5-Module-Theory of Vibrations and Material Characterization
5-Module-Theory of Vibrations and Material Characterization
Relativity
Free Vibrations
Consider a body executing simple harmonic vibrations. In the absence of any frictional
forces the body will continue to vibrate with the same amplitude and frequency for any
length of time. The total energy of the body remains a constant. Such vibrations are called
free vibrations. Example: A pendulum suspended in perfect vacuum.
Consider a body of mass ‘m’ executing free vibrations. Then, if ‘y’ is the displacement,
Kinetic energy of the body
2
1 2 1 dy
= mv = m
2 2 dt
1
Potential energy of the body = 2 K y 2 , where K is the restoring force per unit displace-
ment.
Therefore,
2
1 dy 1
K.E + P.E = m + K y 2 = constant
2 dt 2
Differentiating we get,
1 d2 y dy 1 dy
m2 2 + K 2y =0
2 dt dt 2 dt
or
d2 y
m +Ky =0
dt2
or
d2 y
K
2
+ y=0 (1)
dt m
Equation 1 is similar to the equation
d2 y
+ ω2 y = 0
dt2
which is the equation of motion for a body executing simple harmonic oscillations with an
angular frequency ω and the solution the equation is given by
y = a sin ω t
1
Damped Vibrations
Free vibrations are only ideal cases. Under normal conditions there are frictional forces
acting on the vibrating body. Due to these frictinal forces like air resistance, viscosity etc,
the energy of the body gets dissipated with time. Hence the amplitude goes on decreasing
and finally the vibrations die out. Such vibratins are called damped vibrations.
The frictional forces are proportional to the velocity of the body and in a direction
opposite to the direction of motion of the body. If µ is the frictional force constant, then
the damping or frictional forces are given by −µ dy
dt . Thus the equation of motion in case of
damped vibration is given by,
d2 y dy
m 2
+ ky = −µ
dt dt
or
d2 y dy
m2
+ µ + ky = 0
dt dt
d2 y µ dy
k
+ + y = 0 − − − − − (1)
dt2 m dt m
This equation is of the form,
d2 y dy
2
+ 2b + k 2 y = 0
dt dt
µ k
Where, 2b = m and k 2 = m. The general solution for the above standard differential
equation is given by,
√ √
b2 −k2 )t b2 −k2 )t
y = A1 e−(b+ + A2 e−(b− − − − − − (2)
Where A1 and A2 are constants.
Case 1: Overdamped (b2 > k 2 )
p
When, (b2 > k 2 ), (b2 − k 2 ) is real and therefore both terms on the right hand side
of equation (2) decreases with time. Thus y continuously decreases as time increases and
finally becomes zero. Hence there is no oscillatory behaviour. If the body is displaced to
one side will slowly come back to the mean position and stop there itself. This kind of
motion is called overdamped vibrations.
2
Example: A pendulum suspended in a highly viscous fluid when displaced to one side
just comes back to the equilibrium position without moving to the other side.
Case 2: Critically damped (b2 = k 2 )
When (b2 = k 2 ), the solution is y = (A1 + A2 )e−bt which is again a continuous decrease
in amplitude with time. In this case also the body does not show any vibratory motion.
When the body displaced from the mean position and rests there without swinging over to
the other side.
Example: The movement of the needles of ammeter, voltmeters etc. Such vibrations
are called critically damped vibrations.
Case 3: Under damped (b2 < k 2 )
p
When (b2 < k 2 ), (b2 − k 2 ) is imaginary. Let us write,
b2 − k 2 = (−1)(k 2 − b2 ) = (−1)β 2
p
Where β = (k 2 − b2 ) , so that,
p
(b2 − k 2 ) = iβ
Then,
y = A1 e−(β+iβ)t + A2 e−(β−iβ)t
This can be rearranged to be written in the form,
y = Ce−bt sin(βt + Φ)
As time goes on increasing, the
p amplitude goes on decreases. At the same time the body
also vibrates with a frequency, (k 2 − b2 ). But due to the frictional forces the amplitude
goes on decreasing and the body comes to rest Such vibrations are called under damped
vibrations.
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depends upon the damping coefficient b. It is called under-damped motion
as shown in figure.
In this case the period is slightly increased or frequency decreased because
the period is √ω2π 2π
2 −b2 while in the absence of damping it was ω .
The example of this type of motion is the motion of a pendulum in air,
the motion of the coil of ballastic galvanometer or the electric oscillations in
LCR circuit.
3 Forced Vibrations
When a body is made to vibrated by an external periodic force (which may
or may not have its frequency equal to the natural frequency of the body) the
body, at first, tries to vibrate with its own natural frequency but ultimately it
vibrates with the frequency of applied force. Such vibrations are called forced
vibrations. The forced vibrations, after the removal of external periodic force,
becomes free and die out in due course of time.
Forced vibrations can be defined as the vibrations in which the body
vibrates with a frequency other than its natural frequency under the action
of an external periodic force.
As an example, consider the vibrations of bridge under the influence of
marching soldiers or vibrations of a tuning fork when exposed to the periodic
force of sound waves. In both the cases body vibrates because it is subjected
to an external periodic force. Such vibrations are called forced vibrations.
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3. the external periodic force, represented by
fe = F sin pt
p
where F is the maximum value of this force and 2π
is its frequency
d2 y dy
m 2
= −ky − µ + F sin pt
dt dt
2
dy dy
m 2 + µ + ky = F sin pt
dt dt
Dividing by m
d2 y µ dy k F
2
+ + y= sin pt
dt m dt m m
d2 y dy
2
+ 2b + ω 2 y = f sin pt (14)
dt dt
µ k F
where m = 2b, m = ω 2 and m = f.
Equation (14) is the differential equation of motion of the particle.
y = A sin(pt − θ) (15)
where A is the steady amplitude of vibrations and θ is the angle by which
the displacement y lags behind the applied force F sin pt. A and θ being
arbitrary constants.
Differentiating (15), we have
dy
= Ap cos(pt − θ)
dt
10
d2 y
= −Ap2 sin(pt − θ)
dt2
substituting these values in (14), we have
f
∴A= p (18)
(ω 2 − p2 )2 + 4b2 p2
Dividing equation (17) by (16), we have
2bAP 2bP
tan θ = 2 2
= 2
A(ω − p ) ω − p2
−1 2bP
∴ θ = tan (19)
ω 2 − p2
Substituting the value of A from equation (18) in (15), we get
f
y=p sin(pt − θ) (20)
(ω 2 − p2 )2 + 4b2 p2
Equation (18) gives the amplitude of forced vibration while (19) its phase.
Depending upon the relative values of p and ω, three cases are possible.
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Condition for Resonance
The amplitude of the vibration is given by,
F
a= p
µ2 p2 + (K − mp2 )2
The amplitude will be maximum if the denominator on the right hand side is a minimum.
Therefore,
d 2 2
µ p + (K − mp2 )2 = 0
dp
µ2 = 2m(K − mp2 )
µ2
= K − mp2
2m
µ2 K
2
= − p2
2m m
µ2
= w 2 − p2
2m2
Here, K 2
m = w , is the natural frequency of vibration of the body in the absence of
µ2
any frictional forces. If the frictional forces are very small so that 2m 2 is negligible, then
we obtain, w2 − p2 = 0 or w = p. Then the amplitude will have the maximum value.
This condition is called resonance. When the natural frequency of vibration equals to the
externally applied frequency, resonance take place and the body vibrates with maximum
amplitude.
Ultrasonics
Sound waves of the frequencies above the limits of human audibility i.e., gerater than 20kHz
are called ultrasonics. Propogation these waves through matrial medium depends on the
elastic properties and the density of the medium. In fluids ultrasonic waves are propogated
as longitudinal waves where as in solids, ultrasonic waves travels as both longitudinal as well
as transverse waves. The wavelength of ultrasonic waves are very small and this smallness
in wavelength makes ultrasonic waves are usefull in many of their applications. Particularly,
ultrasonic waves are widely used in medical diagnostics, marine applications, non destructive
testing of finished products and so on.
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Ultrasonics
ULTRASONICS
Ultrasonic waves are longitudinal waves whose frequency is greater than 20 kHz.
Production
piezoelectric Method
Tunable Piezo
Electric
Oscillator
Crystal
Ultrasonic interferometer
Determination of velocity of Ultrasonic waves
Micrometer
Movable Metal
Reector
Liquid
l
2
RF
Quartz
GENERATOR
Crystal
Working: When the generator is switched on, the quartz crystal vibrates
and produces ultrasonic waves in the liquid. The waves are reflected back from
metallic plate producing stationary waves in the medium. When micrometer
is moved slowly so that at one position separation between the plate and the
quartz crystal is exact integral multiple of half the wavelength of waves. Acoustic
resonance occurs. The ammeter shows maximum reading. The reading of the
ammeter is noted down. Let it be R1 . The micrometer is further rotated to get
next acoustic resonance. Let the reading of the ammeter be R2 . R2 ∼ R1 = λ/2,
the wavelength of the ultrasonic waves. The frequency of the ultrasonic waves
is same as RF generator. Using, v = f λ the velocity of the ultrasonic waves is
calculated.
The density of states (DOS) (number of electronic states per unit volume and energy) is greatly
modified for different type of nanostructures depending on the degree of confinement as shown
in the following Figures.
For 3-D materials (Bulk), the DOS varies continuously. The density will be typically of
the order of 1026 /m3 eV.
For a 2-D structure (film), the DOS varies as a step function. The density is typically of
the order of 1018 /m3 eV.
For a 1-D structure (quantum wire), the DOS variation is neither smooth as 3-D nor even
constant (2-D). The density is typically of the order of 10 9 /m3 eV.
For a 0-D structure (nanoparticles), the permitted energy values form discrete bunches of
varying densities because of the confined conditions for electrons. Thus density of energy
levels appear as discrete lines.
(b) Quantum effect: According to quantum mechanics, free carriers in a metal or semiconductor
can take only specific values of energy i.e., energy is quantized.
(c) Width of band decreases.
(d) Thermodynamic stability if altered.
Applications of CNTs:
CNTs are well-suited for virtually any application requiring high strength, durability, electrical
conductivity, thermal conductivity and lightweight properties compared to conventional
materials.
Currently, CNTs are mainly used as additives to synthetics. CNTs are commercially available
as a powder, i.e. in a highly tangled-up and agglomerated form. For CNTs to unfold their
particular properties they need to be untangled and spread evenly in the substrate.
Carbon nanotube enabled nanocomposites have received much attention as a highly attractive
alternative to conventional composite materials due to their mechanical, electrical, thermal,
barrier and chemical properties such as electrical conductivity, increased tensile strength,
improved heat deflection temperature, or flame retardancy. These materials promise to offer
increased wear resistance and breaking strength, antistatic properties as well as weight reduction.
For instance, it has been estimated that advanced CNT composites could reduce the weight of
aircraft and spacecraft by up to 30%.
1) CNTs can store lithium due to which they can be used in batteries and other
electrochemical applications. They can also store hydrogen and find potential applications
in fuel cells.
2) Armchair SWNTs show good conducting properties whereas chiral and zig-zag SWNTs
show semiconducting properties. Hence they are used in transistors and electrochemical
supercapacitors.
3) They are extensively used in medical applications as carriers for drug delivery, to monitor
glucose level and to inject insulin when required.
4) They are being used to develop flat display panels for television and computers.
1) Electronics: Nanomaterials are used in devices like spin FET, spin LED etc. These devices
have increased the data storage capacities of hard discs and have led to small and faster
microprocessors.
3) Automobiles: Nanoparticles are being used to develop light weight and less rubber consuming
tyres for automobiles which will increase the mileage of the automobiles. Nanomaterial catalysts
can be used as catalysts to convert the harmful emissions from automobiles to less harmful gases.
4) Space & Defence: Polymer composites can be used in spacecrafts which have to withstand
high temperature and stress conditions during launching and re-entry into the earth’s
atmosphere. Satellites and spacecrafts use solar energy.
5) Medical: Nanoparticles can be used for detection and treatment of cancer and tumours. They
are also used in drug delivery system.
6) Environmental: Nanoparticle based sensors are capable of detecting water and air pollution
due to toxic ions and pesticides with a very high sensitivity.
7) Textiles: The use of nanotechnology in textile industry has led to the development of water
repellent and wrinkle free clothes.
8) Cosmetics: Zinc oxide and titanium oxide nanoparticles are used in sunscreen lotions which
protect the skin from the UV radiations as these nanoparticles absorb UV radiations.
*******
Nanomaterials dispersed in the form of colloids in solutions, particles or thin films are
characterized by various techniques. Although the techniques to be used would depend
upon the type of material and information one needs to know, usually one is interested in
first knowing the size, crystalline composition, thermal, chemical state and properties like
optical or magnetic properties.
Scanning Electron Microscope (SEM)
Scanning electron microscope is a type of electron microscope that uses a beam of electrons
moving at low energy to focus and scan the surfaces of the specimens with better resolution
power.
Principle: Scanning electron microscope works on the principle of applying kinetic
energy to produce signals due to the interaction of the electrons.
Construction: It consists of an electron gun to produce high energy electron beam.
A magnetic condensing lens is used to condense the electron beam and a scanning coil is
arranged in between magnetic condensing lens and the sample. The scattered electrons are
detected by using detector and can be converted into electrical signal. These signals can be
fed into cathode ray tube through amplifier as shown in figure.
Working: Stream of electrons are produced by the electron gun and these primary
electrons are accelerated by the anode. These accelerated primary electrons are made to
incident on the sample through condensing lenses and scanning coil. These high speed pri-
mary electrons upon falling over the sample produces secondary electrons, backscattered
electrons and diffracted electrons. Secondary and backscattered electrons are used to pro-
duce an image of the specimen. The secondary electrons emitted from the specimen play
the primary role of detecting the morphology and topography of the specimen while the
backscattered electrons show contrast in the composition of the elements of the specimen.
The collected electrons are converted into electrical signals and fed into cathode ray
1
tube through amplifier. The samples are mounted and coated with thin layer of heavy
metal elements to allow spatial scattering of electric charges on the surface of the specimen
allowing better image production, with high clarity.
2
Fourier Transform Infrared Spectroscopy (FTIR)
Fourier transform infrared spectroscopy is a largely used technique to identify the functional
groups in the materials (gas, liquid and solid) by using the beam of infrared radiations
Principle: In FTIR, infrared radiation passes through the sample, part of the infrared
radiation is absorbed by the sample others are transmitted. The frequency at which a par-
ticular bond absorbs infrared radiation will be different over a range of bonds and modes of
vibration depending on atom size, bond length and bond strength. The resulting spectrum
represents the molecular absorption and transmission, creating a molecular finger print of
the sample.
Construction: Fourier transform infrared spectrometer makes use of the Michelson
interferometer for recording the spectra. It consists of an source which generate IR radiation,
sample in the form of gas, solid or liquid and detector which detects the transmitted light.
Michelson interferometer arrangement consisting of beam splitter, fixed mirror and movable
mirror as shown in figure.
Working: A parallel beam of infrared rays incident on the beam splitter. Beam splitter
spilts the light ray into two equal components. Part of the beam falls on a movable mirror
and other on fixed mirror. The rays are reflected back from both the mirrors along the
same path and interfere at beam splitter. A part of this combined beam incident on the
sample is detected by a detector. Constructive and destructive interference occurring at
beam splitter depends upon the path length of the rays.
The recombined beam passing through the sample produces absorption spectrum in
which certain characteristic frequencies are absorbed by molecules present in the sample.
Detector collects the signals from the sample for every millisecond and stores each spectrum
in different locations. With modern computers, by carrying out the Fourier transform
analysis, the resultant spectra are obtained as an output. Thus, better and fast data
acquisition is possible using FTIR spectrometer.
3
Atomic Force Microscopy (AFM)
Atomic force microscopy is an advanced technique of studying properties of materials at an
atomic scale.
Principle: Atomic force microscopy principle is based on the cantilever/tip assembly
that interacts with the sample; this assembly is also commonly referred to as the probe.
Construction: Atomic force microscopy has a flexible cantilever of ≈ 100µm long,
10µm wide and 1µm in height attached to a piezodrive. A tip is mounted on a cantilever
as shown in figure. The resonant frequency is used to control the tip-sample interaction.
AFM tip is in close vicinity of the sample surface, experiences a repulsive force which results
into minute amount of bending of the cantilever. A laser beam is directed on back of the
cantilever as shown in figure. Small deflections caused by the tip-sample imteraction are
recorded by a position sensitive photodiode. By rastering the probe on sample surface and
measuring the cantilever deflections, surface image is obtained.
Working: An AFM can be operated in three different modes viz. (1) Contact mode,
(2) Non-contact mode and (3) Tapping mode.
Contact mode: In this case, the tip is in contact with the sample surface and is almost
forced into it. However due to repulsive interaction between electron charge cloud of the tip
atom and that of the surface atom, the tip is repelled back which bends the cantilever and
deviates the direction of the laser beam. The main disadvantage of this mode is that the
tip or sample can get damaged due to forcing of the tip into sample, especially, polymers
or other organic materials like biological samples which can get damaged by this method.
Non-contact mode: In non-contact mode, the tip or the probe moves at some small
distance away from the sample surface. Therefore, it cannot damage the sample.
Tapping mode: Tapping mode is a combination of contact and non-contact modes.
The resolution of the contact mode is higher than the non-contact mode, because in contact
mode the interaction between tip and surface atoms is much more sensitive to the distance
as compared to that in con-contact mode. With tapping, high resolution advantage of
contact mode and non-destructiveness of non-contact mode are achieved.