SAFETY DATA SHEET

1. IDENTIFICATION
A. Product name
- UT5570-A-YELLOW(XCMM)

B. Recommended use and restriction on use

- General use : urethane top coat
- Restriction on use : Do not use except for purpose

C. Supplier information
- Company name : KCC Paint India Private Limited
- Address : Plot No.K-20, SIPCOT Indl. Park, (Phase-II), Mambakkam, Sriperumbudur, Tamil Nadu-602105
- Emergency telephone
: +91 44 2714 2000
number

2. HAZARD IDENTIFICATION
A. GHS Classification
- Flammable liquids : Category3
- Acute toxicity (oral) : Category5
- Acute toxicity (inhalation: vapor) : Category5
- Skin corrosion/irritation : Category2
- Serious eye damage/irritation : Category2A
- Germ cell mutagenicity : Category1B
- Carcinogenicity : Category1B
- Reproductive toxicity : Category1B
- Specific target organ toxicity(Single exposure) : Category1
- Specific target organ toxicity(Single exposure) : Category3(Narcotic effects)
- Specific target organ toxicity(Single exposure) : Category3(Respiratory tract irritation)
- Specific target organ toxicity(Repeated exposure) : Category1
- Aspiration hazard : Category1
- Acute aquatic toxicity : Category2
- Chronic aquatic toxicity : Category2

B. GHS label elements

○ Hazard symbols

○ Signal words
- Danger
○ Hazard statements
- H226 Flammable liquid and vapour
- H303 May harmful if swallowed.
- H304 May be fatal if swallowed and enters airways
- H315 Causes skin irritation
- H319 Causes serious eye irritation
- H333 May be harmful if inhaled.
- H335 May cause respiratory irritation.
- H336 May cause drowsiness and dizziness.
- H340 May cause genetic defects
- H350 May cause cancer
- H360 May damage fertility or the unborn child
- H370 Causes damage to organs(Refer Section SDS 11)
- H372 Causes damage to organs through prolonged or repeated exposure (Refer Section SDS 11)
- H401 Toxic to aquatic organisms.
- H411 Toxic to aquatic life with long lasting effects
○ Precautionary statements

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 1) Prevention
- P201 Obtain special instructions before use.
- P202 Do not handle until all safety precautions have been read and understood.
- P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
- P233 Keep container tightly closed.
- P240 Ground/bond container and receiving equipment.
- P241 Use explosion-proof electrical/ventilating/lighting/equipment.
- P242 Use only non-sparking tools. Flammable liquids (chapter 2.6) 1, 2, 3
- P243 Take precautionary measures against static discharge.
- P260 Do not breathe gas/mist/vapours/spray.
- P261 Avoid breathing gas/mist/vapours/spray.
- P264 Wash hands thoroughly after handling.
- P270 Do not eat, drink or smoke when using this product.
- P271 Use only outdoors or in a well-ventilated area.
- P273 Avoid release to the environment.
- P280 Wear protective gloves/protective clothing/eye protection/face protection.
- P281 Use personal protective equipment as required.
2) Response
- P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
- P302+P352 IF ON SKIN: Wash with plenty of soap and water.

- P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

- P304+P312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.

- P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
- P307+P311 If exposed: Call a POISON CENTER or doctor/physician.
- P308+P313 If exposed or concerned: Get medical advice/attention.
- P312 Call a POISON CENTER or doctor/physician if you feel unwell.
- P314 Get medical advice/attention if you feel unwell.
- P321 Specific treatment
- P331 Do NOT induce vomiting.
- P332+P313 If skin irritation occurs: Get medical advice/attention.
- P337+P313 If eye irritation persists: Get medical advice/attention.
- P362 Take off contaminated clothing and wash before reuse.

- P370+P378 In case of fire: Use Suitable extinguishing media for extinction(Refer Section MSDS 5).

- P391 Collect spillage.

3) Storage
- P403+P233 Store in a well-ventilated place. Keep container tightly closed.
- P403+P235 Store in a well-ventilated place. Keep cool.
- P405 Store locked up.
4) Disposal

- P501 Dispose of contents/container in accordance with local/regional/national/international regulation

C. Other hazards which do not result in classification : (NFPA Classification)

○ NFPA grade (0 ~ 4 level)
- Health : 2, Flammability : 3, Reactivity : 0

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name Trade names and Synonyms CAS No. Content(%)

Methyl methacrylate, n-butyl methacrylate, 2-
ethylhexyl acrylate-2-hydroxyethyl methacrylate, - 64771-95-5 20 ~ 30
methacrylic acid copolymer
Xylene Dimethylbenzene 1330-20-7 10 ~ 18.6
n-Butyl acetate Acetic acid, butyl ester 123-86-4 10 ~ 10.8

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 Methyl methacrylate, butyl acrylate-2-hydroxyethyl
- 25951-39-7 1 ~ 10
methacrylate copolymer
Solvent naphtha (petroleum), light arom. Naphtha 64742-95-6 1 ~ 10
Rutile, tin zinc - 85536-73-8 1 ~ 5.9
Toluene Methylbenzene 108-88-3 0.3 ~ 4.7
Iron hydroxide oxide (Fe(OH)O) Iron oxide yellow 20344-49-4 4~6
Propylene glycol monomethyl
Propylene glycol methyl ether acetate 108-65-6 1 ~ 10
ether acetate
4-Methyl-2-pentanone Methylisobutyl ketone, MIBK 108-10-1 0.1 ~ 3.3
Ethylbenzene Benzene, ethyl- 100-41-4 0.1 ~ 3.1
Titanium dioxide Titanium oxide (Tio2) 13463-67-7 1 ~ 2.5
2-[(2-Methoxy-4-nitrophenyl)azo]-N-(2-
- 6358-31-2 1 ~ 10
methoxyphenyl)-3-oxobutyramide (C.I. pigment
Secret Secret 자료없음 1 ~ 10

4. FIRST AID MEASURES

A. Eye contact
- Do not rub your eyes.

- Immediately flush eyes with plenty of water for at least 15 minutes and call a doctor/physician.

- Get medical attention immediately.

- Go to the hospital immediately if symptoms(flare, irritate) occur.
- Remove contact lenses if worn.

B. Skin contact

- Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.

- Wash contaminated clothing thoroughly before re-using.

- Get medical attention immediately.
- Go to the hospital immediately if symptoms(flare, irritate) occur.
- Remove contaminated clothing, shoes and isolate.
- Wash thoroughly after handling.

- Wear gloves when washing the patient, and please avoid contact with contaminated clothing.

C. Inhalation contact
- When exposed to large amounts of steam and mist, move to fresh air.
- Take specific treatment if needed.
- Get medical attention immediately.

- If breathing is stopped or irregular, give artificial respiration and supply oxygen.

D. Ingestion contact
- Please be advised by doctor whether induction of vomit is demanded or not.
- Rinse your mouth with water immediately.
- Get medical attention immediately.
- If swallowed, large amounts of water to drink and do not induce vomiting.

E. Delayed and immediate effects and also chronic effects from short and long term exposure
- Not available

F. Notes to physician

- Notify medical personnel of contaminated situations and have them take appropriate protective measures.

- If exposed or concerned, get medical attention/advice.

5. FIREFIGHTING MEASURES
A. Suitable (Unsuitable) extinguishing media

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 - Dry chemical, carbon dioxide, regular foam extinguishing agent, spray
- Avoid use of water jet for extinguishing

B. Specific hazards arising from the chemical

- Not available

C. Special protective actions for firefighters

- Move containers from fire area, if you can do without the risk.
- Cool containers with water until well after fire is out.
- Keep unauthorized personnel out.
- Do not access if the tank on fire.
- Wear appropriate protective equipment.
- Keep containers cool with water spray.
- Vapor or gas is burned at distant ignition sources can be spread quickly.

- Due to the extremely low flash point, irrigating fire extinguishing may be less effective when put out a fire.

6. ACCIDENTAL RELEASE MEASURES

A. Personal precautions, protective equipment and emergency procedures
- Must work against the wind, let the upwind people to evacuate.
- Do not touch spilled material. Stop leak if you can do it without risk.
- Move container to safe area from the leak area.

- Handle the damaged containers or spilled material after wearing appropriate protective equipment

- Do not direct water at spill or source of leak.

- Avoid skin contact and inhalation.
- Cleanup and disposal under expert supervision is advised.
- Keep unauthorized people away,isolate hazard area and deny entry.

B. Environmental precautions
- Prevent runoff and contact with waterways, drains or sewers.
- If large amounts have been spilled, inform the relevant authorities.

C. Methods and materials for containment and cleaning up

- Large spill : Stay upwind and keep out of low areas. Dike for later disposal.

- Notification to central government, local government. When emissions at least of the standard amount

- Dispose of waste in accordance with local regulation.

- Appropriate container for disposal of spilled material collected.
- Small leak: sand or other non-combustible material, please let use absorption.
- Wipe off the solvent.
- Dike for later disposal.
- Do not use plastic containers.
- Prevent the influx to waterways, sewers, basements or confined spaces.
- Spilled material should be treated as a potential risk of waste collected.

7. HANDLING AND STORAGE

A. Precautions for safe handling
- Avoid direct physical contact.
- Get the manual before use.
- Refer to Engineering controls and personal protective equipment.
- Do not handle until all safety precautions have been read and understood.
- Do not inhale the steam prolonged or repeated.
- Avoid contact with heat, sparks, flame or other ignition sources.
- Contaminated work clothing should not be allowed out of the workplace.

B. Conditions for safe storage, including any incompatibilities

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 - Save in cool, dry and well ventilated place.
- Check regularly for leaks.
- Keep sealed when not in use.
- No open fire.

- Prevent static electricity and keep away from combustible materials or heat sources.

- By specifying a storage area for carcinogenic substances.

- Collected them in sealed containers.
- Store away from water and sewer.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

A. Exposure limits
○ ACGIH TLV
- [Xylene] : TWA 100 ppm (434 mg/m3), STEL, 150 ppm (651 mg/m3)
- [n-Butyl acetate] : TWA 50 ppm , STEL 150 ppm
- [Toluene] : TWA 20 ppm (75 mg/m3)
- [4-Methyl-2-pentanone] : TWA, 20 ppm (82 mg/m3) STEL 75 ppm (307 mg/m3)
- [Ethylbenzene] : TWA, 20 ppm (87 mg/m3)
- [Titanium dioxide] : TWA 10 mg/m3

- [Secret] : TWA, 50 mg/m3, Inhalable particulate matter (containing no asbestos and <1% crystalline silica)

- [Secret] : TWA, 20 ppm (61 mg/m3)

- [Secret] : TWA, 50 ppm (152 mg/m3)
- [Secret] : TWA 10 ppm (25 mg/m3) STEL, 15 ppm (37 mg/m3)
○ OSHA PEL
- [Ethylbenzene]:100ppm 435mg/m3
- [4-Methyl-2-pentanone]:100ppm 410mg/m3
- [Secret]:10ppm 25mg/m3
- [Secret]:100ppm 300mg/m3
- [Chrome antimony titanium buff rutile (C.I.Pigment Brown 24)]: 0.5mg/m3
- [Secret]: 15 mg/m3 (Total dust), 5 mg/m3 (Respirable fraction)

- [Secret]: 2 mg/m3 (Inorganic compounds, except oxides), 0.1 mg/m3 (Organic compounds)

- [Rutile, tin zinc]: 2 mg/m3 (Inorganic compounds, except oxides), 0.1 mg/m3 (Organic compounds)

- [Titanium dioxide]: 15 mg/m3 (Total dust)

- [Toluene]: 200 ppm, C 300 ppm
- [Xylene]:100ppm 435mg/m3
- [n-Butyl acetate]:150ppm 710mg/m3

B. Engineering controls
- Business owner is recommended to maintain below recommended exposure limits for the working place with general exhaust of
gas/vapour/mist/fume.

C. Individual protection measures, such as personal protective equipment

○ Respiratory protection

- Under conditions of frequent use or heavy exposure, Respiratory protection may be needed.

- Respiratory protection is ranked in order from minimum to maximum.

- Consider warning properties before use.
- Any chemical cartridge respirator with organic vapor cartridge(s).

- Any chemical cartridge respirator with a full facepiece and organic vaporcartridge(s).

- Any air-purifying respirator with a full facepiece and an organic vapor canister.

- For Unknown Concentration or Immediately Dangerous to Life or Health : Any supplied-air respirator with full facepiece and
operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained
breathing apparatus with a full facepiece.

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 ○ Eye protection

- Wear primary eye protection such as splash resistant safety goggles with a secondary protection face shield.

- Provide an emergency eye wash station and quick drench shower in the immediate work area.

○ Hand protection
- Wear appropriate chemical resistant glove.
○ Skin protection
- Wear appropriate chemical resistant protective clothing.
○ Others
- Not available

9. PHYSICAL AND CHEMICAL PROPERTIES

A. Appearance
- Appearance Liquid
- Color YELLOW
B. Odor Solvent odor
C. Odor threshold Not available
D. pH Not available
E. Melting point/Freezing point Not available
F. Initial Boiling Point/Boiling Ranges Not available
G. Flash point 23 ℃
H. Evaporation rate Not available
I. Flammability(solid, gas) Not available
J. Upper/Lower Flammability or explosive limits Not available
K. Vapour pressure Not available
L. Solubility Not available
M. Vapour density >1
N. Specific gravity(Relative density) 1.0~1.1
O. Partition coefficient of n-octanol/water Not available
P. Autoignition temperature 408
Q. Decomposition temperature Not available
R. Viscosity 65~75KU
S. Molecular weight Not available

10. STABILITY AND REACTIVITY

A. Chemical Stability
- This material is stable under recommended storage and handling conditions.

B. Possibility of hazardous reactions

- Cylinders exposed to fire may vent and release flammable gas.

C. Conditions to avoid
- Avoid contact with incompatible materials and condition.
- Avoid : Accumulation of electrostatic charges, Heating, Flames and hot surfaces
- Avoid contact with heat, sparks, flame or other ignition sources.

D. Incompatible materials
- Not available

E. Hazardous decomposition products

- May emit flammable vapour if involved in fire.

11. TOXICOLOGICAL INFORMATION

A. Information on the likely routes of exposure
○ (Respiratory tracts)

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 - May be fatal if swallowed and enters airways
- May cause respiratory irritation.
○ (Oral)
- May harmful if swallowed.
○ (Eye·Skin)
- Causes serious eye irritation
- Causes skin irritation

B. Delayed and immediate effects and also chronic effects from short and long term exposure
○ Acute toxicity
* Oral
- Product (ATEmix) : 2000mg/kg < ATEmix <= 5000mg/kg
- [Xylene] : LD50=3523 mg/kg rat (EU Method B1)
- [n-Butyl acetate] : LD50 12.2 ㎖/㎏ Rat (ECHA)
- [Solvent naphtha (petroleum), light arom.] : LD50 = 8400 ㎎/㎏ Rat (RTECS)

- [Rutile, tin zinc] : LD50 >2000 ㎎/㎏ Rat (read across, OECD Guideline 401, GLP, ECHA)

- [Toluene] : LD50 5580 ㎎/㎏ Rat (EU Method B.1)

- [Iron hydroxide oxide (Fe(OH)O)] : LD50 > 10000 ㎎/㎏ Rat

- [Propylene glycol methyl ether acetate] : LD50 = 8532 ㎎/㎏ Rat (IUCLID)
- [4-Methyl-2-pentanone] : LD50 2080 ㎎/㎏ Rat (NITE, ECHA)
- [Ethylbenzene] : LD50 = 3500 ㎎/㎏ Rat (NITE)
- [Titanium dioxide] : LD50 > 10000 ㎎/㎏ Rat (HSDB)
- [Secret] : LD50 > 5000 ㎎/㎏ Rat (IUCLID)
- [Secret] : LD50 > 3000 ㎎/㎏ Rat (IUCLID)
- [Secret] : LD50 >2000 ㎎/㎏ 실험종 : Rat (암컷, 사망없음 (OECD TG 423, GLP)) (ECHA)
- [Secret] : LD50 = 3160 ㎎/㎏ Rat (TOMES; HAZARDTEXT)
- [Secret] : LD50 = 3430 ㎎/㎏ rabbit (GLP, ECHA)
- [Secret] : LD50 = 58 ~ 5000 ㎎/㎏ Rat (OECD SIDS)
- [Secret] : LD50 > 90000 ㎎/㎏ Rat (KOSHA)
- [Secret] : LD50 = 2460 ㎎/㎏ Rat (HSDB; SIDS; EHC; PATTY)
- [Secret] : LD50 > 5000 ㎎/㎏ Rat
- [Secret] : LD50 = 3310 ㎎/㎏ Rat (NITE)
* Dermal
- Product (ATEmix) : >5000mg/kg

- [Xylene] : LD50 >4350 ㎎/㎏ Rabbit (IUCLID) LD50 12126 ㎎/㎏ Rabbit (isomer: m-xylene)

- [n-Butyl acetate] : LD50 > 16 mL/kg Rabbit (ECHA)

- [Solvent naphtha (petroleum), light arom.] : LD50 > 2000 ㎎/㎏ Rabbit (IUCLID)
- [Toluene] : rabbit LD50=12,124 mg/kg (HSDB)
- [Propylene glycol methyl ether acetate] : LD50 > 5000 ㎎/㎏ Rabbit (IUCLID)

- [4-Methyl-2-pentanone] : LD50 >16,000 ㎎/㎏ rabbit (NITE), LD0≥2000 mg/kg OECD TG402, GLP(ECHA)

- [Ethylbenzene] : LD50 = 15400 ㎎/㎏ Rabbit (NITE)

- [Titanium dioxide] : LD50 > 10000 ㎎/㎏ Rabbit (IUCLID)
- [Secret] : LD50 >2000 ㎎/㎏ Rabbit (IUCLID)
- [Secret] : LD50 = 3400 ㎎/㎏ rabbit (HSDB)
- [Secret] : LD50 = 777 ~ 2000 ㎎/㎏ rabbit (OECD SIDS)
- [Secret] : LD50 = 2460 ㎎/㎏ Rabbit (SIDS)
- [Secret] : LD50 = 1060 ㎎/㎏ rabbit (NITE)
* Inhalation
- Product (ATEmix) : 20.0mg/L < ATEmix <= 50.0mg/L
- [Xylene] : LC50 5922 ppm 4 hr Rat (25.713 mg/L EPA OPP 81-3, GLP)
- [n-Butyl acetate] : LC50 > 4.9 ㎎/ℓ 4 hr Rat (ECHA)

- [Solvent naphtha (petroleum), light arom.] : LC50 > 5.2 mg/L 4 hr Rat, LC50=3400 ppm 4hr (IUCLID)

- [Toluene] : LC50 >20 ㎎/ℓ Rat (OECD TG 403) (ECHA)

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 - [Propylene glycol methyl ether acetate] : Steam LC50 = 28.8 mg/L/4 hr Rat (KOSHA)
- [4-Methyl-2-pentanone] : LC50 11.6 ㎎/ℓ 4h Rat (OECD TG 403)(ECHA)
- [Ethylbenzene] : LC50 = 17.4 mg/L/4 hr Rat (4000 ppm/4hr)(EHC, ASTDR)
- [Titanium dioxide] : LC50 >3.43 ㎎/ℓ Rat (OECD TG 403)
- [Secret] : dust LC50 ≥ 0.477 ㎎/L 4 hr Rat (IUCLID)

- [Secret] : Dust LC50 = 1.9 mg/L (conversion value) (LC50 = 7.6 mg/L 1 hr) Rat male (OECD TG 403) (ECHA)

- [Secret] : LC50 >2.2 ㎎/ℓ 1 hr Rat (IUCLID)

- [Secret] : Steam LC50 = 24.25 mg/L/4 hr Rat (HSDB)
- [Secret] : Mist LC50 = 0.059 ~ 22 ㎎/L Rat (OECD SIDS)
- [Secret] : LC50 = 19.2 ㎎/ℓ 4 hr Rat (conversion of 6336ppm) (OECD SIDS; EHC 65)
- [Secret] : dust LC50 > 0.29 ㎎/L 4 hr Rat
- [Secret] : LC50 = 39.3 mg/L/4 hr Rat (NLM)
○ Skin corrosion/irritation
- Causes skin irritation
○ Serious eye damage/irritation
- Causes serious eye irritation
○ Respiratory sensitization
- Not available
○ Skin sensitization
- Not available
○ Carcinogenicity
* IARC
- [Secret] : Group 3
- [Ethylbenzene] : Group 2B
- [4-Methyl-2-pentanone] : Group 2B
- [Titanium dioxide] : Group 2b ※ IARC(국제 암 연구기관)는 TiO2를 인체 발암 가능성이 있다고 분류했지만 IARC의 TiO2
발암성 관련 연구논문에서 도료같은 물질에 포함되어 있을 경우 심각한 노출이 발생되지 않을것으로 판단하였으며
NIOSH(미국 국립산업안전 보건연구원)에서는 100nm 미만의 초미세 TiO2를 사용한 만성 동물 흡입 연구 결과에서만 암이
증가하였다는 연구논문이 있음. 따라서 본 제품에 사용하는 TIO2의 입자크기는 280~360nm 수준으로 암이 발생할 수
있다고 판단하기 어려움.
- [Toluene] : Group 3
* OSHA
- Not available
* ACGIH
- [Ethylbenzene] : A3
- [4-Methyl-2-pentanone] : A3
- [Titanium dioxide] : A4
- [Toluene] : A4
- [Xylene] : A4
* NTP
- Not available
* EU CLP
- [Solvent naphtha (petroleum), light arom.] : Carc.1B
○ Germ cell mutagenicity
- May cause genetic defects
○ Reproductive toxicity
- May damage fertility or the unborn child
○ STOT-single exposure
- Causes damage to organs(Refer Section SDS 11)
- May cause drowsiness and dizziness.
- May cause respiratory irritation.
○ STOT-repeated exposure

- Causes damage to organs through prolonged or repeated exposure (Refer Section SDS 11)

○ Aspiration hazard
- May be fatal if swallowed and enters airways

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12. ECOLOGICAL INFORMATION
A. Ecotoxicity
○ Fish
- [Xylene] : LC50=3.3mg/L 96 hr (NITE)
- [n-Butyl acetate] : LC50 18 ㎎/ℓ 96 hr Pimephales promelas (OECD TG 203)(ECHA)

- [Solvent naphtha (petroleum), light arom.] : LC50 = 9.22 ㎎/ℓ 96 hr Oncorhynchus mykiss (IUCLID)

- [Rutile, tin zinc] : LC50 >100 ㎎/ℓ 96 hr Oncorhynchus mykiss (OECD Guideline 203, GLP, ECHA)

- [Toluene] : LC50 5.5 ㎎/ℓ 96 hr (ECHA)

- [Iron hydroxide oxide (Fe(OH)O)] : LC50 472.465 ㎎/ℓ 96 hr (Estimate)

- [Propylene glycol methyl ether acetate] : LC50 100 ㎎/ℓ 96 hr Oryzias latipes (SIDS)

- [4-Methyl-2-pentanone] : ECHA LD50 >179 ㎎/ℓ 96 hr Brachydanio rerio(OECD TG 203, GLP)

- [Ethylbenzene] : LC50 5.1 ㎎/ℓ 96 hr (ECHA)

- [Titanium dioxide] : LL50 >100 ㎎/ℓ 96 hr Oryzias latipes(OECD TG 203)
- [2-[(2-Methoxy-4-nitrophenyl)azo]-N-(2-methoxyphenyl)-3-oxobutyramide (C.I. pigment yellow 074)] : LC50 = 33.605 ㎎/ℓ 96 hr
(Estimate)

- [Secret] : LC50 0.532 ㎎/ℓ 96 hr (ECOSAR Class Hydrazine) (Ecological Structure Activity Relationships (ECOSAR)

- [Secret] : LC50 0.271 ㎎/ℓ 96 hr (Estimate)

- [Secret] : "LC50 >218.6441 mg/L 96 hr Pimephales promelas(Semi-still-water culture, ASTM 2000, GLP) (ECHA)"

- [Secret] : LC50 5000 ㎎/ℓ 96 hr (IUCLID)

- [Secret] : LC50 1376 ㎎/ℓ 96 hr Pimephales promelas(OECD TG 203, GLP)
- [Secret] : LC50 3 ㎎/ℓ 96 hr Brachydanio rerio (OECD SIDS)
- [Secret] : LC50 123.852 ㎎/ℓ 96 hr (Estimate)
- [Secret] : LC50 = 1000 ㎎/ℓ 96 hr
- [Secret] : LC50 1000 ㎎/ℓ 96 hr Oryzias latipes (OECD SIDS)
- [Secret] : ECHA LC50 >1000 ㎎/ℓ 96 hr Oncorhynchus mykiss(OECD TG 203, GLP)
○ Crustaceans
- [n-Butyl acetate] : EC50 44 ㎎/ℓ 48 hr Daphnia magna (ECHA)

- [Solvent naphtha (petroleum), light arom.] : EC50 = 6.14 ㎎/ℓ 48 hr Daphnia magna (IUCLID)

- [Rutile, tin zinc] : EC50 >100 ㎎/ℓ 48 hr Daphnia magna (OECD Guideline 202, GLP, ECHA)

- [Toluene] : EC50 3.78 ㎎/ℓ 48hr (ECHA)

-[Iron hydroxide oxide (Fe(OH)O)] : LC50 485.139 ㎎/ℓ 48 hr (estimate)

- [Propylene glycol methyl ether acetate] : EC50 = 373 ㎎/ℓ 48 hr Daphnia magna (SIDS)

- [4-Methyl-2-pentanone] : ECHA EC50 >200 ㎎/ℓ 48 hr Daphnia magna(OECD TG 202, GLP)

- [Ethylbenzene] : LC50 2.4 ㎎/ℓ ~ 1.8 ㎎/ℓ 48 hr Mysidopsis bahia(EC50 48hr >5.2mg/L, EPA 1985, GLP)

- [Titanium dioxide] : EC50 >100 ㎎/ℓ 48 hr Daphnia magna(48h-EL50Daphnia magna>100 mg/L, 48h-EC50>100, 48h-EC10=91.2
mg/L, OECD TG 202)
- [2-[(2-Methoxy-4-nitrophenyl)azo]-N-(2-methoxyphenyl)-3-oxobutyramide (C.I. pigment yellow 074)] : LC50 = 35.557 ㎎/ℓ 48 hr
(Estimate)
- [Secret] : EC50 32 ㎎/ℓ 48 hr Daphnia magna (ECOTOX)
- [Secret] : LC50 0.119 ㎎/ℓ 48 hr (Estimate)
- [Secret] : LC50 22 mg/L 96 hr ㎎/ℓ(Gammarus sp., Still-water culture) (ECHA)
- [Secret] : LC50 7600 ㎎/ℓ 48 hr (IUCLID)
- [Secret] : EC50 = 1983 ㎎/ℓ 48 hr Daphnia magna (ECOTOX)
- [Secret] : EC50 0.21 ㎎/ℓ 48 hr Daphnia magna (OECD SIDS)
- [Secret] : LC50 2332.935 ㎎/ℓ 48 hr (Estimate)
- [Secret] : EC50 = 1250 ㎎/ℓ 24 hr Daphnia magna (NITE: EHC65, 1987)

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 - [Secret] : LC50 = 13000 ㎎/ℓ 48 hr Daphnia magna (OECD SIDS)
- [Secret] : ECHA EC50 >300.82 ㎎/ℓ 48 hr Daphnia magna(OECD TG 202, GLP)
○ Algae

- [Solvent naphtha (petroleum), light arom.] : EC50 = 19 ㎎/ℓ 72 hr Selenastrum capricornutum (IUCLID)

- [Rutile, tin zinc] : ErC50 1.85 ㎎/ℓ 72 hr Other (OECD Guideline 201, GLP, ECHA)

- [Iron hydroxide oxide (Fe(OH)O)] : EC50 287.651 ㎎/ℓ 96 hr (Estimate)

- [Propylene glycol methyl ether acetate] : EC50 1000 ㎎/ℓ 72 hr Selenastrum capricornutum (SIDS)

- [Ethylbenzene] : EC50 3.6 ㎎/ℓ 96 hr (EPA 1985, GLP)

- [Titanium dioxide] : ErL50 >100 ㎎/ℓ 72 hr (Pseudokirchneriella subcapitata, 72h-ErL50 Pseudokirchneriella subcapitata >100 mg/L
growth rate, static, 72h-EyL50 >100 mg/L static, OECD TG 201)

- [2-[(2-Methoxy-4-nitrophenyl)azo]-N-(2-methoxyphenyl)-3-oxobutyramide (C.I. pigment yellow 074)] : EC50 = 25.518 ㎎/ℓ 96 hr

(Estimate)

- [Secret] : EC50 0.0000781 ㎎/ℓ 96 hr (ECOSAR Class Hydrazine) (Ecological Structure Activity Relationships (ECOSAR)

- [Secret] : EC50 1890.263 ㎎/ℓ 96 hr (Estimate)

- [Secret] : EC50 0.090 ㎎/ℓ 96 hr (Estimate)
- [Secret] : ErC50 0.0455 ~ 0.6999 mg/L 72 hr other (Pseudokirchneriella subcapitata, Still-water culture, OECD Guideline 201)
(ECHA)
- [Secret] : EC50 440 ㎎/ℓ 72 hr (IUCLID)
- [Secret] : EC50 225 ㎎/ℓ 96 hr Selenastrum capricornutum(OECD TG 201, GLP)
- [Secret] : EC50 0.56 ㎎/ℓ 72 hr (OECD SIDS)
- [Secret] : EC50 9.337 ㎎/ℓ 96 hr (Estimate)
- [Secret] : EC50 1000 ㎎/ℓ 96 hr Selenastrum capricornutum (OECD SIDS)
- [Secret] : ECHA EC50 >1000 ㎎/ℓ 72 hr Skeletonema costatum(ISO 10253, GLP)

B. Persistence and degradability

○ Persistence
- [Xylene] : log Kow=3.16 (NITE)
- [n-Butyl acetate] : 2.3 log Kow (25 °C, OECD TG 117)
- [Solvent naphtha (petroleum), light arom.] : log Kow = 2.1 ~ 6 (IUCLID)
- [Toluene] : log Kow 2.73 (HSDB)
- [Propylene glycol methyl ether acetate] : log Kow = 0.43 (IUCLID)
- [4-Methyl-2-pentanone] : ECHA 1.9 log Kow (OECD TG 117)
- [Ethylbenzene] : log Kow 3.6 (ECHA)

- [2-[(2-Methoxy-4-nitrophenyl)azo]-N-(2-methoxyphenyl)-3-oxobutyramide (C.I. pigment yellow 074)] : log Kow = 2.99 (Estimate)

- [Iron hydroxide oxide (Fe(OH)O)] : log Kow 1.18 (Estimate)

- [Secret] : log Kow 3.25 (KowWin estimate) (Ecological Structure Activity Relationships (ECOSAR)

- [Secret] : log Kow = 0.63

- [Secret] : log Kow 5.31 (Estimate)
- [Secret] : -0.5304 log Kow (molbase)
- [Secret] : log Kow = 0.53
- [Secret] : log Kow 1 (OECD TG 117)
- [Secret] : log Kow = 0.97 (11.43) (NLM)
- [Secret] : log Kow = -1.38
- [Secret] : log Kow 0.52 (Estimate)
- [Secret] : log Kow = 0.8 (ISCS)
- [Secret] : log Kow = -0.5 (ICSC)
- [Secret] : log Kow -0.17 (Howard, 1997)
○ Degradability
- [Solvent naphtha (petroleum), light arom.] : BOD5/COD = 0.43

C. Bioaccumulative potential

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 ○ Bioaccumulative potential
- [Ethylbenzene] : BCF 1
-[Iron hydroxide oxide (Fe(OH)O)] : BCF 1.352 (Estimate)
- [Secret] : BCF 10 (EPI Suite)
- [Secret] : BCF = 3.162
- [Secret] : BCF 2453 (Estimate)
- [Secret] : BCF = 31 (NLM)
- [Secret] : BCF 3.162 (Estimate)
○ Biodegration
- [Xylene] : 39 (%) (NITE)
- [n-Butyl acetate] : 83% 28 day (OECD TG 301D) (ECHA)
- [Toluene] : Readily biodegradable (ECHA)

- [Propylene glycol methyl ether acetate] : Biodegradability > 60 (%) 28 day (OECD Screening Information Data Set)

- [4-Methyl-2-pentanone] : ECHA 83% 28 day (OECD TG 301, GLP)

- [Ethylbenzene] : 70-80% 28 day (ISO 14593 CO2, GLP)
- [Secret] : (Cut-off value = -0.5117 non-biodegradable (BIOWIN 5) (EPI Suite)
- [Secret] : 92% 20 days (ECHA)
- [Secret] : Biodegradability = 100 (%) 28 day (IUCLID)
- [Secret] : 96% 20 day(ECHA), Biodegradability = 74 (%) (NITE)

D. Mobility in soil

-[Iron hydroxide oxide (Fe(OH)O)] : Koc = 23.74 (Low reliability of the QSAR predictions of inorganic salts)

- [4-Methyl-2-pentanone] : ECHA 101.85 Koc (estimate)

- [4-Methyl-2-pentanone] : ECHA 101.85 Koc (estimate)
- [Secret] : Koc 3245 (Can be adsorbed on soil) (EPI Suite)
- [Secret] : Koc = 1417
- [Secret] : Koc = 1.838
- [Secret] : log Kow = 0.8 (1)
- [Secret] : 1.153 Koc (TGD guideline, QSAR)(ECHA)

E. Other adverse effects

- Not available

13. DISPOSAL CONSIDERATIONS

A. Disposal methods

- Since more than two kinds of designated waste is mixed, it is difficult to treat separately, then can be reduction or stabilization by
incineration or similar process.

- If water separation is possible, pre-process with Water separation process.

- Dispose by incineration.
- High temperature incinerate

- After taking off organic solvents that are supposed to be recycled, incinerate the rest of them at a high degree.

B. Special precautions for disposal

- The user of this product must dispose by oneself or entrust it to a waste disposer, a person who recycles other’s waste or establishes and
operates waste disposal facilities.

- Dispose of waste in accordance with all applicable laws and regulations.

14. TRANSPORT INFORMATION

A. UN No. (IMDG)
- 1263

B. Proper shipping name

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 - PAINT INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS, VARNISH, POLISH, LIQUID FILLER, AND
LIQUID LACQUER BASE

C. Hazard Class
-3

D. IMDG Packing group

-Ⅲ

E. Marine pollutant
- Applicable

F. Special precautions for user related to transport or transportation measures

- Local transport follows in accordance with Dangerous goods Safety Management Law.

- Package and transport follow in accordance with Department of Transportation (DOT) and other regulatory agency requirements.

- Air transport(IATA): This product is NOT classified as dangerous for IATA Transport.

- EmS FIRE SCHEDULE : F-E (Non-water-reactive flammable liquids)

- EmS SPILLAGE SCHEDULE : S-E (Flammable liquids, floating on water)

15. REGULATORY INFORMATION

A. National and/or international regulatory information
○ POPs Management Law
- Not applicable
○ Information of EU Classification
* Classification
- [Toluene] : H225,H361d,H304,H373,H315,H336
- [Xylene] : H226,H332,H312,H315
- [Ethylbenzene] : H225,H332
- [Secret] : H226,H302,H335,H315,H318,H336
- [Secret] : H226,H335,H315,H318,H336
- [4-Methyl-2-pentanone] : H225,H332,H319,H335
- [Secret] : H226,H314
- [n-Butyl acetate] : H226,H336,
- [Propylene glycol methyl ether acetate] : H226
- [Secret] : H226,H360D,H335
- [Solvent naphtha (petroleum), light arom.] : H350,H340,H304
○ U.S. Federal regulations
* OSHA PROCESS SAFETY (29CFR1910.119)
- Not applicable
* CERCLA Section 103 (40CFR302.4)
- [Xylene] : 45.3599 kg 100 lb
- [n-Butyl acetate] : 2267.995 kg 5000 lb
- [Toluene] : 453.599 kg 1000 lb
- [4-Methyl-2-pentanone] : 2267.995 kg 5000 lb
- [Ethylbenzene] : 453.599 kg 1000 lb
- [Secret] : 2267.995 kg 5000 lb
* EPCRA Section 302 (40CFR355.30)
- Not applicable
* EPCRA Section 304 (40CFR355.40)
- Not applicable
* EPCRA Section 313 (40CFR372.65)
- [Xylene] : Applicable
- [Toluene] : Applicable
- [4-Methyl-2-pentanone] : Applicable
- [Ethylbenzene] : Applicable
- [Secret] : Applicable

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 ○ Rotterdam Convention listed ingredients
- Not applicable
○ Stockholm Convention listed ingredients
- Not applicable
○ Montreal Protocol listed ingredients
- Not applicable

16. OTHER INFORMATION

A. Reference

- The information contained herein is believed to be accurate. It is provided independently of any sale of the product for purpose of hazard
communication. It is not intended to constitute performance information concerning the product. No express warranty, or implied
warranty of merchantability or fitness for a particular purpose is made with respect to the product or the information contained herein.

- This Safety Data Sheet was compiled with data and information from the following sources: KOSHA, NITE, ESIS, NLM, SIDS, IPCS

B. Issue date
- 2022-07-19

C. Revision number and Last date revised

-

D. Other
- This SDS is prepared according to the Globally Harmonized System (GHS).

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