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287 views7 pagesChemistry March 2024 PYQ
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sumbogreedyCopyright
© © All Rights Reserved
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SEAT NUMBER | |
(2024] 11 ]29 T1007 J-852
CHEMISTRY (55)
Time : 3 Hrs. (7 Pages) ie Marks : 71
General Instructions :
The question paper is divided into four sections.
@
2)
(3)
(4)
6)
6)
7)
Section A:
Section B:
Section C:
Section D:
Q.No. I contains Ten multiple choice type of questions
carrying One mark each. Only the first attempt will be
considered for evaluation.
Q. No. 2 contains Eight very short answer type of
questions carrying One mark each,
OQ. No. 310 O. No. 14 are Twelve short answer type of
ng Two marks each, (Attempt any Eight)
questions ca
Q. No. 15 to Q. No. 26 are Twelve short answer type of
questions carrying Three marks each, (Attempt any
Eight)
OQ. No. 27 10 Q. No. 31 are Five long answer type of
questions carrying Four marks each. (Attempt any
Three)
Use of log table is allowed. Use of calculator is not allowed,
Figures to the right indicate full marks
Given: R=8314).K.mol !
Na = 6.022 « 10°
F = 96500C
Page 1 PLO,
| SECTION -A
Q. 1, Select and write the correct answer for the following multiple
choice type of questions :
[10]
() The spin only magnetic moment of Cr* cation is
(a) 3.742BM (b) 3.755BM
(c) 3.873BM (d) 3.633BM
Ali) The linkage present in Lactose is
(a) a, B-1, 2 -glycosidic linkage
(b) a1, 4 ~ glycosidic linkage
(c) B-1,4-glycosidic linkage
(d) =I, 4 ~ glycosidic linkage
(ii) ‘The product of the following reaction is
°
Il
C)Hs -C-CH
H/Ni
ee
(a) CH; -CH, -CH -CH, -OH :
(b) CH; -CH-CH, -CH3 |
oO
(c) CH; -CH) ~CH, -CHy
(d) CH, -CH2 - CH, -COOH
(iv) The pH of 0.001M HCI solution is__- hy [ro
(a) 10 fb) 3
(c) 2 (d) Ul
_(v) | The correct structure of complex having IUPAC name
sodium hexanitrocobaltate (III) is
(a) Nag [Co(NO3)s]
(b) Nay [Co(NO2)¢]
(c) Na; [Co(NO3)¢]
(d) Nag [Co(NO})s]
0/8 s[2] Page 2 <évi) The number of particles present in Face Centred Cubic Unit
Cell is/are
(a) | (b) 2
©) 3 A 4
(vil) The monomer used in preparation of teflon is
(a) Ecaprolactum (b)_ vinyl chloride
(c) styrene A) tetrafluoroethene
(viii) Among the following vinylic halide is
(a) R-CH-R fb) CH, =CH-X
x
x
© OF (4) CH) =CH-CH,-X
(ix) The product of hydrolysis of propyne in the presence of
1% H,SO, and 40% H,SO, is . ce
(a) methanal (b) ethanal
Ae) propanal (d) propanone
(x) If unit of rate constant is mol dm~?s~!, the order of reaction
would be on
{a) zero (b) t
(c) 2 (d) 3
Q. 2. Answer the following questions :
Ai) Write the name of metal nanoparticle used to remove E.coli
bacteria from water. Sihev oce'st
Aii)) Write the name of reduction product formed when ethyl
cyanide is treated with sodium and alcohol. Cv. -¢
‘ CN
__Aiii) Complete the reaction: CH;CH,CIE ?
Ai) Calculate effective atomic number of [Co (NH3),]°* ion.
els] Peged os
CH dative:
(81
P.T.O. (ten
Q. 6.
Q.7.
Q.9.
_ (x) The compounds of Ti** ions are colourless due to -
&) Write SI unit of molar conductivity, Ob"
Gil) Write the sign convention of work done during expansion
™ of gas. >
_ (viii) Write the condition of reverse osmosis./
SECTION - B
npt any EIGHT of the following questions : [16]
Derive an expression for maximum work obtainable during
isothermal reversible expansion of an ideal gas from initial volume
(V,)to final volume (V3).
What are interhalogen compounds? Write the chemical reaction,
when chlorine reacts with dry slaked lime,
What is nano material? Write the reaction involved in sol-gel
process during hydrolysis.
Write classification of proteins with an example.
Calculate the time required to deposit 2-4 g of Cu, when 2-03 A
of current passed through CuSO, solution.
(At. mass of Cu = 63.5 g.mol"!)
Why amines are basic in nature? Among dimethylamine (pK, =
3:27) and diethylamine (pK, = 3-0), which one is more 2
Explain buffer action of sodium acetate-acetic acid buffer.
Q. 10. Write preparation of (a) diethyl ether (b) ethyl cyanide from ethyl
bromide.
|. LH. Henry’s constant for CH3Br,) is 0-159 mol dm-3.bar~! at 25°C.
A. y 38M)
Calculate its solubility in water at 25°C, if its partial pressure is
0-164 bar.
Page 4 Heh Q. 12. Write the structure and name of monomer of
(a) Nylon-6
(b) Natural rubber
Q. 13. Define Lanthanide contraction. Write the balanced chemical
equations when acidified K,Cr,0, reacts with HS.
Q. 14, Derive the relationship between molar mass, density of the
substance and unit cell edge length.
SECTION -C
Attempt any EIGHT of the following questions : [24]
Q. 15. What is osmotic pressure? How will you determine molar mass
of solute from osmotic pressure? T= O*
Q. 16. Write chemical reactions involved in :
(a) Rosenmund reduction.
(b) Gatterman Koch formylation. :
(c) Cannizzaro reaction of methanal. +6395
Q_ 17. Calculate the standard enthalpy of combustion of methane, ifthe
standard enthalpy of formation of methane, see dioxide and
water are -74-8, 393-5 and —285-8 kimol | respectively. Agutr
AQ. 18. What is the action of following on ethyl bromide ?
(a) silver nitrite CMs yr 4 Rath > Heo omyawe “ts
(b) Mg indry ether -)- Bray oy
(c) alcoholic sodium hydroxide oy
Heh, BET TMeOM Chey ay
. 19. For the reaction A + B — P. J ”
If [B] is doubled at constant [A], the rate of reaction doubled. If
[A] is triple and [B] is doubled, the rate of reaction increases by
a factor of 6. Calculate the rate law equation.
018 ]5[2] Page § PTO. 3 Q. 20, Arrange the following in the increasing
order of the property
mentioned:
@)
(ii)
(ii)
Q. 21. Expl
propi
HOCI, HCIO,, HCIO;, HCI, (acidic strength)
MFeMCls MBrsI (ionic character)
HE Hg, Ope HI (thermal stability)
jain Wolf-Kishner reduction reaction. Write preparation of
anone by using ethanoyl chloride and dimethyl cadmium.
Q. 22. Write postulates of Werner theory of co-ordination complexes.
:
Write the name of a hexadentate ligand, ‘E0%*”
_Q. 23. Define electrochemical series and write its two applications.
Q. 24, Identify ‘A’, ‘B’ and ‘C’ in following chain reaction and rewrite
the chemical reactions:
cH
CH,OH—R#2_, we AKON ,p_ LiAlHy 6 cE
ale? Ether
-Q. 25. Define acids and bases according to Bronsted-Lowry theory.
Derive relationship between pH and pOH.
Q. 26. Write the preparation of potassium dichromate from chromite
ore.
SECTION - D
Attempt any THREE of the following questions : [12]
Q. 27. Convert the following :
@
(i)
ii)
2]
acetaldehyde to isopropyl alcohol. 1 -¢
cumene to phenol. <>
anisole to phenol.
Write two uses of neon.
Page 6 228. Define: (i) Extensive and Intensive properties
(ii) Isobaric and Adiabatic processes
What are enzymes?
Write the atomic numbers of transuranium
elements.
Q. 29: Predict the type of cubic lattice of a solid element having edge
length of 400 pm and density is 6-25 g/ml
(Atomic mass of element = 60)
7 Define : Nanoscience
Write chemical reaction for the preparation of polyacrylonitrile.
2. 30, Derive the relation between half life period and rate constant for
first order reaction.
©Wvrite the net cell reaction during discharging of lead accumulator.
© Draw the structure of peroxymonosulphuric acid. -
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