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CH04 Test

The document is a self-assessment test for Chapter 4: Chemical Thermodynamics, consisting of multiple choice questions, very short answer questions, short answer questions, and long answer questions. It covers topics such as enthalpy of formation, spontaneous reactions, and Hess's law. The test is designed to evaluate understanding of key concepts in thermodynamics within a one-hour timeframe for a total of 20 marks.

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aameenaakhan07
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21 views2 pages

CH04 Test

The document is a self-assessment test for Chapter 4: Chemical Thermodynamics, consisting of multiple choice questions, very short answer questions, short answer questions, and long answer questions. It covers topics such as enthalpy of formation, spontaneous reactions, and Hess's law. The test is designed to evaluate understanding of key concepts in thermodynamics within a one-hour timeframe for a total of 20 marks.

Uploaded by

aameenaakhan07
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Ravi

SELF ASSESSMENT TEST FINAL

(Chapter 4 : Chemical Thermodynamics)

Time : 1 Hour ] [Marks : 20

Notes :
1. All questions are compulsory.
2. Figures to the right indicate full marks.

SECTION – A
Q. 1. Multiple Choice Questions (MCQ) : (1 mark each)
(i) The enthalpy of formation for all elements in their standard states is
(a) unity (b) zero (c) less than zero (d) more than one [1]

(ii) The correct thermodynamic conditions for the spontaneous reaction at all
temperatures are
(a) H  0 and S  0 (b) H  0 and S  0
(c) H  0 and S  0 (d) H  0 and S:0 [1]

(iii) A gas is allowed to expand in a well insulated container against a constant


external pressure of 2.5 bar from an initial volume of 2.5 L to a final volume of
4.5 L. The change in internal energy, U of the gas will be
(a) 9500 J (b) ;500 J (c) 91013 J (d) ;1013 J [1]

(iv) In which of the following, entropy of the system decreases ?


(a) Crystallisation of liquid into solid
(b) Temperature of crystalline solid is increased from 0 K to 115 K
(c) H (g) ; 2H(g)

(d) 2NaHCO (s) ; Na CO (s) ;CO (g) ;H O(g) [1]
    
Q. 2. Very Short Answer Questions (VSA) : (1 mark each)
(i) Define isolated system. [1]

(ii) What is an isochoric process ? [1]

SECTION – B
Q. 3. Short Answer Questions (SA-I) : (2 marks each)
(i) Derive the expression for maximum work. [2]

(ii) Calculate the maximum work when 24 g of O are expanded isothermally and

reversibly from the pressure of 1.6 bar to 1.0 bar at 298 K. [2]

SELF ASSESSMENT TEST : CHEMISTRY XII (PART – 1) [CHAPTER 4] 1


Ravi
SECTION – C FINAL

Q. 4. Short Answer Questions (SA-II) : (3 marks each)


(i) (a) Write an expression for pressure volume work.
(b) Obtain the relationship between H and U for gas phase reactions. [3]
(ii) Calculate the standard enthalpy of formation of CH OH(l) from the following

data :
3
(i) CH OH(l) ; O (g) ; CO (g) ;2H O(l), H:9726 kJ mol\
 2   
(ii) C (Graphite);O (g) ; CO (g), cH:9393 kJ mol\
 
1
(iii) H (g) ; O (g) ; H O(l), fH:9286 kJ mol\ [3]
 2  

SECTION – D
Q. 5. Long Answer Questions (LA) : (4 marks)
(a) State Hess’s law of constant heat summation. Illustrate with an example. State
its applications.
(b) Determine whether the following reaction is spontaneous under standard
conditions.
2H O(l) ;O (g) IIIIIJ 2H O (l) H: ;196 kJ, S°: 9126 JK\.
   
Does it have a cross-over temperature ? [4]

Verify your answers with the model answers given on this link.
https://bit.ly/3cgjagr
2 SELF ASSESSMENT TEST : CHEMISTRY XII (PART – 1) [CHAPTER 4]

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