Qualitative Analysis 26
122029
What is
E
present
fm.fi
otmeumens
Carbon
Hydrogen
Ticaldments
Detect by
Lassaigne's Test
Detection of Carbon Hydrogen
time water
co Turnfky
organic acnothxide.to aised
rxnw caco t
sample
Cro
anhydrous
okay Cusoy 5H20
H2o w
cusoynite
Ren indeed
C 240 CO2 Cu 2H GO H2O Cu
CO2 Ca 0H12 Caco H2O
5H20 Custy Cason 5H20 Blue
Whitel
LINE
fusion tubes
makesthe antimetofised
aged
Nagatiescompound and add distiled water
Md boil it then
I filter it
If
Peson
The filtrate which is 0
Methanor
obtained is called
Sodessionextract
metal combines
The Na
with the special elements converts them into ionic
compounds
if n is present
Na C N
11Tcyanide
If s is present
2nA s Nazs
If s is present along with n then instead of Nacn
or Nazs Na SCN sodium thiocyanate is isolated
Na C S N Nasen
If x is present Natx Nax
Cl BrorI
f cannot be detected
in this method bis the
C F bond is
quite strong
Lassaigne's test for Nitrogen detection
soln added
Feso F shlyprdaq
then boiled
Na gag CNO aq
NacNlay
6CN Fe Fe can 6
y Hexacyanidoferrate
camp 111
Lassaigne's Ferrocyanide ion
Fusion extract
it a test
take faidify the soln by
adding conc Hasoy
few of the Fe2 ions in the aq
acidic medium will be oxidised into
Fe that will combine with the
111
Ferrocyanide ion to give a Prussian
blue colour son
Ryns involved Fe2 Fe
Fe Fe CN 6 xH20
Fe CN
1,4
6 3 2920
Prussian blue
colour
Iron 111
hexaganidoferrate 11
Ferri ferrocyanide
Fesou agl soln is prone towards aerial oxditation will
easing be oxidised into Fe and wont FefN get
formed So it is best to prepare an ag son of Fison fresh
The compound responsible for the prussian blue colour
during the detection of N in cassaigne's test is
Kz Fe CN 6 Fe Fe CN 6 a
Fea Fe No Fe Fe CN a
EI Detection of n in
Appian
done by Lastaigne's
S I soln offreshly prepared Fesoy added into
the Na fusion extract followed by acidification
with conc H soy gives prussian blue colouration
Both are correct
III In case n s both are present in the
organic compound the Na fusion extract gives
blood red colour no Prussian blue
S I There are free c ions present in the above
mentioned Na fusion extract SCNO
S I S IX
A If Na fusion is carried out with excess of Na
then usual sodium nitroprasside test for detection
of s can be obtained
R Thethiocyanate ion decomposes to yield cyanide
sulphide ions in preseng.ee p.IerandMirieetexpranet
Lassaigne's test for Sulphur detection
Method 1
acidify by adding CHzcoort followed by the
addition of head acetate Pb Choo
qff.fr 11925 Pb 4300 Pbs 2 Chzcoona
Blacky
Lassaigne's
Fusion extract
taken in a test
tube
Method II
mtytmins.in
Nazs Naz Fe CN Not
Nag Fe CN Nos
Lassaigne's
p Victor
Fusion extract
taken in a test
tube
NEB of 5
along with N is present within the
compound upon adding Fesoy for the detection of
N'i then no pracsian blue colour is obtained due to the
absence of CNO ions Instead the SCN thiocyanate
will combine with Fe3 to give blood red colour
ᵗ
Fest SCN 0 Fe SCN Blood Red
NB 9f during the Na fusion extract preparation the
Na metal was used in exiest quantity then
Nasen
249
Wtf Ntr it willgive
it reduces normal
the Nasen to it will violetcolour
the respective give normal
Nacn Nass Yohium
Prussian
Blue
nitroprassid mfehsontcone.Haso
Lassaigne.s test for Halogen detection
coni boil
add a NO _followed.by AgNoz
if BP is present
1ffffiiFFisprntesT.in
U
Agno Agel Not B
curdy
Agno AgBrd Not
pale yellow
white colour ppt
Lassaigne's is soluble in
Ago Hyhlan
Fusion extract gqgggggiipYp
qq.ua a.gg
ggpppgpg
ppt still remains
it is insoluble Iiii if I is present
both in water
asp4Ht Tom also
Tagnosphatting
why do we add conc HNO before adding the Agnos
If N one S is present then they would form
Nacn Na s respectively that can react parallely
with the Agnos
CNO Agno Agent N03
hitel
520 Agnoz Ages N03
Black
So 5 I n are to interfere in the detection
going
of X so we add HMOs conc boil so that
CN HNO HCN N03
520 HNO Has N03
Lassaigne's test for Phosphorous detection
add some 0 A Naz021 that will oxidise the
phosphorous present in the extract into P0g phospho
The Na Pou is then treated with con HNO
Iffy to produce
NazPOu
HzPOy
3 HNO H3POy 3Nanoz
Now after boiling the above soln we add
Lassaigne's
Ammonium molybdate NHA Moog
Fusion extract
taken in a test we
get a
Canary yellow colour
tube
HzP0g 12 NHA MoDa 21 HNO
NHA Poa 12 Mo03 21 NHgN0z 121720
ammonium phosphomolybdate Yellow colour
85 During the detection of P by Lassaigne's test
the yellow colour plot is obtained due to the
formation of
CN Nos
Fe Fe CN o Nad Fe
NHA Poy 12 Moo NHA Moog
6
A During the detection of halogens by Lasraigne's test
first the Na fusion extract is boiled with conc
HNO3
R If N or s is also present in the compound they
would form CNO 520 ions respectively that
would otherwise interfere with AgNos test for
halogens
A R are correct R correct explanation
of A
Quantitative Analysis application of mole whieft
Estimation of C HI
9
02 91 1102
actions 0 1014g420
09hrs0
0.246g
0.198g Co2
Find out C H in the
organic sample
Catty 0 202 7H20
tet c a
AI calculation for carbon
no of atoms of C'gify no of atoms of C'i
CO2
PLAC
E.ie in fatty
n
Eii.co
a
2 1 1
Calculation for Hydrogen H bt
0.246
If x 0.1014
i
Taff
Tintin
in H2o
Estimation of Nitrogen
111 Dumas method
Cao
29
CattyNz 2 202
1 3H20 ZN2 2
The final pressure reading that is obtained in the Nitrometer
can also have a contribution from aq tension of moisture
so in order to get PN2 Ptotal P
mentioned
in the quest
New apply
P initial press
If 1 P2 final 1 Ptotal Pano
V initial vol
V2 final vol of Nz gas
an
0.3g of sedthod 50 mL of Nz 9 at
organism 300K 715 mm Hg
can
inition i Totes p
Pmt PV NRT
1,5
are EIIi
msn.fi It
11 75 307000
motes
A mole let
i mass of N 28 2
g
i of N in the 0.5 1 100
0
27 1 2024
ii kjeldahl's method
FEN R N2
f
organic conc HzS0y NaOH soln
compound N 42504 NHz is
Quantitatively produced
I convert
Naott
to NHu2S0y This NHz is
Na Jou 21720 thentitrated
2MHz
byadding
sum
The Naott will Add kWh's of
now react with we will get the
the unreacted produced NH
Hasoy if any consumed by
standardsoln
known come of
come Hison
c peg Hason
2 NHFYmtwasmadmhf.com
135
1T
mm.mn I efon
tle any was consumed byadding
NaOH soln Naoh
initial no of mmoles H 504 taken M V mmoles
no of 1
of Naott consumed M2V2
2 immoles
1 Hasoy reacted with NaOH 12
so the no of mmoles of H2s0y that consumed NHz
MV
no of mmoles of NH3 produted
2
Mzt
IM V Mz
M2kI
12MiVi
Therefore the no of moles of NHz produced
2M V1 103
MaV2
W NHS 2M V1 M V2 103 17 g
W N
V2 103
117138
2M V M
i mass of nitrogen in the n'go.cn
211 103
11
1202 100
É
14
That if there is no remaining 42504 after consuming
the NHS produced
no of mmoles of H soy that consumed NH M V
1
NHz produced 2 Mill
i W NHS 2 MV 103 17
g
N N 2x MiV 103 17
11 g
mass of 2 03 14700
1
i
nitrogen
2
11
O.c fumingHN03
S content Na
50420
8
Fin
Mg10H12 NHa0H
T.io 919
present
m
o.ci
g NHab
H3P0a
P content http 877ymi
MgOH 24NAOH
Mg NH POa Mg 107 IM.M 222 gas
N 297
10 2
281
56
86 31 g S
Bason
233g
32
1 4939 1439 gs
32
5
111 1 7
42
11 g c 0.125
pv NRT
an
i t
IIIII.at
287 100 8
704
427
48,722
71127 7
Puri cation and Separation of Organic Compounds
