Chemistry Test Paper

UNIT-2: SOLUTIONS
Time: 90 minutes M.M. 40

General Instructions:
(1) All questions are Compulsory.
(2)The question paper consists of 15 questions divided in to four sections A, B,C&D
(3) Section A contains 2 questions of 1 mark each.
Section B contains 5 questions of 2 marks each.
Section C contains 6 questions of 3 marks each.
Section D contains 2 questions of 5 marks each.

Section –A
1. State Henry law with its mathematical expressions?
2. Define colligative properties.
Section –B
3. An antifreeze solution is prepared from 222.6g of ethylene glycol. C2H4 (OH) 2
and 200g of water. Calculate molality of solution. If the density of the solution is
1.072 g/ml then what shall be the molarity of the solution?
4. Explain along with diagrams the conditions for the Non ideal solutions
exhibiting Positive deviations. Write some examples of Non ideal solutions
exhibiting Positive deviations.
5. What are Azeotropes? Give one example each of minimum boiling and
maximum boiling azeotropes.
6. Calculate the mass of a nonvolatile solute (molecular mass = 40) which should
be dissolved in 114g octane to reduce its vapour pressure to 80%.
7. What is value of Van’t Hoff’s factor when the solute undergoes (a) association
(b) dissociation?
Section –C
8 100 mg of a protein is dissolved in enough water to make 10ml of a solution. If
this solution has an osomotic pressure of 13.3 mm Hg at 250C,what is the molar
mass of protein?(R=0.0821Latmmol-1K-1 and 760mmHg=1atm)
9. Heptane and Octane form ideal solution .At 373 K, the vapour pressures of the
two liquid components are 105.2kPa and 46.8kPa respectively. What will be the
vapour pressure, in bar of a mixture of 25.0g heptane and 35.0g of octane?
10 Boiling point of water at 750 mHg is 99.630C.How much sucrose is to added to
500 g water such that it boils at 100o C.
11. What is osmosis, osmotic pressure & reverse osmosis?
12. Amongst the following compounds, identify which are insoluble, partially
soluble and highly soluble in water?(i) phenol (ii) toluene (iii) formic acid(iv)
ethylene glycol (v) chloroform (vi) Pentanol.
13. If N2 gas is bubbled through water at 298 K, how many millimoles of N2 gas
would dissolve in 1 litre of water .Assume that N2 exerts a partial pressure of
0.987 bar .Given that Henry’s law constant for N2 at 293K is 76.48 bar.

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 Section –D
14.Two elements A & B form compounds having molecular formula AB2 & AB4.
When dissolved in 20g of C6H6, 1g AB2 lowers the freezing point by 2.3 &
1.0g AB4 lowers it by 1.3K.The molar depression constant for benzene is
5.1Kg mol-1. Calculate atomic mass A & B.

15. 19.5 g of CH2FCOOH is dissolved in 500 g of water. The depression in the

freezing point of water observed is 1.00 C. Calculate the van’t Hoff factor and
dissociation constant of fluoroacetic acid.)

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 Chemistry Test Paper
Unit-3: Electrochemistry
Time: 90 minutes M.M. 40

General Instructions:
(1) All questions are Compulsory.
(2)The question paper consists of 15 questions divided in to four sections A, B,C&D
(3) Section A contains 2 questions of 1 mark each.
Section B contains 5 questions of 2 marks each.
Section C contains 6 questions of 3 marks each.
Section D contains 2 questions of 5 marks each.

Section A
1. How much electricity in terms of Coulomb is required to reduce 1 mol of
Cr2O72- to Cr3+.
2. What is Fuel Cell?
Section B
3. A solution of CuSO4 is electrolysed using a current of 1.5 amperes for 10
minutes. What mass of Cu is deposited at the cathode?(Atomic mass of Cu
=63.7)
4. Calculate the equilibrium constant for the reaction Cu (s) + 2Ag+  Cu
+2
+ 2Ag(s) EoCu2+/Cu = +0.34V, EoAg+/Ag = + 0.80V.
5. Write the Nernst equation and emf of the following cells at 298K:
Sn/Sn2+(0.050M)//H+(0.020M)/H2(g)/Pt(s) EoSn2+/Sn= - 0.13V
6. Calculate the standard free energy change for the following reaction at
250C,Au(s) +Ca+2 (1 M) Au3+(1M) + Ca (s) ,The electrode values are
Ca2+ / Ca = –2.87V,Au3+ / Au = +1.50V. Predict whether the reaction will
be spontaneous or not at 250C.
7. How do you account for conductivity of strong and weak electrolyte with
concentration? Plot the graphs also.
Section C
8. State Kohlrausch law . Calculate Limiting molar conductivity of NaCl, HCl
and NaAc are 126.4, 425.9 &91 SCm2 mol-1.Calculate Limiting molar
conductivity of HAc.
9. Resistance of conductivity cell filled with 0.1molL-1 KCl solution is 100
ohm. If the resistance of the same cell when filled with 0.02molL-1 KCl
solution is 520 ohm. Calculate the conductivity & molar conductivity of
0.02molL-1 KCl solution. The conductivity of 0.1 molL-1 solution of KCl is
1.29Sm-1.
10. A Copper –silver is set up.The copper ion concentration in its is 0.10M.The
concentration of silver is not known.The cell potential measured
0.422V.Determine the concentration of silver ion in the cell. EoAg+/Ag = +
0.80V, EoCu2+/Cu = +0.34V.
11. A voltaic cell is set up at 250C With the following half cells
:Al(s)/Al3+(0.001M) and Ni2+(0.50)/Ni(s) ,Write the equation for the cell

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 reaction that occurs when the cell generates an electric current and
determine the cell potential (givenEoNi2+/Ni = -0.25V, Eo Al(s)/Al3+=-1.66V)
12. Write the reaction involved in the following cells: (a) Fuel Cell (b) Lead
Storage Battery.
13. Three electrolytic cells A,B,C containing solutions ZnSO4,AgNO3,and
CuSO4 respectively are connected in series .a Steady current of 1.5 amperes
was respectively are connected in series .A steady current of 1.5 amperes
was passed though them until 1.45g of silver deposited at the cathode of
cell B.How long did the current flow? What mass of copper and zinc were
deposited?
Section D
14. Conductivity of 0.00241M acetic acid is 7.896 X 10-6 S cm-1. Calculate its
molar conductivity. If Λ0 for acetic acid is 390.5 S cm2 mol-1. What is its
dissociation constant?
15. (a) Two half cell reactions of an electrochemical cell are given below:
MnO4- + 8 H+ + 5 e- Mn2+ + 4 H2O Eo =+1.51V
Sn2+  Sn4++ 2e- Eo = +0.15V.
Construct the redox reaction from the two half cell reaction and predict if
the reaction favours formation of reactants or product shown in the reaction
(b). How much electricity in terms of Faraday is required to produce (i)20g of
Ca from molten CaCl2 (ii) 40g of Al from molten AlCl3

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 Chemistry Test Paper
UNIT-4: CHEMICAL KINETICS
Time: 90 minutes M.M. 40

General Instructions:
(1) All questions are Compulsory.
(2)The question paper consists of 15 questions divided in to four sections A, B,C&D
(3) Section A contains 2 questions of 1 mark each.
Section B contains 5 questions of 2 marks each.
Section C contains 6 questions of 3 marks each.
Section D contains 2 questions of 5 marks each.

Section –A
1. Define Pseudounimolecular reaction?
2. The decomposition reaction of ammonia gas on platinum surface has a rate
constant = 2.3 x 10-5 L mol-1s-1. What is the order of the reaction?. .
Section –B
3. Mention the factors that affect the rate of a chemical reaction.
4. From the rate expression for the following reactions determine their order
of reaction and dimensions of the rate constants.
a) H2O2 (aq) + 3 I - (aq) + 2H+  2H2O (l) + 3I-1 Rate = k [H2O] [I-]
b) CH3 CHO (g) CH4(g) + CO(g) Rate = k [CH3 CHO]3/2
5. A reaction is first order in A and second order in B.
i) Write differential rate equation.
ii) How is the rate affected when concentration of B is tripled?
iii) How is the rate affected when the concentration of both A and B is
doubled?
6. The decomposition of NH3 on platinum surface is zero order reaction.
What are the rates of production of N2 and H2 if k = 2.5 x 10-4 mol L-1 S-1?
7. Derive the Integrated rate equation for first order reaction. also find half
life period and plot the graph associated to it.

Section –C
8. For a first order reaction, show that time required for 99% completion is
twice the time required for the completion of 90% of reaction.
9. A first order reaction has a rate constant 0.0051min-1 .If we begin with 0.10
M concentration of the reactant ,what concentration of the reactant will be
left after 3 hours.
10. The half-life for radioactive decay of 14C is 5730 years. An archaeological
artifact containing wood had only 80% of the 14C found in a living tree.
Estimate the age of the sample
11. What is the effect of temperature on the rate constant of a reaction? How
can this temperature effect on rate constant be represented
quantitatively?

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 12. The rate of a reaction quadruples when the temperature changes from 293
K to 313 K. Calculate the energy of activation of the reaction assuming that
it does not change with temperature.
13. A first order reaction takes 40 min for 30% decomposition. Calculate t1/2..

Section –D
14(a) Distinguish between order of reaction & Molecularity.
(b) For a decomposition reaction the values of rate constant k at two different
temperatures are given below:k1 =2.15 x 10-8 L mol-1s-1 at 650K, k2 =2.39 x 10-7 L
mol-1s-1 at 700K Calculate the value of Activation Energy for this reaction.
15.(i) Write short notes on the following:
(a) Activation energy of a reaction (b)Elementary step in a reaction (c)Rate of a
reaction
(ii) The following result has been obtained during the kinetic studies of the
reaction
2A + B  C+D
Experiment [A] mol L-1 [B] mol L-1 Initial rate mol L-1min-1
I 0.1 0.1 6.0 x 10-3
II 0.3 0.2 7.2 x 10-2
III 0.3 0.4 2.88 x 10-1
IV 0.4 0.1 2.40 x 10-2
Determine the rate law and rate constant for the reaction

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 Chemistry Test Paper
UNIT-8: THE d- AND f-BLOCK ELEMENTS
Time: 90 minutes M.M. 40

General Instructions:
(1) All questions are Compulsory.
(2)The question paper consists of 15 questions divided in to four sections A, B,C&D
(3) Section A contains 2 questions of 1 mark each.
Section B contains 5 questions of 2 marks each.
Section C contains 6 questions of 3 marks each.
Section D contains 2 questions of 5 marks each.

Section –A
1. Name an important alloy which contains some of the lanthanoid metals.
Mention its uses.
2. What is the effect of increasing pH on a solution of potassium
dichromate?
Section –B
3. (a) Transition element form generally coloured compounds. Give reason
(b) Transition metals show paramagnetic behaviour. Give reason
4. (a) Name a transition element which does not exhibit variable oxidation
states.
(b) Calculate the magnetic moment of a divalent ion in aqueous solution if
its at.no is 25.
5. (a) Transition metal ions form complex ions. Why?
(b) Transition metals and their compounds possess catalytic properties ?
6. Why is Cr2+reducing and Mn3+oxidising when both have d4configuration
7. (a)The highest oxidation state is exhibited in oxoanions of a metal. Why?
(b)The lowest oxide of transition metal is basic, the highest is
amphoteric/acidic. Why?

Section –C
8. Compare the chemistry of lanthanoids with that of the actinoids with
reference to(i)electronic configuration (ii)Oxidation state (iii)chemical
reactivity
9. What is Lanthanoid contraction? Give its cause. What are its Consequences
10. (a) The actinoids exhibit a larger number of oxidation states than the
corresponding lanthanoids. Give reason
(b) Cobalt (II) is stable in aqueous solution but in the presence of complexing
reagents it is easily oxidized.Why
11. Why are Mn2+compounds more stable than Fe2+ towards oxidation to their
+3 state
12. Give the balanced reaction involved in the preparation of Potassium
dichromate & Potassium permanganate
13. Write balanced ionic equations for reacting ions to represent the action of
alkaline or neutral Potassium permanganate solution on:(i) Iodide
(ii)Thiosulphate

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 Section –D

14. (a)Write balanced ionic equations for reacting ions to represent the action
of acidified Potassium dichromate solution on:(i) Potassium iodide solution
[ii] iron (II) solution
(b) Write balanced ionic equations for reacting ions to represent the action
of acidified Potassium permanganate solution on:(i) oxalic acid (ii)
Sulphurous acid or suphite

15. Account for the following:

a. Zn, Cd and Hg are not considered as transition elements
b. Transition element show variable oxidation state
c. A transition metal exhibit higher oxidation state in oxides and
fluorides
d. E0value for the Mn3+/Mn2+couple is the much more positive than
that forCr3+/Cr2+or Fe3+/Fe2+
e. Transition elements exhibit higher enthalpies of atomization

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 Chemistry Test Paper
UNIT-9: COORDINATION COMPOUNDS
Time: 90 minutes M.M. 40

General Instructions:
(1) All questions are Compulsory.
(2)The question paper consists of 15 questions divided in to four sections A, B,C&D
(3) Section A contains 2 questions of 1 mark each.
Section B contains 5 questions of 2 marks each.
Section C contains 6 questions of 3 marks each.
Section D contains 2 questions of 5 marks each.

Section –A
1. Why is geometrical isomerism not possible in tetrahedral complexes having
two different types of unidentate ligands coordinated with the central metal
ion?
2. Amongst the following, Which one is the most stable complex and Why?(i)
[Fe(H2O)6]3+ (ii) [Fe(NH3)6]3+ (iii) [Fe(C2O4)3]3– (iv) [FeCl6]3–
Section –B
3. Using IUPAC norms write the formulae for the following: (a)Hexaammine
cobalt (III) sulphate (b) Tetraammineaquachloridocobalt (III) chloride(c)
potassiumtetracyanonickelate (II) (d) Iron(III) hexacyanoferrate(II)
4. Write the IUPAC names of the following coordination compounds:(a) [Co
(NH3)4Cl (NO2)]Cl (b) K3 [Fe (CN) 6]
5. Give evidence that [Co(NH3)5Cl] SO4 and [Co(NH3)5SO4]Cl are ionization
isomers
6. What is understood by Linkage Isomerism, explain giving examples:
7. Draw diagram to show splitting of d – orbital in a tetrahedral crystal field.

Section –C
8. [Fe (H2O) 6] is strongly paramagnetic while [Fe(CN)6]3- is weakly
3+

paramagnetic.Explain using VBT.

9. Draw all the structures of geometrical isomers of: (a) [Co(NH3)3(NO2)3] (b)
[CrCl2 (en) 2] + (c) [Co(NH3)4Cl2]+
10. Using VBT Predict the Magnetic behaviour, Hybridization, Shape of
following(a) [Co (NH3)6]+3 (b) [Cr (NH3)6] +3 (c) [Ni (CO)4]
11. (a) Draw all the structures of optical isomers of : [CrCl2(en)2]+
(b) Predict the number of unpaired electrons in the square planar
[Pt(CN)4]2– ion
12. Discuss the role of coordination chemistry in (a) Biological systems (b)
metallurgy /Extraction of metals (c) Medicinal Chemistry
13. What is meant by stability of a coordination compound in solution? State
the factors which govern stability of complexes.

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 Section –D

14. (a) Draw diagram to show splitting of d – orbital in octahedral crystal field.
Explain the two patterns of filling d4 in octahedral crystal Field.
(b) . The Hexaaquomanganese (II) ion contains five unpaired electrons, while
the Hexacyano manganese (II) ion contains only one unpaired electron.
Explain using CFT
15. (a) What is spectrochemical series? Explain the difference between a weak
field ligand and a strong field ligand.
(b) What is the coordination entity formed when excess of aqueous KCN is
added to an aqueous solution of Copper sulphate? Why is it that no
precipitates of Copper sulphide is obtained when H2S (g) is passed through
this solution

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 Chemistry Test Paper
Unit-10:Haloalkanes and Haloarenes
Time: 90 minutes M.M. 40

General Instructions:
(1) All questions are Compulsory.
(2)The question paper consists of 15 questions divided in to four sections A, B,C&D
(3) Section A contains 2 questions of 1 mark each.
Section B contains 5 questions of 2 marks each.
Section C contains 6 questions of 3 marks each.
Section D contains 2 questions of 5 marks each.

Section –A
1. Name the ClCH2C≡CCH2Br according to IUPAC system
2. Write the structures of 1,4-Dibromobut-2-ene?
Section –B
4. Write the mechanism of the following reaction:
EtOH  H 2 O
nBuBr +KCN    nBuCN
5. Predict all the alkenes that would be formed by dehydrohalogenation of the
following halides with sodium ethoxide in ethanol and identify the major
alkene: (i) 1-Bromo-1-methylcyclohexane (ii) 2-Chloro-2-methylbutane.
6. The treatment of alkyl chlorides with aqueous KOH leads to the formation
of alcohols but in the presence of alcoholic KOH, alkenes are major
products. Explain. giving reactions.
7. Haloalkanes react with KCN to form alkyl cyanides as main product while
AgCN forms isocyanides as main product. Explain giving reactions.
Or
7. (a) In the following pairs of halogen compounds, which would undergo
SN2 reaction faster? (b)

(b) In the following pairs of halogen compounds, which compound

undergoes faster SN1 reaction?

Section –C
8. Explain the following : (a)Swarts Reaction (b)Finkelstein reaction
9. How the following conversions can be carried out?(a) Chloroethane to
butane (b) Benzene to diphenyl (c) 2-Bromopropane to 1-bromopropane

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10. Explain why
a) the dipole moment of chlorobenzene is lower than that of cyclohexyl
chloride
b) alkyl halides, though polar, are immiscible with water
c) Grignard reagents should be prepared under anhydrous conditions.
11. Write the structure of the major organic product in each of the following
reactions:
a) CH3CH = C(CH3)2 + HBr  
b) CH3CH2CH = CH2 + HBr  
peroxide

c) CH3CH(Br)CH2CH3 + NaOH water 

12. Give reasons:(a) Aryl halides are extremely less reactive towards
Nucleophilic Substitution reactions.(b) P-Dichlorobenzene has higher m.p
and solubility than those of o- and m- isomers.
13. Give reasons:(a) Allyl chloride is more reactive than n - propyl chloride
towards nucleophilic substitution reaction..(b) p - nitro chlorobenzene
undergoes nucleophilic substitution faster than chlorobenzene..

Section –D
14 . Primary alkyl halide C4H9Br (a) reacted with alcoholic KOH to give
compound (b). Compound (b) is reacted with HBr to give (c) which is an
isomer of (a). When (a) is reacted with sodium metal it gives compound
(d), C8H18 which is different from the compound formed when n-butyl
bromide is reacted with sodium. Give the structural formula of (a) and
write the equations for all the reactions.
15 (a) How the following conversions can be carried out?
(i) 2-Chlorobutane to 3, 4-dimethylhexane (ii) Ethanol to propanenitrile
(b) What happens when
(i) n-butyl chloride is treated with alcoholic KOH (ii) bromobenzene is
treated with Mg in the presence of dry ether,
ALL THE BEST

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 Chemistry Test Paper
Unit-11: Alcohols, Phenols and Ethers
Time: 90 minutes M.M. 40

General Instructions:
(1) All questions are Compulsory.
(2)The question paper consists of 15 questions divided in to four sections A, B, C&D
(3) Section A contains 2 questions of 1 mark each.
Section B contains 5 questions of 2 marks each.
Section C contains 6 questions of 3 marks each.
Section D contains 2 questions of 5 marks each.

Section –A
1. Name the following according to IUPAC system

2. Write the structures of 1-Phenylpropan-2-ol?

Section –B
3. Write the Mechanism Acid dehydration of ethanol to yield ethene.i.e
Dehydration of alcohols to Alkenes.
OR
Write the Mechanism Preparation of ethoxyethane from ethanol. i.e
Dehydration of alcohols to Ethers.
4. Give simple Chemical tests to distinguish between the following pairs of
compounds (i) Phenol And Ethanol (ii) 1o,2o&3o Alcohols
5. Explain the following Name reactions with an example(i) Reimer-Tiemann
reaction (ii)Kolbe’s reaction
6. Give the equations of reactions for the preparation of phenol from cumene
7. Convert the following: (i) Ethyl magnesium chloride → Propan-1-ol(ii)
Methyl magnesium bromide → 2-Methylpropan-2-ol
Section –C
8. Write the names of reagents and equations for the preparation of the following
ethers by Williamson’s synthesis:(i) 1-Propoxypropane (ii) Ethoxybenzene(iii)
2-Methoxy-2-methylpropane
9. Write the equation of the reaction of hydrogen iodide
with:(i)1propoxypropane (ii) methoxybenzene and (iii) benzyl ethyl ether.
10. Complete the following reactions:
(i)

(ii)

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 (iii)

11. Explain why

(i) Phenols not undergo Nucleophilic substitution reaction easily but undergo
elecrophilic substitution reaction easily at ortho and para positions
(ii) Phenol is more acidic than alcohol.
12.

13.
Convert the following:
d) Phenol to 2,4,6 Tribromophenol
e) Propene to Propan -2-ol
f) Propene to Propanol
Section –D
14. Give reasons for the following:
a. Preparation of ethers by acid dehydration of secondary or tertiary
alcohols is not a suitable method.
b. Alcohols are comparatively more soluble in water than the
corresponding hydrocarbons
c. Propanol has higher boiling point than that of the hydrocarbon, butane
d. Ortho – nitrophenol is more acidic than Ortho – methoxyphenol
e. Phenol has small dipole moment than methanol

15.
a) Explain Hydroboration –oxidation reaction with an example
b) Give simple Chemical test to distinguish between Ethanol and methanol.
c) While separating a mixture of ortho and para nitrophenols by
steamdistillation, name the isomer which will be steam volatile. Give reason.
d) Convert Phenol to salicylic acid.
ALL THE BEST
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 Chemistry Test Paper
Unit-12:Aldehydes,Ketones & Carboxylic Acid
Time: 90 minutes M.M. 40

General Instructions:
(1) All questions are Compulsory.
(2)The question paper consists of 15 questions divided in to four sections A, B,C&D
(3) Section A contains 2 questions of 1 mark each.
Section B contains 5 questions of 2 marks each.
Section C contains 6 questions of 3 marks each.
Section D contains 2 questions of 5 marks each.

Section –A
1. Name the CH3COCH2COCH3 according to IUPAC system .
2. Write the structures of Hex-2-en-4-ynoic acid?
Section –B
3. Write the mechanism of reaction between actetaldehyde and HCN.
(i.eMechanism of Nucleophilic addition reaction in carbonyl compounds.)
4. Arrange the following compounds in increasing order of their reactivity in
nucleophilic addition reactions.with reasons
(i) Ethanal, Propanal, Propanone, Butanone.
(ii) Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde,
Acetophenone.
5. Give one chemical test to distinguish between (a) Pentan-2-one and Pentan-
3-one (b) Benzaldehyde and Acetophenone.
6. An organic compound contains 69.77%, 11.63% hydrogen, and the rest
oxygen. The molecular mass of the compound is 86. It does not reduce
Tollen’s reagent but forms an addition compound with sodium hydrogen
sulphite and gives positive iodoform test. On vigorous oxidation it gives
ethanoic and propanoic acids. Write the possible structures of the
compound.
7. Explain why
d) Aldehydes are more reactive than Ketones towards Nucleophilic
addition reaction.
e) Chloroacetic acid is stronger than acetic acid.

Section –C
8. Explain the following : (a) Cannizzaro reaction (b) Cross aldol
condensation
9. An organic compound A with molecular formula C8H16O2 was hydrolysed
with sulphuric acid to give a carboxylic acid B and an alcohol C. Oxidation
of C with chromic acid produced B. C on dehydration gives but-1-
ene.Write equations for the reaction s involved.
10. Explain why
a) Cyclohexanone forms cyanohydrin in good yield but 2,2,6 – tri
methylcyclohexanone does not

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 b) There are two – NH2 group in semi carbazide however only one is
involved in the formation of semi carbazones
c) During the preparation of esters from a carboxylic acid and an alcohol
in the presence of an acid catalyst, the water or the ester should be
removed as fast as it is formed
11. Write the structure of the major organic product in each of the following
reactions:
g)

h)

i)

12. Give one chemical test to distinguish between the following pairs of
compounds: (i) Propanal and Propanone (ii) Acetophenone and
Benzophenone(iii) Benzoic acid and Ethyl benzoate
13. (a) Arrange the following compounds in increasing order of acid
strength.(i)CH3CH2CH(Br)COOH, CH3CH(Br)CH2COOH,
(CH3)2CHCOOH,CH3CH2CH2COOH (ii) Benzoic acid, 4-Nitrobenzoic
acid, 3,4-Dinitrobenzoic acid, 4-Methoxybenzoic acid (acid strength)
(b)Why Carboxylic acids are more acidic than phenols

Section –D
14 (a) An organic compound with molecular formula C9H10O forms 2,4-DNP
derivative, reduces Tollent’s reagent, and undergoes Cannizzaro
reaction.On vigorous oxidation , it gives 1,2-benzene dicarboxylic acid.
Identify the compound
(b)Convert the following: (i) Benzyl alcohol to phenylethanoic acid (ii)
Ethanol to 3-Hydroxybutanal (iii) Propanone to Propene
15. Describe the Following:
a) Hell Volhard Zelinsky
b) Decarboxylation
c) Clemmensen Reaction
d) Rosenmund Reaction
e) Esterification
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 Chemistry Test Paper
Unit-13:Amines
Time: 90 minutes M.M. 40

General Instructions:
(1) All questions are Compulsory.
(2)The question paper consists of 15 questions divided in to four sections A, B,
C&D
(3) Section A contains 2 questions of 1 mark each.
Section B contains 5 questions of 2 marks each.
Section C contains 6 questions of 3 marks each.
Section D contains 2 questions of 5 marks each.

Section –A
1. Name the CH3NHCH(CH3)2 according to IUPAC system .
2. Write the structures of N,N-Diethylbutan-1-amine?
Section –B
3. .Describe a method for the identification of Primary, Secondary and tertiary
amines .Also write chemical equations of the reactions involved.
4. Arrange the following in increasing order of basic strength
a. (C2H5)2NH , (C2H5)3N , C2H5NH2 NH3 (in gas phase)
b. (C2H5)2NH , (C2H5)3N , C2H5NH2 NH3 (in aqueous phase)
5. Accomplish the following conversions: (a) Aniline to Chlorobenzene (b)
Aniline to Phenol.
6. A compound A has the molecular formula C7H7NO.On treatment with Br2
and NaOH it gives B. B gives a foul smelling substance C on treatment with
CHCl3 and KOH. B on treatment with NaNO2 and HCl at 00C and mixing with
alkaline phenol gives a red dye D. Identify A to D.
7. Complete the following reaction:
(i)C6H5NH2 + Br2(aq)  
(ii)C6H5N2Cl        
( i ) HBF 4 ( ii ) NaNO2 / Cu , Heat

Section –C

8. Explain the Following : (i) Sandmeyers Reaction (ii) Carbylamine Reaction

(iii) Gabriel Pthalimide Reaction
9. An aromatic compound A on treatment with aqueous ammonia and heating
forms compound B which on heating with Br2 and KOH forms compound C of
molecular formula C6H7N .Write the structures and IUPAC names of
compounds A,B,C..
10. . Explain why
(i)Amines are less acidic than alcohols of comparable molecular masses?
(ii)Primary amines have higher boiling point than tertiary amines?
(iii)Aliphatic amines are stronger bases than aromatic amines?
11. Give the structures of A, B and C in the following reactions:
(i)CH3COOH   A 
NH 3, Heat
 B 
NaOBr

NaNO2 / HCl
 C
(ii)CH3CH2Br   A  B   
KCN LiAlH 4
 C
HNO 2 , 273 K

(iii)C6H5NO2    A   
Fe / HCl
 B   C
HNO 2 , 273 K C 6 H 5 OH

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12. Give one chemical test to distinguish between the following pairs of
compounds: (i) Methylamine and dimethylamine (ii) Aniline and N-
methylaniline (iii) Ethylamine and aniline.
13.
a) Arrange the following in decreasing order of their basic strength:C6H5NH2,
C2H5NH2, (C2H5)2NH, NH3
b) Write structures and IUPAC names of (i) the amide which gives
propanamine by Hoffmann bromamide reaction.(ii) the amine produced by
the Hoffmann degradation of benzamide

Section –D
14 (a) Write short notes on the following; (i) Coupling reaction (ii)
Hofmann’s bromamide reaction (iii) Diazotisation
(b)Convert the following: (i) Ethanamine into methanamine acid (ii)
Methanamine into ethanamine
15. Account for the Following:
a) Aromatic primary amines cannot be prepared by Gabriel phthalimide
synthesis?
b) pKb of aniline is more than that of methylamine.
c) Ethylamine is soluble in water whereas aniline is not.
d) Although amino group is o– and p– directing in aromatic electrophilic
substitution reactions, aniline on nitration gives a substantial amount of
m-nitroaniline.
e) Diazonium salts of aromatic amines are more stable than those of
aliphatic amines.

ALL THE BEST

Kalra Sir, 09462305605,[email protected]

 Chemistry Test Paper
UNIT-14: Biomolecules
Time: 90 minutes M.M. 40

General Instructions:
(1) All questions are Compulsory.
(2)The question paper consists of 15 questions divided in to four sections A, B,C&D
(3) Section A contains 2 questions of 1 mark each.
Section B contains 5 questions of 2 marks each.
Section C contains 6 questions of 3 marks each.
Section D contains 2 questions of 5 marks each.

Section –A
1. Name the type of bonding which stabilizes -helix structure of proteins?
2. Name the deficiency diseases caused due to lack of vitamin B1, & B12
.
Section –B
3. Name the two components of starch. How do they differ from each other
Structurally?
4. What are essential and non essential amino acids? Give examples of each type?
5. Write a note on zwitter ion.
6. Distinguish between the following: Fibrous &Globular proteins?
7. Write a note on Denaturation of proteins?
Section –C
8 Write the important differences between DNA and RNA?
9. An optically active amino acid (A) can exist in three forms depending on the
pH of the medium. If the molecular formula of (A) is C3H7NO2 write
(i) Structure of compound (A) in aqueous medium. What are such ions called?
(ii) In which medium will the cationic form of compound (A) exist?(iii) In alkaline
medium, towards which electrode will the compound (A) migrate in electric
field?
10. How are vitamins classified?
11.(i) Write two main functions of carbohydrates in plants.
(ii)What do you understand by the term glycosidic linkage?
12. Distinguish between the -helix and -sheet proteins:
13 Name the deficiency diseases caused due to lack of vitamin A,C, D,E,B2,, B6
&K?
Section –D
14. Write the reactions when D-Glucose reacts with following:
(a)Hydrocyanicacid,HCN (b)Tollens reagent (c)HI (d)Conc.HNO3
(e)Hydroxlamime(f)Bromine

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15. (a) How are carbohydrates classified on the basis of their behaviour on
hydrolysis?.
(b) Why cannot Vitamin C be stored in our body
(c) What are different types of RNA found in the cell?
ALL THE BEST

Kalra Sir, 09462305605,[email protected]