Chapter

2 STRUCTURE OF ATOM

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Analysis of NEET and AIIMS (Year 2010-2018)

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3 AIPMT/NEET

AIIMS
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0
2010 2011 2012 2013 2014 2015 2016 2017 2018
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Analysis of JEE Main and BITSAT (Year 2010-2018)

4
JEE Main
Number of Questions

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Chapter Utility Score (CUS)

Exam Weightage Important Concepts Difficulty Level CUS (Out of 10)
NEET 2 Bohr’s model for hydrogen
AIIMS 2 atom, Quantum mechanical 4/5 8.1
JEE Main 3 model, Schrodinger wave
BITSAT 2 equation, Shape of orbitals
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Exercise 1 : Topic-wise MCQs

10. Neutron is discovered by
Topic 1: Sub-Atomic Particles
(a) Chadwick (b) Rutherford
1. Which of the scientist were able to prove that atom is no (c) Yukawa (d) Dalton
longer non-divisible? 11. What is the ratio of mass of an electron to the mass of a
(a) Dalton (b) Michael Faraday proton?
(c) Thomson (d) Chadwick (a) 1 : 2 (b) 1 : 1 (c) 1 : 1837 (d) 1 : 3
2. Which of the following is never true for cathode rays ? 12. The increasing order for the values of e/m (charge/mass) is
(a) They possess kinetic energy. (a) e, p, n, a (b) n, p, e, a (c) n, p, a, e (d) n, a, p, e
(b) They are electromagnetic waves. 13. In which of the following the amount of deviation from
(c) They produce heat. their path in the presence of electric and magnetic field will
(d) They produce mechanical pressure. be maximum?
3. While performing cathode ray experiments, it was observed (a) N2– (b) N3– (c) N– (d) N
that there was no passage of electric current under normal 14. The deflection of the particles from their path in presence
conditions. Which of the following can account for this of electric and magnetic field will be maximum in which of
observation ? the following.
(a) Dust particles are present in air (a) O (b) N (c) U (d) He
(b) Carbon dioxide is present in air 15. Which of the following pairs have identical values of e/m?
(c) Air is a poor conductor of electricity under normal (a) A proton and a neutron
conditions (b) A proton and deuterium
(d) None of the above (c) Deuterium and an a-particle
4. Which is not true with respect to cathode rays? (d) An electron and g-rays
(a) A stream of electrons Topic 2: Atomic Models
(b) Charged particles
(c) Move with speed same as that of light 16. Rutherford’s experiment on the scattering of a -particles
(d) Can be deflected by magnetic fields showed for the first time that the atom has :
5. What is the optimum conditions required to study the (a) electrons (b) protons (c) nucleus (d) neutrons'
conduction of electricity through gases. 17. When atoms are bombarded with alpha particles, only, a
(a) High pressure and low voltage few in million suffer deflection, others pass out undeflected.
(b) High pressure and high voltage This is because
(c) Low pressure and high voltage (a) the force of repulsion on the moving alpha particle is small
(d) Low pressure and low voltage (b) the force of attraction between alpha particle and
6. In discharge tube experiment stream of negatively charged oppositely charged electrons is very small
particles travel from (c) there is only one nucleus and large number of electrons
(a) anode to cathode (b) cathode to anode (d) the nucleus occupies much smaller volume compared
(c) Both (a) and (b) (d) Electrons does not travel to the volume of the atom
7. Millikan performed an experiment method to determine 18. Rutherford’s a-particle dispersion experiment concludes
which of the following? (a) all positive ions are deposited at small part
(a) Mass of the electron (b) Charge of the electron (b) all negative ions are deposited at small part
(c) e/m ratio of electron (d) Both (a) and (b) (c) proton moves around the electron
8. Which is correct statement about proton? (d) neutrons are charged particles.
(a) Proton is nucleus of deuterium 19. Which of the following scientists explained his model on
(b) Proton is a-particle the basis of centrifugal force ?
(c) Proton is ionized hydrogen molecule (a) Thomson (b) Dalton
(d) Proton is ionized hydrogen atom (c) Millikan (d) Rutherford
9. When beryllium is bombarded with alpha particles (Chadwick’s 20. Which of the following does not contain number of neutrons
40
equal to that of 18
experiment) extremely penetrating radiations, which cannot Ar ?
be deflected by electrical or magnetic field are given out. These (a) 19 41 (b) 43 (c) 40 (d) 42
K 21 Sc 21 Sc 20 Ca
are : 21. Number of protons, neutrons and electrons in the element
(a) A beam of protons 231
89 X is
(b) Alpha rays
(c) A beam of neutrons (a) 89, 89, 242 (b) 89, 142, 89
(d) A beam of neutrons and protons (c) 89, 71, 89 (d) 89, 231, 89
STRUCTURE OF ATOM 17

22. Which of the following pairs will have same chemical (c) Radiation ener gy is n ot emitted or absorbed
properties ? continuously but in the form of small packets called
14 and 15
quanta
(a) 6 C 7 N (b) O2– and F– (d) This magnitude of energy associated with a quantum
(c) 40 40 35 37 is proportional to the frequency.
18 Ar and 19 K (d) 17 Cl and 17 Cl
23. What is the difference between two species if one has 31. The value of Planck's constant is 6.63 × 10–34 Js. The velocity
atomic mass = 14 and atomic number = 7 whereas the of light is 3.0 × 108 m s–1. Which value is closest to the
other has atomic mass = 14 and atomic number = 6? wavelength in nanometers of a quantum of light with frequency
(a) Neutrons (b) Protons of 8 × 1015 s–1 ?
(c) Electrons (d) All of these (a) 3 × 107 (b) 2 × 10–25 (c) 5 × 10–18 (d) 4 × 101
24. From the data given below A, B, C and D respectively are, 32. In the photo-electron emission, the energy of the emitted
electron is
(A) 10 e–, atomic no. 11 (B) 10 e–, atomic no. 6
(C) 10 e–, atomic no. 10 (D) 10 e–, atomic no. 9 (a) greater than the incident photon
(a) Na+, C4–, Ne, F– (b) C4–, Ne, Na–, F– (b) same as than of the incident photon
(c) F–, Na+, Ne, C4– (d) F–, Na+, C4–, Ne (c) smaller than the incident photon
25. Match the columns. (d) proportional to the intensity of incident photon
Column-I Column-II 33. In photoelectric effect, at which frequency electron will be
ejected with certain kinetic energy (n 0 = threshold
1 2
(A) 1 H, 1 H and 13 H (p) Isobars frequency).
14 14
(a) n > n0 (b) n0 > n (c) n0 ³ n (d) n ³ n0
(B) 6C and 7N (q) Isotopes 34. Which of the following statements are not correct about
(C) Na+ and Mg2+ (r) Isoelectronic species electromagnetic radiation ?
(a) A – (p), B – (q), C – (r) (i) Electromagnetic waves require medium to travel.
(b) A – (q), B – (p), C – (r) (ii) Different electromagnetic radiations travel at same
(c) A – (r), B – (q), C – (p) speed in vaccum.
(d) A – (p), B – (r), C – (q) (iii) The oscillating electric and magnetic fields produced
26. Chlorine exists in two isotopic forms, C1-37 and C1-35 but by oscillating charged particles are perpendicular to
its atomic mass is 35.5. This indicates the ratio of C1-37 and each other, but not to the direction of propagation.
C1-35 is approximately (iv) The oscillating electric field and magnetic field are
(a) 1 : 2 (b) 1 : 1 (c) 1 : 3 (d) 3 : 1 perpendicular to each other, and also to the direction
27. The number of electrons, neutrons and protons in a species of propagation.
are equal to 10, 8 and 8 respectively. The proper symbol of (a) (i), (ii) and (iii) (b) (ii) and (iii)
the species is (c) (i) and (iii) (d) (i) and (iv)
(a) 16O 8 (b) 18O 8 (c) 18Ne 10 (d) 16O82– 35. Which of the following statement(s) is/are incorrect
28. Assertion : All isotopes of a given element show the same regarding photoelectric effect?
type of chemical behaviour. (i) The number of electrons ejected is proportional to the
Reason : The chemical properties of an atom are controlled intensity of light.
by the number of electrons in the atom. (ii) There is some time lag between the striking of light
(a) Assertion is correct, reason is correct; reason is a beam on the metal surface and the ejection of electrons.
correct explanation for assertion. (iii) The kinetic energy of ejected electrons depends upon
(b) Assertion is correct, reason is correct; reason is not a the brightness of light.
correct explanation for assertion (iv) The kinetic energy of the ejected electron is
(c) Assertion is correct, reason is incorrect proportional to the frequency of the incident radiation.
(d) Assertion is incorrect, reason is correct. (a) (i) and (ii) (b) (ii) and (iii)
(c) (ii) only (d) (ii) and (iv)
Topic 3: Developments Leading to the Bohr’s Model of Atom
36. Assertion : Black body is an ideal body that emits and
29. If the wavelength of the electromagnetic radiation is absorbs radiations of all frequencies.
increased to thrice the digital value, then what will be the Reason : The frequency of radiation emitted by a body goes
percent change in the value of frequency of the from a lower frequency to higher frequency with an increase
electromagnetic radiation. in temperature.
(a) Increases by 33% (b) Decreases by 33% (a) Assertion is correct, reason is correct; reason is a
(c) Increases by 66% (d) Decreases by 66%
correct explanation for assertion.
30. Which one of the following is not the characteristic of
Planck’s quantum theory of radiation ? (b) Assertion is correct, reason is correct; reason is not a
(a) The energy is not absorbed or emitted in whole number correct explanation for assertion
or multiple of quantum (c) Assertion is correct, reason is incorrect
(b) Radiation is associated with energy (d) Assertion is incorrect, reason is correct.
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37. What will be the difference between electromagnetic 45. The third line of the Balmer series, in the emission spectrum
radiation shown in A and B respectively ? of the hydrogen atom, is due to the transition from the
(a) fourth Bohr orbit to the first Bohr orbit
(b) fifth Bohr orbit to the second Bohr orbit
(A) (c) sixth Bohr orbit to the third Bohr orbit
(d) seventh Bohr orbit to the third Bohr orbit
46. Which one of the following pairs is not correctly matched ?
(a) Rutherford-Proton (b) J.J. Thomson-Electron
(c) J.H. Chadwick-Neutron (d) Bohr-Isotopes
(B) 47. If r is the radius of the first orbit, the radius of nth orbit of
H-atom is given by
(a) rn2 (b) rn (c) r/n (d) r2 n2
(i) Velocity (ii) Wavelength 48. The radius of hydrogen atom in the ground state is 0.53 Å.
(iii) Frequency (iv) Energy The radius of Li2+ ion (atomic number = 3) in a similar state is
(a) (ii) only (b) (ii) and (iv) (a) 0.17 Å (b) 0.265 Å (c) 0.53 Å (d) 1.06 Å
(c) (ii), (iii) and (iv) (d) (iv) only 49. The energy of an electron in the nth Bohr orbit of hydrogen
38. Arrange the electromagnetic radiations a, b, c, d and e in atom is
increasing order of energy. Frequencies of a, b and c are 13.6 13.6
1015, 1014 and 1017 respectively whereas wavelength of (a) – 4 eV (b) – 3 eV
n n
(d) and (e) are 350 nm and 100 nm respectively ?
(a) a, b, c, d, e (b) a, b, d, e, c 13.6 13.6
(c) – 2 eV (d) – eV
(c) a, d, b, e, c (d) b, d, a, e, c n n
39. A 600 W mercury lamp emits monochromatic radiation of 49. The energy of second Bohr orbit of the hydrogen atom
wavelength 331.3 nm. How many photons are emitted from is -328 kJ mol -1; hence the energy of fourth Bohr orbit
the lamp per second ? (h = 6.626 × 10–34 Js; velocity of light would be:
= 3 × 108 ms–1) (a) -41 kJ mol-1 (b) -82 kJ mol-1
(a) 1 × 1019 (b) 1 × 1020 (c) 1 × 1021 (d) 1 × 1023 (c) -164 kJ mol-1 (d) -1312 kJ mol-1
40. Calculate the velocity of ejected electron from the metal 50. The energy of an electron in second Bohr orbit of hydrogen
surface when light of frequency 2 × 1015 Hz fall on the atom is :
metal surface and the threshold frequency is 7 × 1014 Hz (a) –5.44 × 10–19 eV (b) –5.44 × 10–19 cal
for metal ? –19
(c) –5.44 × 10 kJ (d) –5.44 × 10–19 J
(a) 1.37 × 106 (b) 1.26 × 106
(c) 1.45 × 107 (d) 1.37 × 107 51. The ionisation potential of a hydrogen atom is –13.6 eV.
What will be the energy of the atom corresponding to n = 2.
Topic 4: Bohr’s Model for Hydrogen Atom (a) – 3.4 eV (b) – 6.8 eV (c) – 1.7 eV (d) –2.7 eV
41. In continous spectrum light of _(i)
___ wavelength is deviated 52. The line spectrum of He+ ion will resemble that of
the ___
ii (a) hydrogen atom (b) Li+ ion
(a) (i) = longest, least (b) (ii) = shortest, least (c) helium atom (d) lithium atom
(c) (i) = shortest, most (d) (i) = longest, most 53. What does negative sign in the electronic energy for
42. An electron from one Bohr stationary orbit can go to next hydrogen atom convey.
higher orbit (a) Energy of electron when n = ¥
(a) by emission of electromagnetic radiation
(b) The energy of electron in the atom is lower than the
(b) by absorption of any electromagnetic radiation
energy of a free electron in motion
(c) by absorption of electromagnetic radiation of particular
frequency (c) The energy of electron in the atom is lower than the
(d) without emission or absorption of electromagnetic energy of a free electron of rest
radiation (d) The energy of electron decreases as it moves away
43. For a Bohr atom angular momentum M of the electron is from nucleus
(n = 0, 1, 2, .....) : 54. In which of the following Bohr’s stationary state, the
electron will be at maximum distance from the nucleus ?
nh 2 2 2 nh2 nh
(a) (b) n h (c) (d) (a) IInd (b) Ist (c) Vth (d) IIIrd
4p 4p 4p 2p 55. The wavelength of the radiation emitted, when in a hydrogen
44. According to Bohr's theory, the angular momentum of an atom electron falls from infinity to stationary state 1, would
electron in 5th orbit is be (Rydberg constant = 1.097×107 m–1)
(a) 10 h / p (b) 2.5 h / p (c) 25 h / p (d) 1.0 h / p (a) 406 nm (b) 192 nm (c) 91 nm (d) 9.1×10–8 nm
STRUCTURE OF ATOM 19

56. The frequency of radiation emitted when the electron falls 66. For Balmer series in the spectrum of atomic hydrogen, the
from n = 4 to n = 1 in a hydrogen atom will be (Given :
ionization energy of H=2.18 ×10 –18J atom –1 and h æ 1 1 ö
= 6.625 × 10–34 J s ) wave number of each line is given by v = R H çç 2 – 2 ÷÷
è n1 n2 ø
(a) 1.54 × 1015 s–1 (b) 1.03 × 1015 s–1
where RH is a constant and n1 and n2 are integers. Which of
(c) 3.08 × 1015 s–1 (d) 2.00 × 1015 s–1
the following statement(s) is (are) correct?
57. Which of the following transitions of electrons in the
hydrogen atom will emit maximum energy ? (i) As wavelength decreases, the lines in the series
(a) n5 ® n4 (b) n4 ® n3 converge.
(c) n3 ® n2 (d) all will emit same energy (ii) The integer n1 is equal to 2.
58. According to the Bohr theory, which of the following (iii) The ionization energy of hydrogen can be calculated
transitions in the hydrogen atom will give rise to the least from the wave number of these lines.
energetic photon ? (iv) The line of longest wavelength corresponds to n2 = 3.
(a) n = 6 to n = 1 (b) n = 5 to n = 4 (a) (i), (ii) and (iii) (b) (ii), (iii) and (iv)
(c) n = 6 to n = 5 (d) n = 5 to n = 3 (c) (i), (i) and (iv) (d) (ii) and (iv)
59. The wavelength (in cm) of second line in the Lyman series
67. Assertion : The radius of the first orbit of hydrogen atom is
of hydrogen atomic spectrum is (Rydberg constant 0.529Å.
= R cm–1)
Reason : Radius of each circular orbit (rn) = 0.529Å (n2/Z),
æ 8R ö æ 9 ö æ 4 ö æ 3R ö where n = 1, 2, 3 and Z = atomic number.
(a) ç ÷ (b) ç ÷ (c) ç ÷ (d) ç ÷
è 9 ø è 8R ø è 3R ø è 4 ø (a) Assertion is correct, reason is correct; reason is a
60. The shortest wavelength in hydrogen spectrum of Lyman correct explanation for assertion.
series when RH = 109678 cm–1 is (b) Assertion is correct, reason is correct; reason is not a
(a) 1002.7 Å (b) 1215.67 Å correct explanation for assertion
(c) 1127.30 Å (d) 911.7 Å
(c) Assertion is correct, reason is incorrect
61. What is the expression of frequency (n) associated with
(d) Assertion is incorrect, reason is correct.
absorption spectra of the photon.
68. An electron, e1 is moving in the fifth stationary state, and
R æ 1 1 ö another electron e2 is moving in the fourth stationary state.
(a) n= H ç 2 - 2 ÷ ni > nf The radius of orbit of electron, e1 is five times the radius of
h çn ÷
è i nf ø orbit of electron, e2 calculate the ratio of velocity of electron
RH æ 1 1 ö e1 (v1) to the velocity of electron e2 (v2).
(b) n= ç 2 - 2 ÷ nf > ni (a) 5 : 1 (b) 4 : 1 (c) 1 : 5 (d) 1 : 4
h çn ÷
è i nf ø 69. The Li2+ ion is moving in the third stationary state, and its
linear momentum is 7.3 × 10–34 kgms–1. Angular momentum
RH æ 1 1 ö
(c) n=– ç 2 - 2 ÷ nf > ni is.
h çn ÷ (a) 1.158 × 10–45 kg m2s–1 (b) 11.58 × 10–48 kg m2s–1
è i nf ø
(d) All the above are correct (c) 11.58 × 10–47 kg m2s–1 (d) 12 × 10–45 kg m2s–1
62. Bohr model can explain : 70. The Bohr orbit radius for the hydrogen atom (n = 1) is
(a) the solar spectrum approximately 0.530 Å. The radius for the first excited state
(b) the spectrum of hydrogen molecule (n = 2) orbit is (in Å)
(c) spectrum of any atom or ion containing one electron (a) 0.13 (b) 1.06 (c) 4.77 (d) 2.12
only 71. According to Bohr’s theory the energy required for an
(d) the spectrum of hydrogen atom only
electron in the Li2+ ion to be emitted from n = 2 state is
63. Which of the following statements do not form a part of
(given that the ground state ionization energy of hydrogen
Bohr’s model of hydrogen atom ?
atom is 13.6 eV)
(a) Energy of the electrons in the orbits are quantized
(b) The electron in the orbit nearest the nucleus has the (a) 61.2 eV (b) 13.6 eV (c) 30.6 eV (d) 10.2 eV
lowest energy 72. Among species H, Li2+, He+, Be3+ and Al3+ Bohr’s model
(c) Electrons revolve in different orbits around the nucleus was able to explain the spectra of
(d) The position and velocity of the electrons in the orbit (a) All of these
cannot be determined simultaneously. (b) None of these
64. Bohr’s theory can be applied to which of the following ions. (c) all other species except Be3+
(a) Na+ (b) Be2+ (c) Li+ (d) Li2+ (d) all other species except Al3+
65. Bohr’s model is not able to account for which of the
following. Topic 5: Towards Quantum Mechanical Model of the Atom
(a) Stability of atom. 73. If electron, hydrogen, helium and neon nuclei are all moving
(b) Spectrum of neutral helium atom. with the velocity of light, then the wavelength associated
(c) Energy of free electron at rest.
with these particles are in the order
(d) Calculation of radii of the stationary states.
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(a) Electron > hydrogen > helium > neon (a) H < Be, B < Li < K. (b) H > Li > K > Be > B
(b) Electron > helium > hydrogen > neon (c) H > Li > Be > B > K (d) H < Li < Be < B < K
(c) Electron < hydrogen < helium < neon 84. The velocity of particle A is 0.1 ms–1 and that of particle B is
(d) Neon < hydrogen < helium < electron 0.05 ms–1. If the mass of particle B is five times that of particle
74. The de Broglie wavelength of a tennis ball of mass 60 g A, then the ratio of de-Broglie wavelengths associated with
moving with a velocity of 10 metres per second is the particles A and B is
approximately (a) 2 : 5 (b) 3 : 4 (c) 6 : 4 (d) 5 : 2
(a) 10–31 metres (b) 10–16 metres 85. Two fast moving particles X and Y are associated with
(c) 10–25 metres (d) 10–33 metres de Broglie wavelengths 1 nm and 4 nm respectively. If mass
Planck’s constant, h = 6.63 × 10–34 Js of X in nine times the mass of Y, the ratio of kinetic energies
75. If the energy difference between the ground state of an of X and Y would be
atom and its excited state is 4.4 × 10–4 J, the wavelength of (a) 3 : 1 (b) 9 : 1 (c) 5 : 12 (d) 16 : 9
photon required to produce the transition : 86. Uncertainty in position of an electron (mass = 9.1 × 10–28 g)
(a) 2.26 × 10–12 m (b) 1.13 × 10–22 m moving with a velocity of 3 × 104 cm/s accurate upto 0.001%
(c) 4.52 × 10 m –16 (d) 4.52 × 10–22 m will be (use h/4p) in uncertainty expression where
76. The mass of a photon with a wavelength equal to h = 6.626 ×10–27 erg-second).
1.54 × 10–8 cm is (a) 1.93 cm (b) 3.84 cm (c) 5.76 cm (d) 7.68 cm
(a) 0.8268 × 10–34 kg (b) 1.2876 × 10–33 kg 87. The measurement of the electron position is associated with
(c) 1.4285 × 10 kg –32 (d) 1.8884 × 10–32 kg an uncertainty in momentum, which is equal to
77. The values of Planck's constant is 6.63 × 10–34 Js. The 1×10–18 g cm s–1. The uncertainty in electron velocity is,
velocity of light is 3.0 × 108 m s–1. Which value is closest to (mass of an electron is 9 × 10– 28 g)
the wavelength in nanometres of a quantum of light with (a) 1 × 109 cm s–1 (b) 1 × 106 cm s–1
frequency of 8 × 1015 s–1? (c) 1 × 105 cm s–1 (d) 1 × 1011 cm s–1
(a) 5 × 10–18 (b) 4 × 101 (c) 3 × 107 (d) 2 × 10–25 88. In an atom, an electron is moving with a speed of 600 m/s
78. The de Broglie wavelength of a car of mass 1000 kg and with an accuracy of 0.005%. Certainity with which the
velocity 36 km/hr is : position of the electron can be located is ( h = 6.6 × 10–34 kg
(a) 6.626 × l0–34 m (b) 6.626 × 10–38 m m2s–1, mass of electron, em = 9.1 × 10–31 kg)
(c) 6.626 × 10–31 m (d) 6.626 × 10– 30 m (a) 5.10 × 10 –3 m (b) 1.92 × 10 –3 m
79. Heisenberg's uncertainity principle is applicable to (c) 3.84 × 10 m –3 (d) 1.52 × 10 –4 m
(a) atoms only (b) electron only
Topic 6: Quantum Mechanical Model of Atom
(c) nucleus only (d) any moving object
80. The position of both, an electron and a helium atom is 89. The orientation of an atomic orbital is governed by
known within 1.0 nm. Further the momentum of the (a) Spin quantum number
electron is known within 5.0 × 10–26 kg ms–1. The minimum (b) Magnetic quantum number
uncertainty in the measurement of the momentum of the (c) Principal quantum number
helium atom is (d) Azimuthal quantum number
(a) 50 kg ms–1 (b) 80 kg ms–1 90. For which one of the following sets of four quantum
–26
(c) 8.0 × 10 kg ms –1 (d) 5.0 × 10–26 kg ms–1 numbers, an electron will have the heighest energy?
81. The Heisenberg uncertainity principle will be most n l m s
significant for which of the following object ? (a) 3 2 1 1/2
(a) Object A of mass 9.11 × 10–30 kg
(b) 4 2 –1 1/2
(b) Object B of mass 9.11 × 10–28 g
(c) 4 1 0 –1/2
(c) Object C of mass 9.11 × 10–24 mg
(d) Object D of mass 9.11 × 10–28 kg (d) 5 0 0 –1/2
82. Assertion : The position of an electron can be determined 91. Which of the following sets of quantum numbers is correct
exactly with the help of an electron microscope. for an electron in 4f orbital ?
Reason : The product of uncertainty in the measurement of (a) n = 4, l = 3, m = + 1, s = + ½
its momentum and the uncertainty in the measurement of (b) n = 4, l = 4, m = – 4, s = – ½
the position cannot be less than a finite limit. (c) n = 4, l = 3, m = + 4, s = + ½
(a) Assertion is correct, reason is correct; reason is a (d) n = 3, l = 2, m = – 2, s = + ½
correct explanation for assertion. 92. What is the correct orbital designation of an electron with
(b) Assertion is correct, reason is correct; reason is not a the quantum number, n = 4, l = 3, m = – 2, s = 1/2 ?
correct explanation for assertion (a) 3s (b) 4 f (c) 5p (d) 6s
(c) Assertion is correct, reason is incorrect 93. Which of the following represents correct set of the four
(d) Assertion is incorrect, reason is correct. quantum numbers for an electron in a 4d subshell ?
83. Arrange the following elements in the order of ease of
(a) 4, 2, 1, 0 (b) 4, 2, 1, – 1/2
detection of wave properties, in the de Broglie experiment.
(c) 4, 3, 2, + 1/2 (d) 4, 3, – 2, – 1/2
H, Li, Be, B, K
STRUCTURE OF ATOM 21

94. The total number of electrons that can be accommodated in 102. If there are five radial nodes, then what can be the correct
all orbitals having principal quantum number 2 and azimuthal representation of the orbital for n = 8.
quantum number 1 is (a) 8 d (b) 8 s (c) 8 p (d) 8 f
(a) 2 (b) 4 (c) 6 (d) 8 103. What can be the representation of the orbital having 3
angular nodes and n = 5.
95. Which of the following is not permissible arrangement of
electrons in an atom? (a) 5 d (b) 5 f (c) 5 p (d) 5 s
104. The number of orbitals present in the fifth shell will be
(a) n = 5, l = 3, m = 0, s = + 1/2
(a) 25 (b) 10 (c) 50 (d) 20
(b) n = 3, l = 2, m = – 3, s = – 1/2 105. The electronic configuration of gadolinium (Atomic number
(c) n = 3, l = 2, m = – 2, s = – 1/2 64) is
(d) n = 4, l = 0, m = 0, s = – 1/2 (a) [Xe] 4f 8 5d 0 6s2 (b) [Xe] 4f 3 5d 5 6s2
96. Which of the following sets of quantum numbers represents (c) [Xe] 4f 6 5d 2 6s2 (d) [Xe] 4f 7 5d 1 6s2
the highest energy of an atom? 106. The number of d-electrons retained in Fe2+
(At. no. of Fe = 26) ion is
(a) n = 3, l = 0, m = 0, s = +1/2
(a) 4 (b) 5 (c) 6 (d) 3
(b) n = 3, l = 1, m = 1, s = +1/2 107. The electronic configuration of an element is 1s2, 2s2 2p6,
(c) n = 3, l = 2, m = 1, s = +1/2 3s2 3p6 3d 5, 4s1. This represents its
(d) n = 4, l = 0, m = 0, s = +1/2 (a) excited state (b) ground state
97. Which set of quantum numbers are not possible? (c) cationic form (d) anionic form
n l m s 108. In a given atom no two electrons can have the same values
for all the four quantum numbers. This is called
(a) 3 2 0 +1/2 (a) Hund’s Rule (b) Aufbau principle
(b) 2 2 1 +1/2 (c) Uncertainty principle (d) Pauli’s exclusion principle
(c) 1 0 0 –1/2 109. The electronic configuration of Cu (atomic number 29) is
(d) 3 2 –2 +1/2 (a) 1s 2 , 2 s 2 2 p 6 ,3s 2 3 p 6 , 4 s 2 3d 9
98. What will be the sum of all possible values of l and m for (b) 1s 2 ,2 s 2 2 p 6 ,3s 2 3 p 6 3d 10 , 4 s1
n=5?
(c) 1s2 ,2s2 2 p6 ,3 p 2 3 p 6 ,4s2 4 p6 ,5s2 5 p1
(a) 12 (b) 13 (c) 4 (d) 9
99. The following quantum numbers are possible for how many (d) 1s 2 , 2 s 2 2 p 6 ,3 p 2 3 p 6 , 4 s 2 4 p 6 3d 3
orbital(s) n = 3, l = 2, m = +2 ? 110. The orbital diagram in which the Aufbau principle is violated is :
2s 2p 2s 2p
(a) 1 (b) 3 (c) 2 (d) 4
100. The orbitals are called degenerate when (a) ­¯ ­¯ ­ (b) ­ ­¯ ­ ­
(a) they have the same wave functions
(b) they have the same wave functions but different (c) ­¯ ­ ­ ­ (d) ­¯ ­¯ ­ ­
energies 111. Maximum number of electrons in a subshell of an atom is
(c) they have different wave functions but same energy determined by the following:
(d) they have the same energy (a) 2 l + 1 (b) 4 l – 2 (c) 2 n2 (d) 4 l + 2
112. The correct order of increasing energy of atomic orbitals is
101. Which of the following graph correspond to one node
(a) 5 p < 4 f < 6 s < 5 d (b) 5 p < 6 s < 4 f < 5 d
(c) 5 p < 5 d < 4 f < 6 s (d) None of these
113. For which element, the valence electron will be present in
Y Y the highest energy orbital.
(a) (b) (a) 3Li (b) 16S (c) 20Ca (d) 21Sc
114. Which of the following electronic configuration of d-orbital
a0 will have highest affinity for gaining an electron?
a0
(a)

Y
Y (b)
(c) (d)
(c)
a0
a0
(d)
 EBD_7374
22 CHEMISTRY

115. Match the columns. 119. Match the columns.

Column-I Column-II Column-I Column-II

(A) Y 2 (p) Energy can be emitted z

or absorbed in packets
(B) de Broglie (q) Significant only for
motion of microscopic (A) dx2 – y2 (p)
objects.
(C) Heisenberg’s (r) The probability of y x
finding an electron at a
point within an atom
(D) Planck’s (s) Every object in motion z
has a wave character.
(a) A – (q), B – (s), C – (r), D – (p)
(b) A – (r), B – (p), C – (q), D – (s) (B) dxy (q)
(c) A – (r), B – (s), C – (q), D – (p)
(d) A – (s), B – (p), C – (r), D – (q) y x
116. Match the columns.
Column-I Column-II
(Quantum number) (Information provided) z

(A) Principal (p) orientation of the orbital

quantum number
(C) dyz (r)
(B) Azimuthal (q) energy and size of orbital
quantum number
x
(C) Magnetic (r) spin of electron y
quantum number
(D) Spin quantum (s) shape of the orbital z
number
(a) A – (q), B – (s), C – (p), D – (r)
(b) A – (s), B – (q), C – (p), D – (r) (D) dz2 (s)
(c) A – (q), B – (p), C – (s), D – (r)
(d) A – (q), B – (s), C – (r), D – (p) x
y
117. Which of the following sets of quantum numbers is correct?
(a) n = 5, l = 4, m = 0, s = + ½ (a) A – (p), B – (s), C – (r), D – (q)
(b) n = 3, l = 3, m = +3, s = + ½ (b) A – (s), B – (p), C – (r), D – (q)
(c) n = 6, l = 0, m = +1, s = – ½ (c) A – (s), B – (p), C – (q), D – (r)
(d) n = 4, l = 2, m = +2, s = 0 (d) A – (s), B – (r), C – (p), D – (q)

118. Which combinations of quantum numbers, n, l , m and s for 120. The five d-orbitals are designated as d xy , d yz , d xz , d
x2 - y2
the electron in an atom does not provide a permissible and d 2. Choose the correct statement
solution of the wave equation ? z
(a) The shapes of the first three orbitals are similar but
1 1 that of the fourth and fifth orbitals are different
(a) 3, 2,1, (b) 3,1,1, - (b) The shapes of all five d-orbitals are similar
2 2
(c) The shapes of the first four orbitals are similar but that
1 1 of the fifth orbital is different
(c) 3, 3,1, - (d) 3, 2, - 2,
2 2 (d) The shapes of all five d-orbitals are different
STRUCTURE OF ATOM 23

Exercise 2 : Exemplar & Past Year MCQs

NCERT Exemplar MCQs 6. Which of the following properties of atom could be
explained correctly by Thomson model of atom?
1. Which of the following conclusions could not be derived (a) Overall neutrality of atom
from Rutherford's a-particle scattering experiment? (b) Spectra of hydrogen atom
(a) Most of the space in the atom is empty. (c) Position of electrons, protons and neutrons in atom
(b) The radius of the atom is about 10–10 m while that of (d) Stability of atom
nucleus is 10–15 m. 7. Two atoms are said to be isobars if
(c) Electrons move in a circular path of fixed energy called (a) they have same atomic number but different mass
orbits. number
(d) Electrons and the nucleus are held together by (b) they have same number of electrons but different
electrostatic forces of attraction. number of neutrons
2. Which of the following options does not represent ground (c) they have same number of neutrons but different
state electronic configuration of an atom? number of electrons
(a) 1s22s22p63s23p63d 84s2 (d) sum of the number of protons and neutrons is same
(b) 1s22s22p63s23p63d 94s2 but the number of protons is different
(c) 1s22s22p63s23p63d104s1 8. The number of radial nodes for 3p orbital is ......... .
(d) 1s22s22p63s23p63d 54s1 (a) 3 (b) 4 (c) 2 (d) 1
3. The probability density plots of 1s and 2s orbitals are given 9. Number of angular nodes for 4d orbital is ........... .
in figure. (a) 4 (b) 3 (c) 2 (d) 1
10. Which of the following is responsible to rule out the
existence of definite paths or trajectories of electrons?
1s (a) Pauli's exclusion principle
2s (b) Heisenberg's uncertainty principle
The density of dots in a region represents the probability (c) Hund's rule of maximum multiplicity
density of finding electrons in the region. (d) Aufbau principle
11. Total number of orbitals associated with third shell will
On the basis of above diagram which of the following
be ............... .
statements is incorrect?
(a) 2 (b) 4 (c) 9 (d) 3
(a) 1s and 2s orbitals are spherical in shape.
12. Orbital angular momentum depends on ............ .
(b) The probability of finding the electron is maximum near
(a) l (b) n and l (c) n and m (d) m and s
the nucleus.
13. Chlorine exists in two isotopic forms Cl-37 and Cl-35, but
(c) The probability of finding the electron at a given its atomic mass is 35.5. This indicates the ratio of Cl-37 and
distance is equal in all directions. Cl-35 is approximately
(d) The probability density of electrons for 2s orbital (a) 1 : 2 (b) 1 : 1 (c) 1 : 3 (d) 3 : 1
decreases uniformly as distance from the nucleus 14. The pair of ions having same electronic configuration
increases. is .............. .
4. Which of the following statement is not correct about the (a) Cr3+, Fe3+ (b) Fe3+, Mn2+
characteristics of cathode rays? (c) Fe , Co 3+ 3+ (d) Sc3+, Cr 3+
(a) They start from the cathode and move towards the 15. For the electrons of oxygen atom, which of the following
anode. statements is correct?
(b) They travel in straight line in the absence of an external (a) Zeff for an electron in a 2s orbital is the same as Zeff for
electrical or magnetic field. an electron in a 2p orbital.
(c) Characteristics of cathode rays do not depend upon (b) An electron in the 2s orbital has the same energy as an
the material of electrodes in cathode ray tube. electron in the 2p orbital.
(d) Characteristics of cathode rays depend upon the (c) Zeff for an electron in 1s orbital is the same as Zeff for an
nature of gas present in the cathode ray tube. electron in a 2s orbital.
5. Which of the following statements about the electron is (d) The two electrons present in the 2s orbital have spin
incorrect? quantum numbers ms but of opposite sign.
(a) It is a negatively charged particle. 16. If travelling at same speeds, which of the following matter
(b) The mass of electron is equal to the mass of neutron. waves have the shortest wavelength?
(c) It is a basic constituent of all the atoms. (a) Electron (b) Alpha particle (He2+)
(d) It is a constituent of cathode rays. (c) Neutron (d) Proton
 EBD_7374
24 CHEMISTRY

Past Year MCQs 26. A stream of electrons from a heated filaments was passed
two charged plates kept at a potential difference V esu. If
17. What is the maximum number of orbitals that can be identified
e and m are charge and mass of an electron, respectively,
with the following quantum numbers?
then the value of h/l (where l is wavelength associated
n = 3, l = 1, ml = 0 [AIPMT 2014, A] with electron wave) is given by: [JEE M 2016, S]
(a) 1 (b) 2 (c) 3 (d) 4
(a) meV (b) 2meV (c) meV (d) 2meV
18. Calculate the energy in joule corresponding to light of
wavelength 45 nm : 27. An e– has magnetic quantum number as –3, what is its
principal quantum number? [BITSAT 2016, A]
(Planck’s constant h = 6.63 × 10 –34 Js; speed of light
(a) 1 (b) 2 (c) 3 (d) 4
c = 3 × 108 ms–1) [AIPMT 2014, A]
28. The first emission line in the atomic spectrum of hydrogen
(a) 6.67 × 1015 (b) 6.67 × 1011
in the Balmer series appears at [BITSAT 2016, S]
(c) 4.42 × 10–15 (d) 4.42 × 10–18
19. In hydrogen atomic spectrum, a series limit is found at 9R 7R
(a) cm -1 (b) cm -1
12186.3 cm–1. Then it belong to [AIIMS 2014, C] 400 144
(a) Lyman series (b) Balmer series
3R 5R
(c) Paschen series (d) Brackett series (c) cm -1 (d) cm -1
20. The correct set of four quantum numbers for the valence 4 36
electrons of rubidium atom (Z = 37) is: [JEE M 2014, S] 29. Which one is the wrong statement ? [NEET 2017, C]
(a) The uncertainty principle is DE ´ Dt ³ h / 4p
1 1
(a) 5, 0, 0, + (b) 5,1, 0, + (b) Half filled and fully filled orbitals have greater stability
2 2
due to greater exchange energy, greater symmetry and
1 1 more balanced arrangement.
(c) 5,1,1, + (d) 5, 0,1, +
2 2 (c) The energy of 2s orbital is less than the energy of
21. For azimuthal quantum number l = 3, the maximum number 2p orbital in case of Hydrogen like atoms
of electrons will be [BITSAT 2014, C] h
(a) 2 (b) 6 (c) 0 (d) 14. (d) de-Broglies's wavelength is given by l = ,
mn
æ Z2 ö where m = mass of the particle, n = group velocity of
22. Based on equation E = – 2.178 × 10-18 J çç 2 ÷÷ , certain the particle
èn ø 30. In Bohr series of lines of hydrogen spectrum, the third line
conclusions are written. Which of them is not correct ? from the red end corresponds to which one of the following
[AIIMS 2015, C] inter-orbit jumps of the electron for Bohr orbits in an atom
(a) Larger the value of n, the larger is the orbit radius. of hydrogen [AIIMS 2017, S]
(b) Equation can be used to calculate the change in energy (a) 5 ® 2 (b) 4 ® 1 (c) 2 ® 5 (d) 3 ® 2
when the electron changes orbit.
31. The radius of the second Bohr orbit for hydrogen atom is :
(c) For n = 1, the electron has a more negative energy than
it does for n = 6 which mean that the electron is more (Plank's const. h = 6.6262 × 10–34 Js ; mass of
loosely bound in the smallest allowed orbit. electron = 9.1091 × 10–31 kg ; charge of electron
(d) The negative sign in equation simply means that the e = 1.60210 × 10–19 C ; permittivity of vaccum
energy or electron bound to the nucleus is lower than Î0 = 8.854185 × 10–12 kg–1 m–3 A2) [JEE M 2017, A]
it would be if the electrons were at the infinite distance
from the nucleus. (a) 1.65Å (b) 4.76Å (c) 0.529Å (d) 2.12Å
23. Which of the following is the energy of a possible excited 32. The number of radial nodes of 3s and 2p orbitals are
state of hydrogen ? [JEE M 2015, A] respectively
(a) –3.4 eV (b) +6.8 eV (c) +13.6 eV (d) –6.8 eV [BITSAT 2017, C]
24. Two electrons occupying the same orbital are distinguished (a) 2, 0 (b) 0, 2 (c) 1, 2 (d) 2, 2
by [NEET 2016, C] 33. The energy of an electron in second Bohr orbit of hydrogen
(a) Principal quantum number atom is : [BITSAT 2017, A]
(b) Magnetic quantum number (a) –5.44 × 10–19 eV (b) –5.44 × 10–19 cal
(c) Azimuthal quantum number (c) –5.44 × 10–19 kJ (d) –5.44 × 10–19 J
(d) Spin quantum number 34. The angular speed of the electron in n th orbit of Bohr
25. Which transition in the hydrogen atomic spectrum will have hydrogen atom is [NEET 2018, C]
the same wavelength as the transition, n = 4 to n = 2 of He+ (a) Directly proportional to n
spectrum? [AIIMS 2016, A] (b) Inversely proportional of n
(a) n = 4 to n = 3 (b) n = 3 to n = 2 (c) Inversely proportional to n 2
(c) n = 4 to n = 2 (d) n = 2 to n = 1 (d) Inversely proportional to n 3
STRUCTURE OF ATOM 25

35. What is maximum wavelength of line of Balmer series of (a) Assertion is correct, reason is correct; reason is a
hydrogen spectrum (R = 1.09 × 107 m–1) [AIIMS 2018, A] correct explanation for assertion.
(b) Assertion is correct, reason is correct; reason is not a
(a) 400 nm (b) 654 nm correct explanation for assertion.
(c) 486 nm (d) 434 nm (c) Assertion is correct, reason is incorrect.
(d) Assertion is incorrect, reason is correct.
36. Assertion : Threshold frequency is the maximum frequency
required for the ejection of electron from the metal surface. 37. If the Planck’s constant h = 6.6×10–34 Js, the de Broglie
wavelength of a particle having momentum of 3.3 × 10–24
Reason : Threshold frequency is characteristic to a metal. kg ms –1 will be [BITSAT 2018]
[AIIMS 2018, C] (a) 0.002 Å (b) 0.5Å (c) 2Å (d) 500Å

Exercise 3 : Try If You Can

1. Which of the following statement concerning probability
1 m h 1 h m
density ( y 2 ) and radial distribution function (4pr 2 y 2 ) for (a) (b) 10 (c) (d) 10
10 h m 10 m h
a s-orbital of H-like species is correct? 8. A hydrogen-like atom with atomic number Z is in the higher
(a) y 2 is minimum at nucleus but 4pr 2 y 2 is maximum excited state of quantum number n. This excited state atom
at nucleus. can make a transition to the 1st excited state by successively
(b) y 2 is maximum at nucleus but 4pr 2 y 2 is minimum emitting two photons of energies 10 eV and 17eV,
at nucleus. respectively. Alternatively the atom from the same excited
(c) Both y 2 and 4pr 2 y 2 are maximum at nucleus. state can make a transition to 2nd excited state by emitting
(d) Both y 2 and 4pr 2 y 2 are minimum at nucleus. two photons of energies 4.25 eV and 5.95 eV, respectively.
2. If the shortest wavelength of the spectral line of H-atom in Determine Z and n.
the Lyman series is X, then the longest wavelength of the (a) n = 6, Z = 3 (b) n = 3, Z = 6
(c) n = 2, Z = 4 (d) n = 9, Z = 9
line in Balmer series of Li 2+ is
9. In a multi-electron atom, which of the following orbitals
x 5x 4x described by the three quantum members will have the same
(a) 9x (b) (c) (d)
9 4 5 energy in the absence of magnetic and electric fields?
3. A hydrogen atom in the ground state is excited by (A) n = 1, l = 0, m = 0 (B) n = 2, l = 0, m = 0
monochromatic radiation of wavelength l Å. The resulting (C) n = 2, l = 1, m = 1 (D) n = 3, l = 2, m = 1
spectrum consists of maximum 15 different lines. What is (E) n = 3, l = 2, m = 0
the wavelength l? (RH = 109737 cm–1) (a) (D) and (E) (b) (C) and (D)
(a) 937.3 Å (b) 1025 Å (c) (B) and (C) (d) (A) and (B)
(c) 1236 Å (d) None of these 10. 1.5 L He gas is taken at 500K and 560 mm pressure in which
4. If radiation corresponding to second line of "Balmer series" 90% He are converted into He+ ions. Spectral line analysis
of Li2+ ion, knocked out electron from first excited state of shows that 85% ions exist in the 3rd level, 10% in the 2nd
H-atom, then kinetic energy of ejected electron would be: level and rest in the ground level. Calculate the total energy
(a) 2.55 eV (b) 4.25 eV (c) 11.25 eV (d) 19.55 eV evolved when all ions return back to ground state.
5. Li 3+ and a proton are accelerated by the same potential, (a) 106 kJ (b) 957.1 kJ (c) 212 kJ (d) 104.9 kJ
then de-Broglie wavelengths l Li and l p have the ratio 11. If an electron undergoes transition from n = 2 to n = 1 in Li2+
ion, the energy of photon radiated will be best given by
(assume m Li = 9 m p )
(a) hv (b) hv1 + hv2
(a) 1 : 3 3 (b) 1 : 1 (c) 1 : 2 (d) 1 : 4 (c) hv1 + hv2 + hv3 (d) all of these
6. Assume that 2 × 10–17 J of light energy is needed by the 12. If l0 and l be the threshold wavelength and the wavelength
interior of the human eye to see an object. How many of incident light, the speed of photoelectrons ejected from
photons of yellow light with l = 595.2 nm are needed to the metal surface is :
generate this minimum energy?
2h 2hc
(a) 6 (b) 30 (c) 45 (d) 60 (a) ( l0 - l ) (b) (l0 - l )
7. If the de-Broglie wavelength of a particle of mass m is 100 m m
times its velocity, then its value in terms of its mass (m) and
Planck’s constant (h) is 2hc æ l0 - l ö 2h æ 1 1 ö
(c) ç ÷ (d) ç - ÷
m è ll0 ø m è l0 l ø
 EBD_7374
26 CHEMISTRY

13. The radii of maximum probability for 3s, 3p and 3d electrons

are in the order (a) 3.5 RH (b) 4 RH (c) 8 RH (d) 8 RH
9
(a) (rmax )3d > (rmax )3 p > (rmax )3s
15. If two particles are associated with same kinetic energy, then
(b) (rmax )3d > (rmax )3s > (rmax )3 p
the de Broglie’s wavelength (l) of these particles is
(c) ( rmax )3 s > ( rmax ) 3 p > ( rmax )3 d
(a) directly proportional to the velocity
(d) none of these
(b) inversely proportional to the velocity
14. The wave number of electromagnetic radiation emitted
during the transition in between two energy levels of Li2+ (c) independent of mass and velocity
ion whose principal quantum number sum is 4 and difference (d) can not be predicted
is 2, is

ANSWER KEYS
Exercise 1 : Topic-wise MCQs
1 (b) 13 (b) 25 (b) 37 (c) 49 (b) 61 (b) 73 (a) 85 (d) 97 (b) 109 (b)
2 (b) 14 (d) 26 (c) 38 (d) 50 (d) 62 (c) 74 (d) 86 (a) 98 (b) 110 (b)
3 (c) 15 (c) 27 (d) 39 (c) 51 (a) 63 (d) 75 (d) 87 (a) 99 (a) 111 (d)
4 (c) 16 (c) 28 (a) 40 (a) 52 (a) 64 (d) 76 (c) 88 (b) 100 (d) 112 (b)
5 (c) 17 (d) 29 (d) 41 (c) 53 (c) 65 (b) 77 (b) 89 (b) 101 (b) 113 (d)
6 (b) 18 (a) 30 (a) 42 (d) 54 (c) 66 (c) 78 (b) 90 (b) 102 (a) 114 (d)
7 (b) 19 (d) 31 (d) 43 (b) 55 (c) 67 (a) 79 (d) 91 (a) 103 (b) 115 (c)
8 (d) 20 (c) 32 (c) 44 (b) 56 (c) 68 (d) 80 (d) 92 (b) 104 (a) 116 (a)
9 (c) 21 (b) 33 (a) 45 (d) 57 (c) 69 (b) 81 (b) 93 (b) 105 (d) 117 (a)
10 (a) 22 (d) 34 (c) 46 (a) 58 (c) 70 (d) 82 (d) 94 (c) 106 (c) 118 (c)
11 (c) 23 (d) 35 (b) 47 (a) 59 (a) 71 (c) 83 (c) 95 (b) 107 (b) 119 (b)
12 (d) 24 (a) 36 (b) 48 (c) 60 (d) 72 (d) 84 (d) 96 (c) 108 (d) 120 (c)
Exercise 2 : Exemplar & Past Year MCQs
1 (c) 5 (b) 9 (c) 13 (c) 17 (a) 21 (d) 25 (d) 29 (c) 33 (d) 37 (c)
2 (b) 6 (a) 10 (b) 14 (b) 18 (d) 22 (c) 26 (b) 30 (a) 34 (d)
3 (d) 7 (d) 11 (c) 15 (d) 19 (c) 23 (a) 27 (d) 31 (d) 35 (b)
4 (d) 8 (d) 12 (a) 16 (b) 20 (a) 24 (d) 28 (d) 32 (a) 36 (d)
Exercise 3 : Try If You Can
1 (b) 3 (a) 5 (a) 7 (b) 9 (a) 11 (a) 13 (c) 15 (a)
2 (d) 4 (d) 6 (d) 8 (a) 10 (b) 12 (c) 14 (c)