Practice Test - 3

PART A Physics
1. ω v nth

1 1 1 1 1
(a) ω ∝ and v ∝ (b) ω ∝ n1/ 2 and v ∝ (c) ω ∝ and v ∝ (d) ω ∝ n − 1/ 2 and v ∝ 1/n
n2 n n2 n3 n

2.

(a) 40 V (b) 45 V (c) 50 V (d) 90 V

3. L
A
H
C
H
B
H
H
g 1 g
(a) (b)
L 2 L
3 g g
(c) (d) 2
2 L L

4.

(a) 6.2 eV (b) 12.4 eV (c) 100 eV (d) 200 eV

5. f0
v
λ λ0
(a) λ < λ 0 , f > f0 (b) λ = λ 0, f = f0 (c) λ = λ 0, f > f0 (d) λ > λ 0, f > f0

6. O
l=2m
60°
O First ball
3/ 5
Second ball
(a) 1.2 m (b) 1.52 m µ=0

(c) 1.38 m (d) 1.6 m

7. n =4
n =3
I0

(a) zero (b) I 0 (c) 2I 0 (d) 4I 0

 8. O
l
θ
m
(a) the bob will still execute SHM
Lift
(b) the tension in the rodT = mg at the next moment
(c) the bob will execute SHM making an angle θ with the vertical
(d) the bob will remain at rest

9.

Frictionless
k surface
m

x
kx 2
(a) Wgravity = Wspring (b) Wspring = − Wgravity (c) Hmax achieved = (d) None of these
mg

10. a
A
S a/4
B
a –=2
+
S
S S

hc A A A A
hc
hc B hc B B B
(a) (b) (c) (d)
hc hc
S S S S

11.
(a) A system could have some heat energy.
(b) A system could have some work.
1
(c) A ball is moving with speed v, here mv 2 is its internal energy.
2
(d) None of the above

12.
(a) Tension T is always greater than mg (b) 0 < T < mg
(c) Tmin = mg (d) Tmax > mg

13.

(a) 1.4 H (b) 0.14 H (c) 2.4 H (d) 0.24 H

14.
dW = 2RdT
Cp
CV
(a) 7 / 5 (b) 5/3 (c) 3/2 (d) 2

15.
g sin θ m

(a) 2g cos θ (b) g sin θ a

(c) 2g tan θ (d) g cos θ
θ

16. φ = 5 t3 − 20 t + 100
t=2
(a) 60 (b) 40 (c) − 40 (d) − 60

17. l A
k0
K = k0
a + bT
b T1 T2 T1

Ak 0  a + bT1  Ak 0  a + bT2 
(a)   (b)  
bl  a + bT2  bl  a + bT1 
Ak 0  a + bT1  Ak 0 a + bT2 
(c) ln   (d) ln  
bl a + bT2  al  a + bT1 

18. t x = αt3 y = βt3

t
(a) 3t α + β 2 2
(b) 3t 2 α 2 + β 2 (c) t 2 α 2 + β 2 (d) α 2 + β2

I
19.

∫ H. dI
(a) energy gained by the substance during complete cycle H
(b) energy lost as heat during complete cycle
(c) energy lost per unit volume during complete cycle
(d) its value is equal to zero as magnetic forces are conservative
Spring
20. balance

(a) buoyant force = 40 N

(b) weight of block = 20 N m
(c) buoyant force = 30 N
(d) weight of block = 40 N Weighing
machine
21. v
5
x t=0 t = 20

→
v
6 8 10 12
2 4 14 16 18 20
3 15 3 3
(a) , (b) , t→
4 4 4 4
15 15 15 –5
(c) 0, (d) ,
4 4 4
22. q v 1 = 1 $i
F = q [ − $j + 1 k
$] v 2 = 2$j
F2 = q (1 $i − 1 k
$) B
(a) ( $i + $j + k$ ) Wb/m 2 (b) ( $i − $j + k$ ) Wb/m 2
(c) ( − $i + $j − k$ ) Wb/m 2 (d) ( $i + $j − k$ ) Wb/m 2

23. 1010 2 3
2 3

550 610
(a) (b)
49 51
555 450
(c) (d)
49 41

24.
(a) [ML2T − 2 ] (b) [MLT − 2 ]
(c) [MT − 2 ] (d) [ML2 ]

25.
100 W
300 W
100 W
100 W

(a) 50 W (b) 600 W

(c) 150 W (d) 33.3 W

26. 2r
(a) PE of satellite will increase (b) KE of satellite will decrease
(c) total mechanical energy of satellite will increase (d) options (a), (b) and (c) all are correct

27.
t1 t2 t

1 1 1 1 1 1
(a) = + (b) = 2 + 2
t t1 t 2 t t1 t2
1 1 1 1 1 1
(c) = − (d) = −
t t1 t 2 t t12 t 22
28. C
V1 V2

1 1
(a) C (V12 − V22 ) (b) C (V12 + V22 )
4 4
1 1
(c) C(V1 − V2 )2 (d) C (V1 + V2 )2
4 4

29. Statement I

Statement II

(a) Both Statement I and Statement II are true and the Statement II is the correct explanation of the Statement I
(b) Both Statement I and Statement II are true but the Statement II is not the correct explanation of the Statement I
(c) Statement I is false but Statement II is true
(d) Both Statement I and Statement II are false

30. Statement I
1
16
1
Statement II
16
(a) Both Statement I and Statement II are true and the Statement II is the correct explanation of the Statement I
(b) Both Statement I and Statement II are true but the Statement II is not the correct explanation of the Statement I
(c) Statement I is false but Statement II is true
(d) Both Statement I and Statement II are false

PART B Chemistry
31. H 2O ( l )
(a) 32 NA (b) 48 NA (c) 16 NA (d) 8 NA

32.

, ,

(a) (b) (c) (d)

33. N2 P4
(a) tripple bond exist between phosphorous atom (b) pπ − pπ bond is weak in P4
(c) pπ − pπ bond is strong in P4 (d) multiple bonds form easily

34.
 3 /2
11 
ψ (3 s) =   (6 − 5 σ + σ 2) e − σ/2
9 3  a0 
2r. Z
σ =
3a0
5Za 0 6Za 0 9Za 0 7Za 0
(a) (b) (c) (d)
2 7 2 3

35.
Cl 2
Hint Cl 2
(a) CH3CH2Cl (b) C2H6 (c) CH4 (d) CH3Cl

36. ( X)
( Y)
( X) ( Y)
(a) SiO2, CO2 (b) Si, CO2 (c) SiO2, CO (d) Si, CO

37.
1.85
(a) 3.23 × 10− 10esu (b) 0.323 × 10− 10esu (c) 2.32 × 10− 10esu (d) 3.32 × 10− 7esu

38.
(a) [Co (NH3 )5 NO2 ] Cl2 and [Co(NO3 )5ONO]Cl2 (b) [Co(NH3 )5Br] SO4 and [Co (NH3 )5SO4 ] Br
(c) [Pt Cl2 (NH3 )4 ] Br 2 and [Pt (NH3 )4Br2 ] Cl2 (d) [Co (NH3 )4 Cl2 ] NO2 and [ Co (NH3 )4 Cl NO2 ] Cl

39. H 3PO 2 PH 3 H 3PO 3

5M 7M 3M 9M
(a) (b) (c) (d)
4 4 4 4

40. α

(a) bithional (b) dettol (c) lysol (d) None of these

41.
I. HCO−2 A. Obtained through Solvay process
II. K 2CO3 B. Green colour due to [Cr (H2O)6 ]3 + ion
III. S 2O32− + FeCl3 solution C. Reduces [Cu (C4H4O6 )2 ]2− to red ppt.
IV. SO23− + K 2Cr2O7 /H+ D. Green colouration
V. Na 2CO3 E. Melts at 850°C
A B C D E A B C D E
(a) V III I II IV (b) IV I II III V
(c) V IV I III II (d) II I V IV III

42. CuSO 4 ( aq)

I2 Na 2S 2O 3
Na 2S 2O 3 H+

(a) 255.5 litre (b) 237.5 litre (c) 305.5 litre (d) 407.5 litre
43. [X]
OH
N

H2SO4 540 K
[X] Nylon 6

(a) cyclohexanone (b) hexamethylene diamine

(c) hexamethylene di-isocyanide (d) caprolactum

44.

(a) 0.3 (b) 0.4 (c) 0.8 (d) 0.5

45.
(a) SF4, CH4, NH3 (b) NF3, BCl3, NH3 (c) BF3, NF3, AlCl3 (d) BF3, BCl3, BBr3

46. C14H10O 2
(OH − ) ( B)

O O OH O O O OH O
(a) Ph C C Ph , Ph C C Ph (b) Ph C C Ph , Ph C C OH

OH Ph
OH O O OH O
(c) Ph C C C , C C (d)

Ph H
HO COOH
O O
47.
A → 2B + C
( g) ( g) ( g)

−1

H 2O = 20 ln 2 = 0.3010 ln 3 = 0.4771
−1 −1
(a) 0.005 min (b) 0.004 min (c) 0.003 min − 1 (d) 0.006 min − 1

48. s
COOH
H NH2
HIO4
H OH
H OH
CH3
(a) CHO  COOH + CH3CHO + HCOOH (b) 4COOH + CH3CHO
(c) 3 COOH + CH3CHO (d) 2COOH + CHO  COOH + CH3CHO

49.

(a) [Cr (H2O)6 ]3 + (b) [ Cr(OH)4 ]− (c) CrO2−

4 (d) [Cr(OH)3(H2O)3 ]

50. ( kp )
 SO 2 ( g ) + NO 2( g ) s SO 3 ( g ) + NO ( g )

SO 2
(a) 2 atm (b) 0.17 atm (c) 0.37 atm (d) 0.27 atm

51.
(a) FeO + SiO2 → FeSiO3 (b) 2Cu2S + 3O2 → 2Cu2O + 2SO2
(c) 2Cu2S + 5O2 → 2CuSO4 + 2CuO (d) 2CuFeS 2 + O2 → Cu2S + 2 FeS + SO2

52.

CaOCl 2 + acetone → product

(a) phenol (b) nitric acid (c) amine (d) acetone

53. I2

I2
(a) 0.525 M (b) 0.625 M (c) 0.225 M (d) 0.50 M

mCPBA HBr
54. A B A B

(a) 1, 2-epoxycyclohexane, trans-2-bromocyclohexanol (b) 1, 2 epoxycylohexane, cis-2-bromocyclohexanol

(c) trans-2-bromocyclohexanol, 1,2-epoxyethane (d) cis-2-bromocyclohexanol, 1,2-epoxyethane

55.
(a) B2, O2, N2 (b) B2, O2, NO (c) B2, F2, O2 (d) B2, O2, Li2

56.
COOH COOH COOH COOH

NO2 NO2
NO2 OCH3
I II III IV
(a) II < III < I < IV (b) IV < III < I < II (c) III < II < I < IV (d) III < II < IV< I

57. A B
T A B
A B
(a) 500 torr (b) 600 torr (c) 700 torr (d) 200 torr

58. BF3 , BCl 3 , BBr3

(a) BF3 > BBr3 > BCl3 (b) BF3 > BCl3 > BBr3 (c) BF3 < BCl3 < BBr3 (d) BBr3 < BF3 < BCl3

59. Statement I

Statement II

(a) Both Statement I and Statement II are true and the Statement II is the correct explanation of the Statement I
(b) Both Statement I and Statement II are true but the Statement II is not the correct explanation of the Statement I
(c) Statement I is false but Statement II is true
 (d) Both Statement I and Statement II are false

60. Statement I
Statement II
(a) Both Statement I and Statement II are true and the Statement II is the correct explanation of the Statement I
(b) Both Statement I and Statement II are true but the Statement II is not the correct explanation of the Statement I
(c) Statement I is false but Statement II is true
(d) Both Statement I and Statement II are false

PART C Mathematics
61. z | z 2 − ( z) 2| = | z|2 , Re ( z) ≥ 0, Im ( z) ≥ 0
(a) point (b) pair of straight line (c) hyperbola (d) ellipse

62. 3×3
x  1
A y = 0
   
 z  0
(a) zero (b) infinite (c) unique (d) None of these

63. y 2 = 4 ax
y 2 4a 3 y 2 4a 3 y 2 4a 3
(a) x + 2a = + 2 (b) x + 2a = − 2 (c) x − 2a = + 2 (d) None of these
2a y 2a y 2a y

2 + sin x dy
64. y = y ( x) = − cos x , y (0) = 1 y ( π /2)
( y + 1) dx
1 3 1 2
(a) (b) (c) (d)
3 2 4 5

65. a, b, c log a 100, 2 log b 10, 2 log c 5 + log c 4

(a) AP (b) GP (c) HP (d) None of these

66.
5 4 3 2
(a) (b) (c) (d)
17 17 17 17
2 cos x − sin x + λ
67. ∫ cos x + sin x − 2
dx = A ln |cos x + sin x − 2| + Bx + C A , B, λ

1 3  3 1  1 3 3 1
(a)  , , − 1 (b)  , , − 1 (c)  , − 1, −  (d)  , − 1, 
2 2  2 2  2 2 2 2

x2 y2
68. r + =1
a2 b2

r 2 − b2 r 2 − a2 r 2 − b2 r 2 − a2
(a) tan− 1 (b) tan− 1 (c) tan− 1 (d) tan− 1
a2 − r 2 b2 − r 2 r 2 − a2 r 2 − b2

69.
 (a) 1 and 2 (b) 1 and 3 (c) 2 and 3 (d) 1, 2 and 3

70. sec 2 (tan − 1 2) + cosec 2 (cot− 1 3)

(a) 17 (b) − 15 (c) 15 (d) 16

71. a b
 π
x + a 2 sin x ; 0≤ x<
 4
 π π
f( x ) =  2x cot x + b ; ≤x≤
 4 2
 a cos 2x − b sin x ; π
<x≤π
 2
x ∈ [0, π ]
π π π −π −π π π π
(a) , (b) , (c) , (d) ,
6 12 6 12 4 12 4 6
x y z
72. = = 2x + y + 3 z − 1 = 0
k 2 − 12
x + 2y − 3 z − 1 = 0 k
(a) 3 (b) − 2 (c) 5 (d) 0

73. A, B C a, b, c
B C
| a × b × c| |a × b + b × c + c × a | |a × b + b × c + c × a |
(a) (b) (c) (d) None of these
2 (b × c ) 2 | (b − c ) | | (b − c ) |

74.

(a) 26 (b) 27 (c) 28 (d) 20

75. x =y =z sin Ax + sin By + sin Cz = 2d 2

A B C
sin 2Ax + sin 2By + sin 2Cz = d 2 sin sin sin A +B+C=π
2 2 2
1 1 1 1
(a) (b) (c) (d)
16 4 13 15

76. x 3 − 6 x 2 + 15 x + 3 = 0
(a) only one positive root (b) two positive and one negative roots
(c) no positive root (d) None of these
5 5
 3 i  3 i
77. z= +  + − 
 2 2  2 2
(a) Re ( z ) = 0 (b) Im ( z ) = 0 (c) Re ( z ) > 0, Im ( z ) > 0 (d) Re ( z ) > 0, Im ( z ) < 0
78. ABC B C BC
x
(2, 1) (1, 2) AB y =
2
AC
1
(a) 2y = x + 3 (b) y = 2x (c) y = ( x − 1) (d) y = x − 1
2

x dx + y dx 1 − x2 − y2
79. =
x dy − y dx x2 + y2
(a) circles passing through the origin (b) parabola
1
(c) circles of radius through the origin (d) not circle
2

80. α, β λ ( x 2 + x) + x + 5 = 0 λ 1, λ 2 λ α, β
α β λ1 λ
+ =4 + 2
β α λ2 λ1
(a) 254 (b) 482 (c) 784 (d) 782

81. $i $i + $j +2 k
$
1 2 3 5
(a) (b) (c) (d)
6 6 6 6
−3 π
sin x + cos x
82. ∫−
4
π
x−
π
dx
4 e 4 +1
(a) 0 (b) 1 (c) 3 (d) None of these
abc
83. ∆ABC AD A b > c, ∠C = 23 ° AD = ∠B
b2 − c 2
(a) 113° (b) 110° (c) 117° (d) 112°

84. R→R f( x ) = x 3 + x 2 + 3 x + sin x f

(a) one-one and onto (b) one-one and into (c) many one and onto (d) many one and into

 1
85. X B 6, 
 2
(a) X = 0 and X = 6 (b) X = 3 (c) X = 0 (d) X = 6

 
86. lim  3 x 2 + 3 x 2 + 3 x 2 − 3 x 2 
x→ ∞  
1 1 −3
(a) (b) − (c) (d) 3
2 2 2

87.

(a) e 4 + e 2 = 2 (b) e 4 + e 3 = 1 (c) e 4 + e 2 = 1 (d) e 4 + e 2 = 4

1 1
88. 2×2 1 0
 

 a b    a b  
(a)    : a, b, c ∈ R  (b)    : a, b, c ∈ R 
 c a − b    b c  
  a − b a    a b  
(c)    : a, b, c ∈ R  (d)  
−  : a, b ∈ R 
  a c    b a b  

89.

Statement I
Statement II
(a) Statement I is true, Statement II is also true and Statement II is the correct explanation of Statement I
(b) Statement I is true, Statement II is also true and Statement II is not the correct explanation of the Statement I
(c) Statement I is true but Statement II is false
(d) Statement I is false but Statement II is true

90. A 2×2 A2 = I 2×2

Tr ( A ) = A |A | = A
Statement I r (A) = 0
Statement II | A | = 1
(a) Statement I is true, Statement II is also true and Statement II is the correct explanation of Statement I
(b) Statement I is true, Statement II is also true and Statement II is not the correct explanation of the Statement I
(c) Statement I is true but Statement II is false
(d) Statement I is false but Statement II is true
Physics
1. (c) Idea In Bohr model, 3. (c) Idea Moment of inertia of discrete masses at a
nh distance L is given by ML2 and moment of
angular momentum, Ln =
2π inertia of a rod about one end is ML2 / 3 and
radius of nth orbit, rn ∝ n2 total mechanical energy is conserved.

Bohr model tells us that angular momentum in n th Moment of inertia of the system about the given
orbit is n times h (or h /2π) axis I = I A + IB + IC
So, Ln =
nh Now, as rod is thin I A = Σm × ( 0)2 = 0
2π Rod B is rotating about one end
nh
⇒ Iω = ML2
2π ∴ IB =
3
2 nh
⇒ (mr ) ω = and for rod call points are always at distance L from
2π
the axis of rotation, so
2
[QI = moment of inertia = m × r ] IC = ΣmL2 = ML2
As, r ∝ n2 [r = radius of n th orbit] ML2 4
n 1 I = 0+ + ML2 = ML2
So, ω ∝ ⇒ ω∝ 3 3 3
n4 n So, if ω is the desired angular speed, gain in kinetic
Also, ω = v /r energy due to rotation of H from horizontal to
∴ v = ωr , r ∝ n 2 vertical position.
1 1 1 4 
and ω∝ 3 So, KR = Iω 2 = ML2 ω 2
n 2 2  3 

1 2
∴ v ∝ = ML2ω 2
n 3
and loss in potential energy of the system in doing
TEST Edge Questions related to angular L 3
momentum, velocity, radius, energy etc., are so = 0 + Mg + MgL = MgL
frequently asked. 2 2
In Bohr’s theory,
nh
Angular momentum Ln =
2π
 e2  Z
Speed of electron vn =  
 2 ε 0 h n So, by conservation of mechanical energy
n 2 2 3
Radius rn = (0.53 Å) ML2ω 2 = MgL
Z 3 2
Z2 3 g
Energy, En = ( −13.6) 2 ⇒ ω=
n 2 L
kq
2. (b) Potential = TEST Edge Questions involving concept such as
r
angular momentum conservation, ( Iω = const. )
kq
⇒ = 90 ⇒ kq = 270 energy conservation etc., and parallel axis
3 theorem ( I = I0 + Md 2 ) and perpendicular axis
Now if smaller sphere is touched to bigger sphere, theorem ( Iz = Ix + Iy ) are frequently asked, so
whole charge will transfer to bigger sphere. important results related to moment of inertia
kq kq 270 from axis of rotation of important object [i.e.,
Hence, V Bigger = = =
R 6 6 ML2
moment of inertia from one end = etc.] must
⇒ V Bigger = 45 V 3
be memorized.
4. (a) Idea In photoelectric effect maximum kinetic TEST Edge Question involving work-energy
energy of e− is given by theorem may also be asked, to solve these type of
(KE)max = hν − W problem, student must know that change in
kinetic energy of a particle is equal to the work
hc done on it by the net force acting on the particle.
Work function of the metal is W = .
λ0
7. (c) Note that two sources of sodium, although produce
It is given that λ 0 = 200 nm because 200 nm EM waves of same wavelength but still they do not
corresponds the wavelength which is just able to act as coherent sources because there is no
emit electrons from the metal. definite relation between their initial phases of EM
Now KE = incident energy of radiation waves produced.
− work function Hence, no interference pattern will be observed
and thus there will be no minima and maxima.
1 1 
∴ KE = hc  −  in Joules Intensity everywhere will be just 2I 0 [= Z 0 + Z 0].
λ λ0 
8. (c) Idea For small extension restoring force
hc 1 1  ( F = − kx ) act on body.
KE (in eV) =  λ − λ  eV
e  0
When lift comes in free fall the ball will execute SHM
 1 1  along the line OA in vertical plane due to tension in
= 12375 eV/A ° × −
100 200  rod.
= 6.18 eV ≈ 6.2 eV O
TEST Edge Question involving (KE )max = hν − W l
θ T
is almost asked every year also dependency of
photocurrent on intensity etc., are also asked. m g
5. (c) When the source remains stationary and emit some A
waves, the wavelength of the waves do not change
and as the observer is moving towards the source
apparent frequency will increase.
⇒ λ = λ 0 and f > f0 TEST Edge Question related to simple hormonic
motion is asked frequently such as given
6. (c) Idea The change in potential energy will be equation or given motion is SHM or not, to solve
converted to kinetic energy. such problem, student must know that in SHM
acceleration ∝-(displacement).
From conservation of mechanical energy
1 1
mg (l − l cos θ ) = mv 2 9. (b) Wspring = k x 2
2 2
v = 2gl (1 − cos θ ) This work done will convert into KE
1 1
 1 ⇒ k x 2 = mv 2
= 2 × 10 × 2 1 −  = 2 5 m /s 2 2
 2
Gravity will do negative work and this KE will
⇒ After the collision, convert into PE
| v − v 2|
e= 1 ⇒ Wgravity = − Wspring
| v − 0|
v3 10. (b) Idea When light rays go from denser to rarer
= v1 − v 2
5 medium, total internal reflection will occur if
v1 − v 2 = 6 …(i) angle of incidence is greater than critical
From momentum conservation angle.
m × v = m (v1 + v 2 ) If S is anywhere in the shaded A
v1 + v 2 = 2 5 …(ii) region, the light rays from S will
⇒ Solving two expressions, v1 = 5.25 m /s strike AB making an angle more hc B
than critical angle and hence
⇒ From mechanical energy conservation
reflected back in the same S
v2 region.
h1 = 1 = 1.38 m
2g
 TEST Edge Other question including concept of R
Also, CV =
total internal reflection such as mirage, early γ −1
visibility of sun etc., are also asked. Student must R
∴ = 2R
remember total internal reflection occurs when γ −1
ray goes from denser to rarer medium and angle ⇒ 2γ − 2 = 1
must be greater than critical angle if angle will be
3
less than critical angle then refraction will occur. ⇒ γ = = Cp /CV
2
11. (d) Heat energy is the energy in transition, a system
could have some internal energy or we could give TEST Edge Question involving concept of work
system some heat energy and system could do done are also asked e.g., work done during
adiabatic change is given by
some work to change its internal energy.
nR p V − p2 V2
1 W= ( T1 − T2 ) = 1 1 etc.
mv 2 is the mechanical energy of the ball not its ( γ − 1) γ−1
2
internal energy. 15. (c) N = ma sin θ − mg cos θ
12. (d) At extreme position (ma cos θ − mg sin θ ) = m × aupwards
T1 = mg cos θ = Tmin ma cos θ − mg sin θ = mg sin θ
O ma cos θ = 2 mg sin θ
a = 2g tan θ
l θ T1

m
a
T2 v=0

co
s
θ N

θ
v mg cos θ
mg
ma
mg

m
g
ma sin θ

si
n
At the lowest position, mg

θ
+ mg cos θ
θ
mv 2
T2 = mg + = Tmax
l d( φ )
16. (c) Idea Emf induced in a coil e = − ,
So, Tmax > mg dt
φ is flux linked with the coil.
13. (b) Value of resistance solenoid is dφ
50 Induced Emf = −
R = = 50 Ω dt
1
Emf = − [15 t 2 − 20]
[Qonly inductive reactance is zero for DC.]
Emf at t = 2 s = − [15 × 4 − 20] = − 40 V
50
Impedance = = 100 Ω
0.5 TEST Edge Question related to induced emf can
also be asked other ways, so student must know
Now, Z 2 = X L2 + R 2
that emf can be induced by changing area of coil,
⇒ X L2 = 1002 − 502 = 7500 magnetic flux of the coil and angle between area
⇒ X C = 75 × 10 ≈ 8.7 × 10 = 87 vector and magnetic field.

Now, 2π ν × L = 87 17. (c) Idea Rate of flow of heat is given by

87 dQ dT
∴ L= = 0.14 H = −KA
2 × 314
. × 100 dt dx
14. (c) Idea In an ideal gas, for small heat change dQ dT
As we know that, = − KA
Cp dt dx
dQ = du + dw and =γ dQ k 0A dT
CV =−
dt a + bT dx
For small change, dQ = dU + dW
On integrating both sides within the proper limits.
nCdT = nCV dT + 2nRdT dQ l T2 dT
dt ∫0
dx = − k 0 A ∫
∴ C = CV + 2R , 4R = CV + 2R T1 a + bT

Given, molar heat capacity = 4R dQ Ak 0  a + bT1 

This gives = ln  
∴ CV = 2R dt bl a + bT2 
 TEST Edge Question 1 1 1
related to equivalent 5×4+ ×5×2− ×5×2−5×4−
thermal conductivity of two or more rods in 2 2 2
1 1
series and parallel at various temperature can be ×5×2+ ×5×2+ 5×2+ ×5×2
asked. = 2 2
20
In series equivalent conductivity is given 15 3
K K ( L + L2 ) = = = m /s
by Keq = 1 2 1 20 4
( L1 K1 + L2 K2 )
(Here note that proper signs are taken)
In parallel equivalent conductivity is given by
 K A + K2 A2  5
Keq =  1 1  ↑
 A1 + A2  v
6 8 10 12
18. (b) Given, x = αt 3, y = βt 3 14
2 4 16 18 20
dx
Then, vx = = 3 αt 2 t→
dt
–5
dy
and vy = = 3 βt 2
dt distance travelled
<v > =
Resultant velocity ∆t
v = v x2 + v y2 = 9 α 2t 4 + 9β 2t 4 Area of s - t graph
=
∆t
= 3t 2 α 2 + β 2 1 1 1
5 × 4 + × 5 × 2 + × 5 × 2 + 5 ×4 +
2 2 2
19. (b) ∫ H ⋅ dI represents the energy lost as heat during 1
×5×2+ ×5×2+ 5×2+ ×5×2
1
the complete cycle of magnetization. = 2 2
20
20. (d) Idea Here concept of force balance and 70 15
= = m /s
Newton’s third law is used also whenever a 20 4
block is dipped in water force of buoyancy
will act. TEST Edge Questions from kinematic including
various graph like v-t graph, a-t graph etc., are
frequently asked, student must know important
concept related to it such as slope of displacement
kx versus time gives instantaneous velocity and
slope of velocity-time gives instantaneous
B mg acceleration etc.
B
22. (a) Idea Force on a charged particle in a uniform
magnetic field is given by
Here, mg = B + kx F = q( v × F)
where, B = reading of weighing machine = 20 N Let, magnetic field is B = B1$i + B2$j + B3 k$
kx = 20 N Applying Fm = q ( v × B ), we have
⇒ mg = 20 + 20 q [ − $j + k$ ] = q [ $i × (B1$i + B2$j + B3 k$ )]
= 40 N ⇒ − $j + k$ = B k$ − B $j
2 3

TEST Edge Question based on Archimede’s By comparing, we have B2 = 1 and B3 = 1

principal can also be asked which is when a solid Further q [ $i − k$ ] = q [ $j × (B1 $i + B2$j + B3 k$ )]
body is wholly or partly immersed in a fluid, it = q [ − B k$ + B $i ]
1 3
experiences an upward thrust or buoyant force
equal to the weight of the fluid displaced by it. Again by comparing, we have B1 = 1 and B3 = 1
∴ B = ( $i + $j + k$ ) Wb/m 2
21. (a) Idea Area of velocity-time graph with sign
gives displacement and without sign gives TEST Edge Question in which both electric field
distance. and magnetic field is applied on a charged
particle in such case force on charged particle is
s Area of v-t graph
<v>= = given by
∆t ∆t F = q( E + v × B)
 − ∆p TE = KE + PE
23. (a) Bulk modulus, K =
∆V /V − GmMe
TE =
∆pV 2 × 108 × V − V 2r
⇒ ∆V = − =− =
K 1010 50 So, as r increase
49V PE → increase
New volume of metal is = V + ∆V =
50 KE → decrease
TE → increase
As mass of metal will remain constant.
TEST Edge Student must know important
So, ρV = ρ′ V ′ −GmMe
formulae for energy of satellite like TE = ,
[where, ρ,V are its initial density and volume while ρ′ 2π
and V ′ are density and volume after application of TE = KE + PE etc.
pressure] Graph related to energy of satellite can also be
ρV 11 × V × 50 550
ρ′ = = = g/cm 3 asked which is as follow.
V′ 49 × V 49
Force MLT − 2
24. (c) Surface tension = = = [MT − 2 ] K
Length L
V2 E
25. (c) Idea In an electrical circuit, P = also in
R U
series connection P1: P2 : P3 = R1: R2 : R3 and in E=K+U
parallel connection
ln 2
1 1
P1 ; P2 : P3 = : :
1 27. (a) The decay constant for the first process is λ 2 =
t1
R1 R2 R3
ln 2
Let resistance of 300 W bulb is R. and for the second process it is λ 2 = .
t1
V2 V2 The probability that an active nucleus decay by the
Hence = 300 W then, as R =
R P first process in a time interval dt is λ 1dt. Similarly,
3R
the probability that it decays by the second
3R R process is λ 2dt. The probability that it either
decays by the first process or by the second
3R process is λ 1dt + λ 2dt . If the effective decay
constant is λ, the probability is also equal to λ dt.
Thus,
λdt = λ 1 dt + λ 2dt
V
1 1 1
∴Resistance of 100 W bulb should be 3R. or λ = λ2 + λ2 ⇒ = +
t t1 t 2
So, we have
∴ Equivalent resistance is R eq = 2R 28. (c) Idea When two isolated capacitors having
2 2 different charges are combined then
V 1 V 300
Hence, (Power )eq = = × = = 150 W lost by charge gained by
charge
( 2R ) 2 R 2 one capacitor  = other capacitor 
TEST Edge Question related to brightness of bulb and charge will arrange in such a way that
etc., can also be asked, so important concept such they reach common potential also energy is
as in series connection, a bulb of less wattage will lost during process.
give more light than bulb of greater wattage.
Initial energy of the system
26. (d) Idea Potential energy of satellite revolving 1 1
Ui = CV12 + CV22
around earth is negative and inversely 2 2
proportional to radius of orbit also kinetic When the capacitors are joined, common potential,
energy and total energy is positive and
CV1 + CV2 V1 + V2
inversely proportional to radius of orbit. V = =
2C 2
GmMe
PE = − , Final energy of the system,
r
GmMe 1
KE = Uf = ( 2C ) V 2
2re 2
 2
1  V + V2  TEST Edge By solving this question, you will be
= 2C  1 
2  2  able to calculate numbers of moles present on any
1 element, ion or molecule present in any
= C (V1 + V2 )2 solution.
4
1
Decreasing in energy = Ui − Uf = C (V1 − V2 )2 32. (a) Idea This problem includes conceptual mixing
4
of acidic character, aromaticity and
TEST Edge Question related to change in nucleophilic substitution reaction.
potential charge and energy can also be asked in Students are advised to identify the most
which battery may also be connected with the stable intermediate obtained among all (after
1 the removal of H+ ) keeping in mind the
circuit. Important relations like q = CV , E = CV 2
2 concept of conjugation and aromaticity.
etc., must be memorised to solve such relations. Then, complete the reaction further using
29. (b) Both Statement I and Statement II are correct but concept of nucleophilic substitution reaction.
Statement II is not explanation of the Statement I. Acidic character The species which easily donate
its hydrogen and produces stable conjugate base
30. (c) Idea Here concept of radioactive reactions and is acid. The species which produces more stabler
basic concept of probability is involved. conjugate base is more stronger acid.
Student must know that nuclear
disintegration is not affected by physical and do not looses H+ hence are not
condition and nearby nucleus
Radioactivity is an independent activity thus does
not depend upon the quantity of substance acidic. looses the H+ easily and produces
remaining. A nuclei can disintegrate at any moment
irrespective of what is happening to its
neighbouring atoms/nuclei. So the probability for a more stabler aromatic cyclopentadienyl anion.
particular nuclei to disintegrate in half life time will
always be1/ 2 also quantity of substance after n half
–H+
life is given by
N  1  N, final quantity
n
=   N0, initial quantity non-aromatic aromatic
N0  2 n, number of half-life (cyclopentadienyl anion)

N Now, cyclopentadienyl anion on reaction with

So, after 4 half-life N = 0
16 3-chloro prop1-ene produces the product via
nucleophilic substitution reaction.
TEST Edge Radioactive disintegration is not
affected by changing physical condition like Cl
temperature, pressure etc., student must know
about relation between half-life and
concentration, questions involving these
product
concepts are frequently asked.
TEST Edge Generally, in JEE Main the
Chemistry problems related to conjugation, aromaticity and
nucleophilic substitution reaction are asked
31. (b) Idea First of all calculate the number of moles frequently. hence, students are advised to
of H2O present then calculate number of understand the concept of aromaticity,
neutrons present in O and H followed by conjugation and various chemical reactions of
number of neutrons present on H2O. Finally,
aromatic and aliphatic intermediates such as
multiply these two results and get the final
cation, anion, radicals etc.
answer.
108
Number of moles of H2O (l ) = =6 33. (b) Idea This problem includes conceptual mixing
18
of existance of phosphorous and reason of
(density = 1.0 g/mL of H2O)
their existance. Students are advised to go
H has no neutron. through the concept of pπ − pπ bonding and
Number of neutrons in H2O = 6 × 8 × 6 × 1023 characteristics of element to show pπ − pπ
= 48 NA bonding to a greater extent than 3rd period
Number of neutrons in O = 16 − 8 = 8 element.
 Existance of N as N2 is due to strong pπ − pπ Symbol % age At mass Relative Simplest
bonding between smaller sized p-orbitals of N. number ratio
Existance of phosphorous as P is due to existance of atom
of weak pπ − pπ bonding due to large size of C 80 12 80 7
≈ 7.0 =1
p-orbital of phosphorous atom. 12 1
H 20 1 20 20
= 20 ≈3
P 1 7
Empirical formula = CH3; Molecular formula = C2H6
N N P P Reaction of ethane When ethane is treated with Cl2
in sunlight it produces CH3CH2Cl
Cl 2 /hν
⇒

P
N N CH3CH3 → CH3CH2Cl

TEST Edge In JEE Main, the questions related to

⇒

Discrete unit of P4 conceptual mixing of molecular formula

due to large size of p-orbital determination and chemical formula of
compound are asked very frequently, so students
of phosphorous, it show.
are advised to go through calculation of
TEST Edge In JEE Main, the questions related to molecular formula determination and various
the concept of back bonding are asked frequently chemical properties of organic compounds.
so students are advised to go through the study of 36. (c) Idea Students are recommended to see the
condition of happening back bonding. product given in option and think that what
Lower the difference between size of atomic is the possibility of starting material
orbitals undergoing back bonding greater will be according to information provided in the
question and chemical properties of starting
extent of overlapping between those orbitals.
material.
For e.g., 2nd period elements such as oxygen, As the most occurring element in the earth crust is
nitrogen, contain double and tripple bond silicon as SiO2 and the chemical reaction of SiO2
respectively while S and P form single bond with with carbon produces CO which is a poisonous gas
itself. as shown below
34. (c) Radial nodes occurs where probability of finding SiO2 + 2 C → Si + 2 CO
electron is zero ↑
Poisonous gas and stable
ψ 2 = 0 or ψ = 0 diatomic molecule

σ 2 − 5σ + 6 = 0 TEST Edge Generally, in JEE Main these types of

2
σ − 3σ − 2 σ + 6 = 0 questions are based on the concept of occurrence
of element and their chemical properties are
σ ( σ − 3) − 2 ( σ − 3) = 0
asked therefore students are advised to go
σ = 2 or 3 through study of occurrence of (such as Al, Sn, Cu
For maximum distance σ = 3 etc.) and their chemical properties.
2 rZ
3= 37. (a) Idea This problem involves conceptual mixing
3 a0
of structure, bond angle, dipole moment,
9a 0 9Za 0
r = Z = charge on water molecule. To solve this type
2 2 of problem student should determine the
35. (a) Idea This problem includes conceptual mixing structure and bond angle of molecule. Now
of determination of molecular formula and use the simple triangle law to calculate the
bond length then calculate the charge on
their chemical reaction. Students are advised
molecule using formula
to calculate the simplest ratio of number of
atoms present in molecule/compound then µ=e×l
to identify the possible molecular formula of where, µ = dipole moment
compound keeping in mind the types of e = charge on molecule, l = bond length.
products given in option and simplest ratio Structure of water molecule Structure of water
of atoms. molecule can be determined as
 V + M −C + A 6 + 2 4×2 4
H= = =4 39. (c) n-factor = =
2 2 4+ 2 3
Hybridisation = sp 3 H3PO2 → PH3 + H3PO3
Due to lone pair-lone pair repulsion the bond angle Oxidation number
of P = − 3
Oxidation number
of P = + 2
decreases to 105°.
mol weight M 3M
H So, equivalent weight = = =
R n-factor 4 4
3
52.5°
O 0.94 A° 40. (b) This problem involves properties of dettol as
52.5°
antiseptic disinfectant and its chemical constitution.

P
52.4°
Q Antiseptic and Disinfectant Dettol is a most
H commonly used antiseptic which is a mixture of 4,
chloro, 3, 5, dimethyl phenol i . e., chloroxylenol and
From the value of bond angle and vector moment, e
terpineol. It is chloroxylenol and terpineol. It is
can be calculated as
chloroxylenol which is responsible for its antiseptic
PQ = QR cos 52.5°
and disinfectant properties.
= 0.94 × 0.605 = 0.572 Å
OH
= 0.572 × 10− 8 cm
We know that µ = e × l = e × AB
µ 1.85 × 10−18 esu cm
e= = H3C CH3
AB 0.572 × 10−8 cm
Cl OH
e = 3.23 × 10− 10 esu
Chloroxylenol α-terpineol
TEST Edge Questions related to dipole
moment, charge and bond length are asked very 41. (c) Idea This problem is based on conceptual
frequently in JEE Main. The problems on mixing of preparation physical and chemical
properties and application of dipole moment will properties of various inorganic compound.
also be asked therefore students are Try to find the exact relation between
recommended to go through study of these compound and information regarding
concepts.
compounds keep a clear idea in your mind
38. (b) Idea This problem includes conceptual mixing regarding concept of preparation and
of type of isomerism shown by coordination properties of inorganic compound.
compound and their molar conductivity.
Exact relation can be determined by using the
l Identify the types of isomerism in information given in both column one by one.
coordination compound.
(i) Fehling solution :
l Determine the number of ions produced by
coordination compound in the aqueous CuSO4 +NaK → C4H4O6 + NaOH
solution. (Rochell’s salt )
l Now use the concept of electrochemistry to (ii) K 2CO3 (m. pt) = 850° C
solve the problem. (iii) FeCl3 + 2S 2O3−− → [Fe(S 2O3 )2 ]− + 3Cl−
Greater the charge on ions produced by violet solution
coordination compound greater will be its molar [Fe(S 2O3 )2 ]− + Fe3 + → 2Fe2 + + S 4O26 −
conductivities. Molecule having different charge on (green)
ions have different molar conductivity. (iv) Cr2O27− + 8H ++
3SO−3 − → 2Cr 3 +
2 −−
[Co(NH3 )5Br] SO4 → [Co(NH3 )5Br]++
+ SO4 (orange ) (green )

[Co(NH3 )5 SO4 ]Br → [Co(NH3 )5SO4 ] + Br + −

+ 3SO−4 − + 4H2O
TEST Edge In JEE Main, problem related to (v) Na 2CO3 : Solvay process.
isomerism in coordination compound and
conductivity in coordination compound both are TEST Edge This type of question is asked in JEE
asked independently as well as combinely Main to know the clear concept of students
sometimes questions having only molecular regarding preparation and properties of
composition is given and molar conductivity is compounds, so the students are advised to go
also asked so student should deep study these through deep and clear students study of
topic by relating these concepts. preparation and properties of compound.
42. (b) Initial moles of Cu2 + = 500 × 0.02 =10 Molecular structure determination Molecular
mole equivalents or milli moles of H+ produced structure of compound having molecular formula
= 500 × 10− 3 = 2 × 10−1 = 0.5 × 2 =1.0 C14H10O2 is determined by calculating degree of
unsaturation
milli moles of Cu2 + converted into Cu = 1 / 2 = 0.5
H N 10
milli moles of Cu2 + remaining in solution u = ( C + 1) − + = (14 + 1) − = 15 − 5 = 10
= 10 − 0.5 = 9.5 2 2 2
2 Cu2 + + 4I− → Cu2I2 + I2 degree of unsaturation is 10 in which 2 units are
and I2 + 2Na 2S 2 O3 → 2NaI + Na 2S 4O6 already considered to be used as diketo group
 O O 
milli moles of Cu2 + remaining    
= millimoles of Na 2S 2O3   C C . Rest 8 unit of unsaturation may be
 
9.5 = 0.4 × V or V = 237.5 L  
 
43. (d) This problem involves conceptual mixing of
Beckman arrangement and polymerisation. satisfied by two phenyl ring each having u = 4. Hence
Beckman rearrangement The acid catalysed correct structure may be
conversion of N. hydroxyl oxime to N substituted O O
amine is known as Beckman rearrangement. The
C C
chemical sequence of the reaction is as follows in
which [ X ] is caprolactum which polymerises to
Nylon 6. Benzilic acid rearrangement Conversion of benzil
OH H
N N to benzilic acid in presence of base is known as
N O benzilic acid rearrangement in general benzilic
+
H H 2O 540 K acid is α hydroxy carboxylic acid the reaction is
– H2O
believed to occur as
Caprolactum O
[X ] O O O O
[ NH.(CH2)5 C ]n –
OH
Nylon 6 C C C C
44. (a) Mass of acetic acid adsorbed by 2 g charcoal OH
= 100 × 10− 3 × ( 0.5 − 0.4) × 60 =0.6 (molecular
x 0.6
wieght of CH3COOH = 60) = = 0.3
m 2 O O O OH
Interamolecular
45. (d) This problem involves conceptual mixing of C C
H-abstraction
C C
structure of compound. As, trihalides of boron have HO O
same structure due to same value of H. (hybrid
V + M −C + A 3 + 3
orbitals) H = = =3
2 2
Hybridisation = sp 2
+
H

F Cl Br OH O
B F B Cl B Br
C C
F Cl Br
OH

46. (b) Idea This problem include conceptual mixing

of molecular structure determination and
benzilic acid rearrangement. This problem can benzilic acid

be solved by using following sequential step. TEST Edge JEE Main examination include this
l Calculate the degree of unsaturation and type of question to judge the knowledge of
then determine the appropriate molecular student in rearrangement reaction of ketone
structure. which are asked generally. Therefore, students
l Complete the reaction using the concept of are advised to go through study of
benzilic acid rearrangement in which rearrangement reaction of carbonyl compound
diketone undergo benzilic acid such as Beckman rearrangement, Pinacol-
rearrangement in presence of base to
Pinacolone rearrangement etc.
produce corresponding benzilic acid.
88 JEE Main Practice Sets

COOH COOH
47. (d) Idea This problem is based on rate law
expression and rate constant of 1st order H NH2 CHO
H OH +
gaseous reaction. This problem can be solved H OH
HCOOH
+
using following steps CH3 CH3CHO
l Write the chemical reaction
l Calculate the total pressure, initial pressure 49. (b) Idea This problem includes conceptual
and final pressure. mixing of chemical reactions of aqueous
l Now, calculate the value of rate constant solution of transition metal ion (Co 3+ ) and
using equation of 1st order rate constant i.e., colour of metal ion. Students are advised to
2.303  p0  determine the oxidation state of transition
k= log   metal ion first followed by calculation of
t  p0 − x 
number of d electrons present in metal ion.
where, p0 = initial pressure
p0 − x = final pressure. When aqueous solution of NaOH is added to
Let initial pressure = p0 aqueous solution of Cr (III) ion it produces
A ( g ) → 2 B( g ) + C( g ) [Cr (H2O)3(OH)3 ]+
After 10 mins p0 − x 2x x [Cr (H2O)6 ]3+ + NaOH → [Cr (OH)3 (H2O)3 ] + H2O
Light green ppt.
At long time , t → ∞ 0 2 p0 p0
Which on further redissolves in aq. NaOH(in
As given, p0 − x + 2x + x = vapour pressure of excess) to produce dark green solution due to
water = 200
formation of [Cr (OH)4 ]−
p0 + 2x + 20 = 200 [Cr (OH)3 (H2O)3 ] + OH →
s
[Cr (OH)4 ]–
p0 + 2x = 180 Excess Dark green solution
and 2p0 + p0 + 20 = 380 TEST Edge The reactions of transition metal ions
3p0 = 360 with common reagents such as NaOH, Na 2CO 3 ,
p0 = 120 torr HCl, H2SO 4 etc., are asked in JEE Main very
120 + 2x = 180 frequently, so students are advised to study the
chemical reaction of various transition metal ions,
2x = 60
such as Fe 2 +, Co 3+ , Mn 2+ , Cr 6+ etc.
x = 30 torr
1  p0  1 120 50. (d) SO2 (g ) + NO2(g ) s SO3(g ) + NO (g )
k = ln   = ln  
t  p0 − x  20  90  at t = 0 2 2 2 2
1 at equilibrium 2 − x 2−x 2+ x 2+ x
k = (ln 12 − ln 9)
20 Total number of moles of gases at equilibrium,
1 ( 2 − x ) + ( 2 − x ) + ( 2 + x ) + ( 2 + x ) + 2 (inert gas)
= (ln 4 + ln 3 − 2 ln 3)
20 =8+ 2
1 = 10
= ( 2 ln 2 − ln 3) = 0.006 min− 1
20 pSO 3 ⋅ pNO
kp =
TEST Edge In JEE Main, these types of problems pSO 2 ⋅ pNO 2
are included to judge the quantitative and 2
2 + x 
theoretical knowledge of student about concern  p
 10 
topic, so students are advised to practice more 25 = 2
and more in determination of value of rate 2 − x 
 p
constant. The question relating half-life time and  10 
quarter life time may also be asked. 2+ x 4
⇒ 5= ,x =
48. (a) This problem includes conceptual mixing of 2−x 3
malaprade oxidation of aminohydroxyl compound. 4
2−
Malaprade oxidation Amino alcohol compound 2−x 3 ×4
pSO 2 = × pTotal =
having amino and hydroxyl compound are 10 10
adjacent to each other undergo cleavage to give 8
fragment product in a same way as in diol. = = 0.27 atm
30
51. (d) Idea This problem is based on the various 53. (c) I2 + 2Na 2S 2O3 → 2NaI + Na 2 S 4O6 …(i)
chemical reactions occuring in the
milli moles of Na 2S 2O3 consumed
Bessemer’s converter. Students are advised
to stick with concept of purification of = 30 × 0.2
metals. To solve this problem go through the = 60 milli moles
reactions occuring in Bessemer process. 60
milli moles of I 2 consumed = = 30 milli moles
(a) FeO + SiO2 → FeSiO3 2
flux slag
3I2 + 6NaOH → 5NaI + NaIO3 + 3H2O …(ii)
This reaction shows slag formation reaction in
milli moles of I2 reacted with NaOH,
which acidic flux SiO2 is added to FeO which
50 × 0.6 30
produces slag. = = 15 milli moles
2 2
(b) 2 Cu2S + 3 O2 → 2 Cu2O + 2 SO2
Total milli moles of I2 consumed in reaction
This reaction shows conversion of copper sulphide
(i) and (ii) = 15 + 30 = 45 milli moles
into copper oxide with evolution of SO2 gas.
45
(c) 2 Cu2S + 5O2 → 2 CuSO4 + 2 CuO molarity of I2 = = 0.225 M
200
This reaction shows conversion of copper sulphide 54. (a) This problem includes conceptual mixing of
into copper sulphate which occurs in Bessemer’s
epoxidation, ring opening and nomenclature.
converter.
Epoxidation When an organic compound
(d) 2 CuFeS 2 + O2 → Cu2S + 2 FeS + SO2
containing double bond undergo reaction with per
This process shows oxidation of impurity, which acid such as mCPBA it produces an epoxide. The
don’t occur in Bessemer’s converter. first step of above reaction complete as follows.
TEST Edge In JEE Main, questions related to mCPBA H—Br
O O H + Br
chemical reaction involved in purification of [1,2 epoxy
metal students are advised to go through study of (A) cyclohexane]
various reactions involved in extraction and O
O H
purification of metals. O
O H
Br
52. (b) Idea This problem includes conceptual mixing H 2O
of preparation of chloroform, chemical OH
Cl
property of chloroform and use of compounds [metachloro perbenzoic acid]
of CHCl 3 . This type of trend related problem is OH
(B)
sticked with preparation and properties of
[trans-2-bromo cyclohexanol]
chloroform. This problem can be solved by
completing the sequence of reaction. The 55. (b) Idea This problem contain conceptual mixing
student must have the knowledge regarding of molecular orbital electronic configuration
use of compound prepared. and magnetic properties of molecules or
Preparation of chloroform From bleaching ions. The student is advised to stick with
powder chloroform are prepared by its reaction with concept of molecular orbital electronic
acetone configuration, magnetic properties of
CaOCl2 + H2O → Ca(OH)2 + Cl2 diatomic molecule. This problem can be
CH3  C CH3 + Ca(OH)2 + Cl2 → HCCl3 solved by following sequential step
 l Write molecular orbital electronic
O configuration.
Chemical properties of CHCl3 CHCl3 on reaction l Count then number of unpaired electrons. If
with nitric acid it produces chloropicrin which is molecule contain unpaired electron then it is
used as an insecticide. paramagnetic.
CHCl3 + HNO2 → CCl3 − NO2 Paramagnetic character of molecule or ions
Chloropicrin Molecules or ions which contains at least one
TEST Edge This type of problem is asked in JEE unpaired electron in molecular orbital of molecule
Main examination to judge the knowledge of use or ion shows paramagnetic character.
of compound prepared by chemical reaction of Molecular orbital electronic configuration
chloroform property and uses of DDT, Freon, etc., (MOEC) of B2 = σ12s σ1*s2 σ 22s σ *22s π 12p x ≡≡ π 12p y
may also be asked very frequently, so students
are advised to study these topics. Unpaired electron = 2
 Hence, B2 is paramagnetic. 2. − I effect It decreases electron density towards
MOEC of O2 = σ12s σ1*s2 σ 22s σ 2*2s σ 22 p z most electropositive atom. e.g., NO2 , CHO etc.
OCH3 is an electron pushing group hence
π 22p x ≡≡ π 22p y π *21p y ≡≡ π *21p y
increases electron density towands ring and
Unpaired electron = 2 causes decrease in acidic strength in comparison
Hence, O2 is paramagnetic. to benzoic acid.
MOEC of NO = σ12s σ1*s2 σ 22s σ 2*2s NO2 is an electron pulling group hence decreases
electron density from ring and hence increases
σ 22p z π 22p x
≡ π *21p x
≡ π 2*p y
acidic strength in comparison to benzoic acid.
10 − 5 Hence correct order is shown in choice (a).
BO = = 2.5
2 COOH COOH COOH COOH
Unpaired electron = 1
Hence, O2 is also paramagnetic < < <
MOEC of N2 = σ12s σ1*s2 σ 22s σ *22σ NO2 NO2

π 22p x
≡ π 22p y σ 22p z OCH3 NO2
10 − 4 acidity increases
BO = =3
2 TEST Edge In JEE Main, questions related to
Unpaired electron = 0 acidic strength order and basic strength order are
Molecule is diamagnetic asked very frequently, therefore students are
recommended to understand the concept of
MOEC of F2 = σ12s σ1*s2 σ 23s σ *22ps σ 22p z π 22p x ≡ π 22py
inductive effect, resonance effect in acidic and
π 22p x ≡ π 22p y basic strength of species.
Unpaired electron = 0
57. (d) Idea This problem includes concept of
Molecule is diamagnetic. Raoult’s law. Students should understand
MOEC of Li2 = σ12s σ1*s2 σ *22s π 22p y ≡≡ π 22p y the theory and numerical approach of
Raoult’s law to solve this type of problem
Unpaired electron = 0
using following steps.
Molecule is diagmagnetic.
• Write the data given in the question and then
Hence, correct set of paramagnetic molecules are asked to answer in the question.
represented by (b). • Write the formula by which problem is
TEST Edge These types of questions are solved.
commonly asked problem, students are • Calculate the required parameter using
recommended to go through study of magnetic formula and must keep the accuracy of
property of diatomic molecule and molecular solution in the mind.
orbital electronic configuration of elements Let, nB mole of B present in 1 mole of mixture that
problems related to extent of paramagnetism can n
has been vapourised thus YB = B X B of B remains
also be asked. 1
1 − nB
in liquid phase will be X B =
56. (a) Idea This problem includes conceptual mixing 1
of acidic strength and inductive effect. To p − pT 0
XB = 0 …(i)
solve this problem identify the group pB − pT0
attached to give system and then the position
at which groups are attached then notice the {p = pT0 + ( pB0 − pT0 ) X B }
effect of group in parent system (benzoic p p0 X
and YB = B = B B …(ii)
acid) here. Now, choose the correct choice. p p
Inductive effect The pull or push of electron density Putting X B and YB in Eq. (i),
of any bond pair can be quantitatively expressed in p − p0
1− nB = 0 T0 …(iii)
term of inductive effect. There are two types of pB − pT
inductive effect (1 − nB ) pB0
nB = …(iv)
1. + I effect It increases electron density towards p
most electronegative effect. pB0
or nB =
e. g ., CH3, OCH3, Butyl. etc. p + pB
 pB0 p − p0
1− = 0 T0
p + pB pB − pT
Mathematics
61. (b) Idea Q If z = x + iy, then z = x − iy and i 2 = −1
p = pB0 pT0 = 100 × 400
i = 0 + 1⋅ i
= 200 torr
⇒ |i|=|0 + 1⋅ i |= 0 + 1 = 1
TEST Edge Questions relating partial pressure ⇒ |i|= 1
and mole fraction are generally asked in JEE
Main. Students are advised to understand the We have given that
concept of colligative properties such as elevation | z 2 − ( z )2 | = | z | 2
in boiling point, depression in freezing point etc., Let, z = x + iy
and their applications.
| ( x + iy ) − ( x − iy )2| = x 2 + y 2
2
58. (c) This problem contain conceptual mixing of Lewis
| x − y 2 + 2ixy − x 2 + y 2 + 2ixy | = x 2 + y 2
2
acidity and back bond.
| 4xy | = x 2 + y 2 [Q| i | = 1]
Transfer of electron from filled orbital of one atom to
vacant orbital of another atom is termed as π back ⇒ x + y 2 = 4xy , pair of straight line.
2

bonding. The back bonding are of three types. TEST Edge Generally, in JEE Main properties of
(a) pπ − pπ back bonding complex number as modulus of complex number
(b) pπ − d π back bonding based question, students are advised to learn the
properties of complex number.
(c) d π − d π back bonding
In BF3, BCl3 and BBr3 each will shown pπ − pπ back x  1 
62. (c) A y  = 0
bonding as follows
z  0
Above equation represent a system of three plane.
F Cl Br
Q Plane may have unique or infinite solution. So it
F B Cl B Br B
can not have two solution.
F Cl Br
63. (c) Idea Q y2 = 4ax; equation of normal at
( at 2 , 2at ) is y + tx = 2at + at 3
difference between size of overlapping p orbital increases
→ Here, equation of the normal chord at any point
extent of π backbonding decreases
(at 2, 2at) of the parabola is
As extent of pπ − pπ back bonding increases Lewis y + tx = 2at + at 3 …(i)
acidity decreases. Hence correct order of Lewis
Equation of the chord with mid point ( x1, y1) isT = S1
acidity is represented by option (c).
yy1 − 2a ( x + x1) = y12 − 4ax1
59. (b) This problem includes conceptual mixing of
yy1 − 2ax = y12 − 2ax1 ...(ii)
elimination reaction, Sytzeff rule and
conjugation. Since, Eq. (i) and (ii) are identical
Elimination reaction In presence of base alkyl 1 t 2at + at 3
= = 2
halide undergo elimination as follows y1 −2a y1 − 2ax1
− 2a y 2 − 2ax1 2at + at 3
t= and 1 =
Cl CH3 Product I y1 − 2a t
Base 2
 − 2a 
= 2a + a  
CH3  y1 
Product II
− y12 4a 3 y 2 4a 3
Sytzeff rule
or + x1 = 2a + 2 ⇒ x1 − 2a = 1 + 2
Product I is obtained according to conjugation 2a y1 2a y1
which deal about stability of product to a greater Hence, the locus of the middle point ( x1, y1) is
extent than product II obtained according to
y 2 4a 3
inductive effect only. x − 2a = + 2
2a y
Hence, correct Statement II is due to conjugation.
60. (a) Solubility is governed by lattice energy, hydration TEST Edge Locus of the given point in different
energy. Lower will be lattice energy more is the way on normal of the parabola related questions
are asked in JEE Main. To understand the basic
solubility but more will be lattice energy less will be
concept of normal of parabola in different cases.
solubility.
 2 + sin x dy P ( A ) . P (B / A )
64. (a) Given that ⋅ = − cos x P ( A /B ) =
( y + 1) dx P ( A ) ⋅ P (B / A ) + P ( A ) P (B / A )
By variable separation, to separate variable x and 1 12
⋅
y, we get 4 51 12 4
= = =
dy − cos x 1 12 3 13 51 17
= ⋅ dx ⋅ + ⋅
y + 1 2 + sin x 4 51 4 51
dy − cos x 67. (b) Idea Here∴∫ f ( x )dx = g( x )
∫ y + 1 = ∫ 2 + sin x dx d
Differentiating w.r.t. x, we get f ( x ) = g( x )
log( y + 1) = − log( 2 + sin x ) + log C dx
d 1
C and log x =
y +1 = dx x
2 + sin x We have given that,
y( 0) = 1 ⇒ C = 4 2 cos x − sin x + λ
If = ∫ dx
4 cos x + sin x − 2
y = −1 +
2 + sin x
= A ln | cos x + sin x − 2 | + Bx + C
 π 4 4 1 d
y   = −1 + = −1 + = ( A ln | cos x + sin x − 2 | + Bx + C )
 2 π 3 3 dx
2 + sin
2 (cos x − sin x )
=A +B
cos x + sin − 2
65. (b) Idea If a , b, c are in HP.
A cos x − A sin x + B cos x + B sin x − 2B
1 1 1 =
Then, , , are in AP. Students are also use cos x + sin x − 2
a b c
2 cos x − sin x + λ
log be ∴
log ba = cos x + sin x − 2
log ae
( A + B ) cos x + (B − A ) sin x − 2B
We have given that, =
cos x + sin x − 2
loga 100, 2 logb 10, 2 logc 5 + logc 4 are in HP
A + B = 2, B − A = − 1, λ = − 2B
1 1 1
∴ , , are in AP 3 1
loga,100 logb 100 logc 25 + logc 4 ⇒ A = ,B = , λ = −1
2 2
1 1 1
, , are in AP TEST Edge Integration trigonometric function,
loga 100 logb 100 logc 100
polynomial function based question are asked. To
2 1 1 understand the relation between integration and
∴ = +
logb 100 loga 100 logc 100 differentiation and also learn the formulae of
integration.
2 logbe 100 loge a loge c
= + 68. (a) Let, equation of circle is x 2 + y2 = r2
loge 100 loge 100 loge 100 Y
2 loge b = loge a + loge c
2 loge b = loge (ac ) ⇒ b 2 = ac
which implies a, b and c are in GP X′ X
TEST Edge In JEE Main, given terms are in AP,
HP and GP related questions are asked. Students
are advised to solve these types of questions to
Y′
understand the relation between AP, GP and HP
and also acquainted yourself with properties Tangent to ellipse is y = mx + a 2m 2 + b 2
of log. If it is a tangent to the circle, then it is perpendicular
66. (b) Let, A and B are the events that card lost is spade from (0,0) is equal to radius,
and card drawn is spade. a 2m 2 + b 2
∴ =r
1 3 m2 + 1
P( A ) = , P ( A ) =
4 4
12 13 r 2 − b2 r 2 − b2
P (B / A ) = , P (B / A ) = ⇒ m= ⇒ θ = tan− 1
51 51 a2 − r 2 a2 − r 2
69. (c) Let, P denotes the families who own a phone and C RHL = lim f (x ) = lim ( 2x cot x + b )
x → π + /4 x → π + /4
denotes the families who own a car. Then,
n(P ) = 25% and n(C ) = 15% π
=
+b
2
n (P ′ ∩ C ′ ) = 65% and n(P ∩ C ) = 2000
 π π  π π
Now, since n (P ′ ∩ C ′ ) = 65% Also, f   = 2 cot   + b = + b
 4 4  4 2
⇒ n (P ∪ C )′ = 65%
For continuity, these three must be equal.
⇒ n (P ∪ C ) = 100 − 65 = 35% π π
Now, n (P ∪ C ) = n (P ) + n (C ) − n (P ∩ C ) ⇒ +a= +b
4 2
⇒ 35 = 25 + 15 − n (P ∩ C ) π
⇒ a −b = …(i)
⇒ n (P ∩ C ) = 5% 4
π
But, n (P ∩ C ) = 2000 Now at, x =
2
2000 × 100
∴ Total number of families = = 40000 LHL, = lim f ( x ) = lim ( 2x cot x + b ) = 0 + b
5 x → π − /2 π
x→
2
Since, n (P ∪ C) = 35%
RHL = lim (a cos 2x − b sin x )= − a − b
and the total number of families = 40000 x → π − /2
Hence, 2 and 3 are correct.  π
Also, f   =0+b
 2
70. (c) Idea Here sec 2 θ = 1 + tan 2 θ , and
 π
So, for continuity, f   = b = − a − b
cosec 2 θ = 1 + cot 2 θ and sin −1(sin x )2 = x 2  2
Consider, the given ⇒ a + 2b = 0 …(ii)
= sec2 (tan−1 2) + cosec2 (cot −1 3) Solving (i) and (ii), we get
= {sec (tan−1 2)} 2 + {cosec (cot −1 3)} 2 π π
b=− ,a =
= {sec (tan−1 2)} 2 + {cosec (cot −1 3)} 2 12 6
= {sec (tan−1 2)} 2 + {cosec (cot −1 3)} 2 TEST Edge The given function is continuous in
= {sec (sec−1 5 )]2 + {cosec ( cosec−1 10 )} 2 open interval and at a point related questions are
2 2 asked. To solve these types of questions students
= ( 5 ) + ( 10 )
are advised to understand the concept of
= 15
continuity and also acquainted yourself with
TEST Edge Generally, in JEE Main trigonometric formulae of limit.
identities and inverse trigonometric functions
72. (b) The given line will be parallel to one of the bisector
related questions are asked. To learn the
planes of the given planes hence equation of
identities to solve the questions.
2x + y + 3 z − 1
Bisector planes =
71. (b) Idea ∴ f ( x ) is continuous in [a , b]. Then, 14
( x + 2y − 3z − 1)
(i) f ( x ) will be continuous in ( a , b ) =±
14
(ii) lim( a + h) = f ( a )
h→ 0 ⇒ 3x + 3y − 2 = 0 and x − y + 6z = 0
(iii) lim( b − h) = f ( b ) x y z
h→ 0 line = = will be parallel to the plane
k 2 − 12
The given function is
x − y + 6 z = 0 ⇒ − 2x + 2y − 12z = 0
 π
x + a 2 sin x ; 0≤x < Comparing direction ratio of line and plane
 4
 π π k =−2
f ( x ) =  2x cot x + b ; ≤x ≤
 4 2 73. (c) Idea Here,
a cos 2x − b sin x π A
; <x ≤π
 2
π
At, x =
4
B C
LHL = lim f (x ) = lim ( x + a 2 sin x ) D
x → π − /4 x → π − /4

π The point A, B, C with position vectors a, b

= +a and c respectively.
4
 1
Area of triangle = |AD|| ⋅ BC | ⇒ f ( x ) is strictly increasing function.
2
1 1
|AC × BC |= |AD|| ⋅ BC| (0, 3) y = f (x)
2 2
|AC × BC |
|AD|=
|BC|
1
We know that area of ∆ABC = BC ⋅ AD
2
1 Also, f ( 0) = 3
= | AB × AC|
2 This implies f ( x ) has no positive root.
|a × b + b × c + c × a |
AD = 77. (b) Idea Here,
| (b − c ) |
( x + a )n + ( x − a )n = nc0 x n + nC2 x n− 2 a 2 + n C4 x n− 4 a 4
TEST Edge The distance between two points in a and i 2 = −1, i 4 = 1
space, three points are collinear related questions
It is given that
are asked. To solve these types of questions 5 5
students are advised to understand the concept of  3 + i  3 −i
z =  + 
cross product of vectors.  2   2 
74. (c) Mathematical distribution of above is 1
= [( 3 + i )5 + ( 3 − i )5 ]
x +y +z =6 25
Where, x , y and z represent one rupee, fifty paisa 1
= 4 [ 5C0 ( 3 )5 + 5C2 ( 3 )3 i 2 + 5C4 ( 3 ) i 4 ]
and twenty paisa coin respectively. 2
∴ Number of ways of choosing r things out of n 1
= 4 [ 3 {( 3 )4 + 10( 3 )2 ( −1) + 5( −1)2}]
things. 2
= n + r − 1 Cr − 1 = 6 + 3 − 1 C3−1 = 8C2 1 16 3
= 4 [ 3 ( 9 − 30 + 5)] = −
8! 8 × 7 × 6! 2 16
= = = 28
6!⋅ 2! 6!⋅ 2! = − 3, purely real number
Hence, there are 28 ways to choose six coins. ∴ Im ( z ) = 0
75. (a) Let, (k , k , k ) be the point of intersection of two lines TEST Edge In JEE Main, properties of conjugate
2 modulus and argument of complex number
⇒ k (sin A + sin B + sin C ) = 2d …(i) relative questions are asked from this concept. To
and k (sin 2A + sin 2B + sin 2C ) = d 2 …(ii) solve these types of questions students are
From Eqs. (i) and (ii) advised to understand the basic concept of
sin 2A + sin 2B + sin 2C 1 conjugate modulus and argument of a complex
= number.
sin A + sin B + sin C 2
A sin A sin B sin C 1 78. (b) Idea Here equation of line passing through the
⇒ =
A B C 2 points (x1 , y1) and ( x2 , y2 ) is
A sin cos cos y −y
2 2 2 y − y1 = 2 1 ( x − x1 )
(using trignometric identities) x2 − x1
( 2 sin A / 2 cos A / 2) ( 2 sin B / 2 cos B / 2) Given that the equation of line AB is
( 2 sin C / 2 cos C / 2) 1 2y = x …(i)
⇒ =
cos A / 2 cos B / 2 cos C / 2 2 A ( h , k)
1
⇒ sin A / 2 sin B / 2 sin C / 2 =
16
y = x/2
76. (c) For the given question,
f ( x ) = x 3 − 6x 2 + 15x + 3
B C
f ′ ( x ) = 3x 2 − 12x + 15 (2, 1) (1, 2)
f ′ ( x ) = 3( x 2 − 2x + 5)
Let coordinate of A are (h, k )
Hence, a > 0 i . e., coefficient of x 2 is positive and
D<0 Q AB = AC

∴ f ′( x ) is positive for all its point f ′ ( x ) > 0 ⇒ AB 2 = AC 2

 (k − 1)2 + (h − 2)2 = (h − 1)2 + (k − 2)2 TEST Edge Homogeneous equation, differential
h 2 + k 2 − 2k − 4h + 1 + 4 = h 2 + k 2 equation to reducible to the separable variable
− 2h − 4k + 1 + 4 type based questions are asked. To solve these
types of questions students are advised to
h =k
understand the concept of these homogeneous
Also, A lies on equation (i) equation.
∴ 2k = k ⇒ k = 0
Simplifying above equation, 80. (d) Idea If α and β are the roots of ax 2 + bx + c = 0
−b c
h =k = 0 then α + β = and αβ =
a a
∴ Coordinate of A is (0,0)
We have given equation as
Equation of line AC
λ (x 2 + x ) + x + 5 = 0
⇒ y − 0 = 2 ( x − 0)
λx 2 + ( λ + 1) x + 5 = 0
y = 2x λ +1 5
Roots are α , β. Here, α + β = − , αβ =
TEST Edge Standard equation of straight line and λ λ
its application related questions are asked. To α β 2 2
solve these types of questions, students are + = 4 ⇒ α + β = 4αβ
β α
advised to learn the formulae of equations of
straight line and also acquainted yourself with its ⇒ (α + β )2 = 6 αβ
application. 2
1 + λ  5
⇒   = 6×
79. (c) Idea This is a homogeneous differential equation  λ  λ
to reduce to the separable variable type.
1 + λ2 + 2λ 30
The parametric of the given equation let ⇒ =
λ2 λ
x = r cos θ, y = r sin θ …(i)
1 + λ2 + 2λ = 30λ
Differentiate to d θ, we get
⇒ dx = cos θ dr − r sin θ d θ ⇒ λ2 − 28 λ + 1 = 0
⇒ dy = sin θ dr + r cos θ d θ λ 1 + λ 2 = 28, λ 1λ 2= 1
Then the given differential equation reduces λ 1 λ 2 λ21 + λ22 ( λ 1 + λ 2 )2 − 2λ 1λ 2
+ = =
rdr 1−r2 λ2 λ1 λ 1λ 2 λ 1λ 2
=
r 2dθ r ( 28)2 − 2 × 1
= = 782
By variable separation [To separate variable r and 1
θ]
TEST Edge Generally, in JEE Main relation
dr
= dθ between roots of quadratic equation and some
1−r2 specific conditions, related questions are
Integrating both sides asked. To solve these types of questions
1 students are advised to understand the basic
∫ 1 − r 2 dr = ∫ dθ concept of relation between the roots of quadratic
equation.
sin− 1 r = θ + α ⇒ r = sin (θ + α )
r = cos α sin θ + sin α cos θ 81. (a) Idea Here, a = a1 $i + a2 $j + a3 k$
Multiplying by r, then a unit vector a$ =
a
r 2 = r sin θ cos α + r cos θ sin α |a$ |
x 2 + y 2 = y cos α + x sin α a⋅ b
The component of b along the a is
2 2
x − x sin α + y − y cos α = 0 |a |2
sin2 α cos 2 α 1 First of all we find,
x 2 − x sin α + + y 2 − y cos α + = $i + $j + 2 k$
4 4 4 A unit vector along $i + $j + 2 k$ =
2 2 6
 sin α   cos α  1
x −  + y −  = Hence, the component of $i along the given vector
 2   2  4
1 $i + $j + 2k$ 1
So, It is clear that circles of radius passing = projection of $i on =
through the origin. 2 6 6
 TEST Edge The component of vector a along and ⇒ 2 cos B sin C = sin A − 1
perpendicular to vector band projection of vector ⇒ sin (B + C ) − sin (B − C ) = sin A − 1
based questions are asked. To solve these types of ⇒ sin A − sin (B − C ) = sin A − 1
questions students are advised to understand the ⇒ sin (B − C ) = 1
concept of projection and component of vector. π
⇒ B −C =
82. (a) We have given that, 2
3π / 4 sin x + cos x π
I =∫ π
dx …(i) ⇒ B =C + = 23 + 90 = 113°
−π / 4 x− 2
e 4 +1
TEST Edge Sine rule and cosine rule of any
π  π 
sin  − x  + cos  − x  triangle properties of triangle related questions
3π / 4 2  2 
I =∫ π / 4− x
are asked. To solve these types of questions,
−π / 4 (e + 1) students are advised to understand the concept of
b a properties of triangle.
Using identity, ∫ f ( x ) dx = ∫ f (a + b − x ) dx
a b
3π / 4 cos x + sin x 84. (a) Idea If f ( x ) is one-one and onto then, it is
=∫ dx
−π / 4 e π / 4 − x (1 + e x − π / 4 ) one-one onto function.
3π / 4 cos x + sin x x −π / 4 Let, f : R → R be function defined
I =∫ e dx …(ii)
−π / 4 (1 + e x − π / 4 ) f ( x ) = x 3 + x 2 + 3x + sin x , x ∈ R
Adding Eqs. (i) and (ii) f ′( x ) = 3x 2 + 2x + 3 + cos x
 π f ′( x ) = g ( x ) + cos x
x −
(cos x + sin x ) 1 + e 4
  g( x ) > 0
3π / 4  
2I = ∫ = dx D = 4 − 36 = − 32 < 0
−π / 4 (1 + e x − π / 4 ) Q
3π / 4 (cos x + sin x ) dx − D 
∫− π / 4 [sin x − cos x ] 3π π/ 4/ 4
Range of g ( x ) is = 
 4a
, ∞

I =0  + 32   8 
, ∞ = , ∞
 12   3 
83. (a) Idea Here for any triangle ABC with sides
a b c
a , b and c = = ∴ f ′( x ) > 0
sin A sin B sin C
a 2 + c2 − b 2 Hence, function is strictly increasing
and cos B =
2 ac lim f ( x ) = ∞
x→∞
In ∆ABC, given that AD is an altitude from A on BC,
abc and lim gf ( x ) = − ∞
b > c, ∠ C = 23° and AD = 2 x →− ∞
b − c2
∴ Function is one-one and onto as f ( x ) is
A
continuous function.
c b
TEST Edge Types of functions such as one-one,
23° onto many one etc., based questions are asked. To
B C
D
a solve such type of question, students are advised
a 2 + c 2 − b2 a b2 − c 2 to understand the basic concept of function and
cos B = = −
2ac 2c 2ac also acquainted yourself with differentiation of
a b2 − c 2 b a b the different function.
= − ⋅ = −  1
2c abc 2 2c 2AD 85. (b) Q Binomial variate is given as, B  6, 
 2
sin A 1
= − 1 1
2 sin C 2 sin C ∴ n = 6, p = ,q =
2 2
Q ln ∆ACD 
 AD = sin C ⇒ b = 1  B(n, p ) = nCr ( p )n − r (q r )
 b AD sin C  Q Binomial coefficient of middle term is greatest
sin A − 1 which is r = 3
⇒ cos B =
2 sin C ∴ P ( X = 3) have highest probability.
86. (a) Consider, the given expression a + b a  a + c b + d 
⇒ c + d c  =  a
   b 
lim 3x 2 + 3x 2 + 3x 2 − 3x 2
x→∞ ⇒ a = c + d, a = b + d
3x +2
3x + 2
3x 2
− 3x 2 ⇒ d = a − b, b = c
= lim
x→∞ 1 1 
3x 2 + 3x 2 + 3x 2 + 3x 2 Thus, set of all matrices that commute with  
1 0
{by rationalisation}
w.r.t. matrix multiplication
3  a b  
3+
x2 3 1 =  ; a, b, ∈ R 
= lim = =  b a − b  
x→∞
3 3 3+ 3 2
3+ + + 3 1
x2 x4 89. (b) n = 20, σ = 2 and X = Σx i
n
87. (c) Idea The equation of normal to the ellipse ∴ Variance ( σ 2 ) = 4
x2
y 2
x − x1 y − y1 or Σxi = nX
+ = 1 at ( x1 , y1 ) is =
a 2 b2 x1 / a 2 y1 / b 2 = 20 × 10 {Q X = 10}
and b 2 = a 2 ( 1 − e2 ) = 200
Here, the equation of the normal at an end Incorrect Σxi = 200
 b2  1
L ae,  of a latus rectum of the ellipse, Also, Σxi2 − (mean)2 = σ 2 …(i)
 a n
b2
2 2 y − 1
x y x − ae a Σxi2 − 100 = 4
+ = 1 is = 20
a 2 b2 ae b2
a2 ab 2 Incorrected Σxi2 = 2080.
Y

90. (c) Idea Here use the multiplication of two square

(0, b) B L′(ae, b2/a) matrices and corresponding elements are
equal of a equal matrix.
A
A′ S (ae, 0)
X Let, A = a b  where, a, b, c, d ≠ 0
c d 
L a b  a b 
B′ (0, -b)
Now, A2 =   
c d  c d 
a 2 + bc ab + bd 
2 ⇒ A2 =  2
b 1 ax
⇒ y − = ( x − ae ) ⇒ ay − b 2 = − a2 ac + cd bc + d 
a e e
also, it is given that A 2 = I
which will pass through B′ ( 0, − b )
If − ab − b 2 = 0 − a 2 a 2 + bc = 1, bc + d 2 = 1
ab = a 2 − b 2 and, ab + bd = 0 = ac + cd
aa 1 − e 2 = a 2 − a 2 (1 − e 2 ) = a 2 e 2 ⇒ b (a + d ) = c (a + d ) = 0
2 4 4 2
⇒ 1−e =e ⇒e + e =1 Q b, c ≠ 0
TEST Edge Equation of the tangent at a point, ⇒ a+d =0
equation of the chord with mid-point and ⇒ Tr ( A ) = 0
equation of chord joining the two points related
questions are asked. To solve these types of also | A | = ad − bc = − a 2 − bc = − 1
questions, students are advised to learn the So, Statement I is true but Statement II is false.
formulae of above equation and understand the
basic concept of the ellipse. TEST Edge Generally, in JEE Main addition,
a b  multiplication and its application related
88. (d) Let, the required matrix be   such that questions are asked. To solve these types of
c d 
questions. students are advised to understand
a b  1 1  1 1  a b  the operation on addition multiplication of
c d  1 0 = 1 0 c d 
       matrix.