Revision nr.

1
ARACROM S.R.L. - Concessionario INVER vernici Dated 20/11/2018
Printed on 20/11/2018
SM. INVERPUR - SECUREX Page n. 12 / /15
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SECTION 16.
2. Exposure
3.
6.
8.
10.
11.
12.
15.Hazards
Composition/information
Accidental
Stability
Toxicological
Ecological
Regulatory
Other information
identification
and ... / ...
controls/personal
release
information
information
reactivity
information
measures>>...
...
/on
...
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>>
>>/...>>
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protection
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ACETONE
As Collect
2-BUTOXYETHANOL
2-DIMETHYLAMINOETHANOL
2-(2-BUTOXYETHOXY)ETHANOL Product
the use
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SOLVENT leaked
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(PETROLEUM),
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always
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2-BUTOXYETHANOL
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SECTION 2-BUTOXYETHANOL: 4.of First aid decomposes
measures in the presence of heat.
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4.1. SKIN
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Description of: first
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class Directive 91/322/EEC. 61
Any
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INDEX additional
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603-014-00-0
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SECTION 3. NDS
Regulation 16. Other
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5.2. 4. Delayed
EU 2-(2-BUTOXYETHOXY)ETHANOL:
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2-DIMETHYLAMINOETHANOL
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Evaporation
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INDEX
Health
toxicity,
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SECTIONINDEX
Auto-ignition 6.
2-(2-BUTOXYETHOXY)ETHANOL
H225 LD50 Accidental
temperature
(Oral) releaseHighly measures
flammable liquid Not and
available
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chemicals - ACGIH
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of 1 Health 101,2
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(Istituto 15 Superiore di Sanità) - Italy mg/k
mg/k
Reg. no. 01-2119954390-39
2-(2-BUTOXYETHOXY)ETHANOL:
H226LD50 temperature information Flammable liquidwith andNot vapour.
available
SECTION
6.1. ETHANEDIOL VLEP
Personal
12. (Dermal) Ecological ITA protective
avoid contact
67,5 10
the air. 2764 mg/kg Rabbit
101,2 15 g
g
Viscosity
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to
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Annex if inhaled.
II of
and Not
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Code
CAS
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01-2119456816-28
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if swallowed and101,2
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procedures.
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H411 relating
statements: to the product Toxic or contained
to aquatic substances life with longpursuant lasting effects. to Annex XVII to EC Regulation 1907/2006

EPY 9.4.7 - SDS 1004.7

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SECTION 2. Hazards identification ... / >>

P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves / eye protection / face protection.
P337+P313 If eye irritation persists: Get medical advice / attention.

VOC (Directive 2004/42/EC) :

Two-pack performance coatings.
VOC given in g/litre of product in a ready-to-use condition : 143,55
Limit value: 140,00
- Catalysed with : 25,00 % COMPONENTE PER INVERPUR
- Thinned with : 1,00 % WATER

2.3. Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.

SECTION 3. Composition/information on ingredients

3.1. Substances

Information not relevant

3.2. Mixtures

Contains:

Identification x = Conc. % Classification 1272/2008 (CLP)

SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM

CAS 64742-95-6 2,5 ≤ x < 3 Flam. Liq. 3 H226, Asp. Tox. 1 H304, STOT SE 3 H335, STOT SE 3 H336,
Aquatic Chronic 2 H411, Note P
EC 918-668-5
INDEX 649-356-00-4
Reg. no. 01-2119455851-35
2-BUTOXYETHANOL
CAS 111-76-2 1≤x< 3 Acute Tox. 4 H302, Acute Tox. 4 H312, Acute Tox. 4 H332, Eye Irrit. 2 H319,
Skin Irrit. 2 H315
EC 203-905-0
INDEX 603-014-00-0
Reg. no. 01-2119475108-36
TITANIUM DIOXIDE
59,9% - metallic element
CAS 13463-67-7 1 ≤ x < 3
EC 236-675-5
INDEX
Reg. no. 01-2119489379-17
2-DIMETHYLAMINOETHANOL
CAS 108-01-0 1≤x< 3 Flam. Liq. 3 H226, Acute Tox. 3 H331, Acute Tox. 4 H302, Acute Tox. 4 H312,
Skin Corr. 1B H314, STOT SE 3 H335
EC 203-542-8
INDEX 603-047-00-0
Reg. no. 01-2119492298-24
2,4,7,9-tetramethyl-5-decyne-4,7 diol
CAS 126-86-3 0 ≤ x < 0,5 Eye Irrit. 2 H319, Skin Sens. 1 H317, Aquatic Chronic 3 H412
EC 204-809-1
INDEX
Reg. no. 01-2119954390-39
ETHANEDIOL
CAS 107-21-1 0 ≤ x < 0,5 Acute Tox. 4 H302, STOT RE 2 H373
EC 203-473-3
INDEX 603-027-00-1
Reg. no. 01-2119456816-28
ACETONE
CAS 67-64-1 0 ≤ x < 0,5 Flam. Liq. 2 H225, Eye Irrit. 2 H319, STOT SE 3 H336, EUH066
EC 200-662-2
INDEX 606-001-00-8
Reg. no. 01-2119471330-49

EPY 9.4.7 - SDS 1004.7

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SECTION 3. Composition/information on ingredients ... / >>

2-(2-BUTOXYETHOXY)ETHANOL
CAS 112-34-5 0 ≤ x < 0,5 Eye Irrit. 2 H319
EC 203-961-6
INDEX 603-096-00-8
Reg. no. 01-2119475104-44

The full wording of hazard (H) phrases is given in section 16 of the sheet.

SECTION 4. First aid measures

4.1. Description of first aid measures

EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 30-60 minutes, opening the eyelids fully. Get
medical advice/attention.
SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention.
INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly
authorised by a doctor.
INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops
breathing, administer artificial respiration. Take suitable precautions for rescue workers.

4.2. Most important symptoms and effects, both acute and delayed

Specific information on symptoms and effects caused by the product are unknown.

4.3. Indication of any immediate medical attention and special treatment needed

Information not available

SECTION 5. Firefighting measures

5.1. Extinguishing media

SUITABLE EXTINGUISHING EQUIPMENT

Extinguishing substances are: carbon dioxide, foam, chemical powder. For product loss or leakage that has not caught fire, water spray
can be used to disperse flammable vapours and protect those trying to stem the leak.
UNSUITABLE EXTINGUISHING EQUIPMENT
Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent
explosions.

5.2. Special hazards arising from the substance or mixture

HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE

Excess pressure may form in containers exposed to fire at a risk of explosion. Do not breathe combustion products.

5.3. Advice for firefighters

GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for
health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of
contaminated water used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with
self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).

SECTION 6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Block the leakage if there is no hazard.

Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to
prevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in
emergency procedures.

6.2. Environmental precautions

The product must not penetrate into the sewer system or come into contact with surface water or ground water.

6.3. Methods and material for containment and cleaning up

EPY 9.4.7 - SDS 1004.7

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SECTION 6. Accidental release measures ... / >>

Collect the leaked product into a suitable container. If the product is flammable, use explosion-proof equipment. Evaluate the
compatibility of the container to be used, by checking section 10. Absorb the remainder with inert absorbent material.
Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point
13.

6.4. Reference to other sections

Any information on personal protection and disposal is given in sections 8 and 13.

SECTION 7. Handling and storage

7.1. Precautions for safe handling

Keep away from heat, sparks and naked flames; do not smoke or use matches or lighters. Without adequate ventilation, vapours may
accumulate at ground level and, if ignited, catch fire even at a distance, with the danger of backfire. Avoid bunching of electrostatic
charges. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering
places in which people eat. Avoid leakage of the product into the environment.

7.2. Conditions for safe storage, including any incompatibilities

Store only in the original container. Store in a well ventilated place, keep far away from sources of heat, naked flames and sparks and
other sources of ignition. Keep containers away from any incompatible materials, see section 10 for details.

7.3. Specific end use(s)

Information not available

SECTION 8. Exposure controls/personal protection

8.1. Control parameters

Regulatory References:

EU OEL EU Directive (EU) 2017/164; Directive 2009/161/EU; Directive 2006/15/EC; Directive 2004/37/EC;
Directive 2000/39/EC; Directive 91/322/EEC.
TLV-ACGIH ACGIH 2016
EU OEL EU Directive (EU) 2017/164; Directive 2009/161/EU; Directive 2006/15/EC; Directive 2004/37/EC;
Directive 2000/39/EC; Directive 91/322/EEC.
TLV-ACGIH ACGIH 2016
EU OEL EU Directive (EU) 2017/164; Directive 2009/161/EU; Directive 2006/15/EC; Directive 2004/37/EC;
Directive 2000/39/EC; Directive 91/322/EEC.
TLV-ACGIH ACGIH 2016
EU OEL EU Directive (EU) 2017/164; Directive 2009/161/EU; Directive 2006/15/EC; Directive 2004/37/EC;
Directive 2000/39/EC; Directive 91/322/EEC.
TLV-ACGIH ACGIH 2016
DEU Deutschland MAK-und BAT-Werte-Liste 2012
ESP España INSHT - Límites de exposición profesional para agentes químicos en España 2015
FRA France JORF n°0109 du 10 mai 2012 page 8773 texte n° 102
GBR United Kingdom EH40/2005 Workplace exposure limits
ITA Italia Decreto Legislativo 9 Aprile 2008, n.81
POL Polska ROZPORZĄDZENIE MINISTRA PRACY I POLITYKI SPOŁECZNEJ z dnia 16 grudnia 2011r
SVK Slovensko NARIADENIE VLÁDY Slovenskej republiky z 20. júna 2007
SVN Slovenija Uradni list Republike Slovenije 15. 6. 2007
EU OEL EU Directive (EU) 2017/164; Directive 2009/161/EU; Directive 2006/15/EC; Directive 2004/37/EC;
Directive 2000/39/EC; Directive 91/322/EEC.
TLV-ACGIH ACGIH 2016

EPY 9.4.7 - SDS 1004.7

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SECTION 8. Exposure controls/personal protection ... / >>

2-BUTOXYETHANOL
Threshold Limit Value
Type Country TWA/8h STEL/15min
mg/m3 ppm mg/m3 ppm
OEL EU 98 20 246 50 SKIN
OEL EU 98 20 246 50 SKIN
TLV-ACGIH 97 20
TLV-ACGIH 97 20
AGW DEU 49 10 196 40 SKIN
MAK DEU 49 10 98 20 SKIN
VLA ESP 98 20 245 50 SKIN
VLEP FRA 49 10 246 50 SKIN
WEL GBR 123 25 246 50 SKIN
VLEP ITA 98 20 246 50 SKIN
NDS POL 98 200
NPHV SVK 98 20 246 SKIN
MV SVN 98 20 SKIN
OEL EU 98 20 246 50 SKIN
TLV-ACGIH 97 20
Predicted no-effect concentration - PNEC
Normal value in fresh water 8,8 mg/l
Normal value in marine water 8,8 mg/l
Normal value for fresh water sediment 8,14 mg/kg
Normal value for the terrestrial compartment 2,8 mg/kg
Health - Derived no-effect level - DNEL / DMEL
Effects on consumers Effects on workers
Route of exposure Acu Acut Chro Chronic Chro Acu Acute Chro
te e nic systemic nic te system nic
loca syst local local loca ic syste
l emi l mic
c
Oral VND 3,2
mg/kg
Inhalation 426 VND VND 49 663 VN VND 98
mg/m3 mg/m3 mg/m3 D mg/m
3
Skin VND 38 VND 75
mg/kg mg/k
g

SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM

Health - Derived no-effect level - DNEL / DMEL
Effects on consumers Effects on workers
Route of exposure Acu Acut Chro Chronic Chro Acu Acute Chro
te e nic systemic nic te system nic
loca syst local local loca ic syste
l emi l mic
c
Oral VND 11
mg/kg
Inhalation VND 32 VND 150
mg/m3 mg/m
3
Skin VND 11 VND 25
mg/kg mg/k
g

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TITANIUM DIOXIDE
Threshold Limit Value
Type Country TWA/8h STEL/15min
mg/m3 ppm mg/m3 ppm
TLV-ACGIH 10
TLV-ACGIH 10
VLA ESP 10
VLEP FRA 10
WEL GBR 4
NDS POL 10 INHAL
TLV-ACGIH 10
Predicted no-effect concentration - PNEC
Normal value in fresh water 1 mg/l
Normal value in marine water 0,12 mg/l
7
Normal value for fresh water sediment 100 mg/kg
0
Normal value for marine water sediment 100 mg/kg
Normal value for the terrestrial compartment 100 mg/kg
Health - Derived no-effect level - DNEL / DMEL
Effects on consumers Effects on workers
Route of exposure Acu Acut Chro Chronic Chro Acu Acute Chro
te e nic systemic nic te system nic
loca syst local local loca ic syste
l emi l mic
c
Inhalation 10 VND
mg/m3

2-DIMETHYLAMINOETHANOL
Threshold Limit Value
Type Country TWA/8h STEL/15min
mg/m3 ppm mg/m3 ppm
WEL GBR 7,4 2 22 6
Predicted no-effect concentration - PNEC
Normal value in fresh water 0,06 mg/l
61
Normal value in marine water 0,00 mg/l
661
Normal value for fresh water sediment 0,05 mg/kg
29
Normal value for the terrestrial compartment 0,01 mg/kg
77
Health - Derived no-effect level - DNEL / DMEL
Effects on consumers Effects on workers
Route of exposure Acu Acut Chro Chronic Chro Acu Acute Chro
te e nic systemic nic te system nic
loca syst local local loca ic syste
l emi l mic
c
Inhalation VND 2,2 VND 7,4
mg/m3 mg/m
3
Skin VND 1,04
mg/k
g

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ETHANEDIOL
Threshold Limit Value
Type Country TWA/8h STEL/15min
mg/m3 ppm mg/m3 ppm
OEL EU 52 20 104 40 SKIN
OEL EU 52 20 104 40 SKIN
TLV-ACGIH 100 (C)
TLV-ACGIH 100 (C)
AGW DEU 26 10 52 20 SKIN
MAK DEU 26 10 52 20 SKIN
VLA ESP 52 20 104 40 SKIN
VLEP FRA 52 20 104 40 SKIN
WEL GBR 52 20 104 40
VLEP ITA 52 20 104 40 SKIN
NDS POL 15 20
NPHV SVK 52 20 104 SKIN
OEL EU 52 20 104 40 SKIN
TLV-ACGIH 100 (C)
Predicted no-effect concentration - PNEC
Normal value in fresh water 10 mg/l
Normal value in marine water 1 mg/l
Normal value for fresh water sediment 37 mg/kg
Normal value for marine water sediment 3,7 mg/kg

ACETONE
Threshold Limit Value
Type Country TWA/8h STEL/15min
mg/m3 ppm mg/m3 ppm
OEL EU 1210 500
OEL EU 1210 500
TLV-ACGIH 1187 500 1781 750
TLV-ACGIH 1187 500 1781 750
AGW DEU 1200 500 2400 1000
MAK DEU 1200 500 2400 1000
VLA ESP 1210 500
VLEP FRA 1210 500 2420 1000
WEL GBR 1210 500 3620 1500
VLEP ITA 1210 500
NDS POL 600 1800
NPHV SVK 1210 500 2420
MV SVN 1210 500
OEL EU 1210 500
TLV-ACGIH 1187 500 1781 750

2-(2-BUTOXYETHOXY)ETHANOL
Threshold Limit Value
Type Country TWA/8h STEL/15min
mg/m3 ppm mg/m3 ppm
OEL EU 67,5 10 101,2 15
OEL EU 67,5 10 101,2 15
TLV-ACGIH 66 10
TLV-ACGIH 66 10
AGW DEU 67 10 100,5 15
MAK DEU 67 10 100,5 15
VLA ESP 67,5 10 101,2 15
VLEP ITA 67,5 10 101,2 15
NDS POL 67 100
NPHV SVK 67,5 10 101,2
MV SVN 67,5 10
OEL EU 67,5 10 101,2 15
TLV-ACGIH 66 10

Legend:
(C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction.
VND = hazard identified but no DNEL/PNEC available ; NEA = no exposure expected ; NPI = no hazard identified.

8.2. Exposure controls

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SECTION 8. Exposure controls/personal protection ... / >>

As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace
is well aired through effective local aspiration.
When choosing personal protective equipment, ask your chemical substance supplier for advice.
Personal protective equipment must be CE marked, showing that it complies with applicable standards.
Provide an emergency shower with face and eye wash station.
HAND PROTECTION
Protect hands with category III work gloves (see standard EN 374).
The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability.
The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time
depends on the duration and type of use.
SKIN PROTECTION
Wear category II professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash
body with soap and water after removing protective clothing.
EYE PROTECTION
Wear airtight protective goggles (see standard EN 166).
RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a
type A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the
presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.)
combined filters are required.
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to
the threshold values considered. The protection provided by masks is in any case limited.
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an
emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing
apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.
ENVIRONMENTAL EXPOSURE CONTROLS
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure
compliance with environmental standards.
Product residues must not be indiscriminately disposed of with waste water or by dumping in waterways.

SECTION 9. Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Not available

Colour Not available
Odour Not available
Odour threshold Not available
pH Not available
Melting point / freezing point Not available
Initial boiling point Not available
Boiling range Not available
Flash point 60 < T ≤ 93 °C
Evaporation Rate Not available
Flammability of solids and gases Not available
60 °C
93 °C
Lower explosive limit Not available
Upper explosive limit Not available
Vapour pressure Not available
Vapour density Not available
Relative density 1,13
Solubility Not available
Partition coefficient: n-octanol/water Not available
Auto-ignition temperature Not available
Decomposition temperature Not available
Viscosity Not available
Explosive properties Not available
Oxidising properties Not available

9.2. Other information

Total solids (250°C / 482°F) 45,92 %

VOC (Directive 2004/42/EC) : 7,96 % - 90,20 g/litre

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SECTION 10. Stability and reactivity

10.1. Reactivity

There are no particular risks of reaction with other substances in normal conditions of use.

2-BUTOXYETHANOL
2-BUTOXYETHANOL: decomposes in the presence of heat.

ETHANEDIOL
ETHANEDIOL: can absorb atmospheric humidity up to twice its own weight. Decomposes at temperatures over 200°C/392°F.

ACETONE
ACETONE: decomposes under the effect of heat.

10.2. Chemical stability

The product is stable in normal conditions of use and storage.

10.3. Possibility of hazardous reactions

The vapours may also form explosive mixtures with the air.

2-BUTOXYETHANOL
2-BUTOXYETHANOL: can react dangerously with: aluminium, oxidising agents. Forms peroxide with air.

ETHANEDIOL
ETHANEDIOL: risk of explosion on contact with: perchloric acid. Can react dangerously with: chlorosulphuric acid, sodium hydroxide,
sulphuric acid, phosphorus pentasulphide, chromium (III) oxide, chromyl chloride, potassium perchlorate, potassium dichromate, sodium
peroxide, aluminium. Forms explosive mixtures with the air.

ACETONE
ACETONE: risk of explosion on contact with: bromine trifluoride, difluoro dioxide, hydrogen peroxide, nitrosyl chloride, 2-methyl-1,3
butadiene, nitromethane, nitrosyl perchlorate. Can react dangerously with: potassium tert-butoxide, alkaline hydroxides, bromine,
bromoform, isoprene, sodium, sulphur dioxide, chromium trioxide, chromyl chloride, nitric acid, chloroform, peroxymonosulphuric acid,
phosphoryl chloride, chromosulphuric acid, fluorine, strong oxidising agents. Develops flammable gases with nitrosyl perchlorate.

2-(2-BUTOXYETHOXY)ETHANOL
2-(2-BUTOXYETHOXY)ETHANOL: can react with oxidising agents. It forms peroxides with atmospheric oxygen. When it reacts with
aluminium is can generate hydrogen. May form explosive mixtures with air.

10.4. Conditions to avoid

Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition.

2-BUTOXYETHANOL
2-BUTOXYETHANOL: avoid exposure to sources of heat and naked flames.

ETHANEDIOL
ETHANEDIOL: avoid exposure to sources of heat and naked flames.

ACETONE
ACETONE: avoid exposure to sources of heat and naked flames.

2-(2-BUTOXYETHOXY)ETHANOL
2-(2-BUTOXYETHOXY)ETHANOL: avoid contact with the air.

10.5. Incompatible materials

ACETONE
ACETONE: acid and oxidising substances.

2-(2-BUTOXYETHOXY)ETHANOL
2-(2-BUTOXYETHOXY)ETHANOL: oxidising substances, strong acids and alkaline metals.

10.6. Hazardous decomposition products

In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released.

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SECTION 10. Stability and reactivity ... / >>

2-BUTOXYETHANOL
2-BUTOXYETHANOL: hydrogen.

ETHANEDIOL
ETHANEDIOL: hydroxyacetaldehyde, glyoxal, acetaldehyde, methane, formaldehyde, carbon monoxide, hydrogen.

ACETONE
ACETONE: ketenes and other irritating compounds.

2-(2-BUTOXYETHOXY)ETHANOL
2-(2-BUTOXYETHOXY)ETHANOL: hydrogen.

SECTION 11. Toxicological information

In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it
contains, using the criteria specified in the applicable regulation for classification.
It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate
the toxicological effects of exposure to the product.

11.1. Information on toxicological effects

2-(2-BUTOXYETHOXY)ETHANOL
2-(2-BUTOXYETHOXY)ETHANOL: can be absorbed by inhalation, ingestion and skin contact; it is irritant to the skin and
especially to the eyes; spleen damage may occur. Inhalation is unlikely to occur at room temperature due to the low vapour
tension of the substance.

ETHANEDIOL
ETHANEDIOL: following ingestion it initially stimulates the CNS; later on depression results. Renal damage with anuria and
uremia may occur. Symptoms of over exposure are: vomiting, somnolence, difficulty in breathing, convulsions. The lethal dose in
man is approximately 1,4 l/kg. The way of entry is inhalation and ingestion.

Metabolism, toxicokinetics, mechanism of action and other information

Information not available

Information on likely routes of exposure

Information not available

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Information not available

Interactive effects

Information not available

ACUTE TOXICITY

LC50 (Inhalation) of the mixture: > 20 mg/l

LD50 (Oral) of the mixture: >2000 mg/kg
LD50 (Dermal) of the mixture: >2000 mg/kg

2-(2-BUTOXYETHOXY)ETHANOL
LD50 (Oral) 2410 mg/kg Rat
LD50 (Dermal) 2764 mg/kg Rabbit

ACETONE
LD50 (Oral) 5800 mg/kg ratto
LD50 (Dermal) 20 mg/kg coniglio
LC50 (Inhalation) 21,09 ppm ratto, 8 h

2-BUTOXYETHANOL
LD50 (Oral) 1746 mg/kg Ratto
LD50 (Dermal) 450 ppm ratto

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SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM
LD50 (Oral) > 3492 mg/kg ratto
LD50 (Dermal) > 3160 mg/kg coniglio
LC50 (Inhalation) > 6,193 mg/l/4h ratto

ETHANEDIOL
LD50 (Oral) > 7712 mg/kg Rat
LD50 (Dermal) > 3500 mg/kg topo
LC50 (Inhalation) > 2,5 mg/l ratto

2-DIMETHYLAMINOETHANOL
LD50 (Oral) 1183 mg/kg ratto
LD50 (Dermal) > 3000 mg/kg coniglio
LC50 (Inhalation) 1641 ppm/96h ratto

TITANIUM DIOXIDE
LD50 (Oral) > 10000 mg/kg Rat

SKIN CORROSION / IRRITATION

Causes skin irritation

SERIOUS EYE DAMAGE / IRRITATION

Causes serious eye irritation

RESPIRATORY OR SKIN SENSITISATION

May produce an allergic reaction.

Contains:
2,4,7,9-tetramethyl-5-decyne-4,7 diol

GERM CELL MUTAGENICITY

Does not meet the classification criteria for this hazard class

CARCINOGENICITY

Does not meet the classification criteria for this hazard class

REPRODUCTIVE TOXICITY

Does not meet the classification criteria for this hazard class

STOT - SINGLE EXPOSURE

Does not meet the classification criteria for this hazard class

STOT - REPEATED EXPOSURE

Does not meet the classification criteria for this hazard class

ASPIRATION HAZARD

Does not meet the classification criteria for this hazard class

SECTION 12. Ecological information

This product is dangerous for the environment and the aquatic organisms. In the long term, it have negative effects on aquatic
environment.

12.1. Toxicity

2-(2-BUTOXYETHOXY)ETHANOL
LC50 - for Fish 1300 mg/l/96h
EC50 - for Crustacea > 100 mg/l/48h

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SECTION 12. Ecological information ... / >>

ACETONE
LC50 - for Fish 4042 mg/l/96h
EC50 - for Crustacea 1680 mg/l/48h

2-BUTOXYETHANOL
LC50 - for Fish 1474 mg/l/96h
EC50 - for Crustacea 1550 mg/l/48h
EC50 - for Algae / Aquatic Plants 911 mg/l/72h

SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM

LC50 - for Fish 9,2 mg/l/96h
EC50 - for Crustacea 3,2 mg/l/48h

ETHANEDIOL
LC50 - for Fish 72860 mg/l/96h
EC50 - for Crustacea > 100 mg/l/48h
EC50 - for Algae / Aquatic Plants 6500 mg/l/72h

2-DIMETHYLAMINOETHANOL
LC50 - for Fish 146,6 mg/l/96h
EC50 - for Crustacea 98,4 mg/l/48h
EC50 - for Algae / Aquatic Plants 34,47 mg/l/72h

12.2. Persistence and degradability

2-(2-BUTOXYETHOXY)ETHANOL
Solubility in water 1000 - 10000 mg/l
Rapidly degradable

ACETONE
Rapidly degradable

2-BUTOXYETHANOL
Solubility in water 1000 - 10000 mg/l
Rapidly degradable

SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM

Rapidly degradable

ETHANEDIOL
Solubility in water 1000 - 10000 mg/l
Rapidly degradable

2-DIMETHYLAMINOETHANOL
Solubility in water 1000 - 10000 mg/l
Rapidly degradable

TITANIUM DIOXIDE
Solubility in water < 0,001 mg/l
Degradability: information not available

12.3. Bioaccumulative potential

2-(2-BUTOXYETHOXY)ETHANOL
Partition coefficient: n-octanol/water 1

ACETONE
Partition coefficient: n-octanol/water -0,23
BCF 3

2-BUTOXYETHANOL
Partition coefficient: n-octanol/water 0,81

ETHANEDIOL
Partition coefficient: n-octanol/water -1,36

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SECTION 12. Ecological information ... / >>

2-DIMETHYLAMINOETHANOL
Partition coefficient: n-octanol/water -0,55

12.4. Mobility in soil

SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM

Partition coefficient: soil/water 1,78

12.5. Results of PBT and vPvB assessment

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.

12.6. Other adverse effects

Information not available

SECTION 13. Disposal considerations

13.1. Waste treatment methods

Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this
product should be evaluated according to applicable regulations.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

SECTION 14. Transport information

The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by
Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA)
regulations.

14.1. UN number

Not applicable

14.2. UN proper shipping name

Not applicable

14.3. Transport hazard class(es)

Not applicable

14.4. Packing group

Not applicable

14.5. Environmental hazards

Not applicable

14.6. Special precautions for user

Not applicable

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

Information not relevant

SECTION 15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Seveso Category - Directive 2012/18/EC: None

Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006

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SECTION 15. Regulatory information ... / >>

Product
Point 3
Contained substance
Point 55 2-(2-BUTOXYETHOXY)ETHANOL
Reg. no.: 01-2119475104-44

Substances in Candidate List (Art. 59 REACH)

On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%.

Substances subject to authorisarion (Annex XIV REACH)

None

Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012:

None

Substances subject to the Rotterdam Convention:

None

Substances subject to the Stockholm Convention:

None

Healthcare controls
Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the
risks related to the workers' health and safety are modest and that the 98/24/EC directive is respected.

VOC (Directive 2004/42/EC) :

Two-pack performance coatings.

German regulation on the classification of substances hazardous to water (VwVwS 2005)

WGK 3: Severe hazard to waters

15.2. Chemical safety assessment

No chemical safety assessment has been processed for the mixture and the substances it contains.

SECTION 16. Other information

Text of hazard (H) indications mentioned in section 2-3 of the sheet:

Flam. Liq. 2 Flammable liquid, category 2

Flam. Liq. 3 Flammable liquid, category 3
Acute Tox. 3 Acute toxicity, category 3
Acute Tox. 4 Acute toxicity, category 4
Asp. Tox. 1 Aspiration hazard, category 1
STOT RE 2 Specific target organ toxicity - repeated exposure, category 2
Skin Corr. 1B Skin corrosion, category 1B
Eye Irrit. 2 Eye irritation, category 2
Skin Irrit. 2 Skin irritation, category 2
STOT SE 3 Specific target organ toxicity - single exposure, category 3
Skin Sens. 1 Skin sensitization, category 1
Aquatic Chronic 2 Hazardous to the aquatic environment, chronic toxicity, category 2
Aquatic Chronic 3 Hazardous to the aquatic environment, chronic toxicity, category 3
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H331 Toxic if inhaled.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H332 Harmful if inhaled.
H304 May be fatal if swallowed and enters airways.
H373 May cause damage to organs through prolonged or repeated exposure.
H314 Causes severe skin burns and eye damage.
H319 Causes serious eye irritation.
H315 Causes skin irritation.
H335 May cause respiratory irritation.
H317 May cause an allergic skin reaction.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
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SECTION 16. Other information ... / >>

H412 Harmful to aquatic life with long lasting effects.
EUH066 Repeated exposure may cause skin dryness or cracking.

LEGEND:
- ADR: European Agreement concerning the carriage of Dangerous goods by Road
- CAS NUMBER: Chemical Abstract Service Number
- CE50: Effective concentration (required to induce a 50% effect)
- CE NUMBER: Identifier in ESIS (European archive of existing substances)
- CLP: EC Regulation 1272/2008
- DNEL: Derived No Effect Level
- EmS: Emergency Schedule
- GHS: Globally Harmonized System of classification and labeling of chemicals
- IATA DGR: International Air Transport Association Dangerous Goods Regulation
- IC50: Immobilization Concentration 50%
- IMDG: International Maritime Code for dangerous goods
- IMO: International Maritime Organization
- INDEX NUMBER: Identifier in Annex VI of CLP
- LC50: Lethal Concentration 50%
- LD50: Lethal dose 50%
- OEL: Occupational Exposure Level
- PBT: Persistent bioaccumulative and toxic as REACH Regulation
- PEC: Predicted environmental Concentration
- PEL: Predicted exposure level
- PNEC: Predicted no effect concentration
- REACH: EC Regulation 1907/2006
- RID: Regulation concerning the international transport of dangerous goods by train
- TLV: Threshold Limit Value
- TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
- TWA STEL: Short-term exposure limit
- TWA: Time-weighted average exposure limit
- VOC: Volatile organic Compounds
- vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation
- WGK: Water hazard classes (German).

GENERAL BIBLIOGRAPHY
1. Regulation (EU) 1907/2006 (REACH) of the European Parliament
2. Regulation (EC) 1272/2008 (CLP) of the European Parliament
3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament
4. Regulation (EU) 2015/830 of the European Parliament
5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament
6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament
7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament
8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament
9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament
10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament
11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament

- The Merck Index. - 10th Edition

- Handling Chemical Safety
- INRS - Fiche Toxicologique (toxicological sheet)
- Patty - Industrial Hygiene and Toxicology
- N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition
- IFA GESTIS website
- ECHA website
- Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy

Note for users:

The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the
suitability and thoroughness of provided information according to each specific use of the product.
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current
health and safety laws and regulations. The producer is relieved from any liability arising from improper uses.
Provide appointed staff with adequate training on how to use chemical products.

EPY 9.4.7 - SDS 1004.7