Grade – 8 Chemistry

Topic 5.3 Salts

Preparing soluble salts

What is a salt?

 A salt is a compound that is formed when the hydrogen atom in an acid is

replaced by a metal

 For example, if we replace the H in HCl with a potassium atom, then the salt

potassium chloride is formed, KCl

 Salts are an important branch of chemistry due to the varied and important uses

of this class of compounds

 These uses include fertilizers, batteries, cleaning products, healthcare products

and fungicides

 The method used depends on the solubility of the salt being prepared

How to name a salt

 The name of salt has two parts

 The first part comes from the metal, metal oxide or metal carbonate used in the

reaction

 The second part comes from the acid

 The name of the salt can be determined by looking at the reactants

 For example hydrochloric acid always produces salts that end in chloride and

contain the chloride ion, Cl -

Other examples:
 o Sodium hydroxide reacts with hydrochloric acid to produce sodium chloride

o Zinc oxide reacts with sulfuric acid to produce zinc sulfate

Preparing soluble salts

 There are two methods of preparing a solution salt:

o Method A

 Adding acid to a solid metal, insoluble base or insoluble carbonate

o Method B

 Reacting a dilute acid and alkali (soluble base)

Method A

Method A: Adding acid to a solid metal, insoluble base or insoluble carbonate

Diagram showing the preparation of soluble salts

 Method

 Add dilute acid into a beaker and heat using a Bunsen burner flame

 Add the insoluble metal, base or carbonate, a little at a time, to the warm dilute acid

and stir until the base is in excess (i.e. until the base stops disappearing and a

suspension of the base forms in the acid)

 Filter the mixture into an evaporating basin to remove the excess base

 Heat the solution to evaporate water and to make the solution saturated. Check the

solution is saturated by dipping a cold, glass rod into the solution and seeing if

crystals form on the end

 Leave the filtrate in a warm place to dry and crystallize

 Decant excess solution and allow crystals to dry or blot to dry with filter paper

Example: preparation of pure, hydrated copper(II) sulfate crystals using method

 Add dilute sulfuric acid into a beaker and heat using a Bunsen burner flame

 Add copper(II) oxide (insoluble base), a little at a time to the warm dilute sulfuric

acid and stir until the copper (II) oxide is in excess (stops disappearing)

 Filter the mixture into an evaporating basin to remove the excess copper(II) oxide

 Leave the filtrate in a warm place to dry and crystallize

 Decant excess solution

 Blot crystals dry with filter paper

copper(II) oxide + sulfuric acid → copper(II) sulphate + water

CuO (s) + H2SO4 (aq) → CuSO4 (aq) + H2O (l)

Method B

Method B: Reacting a dilute acid and alkali (soluble base)

Diagram showing the apparatus needed to prepare a salt by titration

 Method

 Use a pipette to measure the alkali into a conical flask and add a few drops of

indicator (thymolphthalein or methyl orange)

 Add the acid into the burette

 Record the starting volume of acid in the burette

 Add the acid very slowly from the burette to the conical flask until the indicator

changes to the appropriate colour

 Record the final volume of acid in the burette

 Calculate the volume of acid added

o Final volume of acid - initial volume of acid

 Add this same volume of acid to the same volume of alkali without the indicator

 Heat the resulting solution in an evaporating basin to partially evaporate, leaving a

saturated solution (crystals just forming on the sides of the basin or on a glass rod

dipped in and then removed)

 Leave to crystallize, decant excess solution and allow crystals to dry

Preparing insoluble salts

Using two soluble reactants

Diagram showing the filtration of the mixture to remove the precipitate

Method

 Dissolve soluble salts in water and mix together using a stirring rod in a beaker
 Filter to remove precipitate from mixture
 Wash the residue with distilled water to remove traces of other solutions
 Leave in an oven to dry

Example: Preparation of pure, dry lead(II) sulfate crystals using a precipitation

reaction

 Dissolve lead(II) nitrate and potassium sulfate in water and mix together using a
stirring rod in a beaker
 Filter to remove precipitate from mixture
 Wash precipitate with distilled water to remove traces of potassium nitrate solution
 Leave in an oven to dry

lead(II) nitrate + potassium sulfate → lead(II) sulfate + potassium nitrate

Pb(NO3)2 (aq) + K 2SO4 (aq) → PbSO4 (s) + 2KNO3 (aq)

Solubility rules

 Salts are prepared by different methods, depending on whether the salt is soluble
or insoluble so it is important to know the solubility of salts

Solubility of the common salts

Hydrated & anhydrous salts

 When salts are being prepared, some water can be retained within the structure of
the salt during the crystallization process
 Salts that contain water within their structure are called hydrated salts
 Anhydrous salts are those that contain no water in their structure
 A common example is copper(II) sulfate which crystallizes forming the salt
hydrated copper(II) sulfate, which is blue
 When it is heated, the water from its structure is removed, forming anhydrous
copper(II) sulfate, which is white
 The hydrated salt has been dehydrated to form the anhydrous salt
 This reaction can be reversed by adding water to anhydrous copper(II) sulfate

hydrated copper(II) sulfate⇌ anhydrous copper(II) sulfate + water

Water of crystallization

 Water molecules included in the structure of some salts during the crystallisation
process are known as water of crystallisation
 A compound that contains water of crystallisation is called a hydrated compound
  When writing the chemical formula of hydrated compounds, the water of
crystallisation is separated from the main formula by a dot:
o Hydrated copper(II) sulfate is CuSO4∙5H2O
o Hydrated cobalt(II) chloride is CoCl 2∙6H2O
 The formula shows the number of moles of water contained within one mole of the
hydrated salt:
o Hydrated copper(II) sulfate, CuSO4∙5H2O, contains 5 moles of water in 1
mole of hydrated salt
 A compound which doesn’t contain water of crystallisation is called an anhydrous
compound:
o Anhydrous copper(II) sulfate is CuSO4
o Anhydrous cobalt(II) chloride is CoCl 2
 The conversion of anhydrous compounds to hydrated compounds is reversible by
heating the hydrated salt:
o Anhydrous to hydrated salt:
 CuSO4 + 5H2O → CuSO4∙5H2O
o Hydrated to anhydrous salt (by heating):
 CuSO4∙5H2O → CuSO4 + 5H2O

Hydrated copper(II) sulfate and anhydrous copper(II) sulfate

Diagram showing the dehydration of hydrated copper(II) sulfate

Some Hydrated salts

 Hydrated salt Formula Colour

Copper (II) sulfate CuSo4.5H2O Blue

Cobalt (II) chloride CoCl 2.6H2O Pink

Iron (II) sulfate FeSO4.6H2O Green

Magnesium sulfate MgSO4.7H2O White

Sodium carbonate Na2CO3.10H2O White

Calcium sulfate CaSO4.2H2O White