2024-10-06

4001CJA101021240050 - SET B JA

PART-1 : MATHEMATICS

SECTION-I (i)

1) Let . Then which of the following statements holds good?

The number of ways to distribute 6 different things to three persons so that each person
(A)
receives any number of things is N.
(B) Sum of coefficients in expansion of (2x + 1)6 is N
(C) Sum of binomial coefficients in expansion of (2x + 1)6 is N
Number of ways in which two disjoint subsets A and B can be formed from a set (1, 2, 3, 4, 5, 6)
(D)
is N .
0
2) If expression S = (1 + x)9x10 + (1 + x)10x9 + ... + (1 + x)19x expanded as increasing powers of x,
then

(A) number of terms in S is 20

(B) sum of coefficients in S is (220 – 210)
10 20
(C) coefficient of x in S is C10
(D) coefficient of x19 in S is 11

3) If , then which of the following is(are) INCORRECT (where A–1 is inverse of

matrix A, I is an unit matrix of order 3, adj A is adjoint of matrix A, |A| denotes determinant value of
matrix A.)

(A)
is equal to 288

(B)

(C)
is equal to 16

(D)

4) Let and , then

(A)
(B)
(C)
(D)

5) The value of is equal to (where Ck, k = 1, 2, 3, 4 represents integration

constants) -

(A)

(B)

(C)

(D)

6) System of equation x + y + az = b, 2x + 3y = 2a & 3x + 4y + a2z = ab + 2 has

(A) unique solution when a ≠ 0, b ∈ R

(B) no solution when a = 0, b = 1
(C) infinite solution when a = 0, b = 2
(D) infinite solution when a = 1, b ∈ R

7) If ; for n ∈ N, then

(A)

(B) A4 = A5
(C) B9 – B8 = A9
(D) B9 – A9 = A8

8) Which of the following vanishes ?

(A)

(B)

(C)
(D)

SECTION-I (ii)

1) Match each entry in List-I to the correct entries in List-II.

LIST-I LIST-II

If the coefficients of (2r+4)th,(r–2)th terms in the

(I) (P) 3
expansion of (1+x)18 are equal then value of r is

Term independent of x in the expansion of

(II) (Q) 1
is λ then value
of is
where [.] denotes greatest integer function

If and f = P – [P],
(III) where [.] denotes greatest integer function, then (R) 4
value of P(1 – f) is

(IV) If rth term of the expention contain x39 (S) 5

then r is

(T) 6

(U) 7

The correct option is:

(A) I → T;II → R;III → P;IV → S
(B) I → R;II → Q;III → P;IV → T
(C) I → Q;II → R;III → S;IV → P
(D) I → T;II → P;III → Q;IV → R

2)

List-I List-II

(I) If , then minimum value of x + y is (P) 3

If the maximum value

(II) (Q)
of occurs when , then the value of 'a' is

If f(x) = x – 2sinx, is increasing in the interval

(III) (R) 4
, , then b – a is
 If equation of the tangent to the curve where
(IV) (S) 2
it crosses the y-axis is , then p – q is

(T) –3

(U) 1
(A) I → Q;II → P;III → S;IV → R
(B) I → R;II → Q;III → S;IV → P
(C) I → Q;II → S;III → R;IV → P
(D) I → P;II → R;III → Q;IV → S

3) Match the following integrals with their values

List-I List-II

(I) (P) – π log2

(II) (Q)

(III) (R)

(IV) (S) π log 2

(T) π log 4

(U) –π2 log 2

(A) I → R;II → P;III → Q;IV → R
(B) I → R;II → R;III → P;IV → Q
(C) I → R;II → Q;III → P;IV → R
(D) I → R;II → R;III → Q;IV → P

4) Let A,B,C are matrices.

List-I List-II

If |A| = 2, then |2A–1| is equal to

(I) (P) 1
(where A is of order 3 matrix)
 (II) If , then |adj(adj2A)| is equal to (Q) 4
(where A is of order 3 matrix)

If (A + B)2 = A2 + B2 and |A| = 2, then |B| is

(III) (R) 8
equal to (where A & B are of odd order)

If (I – A)–1 = I + A + A2 + ... +A7, then An = 0

(IV) (S) 0
where n is

(T) 2

(U) 5
(A) I → R;II → P;III → S;IV → T
(B) I → Q;II → P;III → S;IV → R
(C) I → Q;II → S;III → P;IV → R
(D) I → R;II → T;III → S;IV → P

SECTION-II

1) If then k is equal to __________.

2) If a3 + b3 + c3 – 3abc = –3, then the value of

3) Consider the function f(x) = x4 + 6x3 + 35x2 + 6x + 1. Let m = number of points of inflection of
f(x)
n = number of stationary points of f(x)
p = number of points of local minima of f(x),
then (m + n + p) is equal to

4) Let A and B are 2 non singular matrices such that . Then least value of k
for which Bk = I,

5) If the integral , then k is equal to

6) exists finitely and is equal to ax3 (loge x –b) +

c, then value of a + b is ________
 PART-2 : CHEMISTRY

SECTION-I (i)

1) Which of the following option(s) represent the CORRECT IUPAC name of the given co-ordination
compounds ?

(A) K3[Fe(C2O4)3] Potassium trioxalatoferrate (III).

(B) K3[Fe(CN)6] Potassium ferricyanide.
(C) [Ni(NH3)4] [NiCl4] Tetraamminenickel (II) - tetrachloridonickelate (II).
(D) [Co(en)3]Cl3 : Tris-(ethane-1,2-diammine)cobalt(III) chloride.

0 0
2) For an ideal liquid - liquid solution of A(PA = 25 torr) & B(PB = 50 torr), select the correct option
(s) (X and Y are mole fractions in liquid and vapour phase respectively)

(A)
always less than

(B) always more than

(C) =

(D)
may be greater, smaller or equal to

3) Indicate the correct statement(s) among the following :

(A) Conductance cells have cell constant values independent of the solution filled into the cell
(B) DC (direct current) is not used for measuring the resistance of a solution in a conductance cell.
(C) Kohlrausch law is valid for both for strong and weak electrolytes.
Specific conductance decreases but molar and equivalent conductances increase on dilution for
(D)
a given electrolyte.

4) Which of the following is true for reversible adiabatic process involving an ideal gas?

(A) Gas with higher γ has high magnitude of slope in a P (y-axis) v/s T (x-axis) curve
(B) Gas with higher γ has high magnitude of slope in a V (y-axis) v/s T (x-axis) curve
(C) Gas with higher γ has high magnitude of slope in a P (y-axis) v/s V (x-axis) curve
(D) Gas with higher γ has low magnitude of slope in a P (y-axis) v/s T (x-axis) curve

5) Select correct statements -

(A)
is always independent of path followed between two points
Entropy of universe is conserved
(B)

For a process in isolated system entropy either increases or remain constant

(C)

(D) Entropy of an ideal gas decreases with increase in temperature at constant V

6) 1 gm of monobasic acid when dissolved in 100 gm of water lowers the freezing point by 0.1854°C.
0.2 gm of same acid required 20 ml of 1/10 N alkali for titration, then for solution of acid: (Assume
molarity = molality) (log2 = 0.3, log3 = 0.48) (Kf(H2O) = 1.8 K kg mol–1)

(A) Degree of dissociation = 0.3

–4
(B) Ka of acid = 9 ×10
(C) pH= 2.52
(D) Molar mass of acid = 100 g/mol

7) 20 ml of liquid A is mixed with 10 ml of liquid B, the volume of resultant homogeous solution is 27

ml. Select the correct option(s) regarding liquid solution :

0
(A) PA < XA P A
0
(B) PB < XB P B

(C) ΔHmix < 0

(D) ΔSmix > 0

8) = – 0.15 (V), = – 0.44 (V), = – 0.77 (V),

= – 0.036 (V), = +1.51 (V)

Which of the following reaction is/are spontaneous under standard conditions ?

(A) Fe(s) + Fe+2(aq) + Mn+2(aq) + H2O(l)

(B) Fe+2(aq) + Fe+3(aq) + Mn+2(aq) + H2O(l)

(C) Fe(s) + Fe+3(aq) + Mn+2(aq) + H2O(l)

(D) Fe+2(s) + Sn+4(aq) Fe+3(aq) + Sn+2(aq)

SECTION-I (ii)

1)

Column - II (Reagent
Column - I (Pair of compounds)
used to distinguish)

+
(I) (P) [Ag(NH3)2]
 (II) (Q) Lucas test

(III) CH3–CH2–C≡CH CH3–C≡C–CH3 (R) NaOH / I2

(IV) (S) 2,4-DNP test

(T) NaHCO3

(U) NaHSO3
(A) I → P,R;II → R,S,T,U;III → P;IV → Q,R
(B) I → P;II → S,T;III → R;IV → Q,R
(C) I → P,R;II → Q;III → P;IV → R
(D) I → Q,R;II → R,S,T;III → Q;IV → P,R

2) The standard reduction potential data at 25°C is given below

3+ 2+
E° (Fe , Fe ) = +0.77 V ;
E° (Fe2+, Fe) = –0.44 V ;
E° (Cu2+, Cu) = +0.34 V ;
E° (Cu+, Cu) = +0.52 V ;
E° (O2(g) + 4H+ + 4e– → 2H2O] = +1.23 V ;
E° [(O2(g) + 2H2O + 4e– → 4OH–)] = +0.40 V ;
E° (Cr3+, Cr) = –0.74 V ;
E° (Cr2+, Cr) = –0.91 V ;
Match E° of the redox pair in List-I with the values given in List-II and select the correct answer
using the code given below the lists :

List I List II

(I) E°(Fe3+, Fe) (P) –0.18 V

(II) E(4H2O 4H+ + 4OH– ) (Q) –0.4 V

(III) E°(Cu2+ + Cu → 2Cu+) (R) –0.04 V

(IV) E°(Cr3+, Cr2+) (S) –0.83 V

(T) –3.1 V

(U) –0.60 V
(A) I → S;II → P;III → Q;IV → R
(B) I → Q;II → R;III → S;IV → P
(C) I → P;II → Q;III → R;IV → S
(D) I → R;II → S;III → P;IV → Q

3) One mole of an ideal gas undergoing from state A to State-B through different processes List-I
shows graph of the process & List-II shows change in parameter in these process. Match the
following
 List-I List-II

(I) (P) q>0

(II) (Q) W>0

(III) (R) ΔU > 0

(IV) (S) ΔH > 0

(T) W<0

(U) q=0
(A) I → P,Q;II → R;III → S,T;IV → Q
(B) I → P,R,S,T;II → P,T;III → P,R,S,T;IV → Q
(C) I → Q,R,S;II → P,Q,U;III → P,R,T;IV → R
(D) I → P,Q;II → R;III → T;IV → U

4) Match the column based on phase diagram (temperature v/s mole fraction) of a solution of

liquid A & liquid B given below.

 Column-
Column-I
II

Solution of composition XA =
0.8 is heated upto T1
(I) temperature. Then the mole (P) 0.2
fraction of ‘A’ in vapour form
at equilibrium

Solution of composition XA =
0.8 is heated upto T2
(II) temperature. Then the mole (Q) 0.26
fraction of ‘B’ in vapour form
at equilibrium.

Solution of composition XA =
0.66 is heated upto T4
(III) temperature. Then the mole (R) 0.66
fraction of ‘A’ in vapour form
at equilibrium.

Solution of composition XA =
0.3 is heated upto T3
(IV) temperature. Then the mole (S) 0.7
fraction of ‘B’ in liquid form
at equilibrium.

(T) 0.8

(U) 1.0
(A) I → R;II → P;III → S;IV → Q
(B) I → T;II → R;III → S;IV → Q
(C) I → T;II → Q;III → R;IV → T
(D) I → S;II → R;III → Q;IV → T

SECTION-II

1) KCl solution of conductivity 0.14 S m–1 shows a resistance of 4.19 Ω in a conductivity cell. If the
same cell is filled with an HCl solution, the resistance drops to 1.03 Ω. The conductivity of the HCl
solution is
____× 10–2 S m–1. (Round off to the Nearest Integer).

2) During an electrolysis of conc. H2SO4, perdisulphuric acid (H2S2O8) and O2 form at anode in
equimolar amount. The mole of H2 that will form simultaneously at other electrode will be x times of
O2. What is the value of x?
(Given : 2H2SO4 → H2S2O8 + 2H+ + 2e–)

3) 62 g ethylene glycol is dissolved in 500 gram water. The solution is placed in a refrigerator
maintained at a temperature of 263 K. What amount of ice (in grams) will separate out at this
temperature? (Kf water = 1.86 K molality–1)
4) One mole of an ideal gas at 900 K, undergoes two reversible processes, I followed by II, as shown

below. If the work done by the gas in the two processes are same, the value of ℓn is ___.

(U : internal energy, S : entropy, p : pressure, V : volume, R : gas constant)

(Given : molar heat capacity at constant volume, ,m of the gas is R)

5) What is the difference between the EAN value of [Fe(CO)5] & [Ni(CO)4]

6) The vapour pressures of two volatile liquids A and B at 25°C are 50 Torr and 150 Torr,
respectively. If the liquid mixture contains 0.3 mole fraction of A, then the mole fraction of B in the

vapour phase is The value of x is ________.

PART-3 : PHYSICS

SECTION-I (i)

1) A particle of mass M is performing SHM with amplitude A. When the particle was at A/2 and
moving away from mean position, a block of same mass was kept on it such that is sticks to it.

(A)
The new amplitude =
(B) The time period remains unchanged

(C)
The new amplitude =
(D) The time period increases

2) A rectangular coil in the plane of the page has dimension a and b. A long wire that carries a
current I = 2t is placed directly on the coil as shown. Choose the CORRECT options.
(A)
Magnetic flux through coil is for 0 < x < b
(B) x → b, flux ϕ is maximum

(C)
flux ϕ is minimum

(D)
induced emf

3) A ray of light travelling in the direction is incident on a plane mirror. After reflection, it

travel along the direction . Then choose the CORRECT statement(s).

(A) Mirror is kept in x-y plane

(B) Normal of the mirror is along
(C) Angle of incident is 37°
(D) Mirror is kept in x-z plane

4) Two different coils have self-inductance L1 = 8 mH and L2 = 2mH. The current in one coil is
increased at a constant rate. The current in the second coil is also increased at the same constant
rate. At a certain instant of time, the power given to the two coils is the same. At that time, the
current, the induced voltage and energy stored in the first coil are I1, V1 and W1 respectively.
Corresponding values for the second coil at the same instant are I2,V2 and W2 respectively then :-

(A)

(B)

(C)

(D)

5)

A series RLC circuit is driven by a generator at frequency 1000 Hz. The inductance is 90.0 mH;
capacitance is 0.500 µF; and the phase constant has a magnitude of 60.0° (Take π2 = 10)

(A) Here current leads the voltage in phase

(B) Here voltage leads the current in phase
(C)
Resistance of circuit is

(D)
At resonance ω = rad/sec.

6) In damped oscillation relaxation time is the time taken by physical quantity to drop to times of
its original value. m is the mass of oscillator and b is damping constant. Choose the correct
statement/s :

(A)
relaxation time of amplitude is

(B)
relaxation time of velocity is

(C)
relaxation time of energy is

(D)
relaxation time of velocity is

7) Initially key was placed on (1) till the capacitor got fully charged. Key is placed on (2) at t=0. The

time when the energy in both capacitor and inductor will be same

(A)

(B)

(C)

(D)

8) Which of the following figure represents damped harmonic motion ?

(A)
(B)

(C)

(D)

SECTION-I (ii)

1) The speed V of a particle of mass 1 kg moving along a straight line when it is at a distance (x)
from a fixed point on the line, is given by V2 = 144 – 9x2. Match the following.

List - I List - II

(I) Motion is simple harmonic with time period (P) 2π/3 units

(II) Maximum displacement from fixed point is (Q) 27 units

Magnitude of acceleration at a distance 3 units from the fixed

(III) (R) 4 units
point is

(IV) Potential energy at a distance x = 2 unit from fixed point is (S) 2 units

(T) 18 units

(U) 28 units
(A) I → P;II → S;III → Q;IV → R
(B) I → P;II → R;III → T;IV → U
(C) I → R;II → R;III → U;IV → T
(D) I → P;II → R;III → Q;IV → T

2) In the circuit shown in figure, switch remains open for long time. It is closed at time t = 0. Match

the following two lists various time

List-I List-II
 (I) Current from battery at t = 0 (P) 3A

(II) Current from battery at t = ∞ (Q) 1A

(III) Current throught 3Ω resister at t = 0 (R) zero

(IV) Currrent through 3Ω resistor at t = ∞ (S) 1.5A

(T) 4.5A

(U) 2A

Which one of the following options is correct ?

(A) I → S;II → T;III → R;IV → P
(B) I → R;II → P;III → S;IV → T
(C) I → T;II → S;III → R;IV → P
(D) I → R;II → P;III → T;IV → S

3) Match the following columns and select the correct option from the codes given below.

Column-I Column-II

(I) Gauss's Law (P) Electric Current

(II) Ampere Circuit Law (Q) Electric Field

(III) Faraday's Law (R) Magnetic Field

(IV) Kirchhoff's Law (S) Electromagnetic Induction

(T) Capacitance

(U) None of these

(A) I → Q;II → R;III → T;IV → P
(B) I → Q;II → R;III → S;IV → P
(C) I → T;II → R;III → U;IV → Q
(D) I → Q;II → P;III → U;IV → R

4) A particle is performing SHM x = A sin (ωt + ϕ) whose time period is T. List-I contains events
related to the motion of particle and List-II contains the minimum time after which that event
happen. Choose the correct match from option if ϕ = π/4

List–I List–II

(I) Particle comes to rest (P) T/4

(II) Velocity is maximum (Q) T/6

(III) Kinetic energy = Potential energy (R) 3T/8

(IV) Velocity is half of maximum velocity (S) T/24

(T) T/2

(U) T/8
(A) I → P;II → T;III → U;IV → Q
(B) I → U;II → R;III → P;IV → S
(C) I → R;II → Q;III → S;IV → T
(D) I → S;II → Q;III → R;IV → T

SECTION-II

1) An LCR series circuit of capacitance 62.5 nF and resistance of 50 Ω. is connected to an A.C.

source of frequency 2.0 kHz. For maximum value of amplitude of current in circuit, the value of
inductance is ______mH.
(take π2 = 10)

2) A small block of mass m = is attached to two springs each of force constant k = 10 N/m as

shown in figure. The block is executing SHM with amplitude A = . When the block is at
equilibrium position one of the spring breaks without changing momentum of block. What is new

amplitude (in cm) of oscillation.

3) Two straight conducting rod are connected by flexible conducting wires to form a rectangular
outline (figure i). The sides of the rectangle are a = 30 cm and b = 50 cm. The circuit is placed in a
uniform magnetic field with induction B = 5 × 10–3 T directed perpendicular to the plane. What is the
charge Δq (in µC) that flows along the contour, if you turn it by 180° symmetrically as shown without
the wires touching each other (figure ii)? Loop resistance R = 1 ohm. Take self-inductance of the

system to be L = 1 H. Fill in OMR sheet.

4) An ideal inductor takes a current of 10A when connected to a 125 V, 50 Hz ac supply. A pure
resistor across the same source takes 12.5 A. If the two are connected in series across a ,
40 Hz supply, the current through the circuit will be :-

5) Incident ray and plane mirror are rotating with 3°/sec and (5°/sec) clock wise and anticlock wise
respectively. Find out angular speed (in °/sec.) of reflected light :-

6) The resultant amplitude due to superposition of the two S.H.M.s x1 = 10 sin (ωt + 30°) and x2 =
–10 cos (ωt – 60°) is ______.
 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I (i)

Q. 1 2 3 4 5 6 7 8
A. A,B,D A,C,D C,D B,C A,B,C,D B,C,D A,B,C A,B,C,D

SECTION-I (ii)

Q. 9 10 11 12
A. D C B B

SECTION-II

Q. 13 14 15 16 17 18
A. 575 27 2 127 3 1

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24 25 26
A. A,C,D A,D A,B,C,D C,D C C,D A,B,C,D A,B,C

SECTION-I (ii)

Q. 27 28 29 30
A. A D B C

SECTION-II

Q. 31 32 33 34 35 36
A. 57 3 314 10 0 14

PART-3 : PHYSICS

SECTION-I (i)

Q. 37 38 39 40 41 42 43 44
A. A,D A,B,C,D B,C,D A,C,D B,C,D A,B,C A,C B,D

SECTION-I (ii)

Q. 45 46 47 48
A. D A B B
 SECTION-II

Q. 49 50 51 52 53 54
A. 100 75 5 10 13 0
 SOLUTIONS

PART-1 : MATHEMATICS

1)

(A) Each things has 3 ways to go ⇒ 36

(B) f(1) = 36
(C) 26

(D)

2)

S = a0 + a1x + ... + a19x19

(A) number of terms = 20
(B) sum of coefficients
= 29 + 210 + ... + 219 = 220 – 29
(C) coeff of x10

= 20C10

(D) coeff of x19 is

3)

|A5 – 2A4| = 0 and

5)

All options are correct.

6)
for a = 0 D = 0, Dx = 0, Dy = 0, Dz = 2 – b
so for a = 0, b = 2 ⇒ Infinite Solutions.
for a = 0, b = 1 ⇒ No solution.
for a = 1, D = 0, Dx = 0, Dy = 0, Dz = 0
⇒ Infinite solutions.
If a ≠ 0 but a = 1 does't have unique solutions.

7)

=
An+1 = An

= = An+1

8)

Apply P-5 and verify

12)

(P) |A| = 2
(Q)

(R) (A + B)2 = A2 + B2
⇒ AB + BA = 0
⇒ |AB|=|–BA|= –|BA|= –|AB|
⇒ |AB| = 0
⇒ |B|= 0
(S) ⇒ (I – A)(I – A)–1
= (I – A)(I + A + A2 + ... + A7)
⇒ I = (I + A + A2 + ... + A7)
– A – A2 – A3 – ... – A8
= I – A8
∴ LHS = RHS, iff A8 = 0 ⇒ n = 8
 14)

Δc = Δ2
=

15)

f'(x) = 4x3 + 18x2 + 70x + 6

and f''(x) + 12x2 + 36x + 70

∴ f''(x) = 12 + 43 > 0 ∀ x ∈ R
so f(x) has no inflection point and f'(x) = 4x3 + 18x2 + 70x + 6 is strictly increasing function, so
equation
f'(x) = 0 has exactly one real root
⇒ f(x) has 1 stationary point.
Since f(x) is concave up ∀ x ∈ R
⇒ stationary point is the point of local minima
∴ m = 0, n = 1, p = 1

16) AB2 = BA
B2 = A–1BA
B4 = (A–1)2 BA2
B16 = (A–1)2 B4A2
B16 = (A–1)4 BA4
B64 = (A-1)4B4A4
B64 = (A–1)6 BA6
B128 = (A–1)7BA7
B128 = B
∴ Least value of k is 127.

17)

Use wall's formula

PART-2 : CHEMISTRY

19)

In[Co(en)3]Cl3, en is ethane-1,2-diamine not diammine.

20)

Ans : → for ideal solution :-

0
A → PA = 25 torr
B→ Torr → more vapour pressure
↓
means B forms more vapours and will be more in vapour phase.
so YB > YA → in vapour phase this means, XB < XA → in liquid phase.

hence ............. [A]

we cannot comment about the relation between and - [D]

[A,D]

21)

Correct options are A, B, C and D

(A) Conductivity cells have cell constant values independent of the solution filled into the cell. The

value of the cell constant depends on the length and the area of the electrodes. It is the ratio al​
Hence, the option (A) is correct.
(B) DC (direct current) is not used for measuring the resistance of a solution. A.C current is used for
this purpose. Hence, option B is correct.
(C) Kohlrausch law is valid both for strong and weak electrolytes. However, the law is particularly
valuable to calculate Λo​ of weak electrolytes.
Hence, option C is correct.
(D) The specific conductivity k decreases but the molar conductivity λM​ and the equivalent
conductivity λE​ increase on dilution. This is because, on dilution, the total number of ions increases
(due to an increase in the degree of dissociation) and the number of ions per unit volume decreases.
Hence, option D is correct.

22)

23)

(A) Incorrect

∴ ΔS = Independent of path not

(B) Incorrect
For spontaneous process ΔSuni > 0
(C) From 2nd law of thermodynamics
(ΔSisolated > 0)
(C) ⇒ Correct

(D) ΔS =
At constant volume

On T↑ ΔS↑ ∴ (D) → Incorrect

Ans ⇒ (C)
 24)

Water: 100 gm = 100 ml

Solution is highly dilute
So, Solution = 100 ml

and M=0.1
ΔTf = i mkf

i=

α = 0.03 (α < 0.1)

; pH= 3–log3 = 2.52

2 –5
Ka= Cα = 9 ×10

25)

ΔVmix < 0 (Negative deviated non ideal solution)

Entropy change of mixing of liquids is positive.

26)

(A) = 1.51 – (– 0.44) > 0 ΔG° < 0

(B) = 1.51 – 0.77 > 0 ΔG° < 0
(C) = 1.51 – (0.036) > 0 ΔG° < 0
(D) = (+0.15) – 0.77 < 0 ΔG° > 0

27)
 28)

(I) e– + Fe3+ → Fe+2 = –1 × F × 0.77

– 2+
2e + Fe → Fe = –2 × F × (–0.44)
Required equation
Fe3+ + 3e– → Fe = –3 × F × E°
= +
–3 × F × E° = –1 × F × 0.77 – 2 × F × (–0.44)

(II) O2(g) + 4H+ + 4e– → 2H2O = 1.23 V ... (i)

O2(g) + 2H2O + 4e– → 40H– = 0.40 V ... (ii)
Required equation
4H2O 4H+ + 4OH–

(III)
(IV) Cr+3 + 3e– → Cr = –3 × F × (–0.74)
+2 –
Cr + 2e → Cr = –2 × F × (–0.91)
Required equation
Cr3+ + e– → Cr+2 = –1 × F × (E°)

–3 × F × (–0.74) = –2 × F × (–0.91) –1 × F × E°
E° = 1.82 – 2.22 = –0.4 V

29)

(I) ΔT > 0 ⇒ ΔH > 0, ΔU > 0, expansion ⇒ W < 0 and q > 0 (∵ ΔU = q + W)

(II) ΔT = 0 ⇒ ΔH = ΔU = 0, expansion ⇒ W < 0 and q > 0
(III) ΔT > 0 ⇒ ΔH > 0, ΔU > 0, expansion ⇒ W < 0 and q > 0
(IV) P = constant ⇒ q = ΔH, ∵ Compression ⇒ ΔT < 0 and W > 0.

30)

(P)-5; (Q)-2; (R)-3; (S)-4

31)
For same conductivity cell, G* is constant and hence κ.R. = constant.
∴ 0.14 × 4.19 = κ × 1.03

or, κ of HCl solution =

= 0.5695 Sm–1
= 56.95 × 10–2 Sm–1 ≈ 57 × 10–2 Sm–1

32)

Cathode {2H2O → H2 + 2OH– – 2e–} × 3.

Net : 2H2SO4 + 8H2O → H2S2O8 + O2 + 3H2 + 6H+ + 6OH–
Hence ratio of and is 1 : 3.

33) ΔTf = 273 – 263 = 10 °C

ΔTf = i kf. m

10 =
wsolvent = 186 g
Mass of ice freezed = 500 - 186 = 314 g

34)

ΔUI = nCv,m ΔT = WI {qI = 0}

– 1800 R = 1 × × ΔT
= ΔT = – 720 K

T2 = 180 K

WII = WI = – 1800 R

= – 1 × R × 180 ln

ln = 10 ⇒ 10

35)

[Fe(CO)5]
EAN = 26 – 0 + 10 = 36
[Fe(CO)2(NO)2]
EAN ⇒ 26 – 0 + 2 × 2 + 2 × 3 = 36
Difference ⇒ 0

36)
PA = PT YA = 50 × 0.3 ............(1)
PB = PT YB = 150 × 0.7 ............(2)
On (1) / (2) :

............(3)
YA + YB = 1 ............(4)
From (3) and (4) :

YB =

PART-3 : PHYSICS

37)
Velocity just after collision

38)

39)

y component of velocity is changing

Mirror must be in x-z plane
Since ray was initially travelling towards +y axis
Normal must be along –ve y i.e.

angle of incidence = 37°

40)
v=–L

Power given is same

v1I1 = v2I2

43)

For given situation

⇒ q = q0 cos ωt & i = –q0ωsinωt

According to given conditions

⇒ cot2ωt = 1

⇒ ωt = .........

.....

49)

50)

ω= =
when spring breaks new ω =
Equilibrium position of original system
(2k)x0 = mg
 0
or x = m
New equilibrium is at kx = mg

x= m
thus

vmax = Aw = ( )×

= A2 –

A2 = + = = ⇒A= m ]

51)

ϕi = Bab
ϕf = 0

52)

C–1 :

ωL = 12.5
C–2 :

C–3 :

53)

ωr = –ωi + 2 ωm
ωr = (–3) + 2(5)
= 13°/sec.