Acidic buffer cannot be obtained by
(C) C < A < B
(A) 50 ml, 0.1 M KOH + 100 ml, 0.1 M C6H5COOH
(D) A < B < C
(B) 100 ml, 0.2 M NaOH + 50 ml, 1 M CH3COOH
36. A : Benzoic acid is a stronger acid than formic acid.
R : Higher the pKa, stronger will be the acid. (C) 500 ml, 1 M KOH + 500 ml, 1 M C6H5COOH
Both Assertion & Reason are true and the reason is (D) 500 ml, 0.1 M NaOH + 500 ml, 0.5 M CH3COOH
(A)
the correct explanation of the assertion
43. Which of the following mixture of solutions can behave as
Both Assertion & Reason are true but the reason is
(B) a buffer solution?
not the correct explanation of the assertion
(C) Assertion is true statement but Reason is false (A) 10 mL of 1 M HCl + 10 mL of 1 M NH4OH

(D) Both Assertion and Reason are false statements (B) 10 mL of 1 M HCl + 10 mL of 0.5 M NH4OH

37. For a diprotic weak acid (H2A) the value of K and K

a1 a2
(C) 10 mL of 0.5 M HCl + 10 mL of 0.5 M NH4OH
are 3 × 10–6 and 3 × 10–10 respectively. The pH of its 1M (D) 10 mL of 0.5 M HCl + 10 mL of 1 M NH4OH
aqueous solution will be
44. Out of the following, which forms buffer on mixing?
(A) 5.55
(A) 20 ml of 0.5 M CH3COOH and 50 ml of 0.2 M NaOH
(B) 3.74
(C) 6.92 (B) 100 ml of 0.1 M HCOOH and 100 ml of 0.1 M KOH

(D) 2.76 (C) 75 ml of 0.1 M NaOH and 150 ml of 0.1 M CH3COOH

38. Pair of solution which can represent acidic buffer is (D) 50 ml of 0.2 M KOH and 10 ml of 0.5 M HCOOH

(A) HClO4 + NaClO4 45. Which one of the following pairs of solution will not act as
an acidic buffer?
(B) Na2SO4 + H2SO4
(A) H2CO3 and Na2CO3
(C) Na2S + H2S
(B) H2SO4 and Na2SO4
(D) HCl + NaCl
(C) CH3COOH and CH3COONa
39. Which of the following salt undergoes cationic hydrolysis
? (D) HCN and NaCN

(A) NH4Cl 46. Select the correct option regarding boric acid

(B) NaHCO3 (A) Arrhenius acid

(B) Tribasic acid
(C) NaNO3
(C) Bronsted acid
(D) NaCN
(D) Lewis acid
40. A : H O+ and OH– are not conjugate acid base pair.
3 47. If pH of neutral water at 90°C is 5 then the ionic product of
R : NaOH is non-electrolyte. water at 90°C is
Both Assertion & Reason are true and the reason is
(A) (A) 10–7
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is (B) 10–10
(B)
not the correct explanation of the assertion
(C) 10–12
(C) Assertion is true statement but Reason is false
(D) Both Assertion and Reason are false statements (D) 10–14

4
Practice Test Ionic Equilibrium

48. A : Hydride ion (H–) is a conjugate base of H . 54. For a weak base, pKb is 4.8. If pOH of the solution of
2
– weak base and its salt with a strong acid is 5.8, the ratio
R : Hydroxide ion (OH ) is a conjugate base of H2O. of concentration of base to its salt with a strong acid will
be
Both Assertion & Reason are true and the reason is
(A)
the correct explanation of the assertion (A) 0.1
Both Assertion & Reason are true but the reason is (B) 3
(B)
not the correct explanation of the assertion
(C) 6
(C) Assertion is true statement but Reason is false
(D) 10
(D) Both Assertion and Reason are false statements
55. If the pH of a solution is increased from 2 to 5 then its H+
49. Equal volumes of three aqueous solutions with pH values concentration will
11, 12, 13 are mixed in a vessel at 25°C. The OH– ion
(A) Reduce to half
concentration in the mixture is
(B) Become double
(A) 3.7 × 10–2 M
(C) Increase by 100 times
(B) 4.9 × 10–3 M
(D) Become times
1
th
1000

(C) 3.7 × 10–4 M

56. What is pH of the resulting solution when equal volumes
(D) 2.1 × 10–2 M of 0.01 M H2SO4 and 0.1 M HCl are mixed? (log 3 =
0.477)
50. The combination(s) represent acid base reaction is/are
(A) 3.25
(A) H2SO4 + CH3COOH
(B) 2.21
(B) H2SO4 + HNO3 (C) 2.98
(C) CO2 + CaO (D) 1.22
(D) All of these 57. pKa and pKb of weak acid HA and weak base BOH are
51. The pH of 1 M 4.5 and 4.69 respectively. The pH of 0.2 M solution of salt
PO
3−
aqueous solution will be [pKb
4 (BA) will be
( PO
3−
) = 1.62]
4
(A) 7.095
(A) 13.19 (B) 6.905
(B) 8.62 (C) 4.89
(C) 6.19 (D) 5.99
(D) 11.9 58. At 298 K, pH of 0.1 M NaOH is
52. Ratio of concentration of acetic acid to sodium acetate (A) 13
required to get a buffer solution of pH of 5.76 will be (pKa
of acetic acid is 4.76) (B) 14

(A) 10 : 1 (C) 1

(B) 1 : 10 (D) 2

(C) 1 : 1 59. Solubility of CO2 in water can be increased by

(D) 100 : 1 (A) Increasing volume

53. At t°C, K for water is 6.4 × 10–13. The pH of water at t°C (B) Increasing pressure
w
will be (C) Increasing temperature

(A) 6.91 (D) All of these

(B) 5.90 60. A buffer solution cannot be prepared from a mixture of

(C) 6.09 (A) Sodium acetate and acetic acid in water
(D) 5.15 (B) Ammonia and ammonium chloride in water
(C) Sodium acetate and hydrochloric acid in water
(D) Aniline and Anilinium ion in water

5
Practice Test Ionic Equilibrium

61. Which of the following aqueous solution is acidic in 67. Equal volumes of two strong acids having pH = 4 and pH
nature? (Ka(CH3COOH) = Kb(NH4OH) = 10–5) = 6 are mixed. How much volume of this mixture is
required to neutralise the 100 ml 0.2 N NaOH solution?
(A) 0.1 M CH3COONa (A) 3.96 litre
(B) 0.01 M CH3COONa (B) 3.96 ml

(C) 0.01 M CH3COONH4 (C) 3.96 × 105 ml

(D) 0.01 M NH4Cl (D) 3.96 × 106 ml

62. 100 ml of 0.4 M KOH solution is mixed with 400 ml of 0.1 68. pH of a strong acid solution is 2. What volume of water
M formic acid solution. The pH of the resultant solution must be added to its 1 L of solution so that pH of new
will be solution becomes 3?
(pKa of formic acid = 3.75)
(A) 1 L
(A) 9.2
(B) 2 L
(B) 7.5
(C) 10 L
(C) 8.3
(D) 9 L
(D) 10.2
69. K for triethyl amine is 6.5 × 10–5. Calculate K for
63. On dilution, the pH of a strong acid is increased from 1 to b a
triethyl ammonium ion?
1.5. The change in [H3O+] of the acid is (given 10–1.5 =
0.032) (A) 1.47 × 10–9
(A) 0.068 M (B) 1.54 × 10–10
(B) 0.032 M
(C) 1.47 × 10–8
(C) 0.028 M
(D) 1.54 × 10–8
(D) 0.018 M
70. The resulting solution obtained by mixing 100 ml, 0.1 M
64. A solution is 0.1 M with respect to Ag+, Cu2+, Mn2+ and
H2SO4 and 50 ml, 0.4 M NaOH will be
Sr2+. Which will precipitate first when CO is added in
2−
3
(A) Neutral
the solution?
(B) Strongly acidic
(A) Ag2CO3 (Ksp = 8.1 × 10–12)
(C) Basic
(B) CuCO3 (Ksp = 1.4 × 10–10) (D) Weakly acidic

(C) MnCO3 (Ksp = 1.8 × 10–11) 71. If 100 mL solution of pH = 2 is mixed with 100 mL of
solution of pH = 3, then pH of mixture will be
(D) SrCO3 (Ksp = 1.1 × 10–10) (A) 1.5

65. 1 L aqueous solution of HCl of pH 3 is diluted with water (B) 2.26

so that the pH of solution becomes 5. Volume of water (C) 0.39
added to the solution is
(D) 3.5
(A) 10 L
72. The solubility products of two salts AB2 and C2D3 are
(B) 100 L
same then the relation between solubilities of salt
(C) 1000 L C2D3(S') and AB2(S) is
(D) 99 L (A) −−−'
S = 27√2S

66. Ka
2
(B) S
' 3
= 108S
of citric acid at 298 K is
(Given : K = 7.4×10–4, = 4.0 × 10–7).
−−−−−
a1 Ka
3
(C) 5
S = √27S
'3

3 −−−−−
(A) 1.7 × 10–5 (D) S = √27S
'5

(B) 4.3 × 10–12 73. pH of 0.1 M NaOH solution is

(A) 1
(C) 5.9 × 10–2
(B) 12
(D) 4.2 × 10–13
(C) 6
(D) 13

6
Practice Test Ionic Equilibrium

74. pH of resulting solution when equal volume of 0.1 M 81. The pH of a solution at 25°C that contains 10–10 M
NaOH mixed with 0.1 M H2SO4 is (log5 = 0.7)
hydroxide ions (OH–) is
(A) 1.3
(A) 2
(B) 5.7
(B) 10
(C) 7
(C) 4
(D) 10.6
(D) 14
75. Equal volumes of acidic solutions having pH 3, 4 and 5
82. A : Dissociation of acetic acid can be suppressed by
are mixed. H+ concentration in mixture will be addition of sodium acetate into the solution.
R : Mixture of acetic acid and sodium acetate behave as
(A) 1.85 × 10–5 M acidic buffer.
(B) 3.7 × 10–4 M Both Assertion & Reason are true and the reason is
(A)
the correct explanation of the assertion
(C) 1.11 × 10–5 M
Both Assertion & Reason are true but the reason is
(B)
(D) 1.85 × 10–4 M not the correct explanation of the assertion
(C) Assertion is true statement but Reason is false
76. If the pH of an aqueous solution of monoprotic weak acid
is pKa –1 at 25°C, then molarity of H+ ion will be (Ka of (D) Both Assertion and Reason are false statements

acid = 10–3) 83. With increase in the temperature from T1 to T2,

equilibrium constant K1 of an endothermic reaction
(A) 10–3 changes to K2. Select the correct relation from the
(B) 10–4 following (assume enthalpy of reaction to be independent
of temperature)
(C) 10–2
(A) K1 < K2
(D) 10–5 (B) K1 = K2
77. If pH of neutral water at 90°C is 5 then the ionic product of (C) K1 ≥ K2
water at 90°C is
(D) K1 > K2
(A) 10–7
84. At 298 K, pH of a saturated solution of a diacidic base
(B) 10–10 X(OH)2 is 11. The solubility product (Ksp) of X(OH)2 is

(C) 10–12 (A) 5.0 × 10–10

(D) 10–14 (B) 7.0 × 10–9

78. An example of an acidic buffer is (C) 7.0 × 10–8

(A) Formic acid and acetic acid (D) 4.0 × 10–9
(B) Sodium acetate and sodium chloride
85. Solution which can act as an acidic buffer is
(C) Acetic acid and sodium acetate
(A) NaCl + CH3COOH
(D) Ammonium hydroxide and ammonium cyanide
(B) NaOH + HClO4
79. Approximate pH of 10–8 M HNO in aqueous medium is
3
(C) CH3COOH + CH3COONa
(A) 6
(D) NaClO4 + HClO4
(B) 7.04
86. If pH of a saturated solution of a diacidic base B(OH)2 is 8
(C) 6.96
then the solubility product, Ksp of B(OH)2 is
(D) 8
(A) 10–12
80. A : Solution of NH4Cl is acidic in nature.
R : NH4OH is weak base. (B) 5 × 10–12
Both Assertion & Reason are true and the reason is (C) 10–19
(A)
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is (D) 5 × 10–19
(B)
not the correct explanation of the assertion
(C) Assertion is true statement but Reason is false
(D) Both Assertion and Reason are false statements

7
Practice Test Ionic Equilibrium

87. What will be the pH of solution obtained by mixing 25 ml 93. What is pH of the resulting solution when equal volumes
of 0.2 M HCl with 25 ml of 0.2 M Ba(OH)2? of 0.01 M H2SO4 and 0.1 M HCl are mixed? (log 3 =
0.477)
(A) 7
(A) 3.25
(B) 1
(B) 2.21
(C) 13
(C) 2.98
(D) 14
(D) 1.22
88. Given, pH of a solution A is 3 and another solution B
having pH = 3. If equal volume of both is mixed then 94. How much water should be added to 100 mL of HCl
resultant pH of the solution will be solution to increase its pH from 3 to 4?
(A) 6 (A) 100 ml
(B) 3 (B) 200 ml
(C) 2.3 (C) 900 ml
(D) 2.7 (D) 1000 ml
89. pH of a solution obtained by mixing equal volume of two 95. pH of a saturated diacidic base B(OH)2 is 10. The
solutions of pH 2 and 3, is approximately equal to (log55 solubility product of B(OH)2 at 25°C is
= 1.74)
(A) 2.26 (A) 2 × 10–12

(B) 2.5 (B) 5 × 10–13

(C) 1.5 (C) 5 × 10–11
(D) 3.5
(D) 2 × 10–16
90. Which of the following solution will have pH value close
to 1.0? 96. Which pair of solution can form an acidic buffer?

(A) 75 ml of M
HCl + 25 ml of M
NaOH (A) H2CO3 and NaHCO3
5 5

(B) H2CO3 and H2SO4

(B) 55 ml of M

10
HCl + 45 ml of M

10
NaOH
(C) HNO3 and CH3COOH
(C) 10 ml of M
HCl + 90 ml of M
NaOH
(D) NH4Cl and HCl
10 10

(D) 100 ml of M
HCl + 100 ml of M
NaOH
10 10
97. Which of the following equimolar solution of given salts
will show the lowest pH in water?
91. When 40 cm3 of N aOH , 50 cm
M 3 of H N O and 10
M
3

(A) CH3COONa
4 5

3
cm of H C l solutions are mixed and the volume is
M

made upto 500 mL, the pH of resulting solution is (B) CH3COONH4

(A) 2 (C) NaBr

(B) 3 (D) (NH4)2SO4

(C) 4 98. 50 ml of 0.1 M RbOH is added to 75 ml of 0.1 M NH4Br to
(D) 5 make a basic buffer. If pKa of NH is 9.25, then the pH of
+

buffer formed is
92. Which of the following solutions will have pH value more
than 12? (A) 9.25
M M
S1 : 100 ml
10
KOH + 200 ml
10
H N O3
(B) 4.75
M M
S2 : 50 ml
10
KOH + 100 ml
20
H N O3
(C) 4.45
M M
S3 : 50 ml
5
KOH + 100 ml
20
H N O3
(D) 9.55
M 1
S4 : 100 ml KOH + 900 ml H N O3
10 100

(A) S3

(B) S1

(C) S4

(D) S2

8
Practice Test Ionic Equilibrium

99. Which of the following solutions will have pH value more 104.Which one of the following pairs is not an acidic buffer?
than 12?
M M (A) NaHCO3 and H2CO3
S1 : 100ml KOH + 200ml HNO3
10 10

S2 : 50ml
M
KOH + 100ml
M
HNO3
(B) NaHSO4 and H2SO4
10 20

S3 : 50ml
M
KOH + 100ml
M
HNO3 (C) HCOONa and HCOOH
5 20

S4 : 100ml
M
KOH + 900ml
1
HNO3
(D) NaCN and HCN
10 100

(A) S3 105.The pKa of acetic acid and pKb of ammonium hydroxide

are 4.76 and 4.75 respectively. The pH of resultant
(B) S1 solution made by mixing 100 ml each of 0.1 M acetic acid
and 0.1 M ammonium hydroxide, is
(C) S4
(A) 3
(D) S2
(B) 7.005
100.A : The solubility of CH3COONa ismore at lower pH. (C) 6.5
R : At lower pH the concentration of CH3COO– ion (D) 14
decreases due to its protonation.
106.Which one of the following pairs of solution will not act as
Both Assertion & Reason are true and the reason is an acidic buffer?
(A)
the correct explanation of the assertion
(A) H2CO3 and NaHCO3
Both Assertion & Reason are true but the reason is
(B)
not the correct explanation of the assertion (B) H2SO4 and Na2SO4
(C) Assertion is true statement but Reason is false (C) CH3COOH and CH3COONa
(D) Both Assertion and Reason are false statements (D) HCN and NaCN
101.At 298 K, a certain buffer solution contains equal 107.If 1 M weak acid solution HA is 1% ionized then
concentrations of HY and Y–. pH of the buffer solution is percentage ionisation of 4M solution of the acid HA will
(Given that hydrolysis constant of Y– is 10–9) be

(A) 4.31 (A) 0.1%

(B) 5 (B) 0.2%

(C) 8.2 (C) 0.5%

(D) 9 (D) 4%

102.Which will make acidic buffer? 108.The solubility of a salt A2B in pure water will be (Ksp of

(A) 100 mL of 0.1 M HCl and 50 mL of 0.2 M NH4OH A2B = 1.08 × 10–16)

100 mL of 0.1 M CH3COOH and 50 mL of 0.1 M (A) 3 × 10–6 mol L–1

(B)
NaOH
(B) 2 × 10–8 mol L–1
(C) 100 mL of 0.1 M HCl and 50 mL of 0.1 M NaOH
(C) 4 × 10–12 mol L–1
(D) 100 mL of 0.2 M HCl and 100 mL of 0.1 M CH3COOH
(D) 3 × 10–18 mol L–1
103.Given below are two statements: One is labelled as
Assertion(A) and the other is labelled as Reason(R).
Assertion(A): CH3COOH is a strong acid.
Reason(R): pH of 0.1 M CH3COOH is equal to one.
In the light of the above statements, choose the most
appropriate answer from the options given below:
Both Assertion & Reason are true and the reason is
(A)
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is
(B)
not the correct explanation of the assertion
(C) Assertion is true statement but Reason is false
(D) Both Assertion and Reason are false statements

9
Practice Test Ionic Equilibrium

109.0.1 mole of HCl is added to 1 litre of a buffer solution

made up of 0.1 M CH3COOH and 0.3 M CH3COONa.
The final pH of the solution will be (pKa of acetic acid is
4.75)
(A) 5.05
(B) 4.45
(C) 4.75
(D) 6.2

110.Given below are two statements: one is labelled as

Assertion (A) and other is labelled as Reason (R):
Assertion (A) : The value of Kw gets decreased on
increasing temperature.
Reason (R) : Value of Kw depends on [H3O+].
In the light of the above statements, choose the correct
answer from the options given below:-
Both Assertion & Reason are true and the reason is
(A)
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is
(B)
not the correct explanation of the assertion
(C) Assertion is true statement but Reason is false
(D) Both Assertion and Reason are false statements

10