etd New

DAY-06 SEAT NUMBER

2021 1X 24 1030 J-565 (E)

CHEMISTRY (55)

Time 3 Hrs. (7 Pages) Max. Marks: 70

General Tnstructions:
The question paper is divided into four sections.
(1) SectionA: Q.No. 1 contains Ten multiple choice typeofquestions
carrying One mark each.
O. No. 2 contains Eight very short answer ype of
questions carrying One mark each.
(2) Section B: Q. No. 3 to Q. No. 14 are Twelveshort answer type af
questions carying Two marks each. (Atiempt any Eight)
3) Section C: Q No. 15 to Q. No. 26 are Twelve short answer type of
questions carrying Three marks each.(Attempt any
Eight)
(4) Section D : Q No. 27 to Q. No. 31 are Five long answer type of
questions carrying Four marks each.(Attempt any
Three)
(5) Use of log table is allowed. Use of calculator is not allowed.
(6) Figures to the right indicate full marks.

(7) For each multiple choice type of question, it is mandatory to write

the correct answer along with its alphabet e.g.
(a). 6). **

/(c)..... (a). etc.

No mark (s) shall be given, if ONLY the correct answer or the
alphabet of the correct answer is written.
Only the first attempt will be considered for evaluation

Page 1
P.T.O.
 SECTION - A

Q. 1. Select and write the correct answer for the following multiple [10
choice type of questions
) The product obtained in the following reaction
P23 is,
T1-
CH3-CH=CH-CH, -CHOH2/N
(a) Pent-3-en-1-ol b) Pentan-1-ol

(c) Pentan-2-ol (d) Pentanal

ionic solid
() Amongst the following, the solubility of which
in
030 decreases with increase temperature?
(b) NaBr
(a) (a) KNO
(d) KCI
Mc) Na,SO4
(ii) The correct IUPAC name of Na, [AIF]is
a) Sodium hexafluoroaluminate (I11)
b
e (b) Sodium hexafluoroaluminate (1)
( c ) Sodium hexafluoroaluminium(11
(d) Sodium hexafluoroaluminium (11)
value?
(iv) Which ofthe following acids has highest pKa
(a) Mono chloroacetic acid (b) Dichloroacetic acid
p
Tose
A (c) Trichloroacetic acid VMd) Acetic acid
(v) Number of carbon
atoms present in isoprene unit is
P322
(a) 6 b) 5
153 (c) 4 (d) 3

metal ion amongst the following is

(vi) The colourless transition

ot17a) Cu
3 (b) Cu
++
(c) (c) Ni (d) Co

Page 2
051613
P 232
) CI+ dryAH20B
ether
he
(

IX
2 4 )
product B' in the above
reaction sequence is
(a) Mg (6) TMg-CI
(c) C Mg
(Vii)
Carbylamine test is given by
P

o
qv
á ) aniline
o (6) dimethylamine
c)trimethylamine
(d) both
dimethylamine and trimethylamine
1x) A weak monobasic acid is
0.05% dissociated in 0.02 M
Pso
solution, dissociation constant
of the acid is
(a) 5x 10-10
6 ) 5 x 10
(c) 50x 10
(d) 0.5x 10
(x) The rate constant for the reaction

. 2 2N,0s(g)2N,O4(g) +O2(g) is 4.98 x10s. The

order of reaction is
(a) 0
(c) 2
(d) 3

Q. 2. Answer the following questions

TNO7-l)
P160
Write the name of interhalogen 81
compound of chlorine which
has square pyramidal structure.

0lii) Write the name of sugar present in RNA.

2.303 RT
4 . 2

(ii) Write the value of -

Fi n Nernst equation.

Page 3
P.T.O.
 P. What is the coordination number of atoms in simple cubic
crystal lattice?
' 6

P3S0
P3S (v) Write the name of nanostructural material used in tyres
to
6 -6
6 - C
) )
increase their life.

p6 (vi) Write the

G9 (vi) name of reagent used during conversion of
acetaldehyde to acetaldehyde cyanohydrin.
TMo.9vi,
a 1 ( v i i ) Write the chemical formula of Haematite.
(vii) In a particular reaction, 2kJ of heat is released by the system
p12 and 6 kJ of work is done on the system. Calculate AU.

SECTION - B

Attempt any EIGHT of the following questions: [161

. 3. What are bidentate Ligands? Give one
example.
P

Q. 4. Draw the structure of

sulphurous acid. Write two uses of helium.
Q. 5. The molar conductivity of 0.01M acetic acid at 25°C is
182 cm mol. Calculate its degree of
dissociation
in 0.01M
solution and dissociation constant,
if molar conductivity of acetic
acid at zero concentration is 400R- em2 mol- a0:09>
Q. 6. Write classification of
proteins on the basis of molecular
with example. shapes
130

. 7. What is pseudo-first order reaction?

6.S
6 . S
Explain with suitable example.
Q. 8. What is the molar mass of
solute if a solution
a
u dissolving 0.822 g of it in 0.3 prepared by
dm of water has an osmotie
pressure of 0.196 atm. at 298 K ?
Q.9. Write a note on Kolbe reaction.

Page 4
 Q. 10. Iron exhibits +2 and +3 oxidation states. Write their electronic
0
Tagle 9
configuration. Which willbe more stable? Why?

Q 11. How is benzophenone prepared from benzonitrile??

Q. 12. Write names and structure of monomers used in the preparation
P9 of Nylon 6, 6 polymer.
Derive the relationship between pH and pOH.
s 13.
PQ.
chlorobenzene?
Q. 14. What is action of the following on

p 10 Methyl chloride in presence of anhydrous AlCl,

i) Fuming H, SO

SECTION C

of the following questions 24]

Attempt any EIGHT

Q. 15. Calculate the standard enthalpy of

NgH4(g)+H2(g)>2NH3(g)
1 i f AH°(N-H) =389 kJ mol
AH°(H-H) = 435 kJ mol

AH°(N-N) = 159 kJ mol

ethanamine from
Q. 16. Write reactions to prepare
Prs ) acetonitrile
13.2
a () nitroethane
(1i) propionamide

Q. 17. Explain three principles ofgreen chemistry.

18. Write chemical equations involved during manufacture of
70.
l6-9

sulphuric acid by contact process.

P.1
i t e two
P I S Y rWrite uses ofsulphur dioxide.

Page 5 P.T.O.
5 5
 1 9 . Explain SN reaction mechanism for alkaline hydrolysis of
2 n

bromomethane.
.20. Why La(OH), is the strongest base, while Lu(OH), is the weakest
base? Write two applications of catalytic properties of transition
P 73
metals and compounds.
- 6

Q. 21. Convert the following:

Pyo 0) chlorobenzene to phenol
eX PG () ethanal to ethanol
P r g
(ii) iodomethane to methoxy methane
22. Define
p Cryoscopic constant.
C s Derive the relation between elevation of boiling point and molar
C mass of solute.

Q. 23. Define solubility product.

Derive the relationship between solubility and solubility product
for Pbl
3.92

Q. 24. A compound forms hexagonal close packed (hep) structure. What

P. is the number of
(i) octahedral voids
Psp-
(ii) tetrahedral voids

(iil) total voids formed in 0.4 mol ofit?

Q. 25. lustrate with example, the

difference between a double salt and

coordinate compounds.
Write two applications of coordinate compounds.

Q. 26, VWrite a note on 'aldol' condensation reaction of ethanal.

7 Write chemical reaction involved
when benzaldehyde is treated

a17/1
P7/1w with concentrated caustic potash.

Page 6
55
 SECTION -D

Attempt any THREE of the following questions 12]

Define isomorphism. Derive integrated rate law expression for

2,
first order reaction.

Q. 28. What is the action of concentrated H, SO on,

PIs CaF
DISyi) Cane sugar
nucleotide? Write reaction for the preparation
of
B1 What is
P9polyacrylonitrile (PAN).
migration of ions.
Q, 29. State Kohlrausch law of independent
a and explain two applications of electrochemical
series.
a l/tSWrite
Write unit of cell constant.
PaC
Q. 30. Define:

GU ) Intensive property
Enthalpy ofsublimation
p7)
2 moles of an ideal gas are expanded isothermally and reversibly
P70
from 20L to 30L at 300K
Calculate the work done.
[R 8.314 JK mol

Q. 31. Define mineral.

Y P Write IUPAC name of[ Fe (CO),] complex.
How will you convert

P)
P a o )
methyl iodide to methyl isocyanide.
Pr-63
() methyl cyanide to ethanoic acid.
O

Page 7