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17 views22 pages

En US

Uploaded by

Shoba Raj
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Safety Data Sheet

Hempadur XP 87559 Base

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2020/878 - Europe

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1 Product identifier
Product name : Hempadur XP 87559 Base
Product identity : 8755959700, 0000BC9E
Product type : epoxy paint

1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : metal industry, ships and shipyards.
Ready-for-use mixture : 87559 4 Li / 98550 1 Li
Identified uses : Industrial applications, Used by spraying.

1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Company details : HEMPEL A/S Emergency telephone number (with hours of operation)
Lundtoftegårdsvej 91
DK-2800 Kgs. Lyngby +45 45 93 38 00 (08.00 - 17.00)
Denmark See section 4 First aid measures.
Tel.: + 45 45 93 38 00
[email protected]
Date of issue : 17 December 2024
Date of previous issue : 9 December 2024.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture


Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 2, H225 FLAMMABLE LIQUIDS
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION
Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION
Skin Sens. 1, H317 SKIN SENSITIZATION
Repr. 2, H361d TOXIC TO REPRODUCTION
Aquatic Chronic 2, H411 AQUATIC HAZARD (LONG-TERM)
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements


Hazard pictograms :

Signal word : Danger


Hazard statements : H225 - Highly flammable liquid and vapor.
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H361d - Suspected of damaging the unborn child.
H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements :
Prevention : Wear protective gloves, protective clothing, eye protection, face protection, or hearing protection. Keep
away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid
release to the environment.
Response : Collect spillage.
Hazardous ingredients : bisphenol A-(epichlorhydrin) epoxy resin MW =< 700
formaldehyde, polymer with (chloromethyl)oxirane and phenol
toluene
1,6-hexanediol diglycidylether
1,3-bis(12-hydroxyocta-decanamide-N-methyle)benzene
Supplemental label elements : Contains epoxy constituents. May produce an allergic reaction.
Special packaging requirements

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Hempadur XP 87559 Base

SECTION 2: Hazards identification


Containers to be fitted with child- Not applicable.
resistant fastenings :
Tactile warning of danger : Not applicable.

2.3 Other hazards


This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
Other hazards which do not result None known.
in classification :

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Product/ingredient name Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type

bisphenol A-(epichlorhydrin) REACH #: 01-2119456619-26 ≥10 - ≤25 Skin Irrit. 2, H315 Skin Irrit. 2, H315: C ≥ 5% [1]
epoxy resin MW =< 700 EC: 216-823-5 Eye Irrit. 2, H319 Eye Irrit. 2, H319: C ≥ 5%
CAS: 1675-54-3 Skin Sens. 1, H317
Index: 603-074-00-8 Aquatic Chronic 2, H411
formaldehyde, polymer with REACH #: 01-2119454392-40 ≥5 - ≤10 Skin Irrit. 2, H315 - [1]
(chloromethyl)oxirane and EC: 701-263-0 Skin Sens. 1, H317
phenol CAS: 9003-36-5 Aquatic Chronic 2, H411
toluene REACH #: 01-2119471310-51 ≥5 - <10 Flam. Liq. 2, H225 - [1] [2]
EC: 203-625-9 Skin Irrit. 2, H315
CAS: 108-88-3 Repr. 2, H361d
Index: 601-021-00-3 STOT SE 3, H336
STOT RE 2, H373
Asp. Tox. 1, H304
1,6-hexanediol diglycidylether REACH #: 01-2119463471-41 ≥1 - ≤3 Skin Irrit. 2, H315 - [1]
EC: 240-260-4 Eye Irrit. 2, H319
CAS: 933999-84-9 Skin Sens. 1, H317
Aquatic Chronic 3, H412
hydrocarbons, C9-C11, n- REACH #: 01-2119463258-33 ≥1 - ≤3 Flam. Liq. 3, H226 - [1]
alkanes, isoalkanes, cyclics, EC: 265-150-3 STOT SE 3, H336
<2% aromatics CAS: 64742-48-9 Asp. Tox. 1, H304
Index: 649-327-00-6 EUH066
propan-2-ol REACH #: 01-2119457558-25 ≥1 - ≤3 Flam. Liq. 2, H225 - [1] [2]
EC: 200-661-7 Eye Irrit. 2, H319
CAS: 67-63-0 STOT SE 3, H336
Index: 603-117-00-0
1,3-bis(12-hydroxyocta- REACH #: 01-0000016979-49 <1 Skin Sens. 1B, H317 - [1]
decanamide-N-methyle) EC: 423-300-7 Aquatic Chronic 4, H413
benzene
4,4'-isopropylidenediphenol REACH #: 01-2119457856-23 <0.1 Eye Dam. 1, H318 M [Acute] = 1 [1] [3] [4]
EC: 201-245-8 Skin Sens. 1, H317 M [Chronic] = 10
CAS: 80-05-7 Repr. 1B, H360F
Index: 604-030-00-0 STOT SE 3, H335
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
See Section 16 for the full text of the H statements declared
above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[3] Substance of equivalent concern - Endocrine disrupting properties
[4] Substance with carcinogenic, mutagenic or reproductive toxicity properties

SECTION 4: First aid measures

4.1 Description of first aid measures


General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention/advice.

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SECTION 4: First aid measures


Inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. Give nothing by mouth. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. If unconscious, place in recovery position and get medical attention
immediately.
Skin contact : Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or
thinners. Remove contaminated clothing and shoes.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to
the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.
Specific treatments : No specific treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media


Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used: waterjet.

5.2 Special hazards arising from the substance or mixture


Hazards from the substance or Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if
mixture : heated, a pressure increase will occur and the container may burst, with the risk of a subsequent
explosion. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with
this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion products : Decomposition products may include the following materials: carbon oxides sulfur oxides halogenated
compounds metal oxide/oxides

5.3 Advice for firefighters

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SECTION 5: Firefighting measures


Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


Avoid all direct contact with the spilled material. Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Refer to
protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk or without suitable training. If the
product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.

6.2 Environmental precautions


Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if
released in large quantities.

6.3 Methods and materials for containment and cleaning up


Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same
hazard as the spilled product.

6.4 Reference to other sections


See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling


Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or
explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the
product should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment
should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving
container with bonding strap. No sparking tools should be used. Contains epoxy constituents. Avoid all possible skin contact with epoxy and
amine containing products, they may cause allergic reactions.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.

7.2 Conditions for safe storage, including any incompatibilities


Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources.
Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized
access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.

7.3 Specific end use(s)


See separate Product Data Sheet for recommendations or industrial sector specific solutions.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters


Occupational exposure limits

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SECTION 8: Exposure controls/personal protection

Product/ingredient name Exposure limit values

toluene EU OEL (Europe, 1/2022) Absorbed through skin.


TWA 8 hours: 192 mg/m³.
TWA 8 hours: 50 ppm.
STEL 15 minutes: 384 mg/m³.
STEL 15 minutes: 100 ppm.
propan-2-ol EU OEL (Europe, 2/2010)
(ACGIH) TWA 8 hours: 200 ppm.
(ACGIH) STEL 15 minutes: 400 ppm.

Biological exposure indices


Product/ingredient name Exposure limit values

No exposure limit value known.

Recommended monitoring procedures


Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres -
Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure
to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of
procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Derived effect levels
Product/ingredient name Type - Population - Exposure Value Effects
bisphenol A-(epichlorhydrin) epoxy resin MW DNEL - Workers - Long term - Dermal 8.33 mg/kg bw/day Effects: Systemic
=< 700
DNEL - Workers - Long term - Inhalation 12.25 mg/m³ Effects: Systemic
formaldehyde, polymer with (chloromethyl) DNEL - Workers - Long term - Dermal 104.15 mg/kg bw/day Effects: Systemic
oxirane and phenol
DNEL - Workers - Long term - Inhalation 29.39 mg/m³ Effects: Systemic
toluene DNEL - Workers - Long term - Dermal 384 mg/kg bw/day Effects: Systemic
DNEL - Workers - Long term - Inhalation 192 mg/m³ Effects: Systemic
1,6-hexanediol diglycidylether DNEL - Workers - Long term - Dermal 6 mg/kg bw/day Effects: Systemic
DNEL - Workers - Long term - Inhalation 10.57 mg/m³ Effects: Systemic
hydrocarbons, C9-C11, n-alkanes, isoalkanes, DNEL - Workers - Long term - Inhalation 1500 mg/m³ Effects: Systemic
cyclics, <2% aromatics
DNEL - Workers - Long term - Dermal 300 mg/kg bw/day Effects: Systemic
propan-2-ol DNEL - Workers - Long term - Dermal 888 mg/kg bw/day Effects: Systemic
DNEL - Workers - Long term - Inhalation 500 mg/m³ Effects: Systemic
4,4'-isopropylidenediphenol DNEL - Workers - Long term - Dermal 0.031 mg/kg bw/day Effects: Systemic
DNEL - Workers - Long term - Inhalation 2 mg/m³ Effects: Systemic
Predicted effect concentrations
Product/ingredient name Compartment Detail Value
bisphenol A-(epichlorhydrin) epoxy resin MW Fresh water 0.006 mg/l
=< 700
Marine 0.0006 mg/l
Sewage Treatment Plant 10 mg/l
Fresh water sediment 0.996 mg/l
Marine water sediment 0.0996 mg/l
Soil 0.196 mg/l
formaldehyde, polymer with (chloromethyl) Fresh water 0.003 mg/l
oxirane and phenol
Marine water 0.0003 mg/l
Sewage Treatment Plant 10 mg/l
Fresh water sediment 0.294 mg/kg dwt
Marine water sediment 0.0294 mg/kg dwt
Soil 0.237 mg/kg dwt
toluene Fresh water 0.68 mg/l
Marine water 0.68 mg/l
Sewage Treatment Plant 13.61 mg/l
Fresh water sediment 16.39 mg/kg
Marine water sediment 16.39 mg/kg
Soil 2.89 mg/kg
1,6-hexanediol diglycidylether Fresh water 0.0115 mg/l
Fresh water sediment 0.283 mg/kg dwt
Marine water 0.00115 mg/l
Marine water sediment 0.0283 mg/kg dwt
Soil 0.223 mg/kg dwt

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SECTION 8: Exposure controls/personal protection


Sewage Treatment Plant 1 mg/l
propan-2-ol Fresh water 140.9 mg/l
Marine 140.9 mg/l
Fresh water sediment 552 mg/kg
Marine water sediment 552 mg/kg
Soil 28 mg/kg
Sewage Treatment Plant 2251 mg/l
4,4'-isopropylidenediphenol Fresh water 0.018 mg/l
Marine water 0.016 mg/l
Sewage Treatment Plant 320 mg/l
Sediment 1.2 mg/kg
Soil 3.7 mg/kg

8.2 Exposure controls


Appropriate engineering controls
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust
lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.

Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles.
Hand protection : Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:

Recommended: Silver Shield / Barrier / 4H gloves, nitrile rubber (>0.3 mm), Viton®
Short term exposure: natural rubber (latex) (>0.4 mm)
May be used: neoprene rubber (>0.1 mm), butyl rubber (>0.5 mm), polyvinyl chloride (PVC), nitrile
rubber (>0.1 mm), butyl rubber (>0.3 mm), polyvinyl alcohol (PVA)

Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator. If
working areas have insufficient ventilation: When the product is applied by means that will not generate
an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter of type A,
when grinding use particle filter of type P. Be sure to use an approved/certified respirator or equivalent.
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties


Physical state : Viscous liquid.
Color : Brown.
Odor : Amine-like.
pH : Testing not relevant or not possible due to nature of the product.
Melting point/freezing point : Testing not relevant or not possible due to nature of the product.
Boiling point/boiling range : Testing not relevant or not possible due to nature of the product.
Flash point : Closed cup: 14°C (57.2°F)

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SECTION 9: Physical and chemical properties


Evaporation rate : Testing not relevant or not possible due to nature of the product.
Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge, heat and oxidizing materials.
Slightly flammable in the presence of the following materials or conditions: reducing materials.
Vapor pressure : Vapor Pressure at 20˚C Vapor pressure at 50˚C

Ingredient name mm Hg kPa Method mm Hg kPa Method


toluene 23.17 3.1 90 12

Vapor density : Not available.


Specific gravity : 1.68 g/cm³
Partition coefficient (LogKow) : Testing not relevant or not possible due to nature of the product.
Auto-ignition temperature : Ingredient name °C °F Method
toluene 480 896

Decomposition temperature : Testing not relevant or not possible due to nature of the product.
Dynam ic ( r oom t em per at ur e) : Not available.
Kinem at ic ( r oom t em per at ur e) : Not available.
Kinem at ic ( 40° C) : Not available.

Viscosity : Aspiration hazard (H304) Not classified. Testing not relevant due to nature of the product.
Explosive properties : Explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge, heat and oxidizing materials.
Slightly explosive in the presence of the following materials or conditions: reducing materials and
moisture.
Oxidizing properties : Testing not relevant or not possible due to nature of the product.

9.2 Other information


Solvent(s) % by weight : Weighted average: 10 %
Water % by weight : Weighted average: 0 %
VOC content : 174.2 g/l
TOC Content : Weighted average: 148 g/l
Solvent Gas : Weighted average: 0.046 m³/l

SECTION 10: Stability and reactivity

10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability


The product is stable.

10.3 Possibility of hazardous reactions


Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid


Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat
or sources of ignition.

10.5 Incompatible materials


Highly reactive or incompatible with the following materials: oxidizing materials and acids.
Reactive or incompatible with the following materials: reducing materials, organic materials and moisture.

10.6 Hazardous decomposition products


When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides sulfur oxides halogenated compounds metal oxide/oxides

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SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008


Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory
system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by
absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting
in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible
damage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs via
vomiting.
Epoxy and amine containing products can cause skin disorders such as allergic eczema. The allergy may arise after only a short exposure
period.
Acute toxicity
Product/ingredient name Result Dose / Exposure Effects
bisphenol A-(epichlorhydrin) epoxy Rat - Oral - LD50 >2000 mg/kg
resin MW =< 700
Rabbit - Dermal - LD50 >2000 mg/kg
Rat - Dermal - LD50 >2000 mg/kg
formaldehyde, polymer with Rat - Oral - LD50 >2000 mg/kg
(chloromethyl)oxirane and phenol
Rabbit - Dermal - LD50 >2000 mg/kg
toluene Rat - Oral - LD50 636 mg/kg
Rat - Inhalation - LC50 Vapor >20 mg/l [4 hours]
1,6-hexanediol diglycidylether Rat - Dermal - LD50 >2000 mg/kg
Rat - Oral - LD50 2190 mg/kg
hydrocarbons, C9-C11, n-alkanes, Rat - Oral - LD50 >2000 mg/kg
isoalkanes, cyclics, <2% aromatics
propan-2-ol Human - Oral - LDLo 3570 mg/kg Toxic effects: Behavioral - Coma Lung,
Thorax, or Respiration - Respiratory
depression Gastrointestinal - Nausea or
vomiting
Rabbit - Intraperitoneal - LD50 667 mg/kg
Rabbit - Dermal - LD50 >5000 mg/kg
Rat - Oral - LD50 >5000 mg/kg
1,3-bis(12-hydroxyocta-decanamide- Rat - Oral - LD50 >2000 mg/kg
N-methyle)benzene
Rat - Dermal - LD50 >2000 mg/kg
Rat - Inhalation - LC50 Dusts and >5 mg/m³ [4 hours]
mists
4,4'-isopropylidenediphenol Rat - Oral - LD50 3250 mg/kg
Rabbit - Dermal - LD50 >2000 mg/kg
Rat - Oral - LD50 3250 mg/kg
Acute toxicity estimates
Product/ingredient name Oral Dermal Inhalation Inhalation Inhalation
mg/kg mg/kg (gases) (vapors) (dusts and
ppm mg/l mists)
mg/l
1,6-hexanediol diglycidylether 2190
4,4'-isopropylidenediphenol 3250
Irritation/Corrosion
Product/ingredient name Result Species Exposure
bisphenol A-(epichlorhydrin) epoxy Rabbit - Eyes - Mild irritant
resin MW =< 700
Rabbit - Skin - Mild irritant
formaldehyde, polymer with Rabbit - Skin - Mild irritant Duration of treatment/ Amount/concentration applied: 500
(chloromethyl)oxirane and phenol exposure: 24 hours microliters
toluene Rabbit - Eyes - Mild irritant Duration of treatment/ Amount/concentration applied: 100
exposure: 0.5 minutes mg
Rabbit - Skin - Moderate irritant Duration of treatment/ Amount/concentration applied: 20 mg
exposure: 24 hours
1,6-hexanediol diglycidylether Rabbit - Skin - Irritant
Rabbit - Eyes - Irritant
hydrocarbons, C9-C11, n-alkanes, Rabbit - Eyes - Mild irritant
isoalkanes, cyclics, <2% aromatics
propan-2-ol Rabbit - Eyes - Moderate irritant Duration of treatment/ Amount/concentration applied: 100
exposure: 24 hours milligrams
Rabbit - Skin - Mild irritant Amount/concentration applied: 500
milligrams
4,4'-isopropylidenediphenol Rabbit - Eyes - Severe irritant Duration of treatment/ Amount/concentration applied: 250
exposure: 24 hours Micrograms

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SECTION 11: Toxicological information


Rabbit - Skin - Mild irritant Duration of treatment/ Amount/concentration applied: 500
exposure: 24 hours milligrams
Sensitizer
Product/ingredient name Species - Route of exposure Result
bisphenol A-(epichlorhydrin) epoxy Guinea pig - skin Result: Sensitizing
resin MW =< 700
1,6-hexanediol diglycidylether Guinea pig - skin Result: Sensitizing
Mutagenic effects
No known data avaliable in our database.

Carcinogenicity
No known data avaliable in our database.

Reproductive toxicity
No known data avaliable in our database.

Specific target organ toxicity (single exposure)


Product/ingredient name Category Route of exposure Target organs
toluene Category 3 Narcotic effects
hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, Category 3 Narcotic effects
<2% aromatics
propan-2-ol Category 3 Narcotic effects
4,4'-isopropylidenediphenol Category 3 Respiratory tract irritation
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of exposure Target organs
toluene Category 2 - -

Aspiration hazard
Product/ingredient name Result
toluene ASPIRATION HAZARD - Category 1
hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, ASPIRATION HAZARD - Category 1
<2% aromatics
Information on the likely routes of exposure
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
No known significant effects or critical hazards.

11.2 Information on other hazards


Endocrine disrupting properties : The product does not meet the criteria to be considered as having endocrine disrupting properties
according to the criteria set out in either Regulation (EC) No. 1907/2006 or Regulation (EC) No
1272/2008.
Other information : No additional known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity
Do not allow to enter drains or watercourses. Toxic to aquatic life with long lasting effects.
Product/ingredient name Result Species Exposure
bisphenol A-(epichlorhydrin) epoxy Acute - EC50 Algae 11 mg/l [72 hours]
resin MW =< 700
Acute - LC50 Fish 2 mg/l [96 hours]
Acute - EC50 Daphnia 1.8 mg/l [48 hours]
formaldehyde, polymer with Acute - EC50 Fish 2.54 mg/l [96 hours]
(chloromethyl)oxirane and phenol
Acute - LC50 Algae 1.8 mg/l [72 hours]
Acute - LC50 Daphnia 2.55 mg/l [48 hours]
toluene Chronic - NOEC - Fresh water Daphnia - Water flea - Daphnia magna 1000 µg/l [21 days]
Chronic - NOEC - Fresh water Algae - Green algae - Pseudokirchneriella <500000 µg/l [96 hours]
subcapitata
1,6-hexanediol diglycidylether Acute - LC50 Fish 30 mg/l [96 hours]

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Hempadur XP 87559 Base

SECTION 12: Ecological information


Acute - LC50 Daphnia 47 mg/l [48 hours]
Acute - EC50 Algae 23.1 mg/l [48 hours]
1,3-bis(12-hydroxyocta-decanamide- Acute - LC50 Fish >100 mg/l [96 hours]
N-methyle)benzene
Acute - LC50 Algae >100 mg/l [72 hours]
4,4'-isopropylidenediphenol Chronic - NOEC - Fresh water Fish - Green Swordtail - Xiphophorus helleri 0.2 - 20 ppb [60 days]
- Juvenile (Fledgling, Hatchling, Weanling)
Chronic - NOEC - Fresh water Daphnia - Water flea - Daphnia magna - 0.8 mg/l [21 days]
Neonate
Acute - LC50 Fish 7.5 mg/l [96 hours]

12.2 Persistence and degradability


Product/ingredient name Test Result
bisphenol A-(epichlorhydrin) epoxy OECD Inherent Biodegradability: Zahn-Wellens/ 12% [28 days] - Not readily
resin MW =< 700 EMPA Test
formaldehyde, polymer with OECD Ready Biodegradability - CO₂ Evolution Test 16% [28 days] - Not readily
(chloromethyl)oxirane and phenol
toluene 100% [14 days] - Readily
1,6-hexanediol diglycidylether OECD Ready Biodegradability - Closed Bottle Test 47% [28 days] - Inherent
hydrocarbons, C9-C11, n-alkanes, OECD Ready Biodegradability - Manometric 80% [28 days] - Readily
isoalkanes, cyclics, <2% aromatics Respirometry Test
propan-2-ol 86% [14 days]
1,3-bis(12-hydroxyocta-decanamide- 5% [28 days]
N-methyle)benzene
4,4'-isopropylidenediphenol 1 - 2% [28 days] - Not readily

Product/ingredient name Aquatic half-life Photolysis Biodegradability


bisphenol A-(epichlorhydrin) epoxy Not readily
resin MW =< 700
formaldehyde, polymer with Not readily
(chloromethyl)oxirane and phenol
toluene Readily
1,6-hexanediol diglycidylether Inherent
hydrocarbons, C9-C11, n-alkanes, Readily
isoalkanes, cyclics, <2% aromatics
propan-2-ol Readily
1,3-bis(12-hydroxyocta-decanamide- Not readily
N-methyle)benzene
4,4'-isopropylidenediphenol Not readily

12.3 Bioaccumulative potential


Product/ingredient name LogPow BCF Potential
bisphenol A-(epichlorhydrin) epoxy resin MW =< 700 2.64 - 3.78 31 Low
formaldehyde, polymer with (chloromethyl)oxirane and phenol 2.7 150 Low
toluene 2.73 90 Low
1,6-hexanediol diglycidylether 0.822 3.57 Low
hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% 5 - 6.7 10 - 2500 High
aromatics
propan-2-ol 0.05 3 Low
4,4'-isopropylidenediphenol 3.4 20 - 67 Low

12.4 Mobility in soil


Soil/Water partition coefficient
Product/ingredient name logKoc Koc

bisphenol A-(epichlorhydrin) epoxy resin MW =< 3.26 1800


700
toluene 2.07 117.115
1,6-hexanediol diglycidylether 2.7 497.492
propan-2-ol 0.54 3.4364
4,4'-isopropylidenediphenol 3.16 1436.23
Results of PMT and vPvM assessment

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Safety Data Sheet
Hempadur XP 87559 Base

SECTION 12: Ecological information

Product/ingredient name PMT P M T vPvM vP vM

bisphenol A-(epichlorhydrin) epoxy resin MW =< 700 No No No No No No No


formaldehyde, polymer with (chloromethyl)oxirane and phenol No No No No No No No
toluene No No No No No No No
1,6-hexanediol diglycidylether No No No No No No No
hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% No No No No No No No
aromatics
propan-2-ol No No No No No No No
1,3-bis(12-hydroxyocta-decanamide-N-methyle)benzene No No No No No No No
4,4'-isopropylidenediphenol No No No No No No No
Mobility : The product does not meet the criteria to be considered as a PMT or vPvM.

12.5 Results of PBT and vPvB assessment


Regulation (EC) No. 1907/2006 [REACH]
Product/ingredient name PBT P B T vPvB vP vB
bisphenol A-(epichlorhydrin) epoxy resin MW =< 700 No No No No No No No
formaldehyde, polymer with (chloromethyl)oxirane and phenol No No No No No No No
toluene No No No No No No No
1,6-hexanediol diglycidylether No No No No No No No
hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% No No No No No No No
aromatics
propan-2-ol No No No No No No No
1,3-bis(12-hydroxyocta-decanamide-N-methyle)benzene No No No No No No No
4,4'-isopropylidenediphenol No No No No No No No

Regulation (EC) No. 1272/2008 [CLP]


Product/ingredient name PBT P B T vPvB vP vB

bisphenol A-(epichlorhydrin) epoxy resin MW =< 700 No No No No No No No


formaldehyde, polymer with (chloromethyl)oxirane and phenol No No No No No No No
toluene No No No No No No No
1,6-hexanediol diglycidylether No No No No No No No
hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% No No No No No No No
aromatics
propan-2-ol No No No No No No No
1,3-bis(12-hydroxyocta-decanamide-N-methyle)benzene No No No No No No No
4,4'-isopropylidenediphenol No No No No No No No
Conclusion/Summary : The product does not meet the criteria to be considered as a PBT or vPvB.

12.6 Endocrine disrupting properties


The product does not meet the criteria to be considered as having endocrine disrupting properties according to the criteria set out in either
Regulation (EC) No. 1907/2006 or Regulation (EC) No 1272/2008.
12.7 Other adverse effects
No known significant effects or critical hazards.

SECTION 13: Disposal considerations

13.1 Waste treatment methods


The generation of waste should be avoided or minimized wherever possible. Residues of the product is listed as hazardous waste. Dispose
of according to all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Spillage, remains, discarded clothes and similar should be discarded in a fireproof
container.
European waste catalogue no. (EWC) is given below.
European waste catalogue (EWC) : 08 01 11*
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible.

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Safety Data Sheet
Hempadur XP 87559 Base

SECTION 14: Transport information

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.
14.1 14.2 14.3 14.4 14.5
UN / ID no. Proper shipping name Transport hazard class(es) PG* Env* Additional information

ADR/RID UN1263 PAINT 3 II Yes. The environmentally


Class hazardous substance mark
is not required when
transported in sizes of ≤5 L
or ≤5 kg.
Special provisions 640 (C)
Tunnel code (D/E)

IMDG UN1263 PAINT. (bisphenol A- 3 II Yes. The marine pollutant


Class (epichlorhydrin) epoxy resin MW =< mark is not required
700) when transported in
sizes of ≤5 L or ≤5 kg.
Emergency schedules
F-E, S-E

IATA UN1263 PAINT 3 II Yes. The environmentally


Class hazardous substance mark
may appear if required by
other transportation
regulations.
PG* : Packing group
Env.* : Environmental hazards

14.6 Special precautions for user


Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
14.7 Maritime transport in bulk according to IMO instruments
Not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern
Annex XIV
None of the components are listed.
Substances of very high concern
Ingredient name Intrinsic property Status Reference number Date of revision
4,4'-isopropylidenediphenol Toxic to reproduction Recommended ED/01/2018 10/1/2019
4,4'-isopropylidenediphenol Endocrine disrupting Recommended ED/01/2018 10/1/2019
properties for human health
4,4'-isopropylidenediphenol Endocrine disrupting Recommended ED/01/2018 10/1/2019
properties for environment
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
Not applicable.
Other EU regulations
Seveso category This product is controlled under the Seveso III Directive.
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b
E2: Hazardous to the aquatic environment - Chronic 2

15.2 Chemical Safety Assessment


-

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Safety Data Sheet
Hempadur XP 87559 Base

SECTION 16: Other information


Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
EUH statement = CLP-specific Hazard statement
RRN = REACH Registration Number
DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration
Full text of abbreviated H statements : H225 Highly flammable liquid and vapor.
H226 Flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H360F May damage fertility.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
H413 May cause long lasting harmful effects to aquatic life.
EUH066 Repeated exposure may cause skin dryness or cracking.
Full text of classifications [CLP/GHS] : Aquatic Acute 1 AQUATIC HAZARD (ACUTE) - Category 1
Aquatic Chronic 1 AQUATIC HAZARD (LONG-TERM) - Category 1
Aquatic Chronic 2 AQUATIC HAZARD (LONG-TERM) - Category 2
Aquatic Chronic 3 AQUATIC HAZARD (LONG-TERM) - Category 3
Aquatic Chronic 4 AQUATIC HAZARD (LONG-TERM) - Category 4
Asp. Tox. 1 ASPIRATION HAZARD - Category 1
Eye Dam. 1 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Eye Irrit. 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Flam. Liq. 2 FLAMMABLE LIQUIDS - Category 2
Flam. Liq. 3 FLAMMABLE LIQUIDS - Category 3
Repr. 1B TOXIC TO REPRODUCTION - Category 1B
Repr. 2 TOXIC TO REPRODUCTION - Category 2
Skin Irrit. 2 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1 SKIN SENSITIZATION - Category 1
Skin Sens. 1B SKIN SENSITIZATION - Category 1B
STOT RE 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
STOT SE 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 3
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification Justification
FLAMMABLE LIQUIDS On basis of test data
SKIN CORROSION/IRRITATION Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION Calculation method
SKIN SENSITIZATION Calculation method
TOXIC TO REPRODUCTION Calculation method
AQUATIC HAZARD (LONG-TERM) Calculation method

Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

Version: 0.09 Page: 13/22


Safe Use of Mixture Information
Hempadur XP 87559 Base

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Outdoor painting by professionals by dipping or with brush, roller, putty knife etc.
This safe use information is : Professional low-energy painting, near-industrial setting - Level I
linked to HMP I/PW 06a
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Outdoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions

Risk management measures (RMM)


Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
application hours according to EN 166. tested to EN374.

Loading of application PROC08b More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
equipment and handling hours according to EN 166. tested to EN374.
of coated parts before
curing

Industrial application of PROC10 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
coatings by other than hours according to EN 166. tested to EN374.
spraying

Film formation - force PROC04 More than 4 Outdoors 3-5 None None None
drying, stoving and other hours
technologies

Cleaning PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
hours according to EN 166. tested to EN374.

Waste management PROC08b More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
hours according to EN 166. tested to EN374.
See section 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 14/22
Safe Use of Mixture Information
Hempadur XP 87559 Base

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Outdoor painting by professionals by dipping or with brush, roller, putty knife etc.
This safe use information is : Professional painting, outdoor brush/roller - Level I
linked to CEPE / HMP PW 06a
Sector(s) of use : Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Outdoor use

Risk management measures (RMM)


Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
application hours according to EN 166. tested to EN374.

Loading of application PROC08a More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
equipment and handling hours according to EN 166. tested to EN374.
of coated parts before
curing

Professional application of PROC10 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
coatings by brush or roller hours according to EN 166. tested to EN374.

Film formation - force PROC04 More than 4 Outdoors 3-5 None None None
drying, stoving and other hours
technologies

Cleaning PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
hours according to EN 166. tested to EN374.

Waste management PROC08a More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
hours according to EN 166. tested to EN374.
See section 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 15/22
Safe Use of Mixture Information
Hempadur XP 87559 Base

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Outdoor spray painting by professionals for specialist applications, with respiratory protection
This safe use information is : Professional spray painting, near-industrial setting - Level II
linked to HMP I/PW 05b
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Outdoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions

Risk management measures (RMM)


Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
application hours according to EN 166. tested to EN374.

Loading of application PROC08b More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
equipment and handling hours according to EN 166. tested to EN374.
of coated parts before
curing

Industrial application of PROC07 More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear suitable gloves
coatings by spraying hours conforming to EN140 with according to EN 166. tested to EN374.
an assigned protection
factor of at least 10.

Film formation - force PROC04 More than 4 Outdoors 3-5 None None None
drying, stoving and other hours
technologies

Cleaning PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
hours according to EN 166. tested to EN374.

Waste management PROC08b More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
hours according to EN 166. tested to EN374.
See section 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 16/22
Safe Use of Mixture Information
Hempadur XP 87559 Base

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Outdoor spray painting by professionals for specialist applications, with respiratory protection
This safe use information is : Professional spray painting, outdoor (Level II)
linked to CEPE PW 05b
Sector(s) of use : Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Outdoor use

Risk management measures (RMM)


Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
application hours according to EN 166. tested to EN374.

Loading of application PROC08a More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
equipment and handling hours according to EN 166. tested to EN374.
of coated parts before
curing

Professional application of PROC11 More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear suitable gloves
coatings by spraying hours conforming to EN140 with according to EN 166. tested to EN374.
an assigned protection
factor of at least 10.

Film formation - force PROC04 More than 4 Outdoors 3-5 None None None
drying, stoving and other hours
technologies

Cleaning PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
hours according to EN 166. tested to EN374.

Waste management PROC08a More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
hours according to EN 166. tested to EN374.
See section 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 17/22
Safe Use of Mixture Information
Hempadur XP 87559 Base

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor painting by professionals with brush or roller, with good general room ventilation (open doors/windows)
This safe use information is : Professional painting, indoor brush/roller - Level I
linked to CEPE / HMP PW 04a
Sector(s) of use : Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Indoor use

Risk management measures (RMM)


Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
application hours ventilation according to EN 166. tested to EN374.

Loading of application PROC08a More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
equipment and handling hours ventilation according to EN 166. tested to EN374.
of coated parts before
curing

Professional application of PROC10 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
coatings by brush or roller hours ventilation according to EN 166. tested to EN374.

Film formation - force PROC04 More than 4 Good general room 3-5 None None None
drying, stoving and other hours ventilation
technologies

Cleaning PROC05 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
hours ventilation according to EN 166. tested to EN374.

Waste management PROC08a More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
hours ventilation according to EN 166. tested to EN374.
See section 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 18/22
Safe Use of Mixture Information
Hempadur XP 87559 Base

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor spray painting by professionals for specialist applications, with good general room ventilation plus respiratory protection
This safe use information is : Professional spray painting, indoor (Level II)
linked to CEPE / HMP PW 03b
Sector(s) of use : Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Indoor use

Risk management measures (RMM)


Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
application hours ventilation according to EN 166. tested to EN374.

Loading of application PROC08a More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
equipment and handling hours ventilation according to EN 166. tested to EN374.
of coated parts before
curing

Professional application of PROC11 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear suitable gloves
coatings by spraying hours ventilation conforming to EN140 with according to EN 166. tested to EN374.
an assigned protection
factor of at least 10.

Film formation - force PROC04 More than 4 Good general room 3-5 None None None
drying, stoving and other hours ventilation
technologies

Cleaning PROC05 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
hours ventilation according to EN 166. tested to EN374.

Waste management PROC08a More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
hours ventilation according to EN 166. tested to EN374.
See section 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 19/22
Safe Use of Mixture Information
Hempadur XP 87559 Base

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor painting by professionals by dipping or with brush, roller, putty knife etc. with enhanced ventilation or local exhaust ventilation (LEV)
This safe use information is : Professional low-energy painting, near-industrial setting - Level I
linked to HMP I/PW 02a
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Indoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions

Risk management measures (RMM)


Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
application hours (mechanical) room according to EN 166. tested to EN374.
ventilation

Loading of application PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
equipment and handling hours (mechanical) room according to EN 166. tested to EN374.
of coated parts before ventilation
curing

Industrial application of PROC10 More than 4 Local exhaust Refer to Wear a respirator Use eye protection Wear suitable gloves
coatings by other than hours ventilation relevant conforming to EN140 with according to EN 166. tested to EN374.
spraying technical an assigned protection
standards factor of at least 10.

Film formation - force PROC04 More than 4 Enhanced 5 - 10 None None None
drying, stoving and other hours (mechanical) room
technologies ventilation

Cleaning PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
hours (mechanical) room according to EN 166. tested to EN374.
ventilation

Waste management PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
hours (mechanical) room according to EN 166. tested to EN374.
ventilation
See section 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 20/22
Safe Use of Mixture Information
Hempadur XP 87559 Base

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor spray painting by professionals with efficient ventilation such as spray booth or local exhaust ventilation
This safe use information is : Professional spray painting, near-industrial setting - Level I
linked to HMP I/PW 01a
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Indoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions

Risk management measures (RMM)


Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
application hours (mechanical) room according to EN 166. tested to EN374.
ventilation

Loading of application PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
equipment and handling hours (mechanical) room according to EN 166. tested to EN374.
of coated parts before ventilation
curing

Industrial application of PROC07 More than 4 Local exhaust Refer to Wear a respirator Use eye protection Wear suitable gloves
coatings by spraying hours ventilation relevant conforming to EN140 with according to EN 166. tested to EN374.
technical an assigned protection
standards factor of at least 10.

Film formation - force PROC04 More than 4 Enhanced 5 - 10 None None None
drying, stoving and other hours (mechanical) room
technologies ventilation

Cleaning PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
hours (mechanical) room according to EN 166. tested to EN374.
ventilation

Waste management PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
hours (mechanical) room according to EN 166. tested to EN374.
ventilation
See section 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 21/22
Safe Use of Mixture Information
Hempadur XP 87559 Base

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor or outdoor spray painting by professionals for specialist applications, with good general room ventilation plus respiratory protection
This safe use information is : Professional spray painting, near-industrial setting
linked to Expert judgment
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Indoor or outdoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions Assumes that activities are undertaken with appropriate and well maintained equipment by trained
personnel operating under supervision.
Others : Depending on actual conditions of application. Please consult your local HEMPEL representative
for further advise.

Risk management measures (RMM)


Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemically resistant
application hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with
factor of at least 10. specific activity training.

Loading of application PROC08b More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemically resistant
equipment and handling hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
of coated parts before an assigned protection in combination with
curing factor of at least 10. specific activity training.

Industrial application of PROC07 More than 4 Good general room 3-5 Use a properly fitted, air- Use eye protection Wear chemically resistant
coatings by spraying hours ventilation - Outdoors purifying or air-fed according to EN 166. gloves (tested to EN374)
respirator. EN 14594 with in combination with
an assigned protection specific activity training.
factor of at least 20.

Film formation - force PROC04 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
drying, stoving and other hours ventilation - Outdoors according to EN 166. tested to EN374.
technologies

Cleaning PROC05 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemically resistant
hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with
factor of at least 10. specific activity training.

Waste management PROC08b More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemically resistant
hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with
factor of at least 10. specific activity training.
See section 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 22/22

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