Zm_m§H$ Roll No.

Tear Here
Sl.No. :

No. of Questions – 20 SS–41–Chem.

No. of Printed Pages – 15

CÀM _mÜ`{_H$ narjm, 2024

SENIOR SECONDARY EXAMINATION, 2024
agm¶Z {dkmZ

TEAR HERE TO OPEN THE QUESTION PAPER

CHEMISTRY
g_` : 3 KÊQ>o 15 {‘ZQ>
nyUmªH$ : 56

àíZ nÌ H$mo ImobZo Ho$ {bE `hm± \$m‹S>|

narjm{W©`m| Ho$ {bE gm_mÝ` {ZX}e …
GENERAL INSTRUCTIONS TO THE EXAMINEES :
1) narjmWu gd©àW_ AnZo àíZ-nÌ na Zm_m§H$ A{Zdm`©V… {bI| &
Candidate must write first his / her Roll No. on the question paper
compulsorily.
2) g^r àíZ A{Zdm`© h¢ &
All the questions are compulsory.
3) àË`oH$ àíZ H$m CÎma Xr JB© CÎma-nwpñVH$m _| hr {bI| &
Write the answer to each question in the given answer-book only.
4) {OZ àíZm| Ho$ AmÝV[aH$ IÊS> h¢, CZ g^r Ho$ CÎma EH$ gmW hr {bI| &
For questions having more than one part, the answers to those parts are to
be written together in continuity.
5) àíZ-nÌ Ho$ {hÝXr d A§J«oOr ê$nm§VaU _| {H$gr àH$ma H$s Ìw{Q> / A§Va / {damoYm^mg hmoZo na {hÝXr
^mfm Ho$ àíZ H$mo ghr _mZ| &
If there is any error / difference / contradiction in Hindi & English version of
the question paper, the question of Hindi version should be treated valid.
6) àíZ H$m CÎma {bIZo go nyd© àíZ H$m H«$‘m§H$ Adí¶ {bI|&
Write down the serial number of the question before attempting it.
`hm± go H$m{Q>E

7) àíZ H«$_m§H$ 16 go 20 ‘| AmÝV[aH$ {dH$ën h¢ &

Question No. 16 to 20 have internal choice.

SS-41-Chem. 5033 [ Turn Over

 2
IÊS> - A
SECTION - A
dñVw{Zð> àíZ :
Multiple Choice Questions :
1) {ZåZm§{H$V àíZm| ‘| {XE JE ghr {dH$ën H$m M¶Z H$a CÎma nwpñVH$m ‘| {b{IE : [8]
Write the answer of following multiple choice questions in the given answer book :
i) MmbH$Vm H$m SI ‘mÌH$ h¡ - [½]
(A) S
(~) 
(g) Scm–1
(X) Sm–1
SI unit of conductivity is -
(A) S
(B) 
(C) Scm–1
(D) Sm–1

ii) gdm©{YH$ g§»¶m ‘| Am°³grH$aU AdñWmE± àX{e©V H$aZo dmbm VËd h¡ - [½]
(A) Mn
(~) Ni
(g) Fe
(X) Cr
Element showing the highest number of oxidation states is -
(A) Mn
(B) Ni
(C) Fe
(D) Cr

5033
SS-41-Chem.
 3
iii) [Fe(Co)5] ‘| Fe H$s Am°³grH$aU AdñWm h¡ - [½]

(A) 0

(~) +2

(g) +3

(X) +4

Oxidation state of Fe in [Fe(Co)5] is -

(A) 0

(B) +2

(C) +3

(D) +4

iv) H«$mo‘mBQ> A¶ñH$ H$m amgm¶{ZH$ gyÌ h¡ - [½]

(A) MnO2

(~) Na2Cr2O4

(g) FeCr2O4

(X) Na2CrO4

The chemical formula of chromite ore is -

(A) MnO2

(B) Na2Cr2O4

(C) FeCr2O4

(D) Na2CrO4

5033
SS-41-Chem. [ Turn Over
 4
v) EH$ ‘mob CoCl3.5NH3 {db¶Z ‘| A{Y³¶ AgNO3 {db¶Z {‘bmZo na Adjo{nV AgCl Ho$ ‘mobm|
H$s g§»¶m h¡ - [½]
(A) 1
(~) 2
(g) 3
(X) 5
Number of moles of precipitated AgCl on adding excess silver nitrate solution
in the solution of one mole of CoCl3.5NH3 is -
(A) 1
(B) 2
(C) 3
(D) 5

vi) hr‘mo½bmo~rZ ‘§o CnpñWV YmVw h¡ - [½]

(A) Mn
(~) Fe
(g) Co
(X) Ni
Metal present in haemoglobin is -
(A) Mn
(B) Fe
(C) Co
(D) Ni

vii) C^¶X§Vr {bJÝS> h¡ - [½]

(A) Cl–
(~) H2O
(g) NH3
(X) NO 2
Ambidentate ligand is -
(A) Cl–
(B) H2O
(C) NH3
(D) NO 2
5033
SS-41-Chem.
 5
viii) ‘oS>moñdrQ> go àmá ¶m¡{JH$ h¡ - [½]
(A) g¡{b{gb EopëS>hmBS>
(~) {gZo‘¡pëS>hmBS>
(g) d¡boaopëS>hmBS>
(X) doZb
o rZ
The compound obtained from meadow sweet is -
(A) Salicyl aldehyde
(B) Cinnamaldehyde
(C) Valeraldehyde
(D) Vanillin

COOH

ix) H$m IUPAC Zm‘ h¡ - [½]

COOH

(A) W¡{bH$ Aåb

(~) ~oÝOrZ-1, 2- S>mBH$m~m©op³g{bH$ Aåb
(g) ~oÝOrZ-1, 2- S>mBAmoBH$ Aåb
(X) ’o${Zb-1, 2- S>mBH$m~m©op³g{bH$ Aåb
COOH

IUPAC name of is -
COOH

(A) Phthalic acid

(B) Benzene -1, 2- dicarboxylic acid
(C) Benzene -1, 2-dioic acid
(D) Phenyl -1, 2- dicarboxylic acid

5033
SS-41-Chem. [ Turn Over
 6
x) Zm{^H$amJr ¶moJO A{^{H«$¶m ‘| H$m~m©o{Zb H$m~©Z H$s g§H$aU AdñWm ‘§o n[adV©Z hmoVm h¡ - [½]
(A) sp2 go sp
(~) sp go sp2
(g) sp2 go sp3
(X) sp3 go sp2
Change occurs in hybridisation state of carbonyl carbon in nucleophilic addition
reaction is -
(A) sp2 to sp
(B) sp to sp2
(C) sp2 to sp3
(D) sp3 to sp2

xi) Q´>mB‘o{WbEo‘rZ ‘| ZmBQ´>moOZ H$s g§H$aU AdñWm h¡ - [½]

(A) sp
(~) sp 2
(g) sp 3
(X) dsp 2
The hybridisation state of nitrogen in trimethylamine is -
(A) sp
(B) sp 2
(C) sp 3
(D) dsp 2

xii) Obr¶ {db¶Z ‘| gdm©{YH$ jmaH$s¶ àm~ë¶ Xem©Zo dmbm ¶m¡{JH$ h¡ - [½]
(A) (C2H5)3N
(~) (C2H5)2NH
(g) C2H5NH2
(X) NH3
The compound showing highest basic strength in aqueous solution is -
(A) (C2H5)3N
(B) (C2H5)2NH
(C) C2H5NH2
(D) NH3

5033
SS-41-Chem.
 7
xiii) {ZåZ{b{IV ‘| go {ÛVr¶H$ Eo‘rZ h¡ - [½]
(A) àmonoZ -2- Eo‘rZ
(~) noÝQ>oZ -3- Eo‘rZ
(g) N - ‘o{WbEWoZo‘rZ
(X) N,N- S>mB‘o{Wb‘oWoZo‘rZ
Secondary amine among the following is -
(A) Propan -2- amine
(B) Pentan -3-amine
(C) N-Methylethanamine
(D) N,N- Dimethylmethanamine

xiv) Jmo{bH$mH$ma àmoQ>rZ h¡ - [½]

(A) BÝgw{bZ
(~) {H$ao{Q>Z
(g) ‘m¶mo{gZ
(X) H$mobmOZ
Globular protein is -
(A) Insulin
(B) Keratin
(C) Myosin
(D) Collagen

xv) ½bwH$mog h¡ - [½]

(A) EH$ EoëS>monoÝQ>mog
(~) EH$ H$sQ>monoÝQ>mog
(g) EH$ EoëS>moh¡³gmog
(X) EH$ H$sQ>moh¡³gmog
Glucose is -
(A) An aldopentose
(B) A ketopentose
(C) An aldohexose
(D) A ketohexose
5033
SS-41-Chem. [ Turn Over
 8
xvi) Xþ½Y eH©$am h¡ - [½]
(A) gyH«$mog
(~) b¡³Q>mog
(g) ‘mëQ>mog
(X) J¡b¡³Q>mog
Milk sugar is -
(A) Sucrose
(B) Lactose
(C) Maltose
(D) Galactose

2) [aº$ ñWmZm| H$s ny{V© H$s{OE -

Fill in the blanks - [5]
i) ‘mobaVm H$s BH$mB© ............ h¡ & [½]
The unit of molarity is ___________

ii) hoZar Ho$ {Z¶‘ H$m J{UVr¶ ê$n ................. h¡& [½]
The mathematical form of Henry's Law is __________.

iii) A{^H$maH$ AUwAm| Ho$ gdm©{YH$ A§e H$s J{VO D$Om© H$mo .......... H$hVo h¢ & [½]
The kinetic energy of maximum fraction of reactant molecules is called ______.

iv) ........................ Am¡a Eop³Q>Zm°¶S> Am§V[aH$ g§H«$‘U VËd H$hbmVo h¢ & [½]
___________ and actinoids are called as inner transition elements.

v) K4[Fe(CN)6] ‘| ............... g‘Ýd¶ ‘§S>b h¡ & [½]

___________ is coordination sphere in K4[Fe(CN)6].

vi) ~opÝO{bH$ EoëH$mohm°bm| ‘| –OH g‘yh ................ g§H$[aV H$m~©Z go ~§{YV hmoVm h¡ & [½]
In benzylic alcohols –OH group is bonded with ________ hybridised carbon.

5033
SS-41-Chem.
 9
vii) .......... EÝOmB‘ H$s CnpñW{V ‘| ½byH$mog, EWoZm°b ‘| n[ad{V©V hmo OmVm h¡ & [½]
Glucose is converted to ethanol in presence of _________ enzyme.

viii) gmo{S>¶‘ ~oÝOmoEQ> H$m Cn¶moJ ................. Ho$ ê$n ‘| hmoVm h¡ & [½]
Sodium benzoate is used as ___________.

ix) {dQ>m{‘Z ................. H$s H$‘r go ~oar-~oar amoJ hmo OmVm h¡ & [½]
Deficiency of vitamin ________ causes Beri-Beri disease.

x) RNA ‘| CnpñWV eH©$am H$m Zm‘ ................. h¡ & [½]

The name of Sugar present in RNA is __________.

3) A{V bKwÎmamË‘H$ àíZ :

Very short answer questions : [8]
i) g§V¥á {db¶Z H$mo n[a^m{fV H$s{OE & [1]
Define saturated solution.

ii) gmo{S>¶‘ A‘bJ‘ {db¶Z ‘§o CnpñWV {dbo¶ VWm {dbm¶H$ Ho$ Zm‘ {b{IE &
[½+½=1]
Write names of solute and solvent present in sodium amalgam solution.

1 3
iii) doJ = K[A] 2 [B] 2
Cnamo³V doJ 춧OH$ dmbr A{^{H«$¶m H$s Hw$b H$mo{Q> n[aH${bV H$s{OE &[1]
1 3
Rate = K[A] 2 [B] 2 Calculate the overall order of a reaction which has above
rate expression.

iv) BboH$Q´>m°ZamJr à{VñWmnZ A{^{H«$¶m Ho$ {bE Eo{Zgm°b ‘| CnpñWV - OCH3 g‘yh H$m {ZX}er à^md
{b{IE & [1]
Write directive influence of – OCH 3 group present in anisole for
electrophilic substitution reaction.

v) ’$sZm°b H$s ~«mo‘rZ Ob Ho$ gmW A{^{H«$¶m go àmá ídoV Adjon H$m amgm¶{ZH$ Zm‘ {b{IE &
[1]
Write chemical name of white precipitate obtained on the reaction of phenol
with bromine water.
5033
SS-41-Chem. [ Turn Over
 10
vi) NH2-NHCONH2 H$m amgm¶{ZH$ Zm‘ {b{IE & [1]
Write chemical name of NH2-NHCONH2.

vii) ~oÝOrZS>mBEoOmo{Z¶‘ ³bmoamBS> Am¡a ’$sZm°b Ho$ ‘ܶ A{^{H«$¶m go ~Zo CËnmX H$m Zm‘ {b{IE & [1]
Write name of the product obtained from the reaction between
benzenediazonium chloride and phenol.

viii) àmW{‘H$ Eo‘rZm| Ho$ {bE AmBgmogm¶ZmBS> narjU {b{IE & [1]
Write isocyanide test for primary amines.

IÊS> - ~
SECTION - B
bKw Î mamË‘H$ àíZ :
Short answer type questions : [12×1½=18]

4) J¡g A Ho$ 0.5 ‘mob VWm J¡g B Ho$ 4.5 ‘mob H$mo {‘{lV H$aZo na ~Zo {db¶Z ‘| J¡g A Ho$ ‘mob A§e H$s
JUZm H$s{OE & [1½]
Calculate the mole fraction of gas A in the solution made on mixing 0.5 moles of
gas A and 4.5 moles of gas B.

5) 0.05 ‘mob EWoZmoBH$ Aåb 250g ~oÝOrZ ‘| Kw{bV h¡& {db¶Z H$s ‘mobbVm H$s JUZm H$s{OE & [1½]
0.05 moles of ethanoic acid is dissolved in 250g benzene. Calculate the molality of
the solution.

6) S>oݶb gob H$mo {M{ÌV H$s{OE& [1½]

Draw the Daniell cell.

7) EH$ àW‘ H$mo{Q> H$s A{^{H«$¶m H$m doJ pñWam§H$ 1.386×10–14 S–1 h¢& Bg A{^{H«$¶m Ho$ {bE AYm©¶w H$s
JUZm H$s{OE & [1½]
Rate constant of a first order reaction is 1.386×10–14 S–1 calculate the half-life of
the reaction.

8) A§VamH$mer ¶m¡{JH$m§o Ho$ H$moB© VrZ ^m¡{VH$ A{^bjU {b{IE & [1½]
Write any three physical characteristics of interstitial compounds.

5033
SS-41-Chem.
 11
9) g§H«$‘U YmVwE±, CËàoaH$s¶ JwU ³¶m| àX{e©V H$aVr h¡? g‘PmBE & [1½]
Why transition metals exhibit catalytic properties? Explain.

10) Bbo³Q´>m°Z AnZ¶H$ g‘yh hmoVo hþE ^r Cl - g‘yh Eoamo‘¡{Q>H$ Bbo³Q´>mZamJr A{^{H«$¶mAm| ‘| Am°Wm©o-Am¡a n¡am-
{ZX©oeH$ ³¶m| h¡? H$maU Xr{OE & [1½]
Despite being an electron withdrawing group why Cl-group is ortho-and para-
directing in electrophilic aromatic substitution? Give reason.

OH

11) 
gm§Ð HNO3
 [A]

Cnamoº$ A{^{H«$¶m ‘| [A] H$m IUPAC Zm‘ VWm amgm¶{ZH$ gyÌ {b{IE & [¾ + ¾ = 1½]
OH


Conc. HNO3
[A]

Write IUPAC name and chemical formula of [A] in the above reaction.

12) 413k Vmn na EWoZm°b H$mo gm§Ð H2 SO4 Ho$ gmW J‘© H$aZo na ¶m¡{JH$ [x] ~ZVm h¡& [x] H$m IUPAC Zm‘
Am¡a {Z{hV A{^{H«$¶m H$m amgm¶{ZH$ g‘rH$aU {b{IE & [½+1=1½]
Compound [x] is formed on heating ethanol with conc. H2SO4 at 413k temperature.
Write IUPAC name of [x] and chemical equation of the reaction involved.

13) 
Amo{b¶‘
 [A] 
(i) NaOH, Ja‘
 [B]
(ii) H +

Cnamo³V A{^{H«$¶m AZwH«$‘ ‘| [A] Am¡a [B] Ho$ amgm¶{ZH$ gyÌ {b{IE & [¾ + ¾ = 1½]


Oleum
 [A] 
(i) NaOH, heat
(ii) H +
 [B]

Write chemical formula of [A] and [B] in above reaction sequence.

5033
SS-41-Chem. [ Turn Over
 12
14) Eo{ZbrZ H$s jmaH$s¶ gm‘϶© H$s A‘mo{Z¶m Ho$ gmW VwbZm H$s{OE - [1½]
Compare basic strength of aniline with ammonia.

15) DNA H$s {ÛHw§$S>bZr g§aMZm H$mo {M{ÌV H$s{OE & [1½]
Draw the double strand helix structure of DNA.

IÊS> - g
SECTION - C
XrK© CÎmamË‘H$ àíZ :
Long answer type questions :

16) i) A{^{H«$¶m H$s H$mo{Q> H$mo n[a^m{fV H$s{OE &

ii) N>X²‘ àW‘ H$mo{Q> H$s A{^{H«$¶m H$mo Cn¶wº$ CXmhaU XoH$a g‘PmBE &
[1+2=3]
i) Define order of reaction.
ii) Explain pseudo first order reaction by giving appropriate example.
AWdm/OR
i) A{^{H«$¶m H$s AmpÊdH$Vm> H$mo n[a^m{fV H$s{OE &
ii) EH$ amgm¶{ZH$ A{^{H«$¶m Ho$ hmo gH$Zo ‘| g{H«$¶U COm© H$s ^y{‘H$m H$mo g‘PmBE &
[1+2=3]
i) Define molecularity of a reaction.
ii) Explain the role of activation energy in the feasibility of a chemical reaction.

17) g§¶moOH$Vm Am~§Y {gÕmÝV Ho$ AmYma na g§H$w b [Co(NH3)6]3+ H$s Á¶m{‘{V Am¡a Mw~§ H$s¶ àH¥${V H$mo g‘PmBE&[3]
Explain the geometry and the magnetic nature of complex [Co(NH3)6]3+ on the
basis of valence bond theory.
AWdm/OR

5033
SS-41-Chem.
 13
g§¶moOH$Vm Am~§Y {gÕmÝV Ho$ AmYma na g§Hw$b [CoF6]3– H$s Á¶m{‘{V Am¡a Mw§~H$s¶ àH¥${V H$mo g‘PmBE &
[3]
Explain the geometry and the magnetic nature of complex [CoF6]3– on the basis of
valence bond theory.

18) g‘PmBE -
i) g‘md¶dr h¡bmoEoëHo$Zm| ‘| l§¥IbZ ~T>Zo Ho$ gmW ³dWZm§H$ H$‘ hmoVo OmVo h¢&
ii) g‘md¶dr S>mB³bmoamo~oÝOrZm| Ho$ p- g‘md¶dr H$m JbmZm§H$ o-Am¡a m-g‘md¶{d¶m| H$s VwbZm ‘|
A{YH$ hmoVm h¡&
iii) {H$gr Y«wdU KyU©H$ ¶m¡{JH$ H$m ao{g{‘H$ {‘lU gX¡d Y«wdU AKyU©H$ hmoVm h¡ &
[1+1+1=3]
Explain -
i) The boiling points of isomeric haloalkanes decrease with increase in branching.
ii) The melting point of p - isomer is higher than those of o - and m - isomers of
isomeric dichlorobenzenes.
iii) The racemic mixture of a optically active compound is always optically inactive.
AWdm/OR
{ZåZ{b{IV H$mo EH$ nX ‘| n[ad{V©V H$s{OE -
(Ho$db amgm¶{ZH$ g‘rH$aU {b{IE)
i) ~oÝOrZS>mBEo‹Omo{Z¶‘ ³bmoamBS go Am¶moS>mo~oÝOrZ >
ii) ³bmoamo~oÝOrZ go S>mB’o${Zb
iii) ³bmoamoEWoZ go EWrZ
[1+1+1=3]
Convert the following in single step - (Write chemical equation only)
i) Benzenediazoniumchloride to iodobenzene.
ii) Chlorobenzene to diphenyl.
iii) Chloroethane to ethene

5033
SS-41-Chem. [ Turn Over
 14
IÊS> - X
SECTION - D
{Z~§ Y mË‘H$ àíZ :
Essay type questions :

19) i) ‘mZH$ hmBS´>moOZ Bbo³Q´>m°S> H$s g§aMZm H$m dU©Z H$s{OE &
ii) ewîH$ gob Ho$ Cn¶moJ Ho$ Xm¡amZ EoZmoS> Am¡a H¡$WmoS> na hmoZo dmbr gob A[^{H«$¶mAm| Ho$ g‘rH$aU {b{IE&
[2+2=4]
i) Describe the construction of standard hydrogen electrode.
ii) Write equations of cell reactions taking place at anode and cathode during
use of dry cell.
AWdm / OR
i) Ob Ed§ dm¶w H$s CnpñW{V ‘| bmoho H$m g§jmaU H¡$go hmoVm h¡? dU©Z H$s{OE &
ii) ‘³¶y©ar gob Ho$ Cn¶moJ Ho$ Xm¡amZ EoZmoS> Am¡a H¡$WmoS> na hmoZo dmbr gob A{^{H«$¶mAm| Ho$ g‘rH$aU
{b{IE & [2+2=4]
i) How does corrosion of iron occurs in presence of water and air? Describe.
ii) Write equations of cell reactions taking place at anode and cathode during
use of mercury cell.

20) i) bmb-MtQ>r Ho$ S>§H$ ‘| CnpñWV Aåb H$m IUPAC Zm‘ {b{IE &
ii) H¡${ZOmamo A{^{H«$¶m H$mo Cn¶wº$ amgm¶{ZH$ g‘rH$aU XoH$a g‘PmBE &
iii) CH 3CooNa 
[ NaOH+CaO]

 [A]  Na 2 CO3 Cnamoº$ A{^{H«$¶m ‘| [A] H$m amgm¶{ZH$ gyÌ
{b{IE &
[1+2+1=4]
i) Write IUPAC name of an acid present in red-ant sting.
ii) Explain the Cannizzaro reaction by giving suitable chemical equation.
iii) CH 3CooNa 
[ NaOH+CaO]

 [A]  Na 2 CO3 . Write chemical formula of [A] in
above reaction.
AWdm/OR

5033
SS-41-Chem.
 15

i) {gaHo$ ‘| CnpñWV Aåb H$m IUPAC Zm‘ {b{IE &

ii) amo‹OoZ‘§wS> AnM¶Z H$mo Cn¶wº$ amgm¶{ZH$ g‘rH$aU XoH$a g‘PmBE &
[1+2+1=4]

iii)  Co,HCl

© AlCl3 /CuCl
{ZOb
 [Z]

Cnamoº$ A{^{H«$¶m ‘| [Z] H$m amgm¶{ZH$ gyÌ {b{IE &

i) Write IUPAC name of an acid present in vinegar.

ii) Explain the Rosenmund reduction by giving suitable chemical equation.

iii) 
Co,HCl
Anhyd. AlCl3 /CuCl
 [Z]

Write chemical formula of [Z] in above reaction.



5033
SS-41-Chem.
 E
ER
H
NG
I
TH
NY
A
TE
RI
W
O T
N
DO