;loti ons Assignment
- uta m
Gia
l
G. S. Tutorials
il [email protected]
Ph. - 0161-2678660, Mobile No. 94173-87754, E-ma
- 141010.
H.1.G. 961, Punjab Housing Board Colony, Ludhiana
Q 16. 0.5 KCI was dissolved in I00 g water and
the solution
Q 1• _Whe~ and why is molality preferred over molarity in
handling originally at 20°C, froze at -0.24°C. Calculate the percentage
solutions m chemistry? ionization of salt Kr per I 000 g of water= I .86°C.
acetic a
Q _2. A solutions contains 25% water , 25% ethanol and 50% Q J7. 2.0 g of benzoic acid dissolved in 25.0 g of benzene shows
ion
acid by mass. Calculate the mole fraction of each compound. depression in freezing point equal to I .62 K. Molal depress
age
constant ( Kr) of benzene is 4.9 K kg mol- • What is percent
1
Q 3. A solution contains 2.80 moles of acetone and 8.20
moles of
association of the acid ?
chlorofonn. Calculate the mole fraction of acetone.
ng Q 18. 0.01 m aqueous solution of K 3 [Fe(CN)6] freezes at-0.062°C.
Q 4. Calculate the molaJity of a solution obtained by dissolvi What is the apparent percentage of dissociation ? (Kr for water
=
15.87 g ethyl alcohol (C 2H5OH) in 168 g of water (H2O). 1.86 K kg mor )
1
ng
Q 5. Determine the molality of a solution formed by dissolvi Q 19. State and derive Raoult's law for a solution contain
ing
0.850 g ofNH3 in JOO g of water. non-volatile solutes.
Q 6. The density of I0% by mass of KCI solution is 1.06
g cm-3•
Q 20. Define molarity and mole fraction.
Calculate the molarity of this solution.
22 Q 21. Distinguish between ideal and non-ideal solutions ?
Q 7. The vapour pressures of pure liquids A & B at 20°C are
and 75 mm of Hg respectively. A solution is prepared by mixing
Q 22. Define the tenn-colligative properties.
equal moles of A and B assuming the solution to be ideal,
caJculate the vapour pressure of the solution. y.
Q 23. Define osmotic pressure. Show that it is a colligate propert
of
Q 8. Vapour pressure of water at 293 K is 17.51 mm. Lowering
e of a sugar solution is 0.0614 mm. Calculate Q 24. What are isotonic solutions ? Give one example.
vapour pressur
[a] Relative lowering of vapour pressure
Q 25. What is van 't Hoff factor ?
[b] Vapour pressure of the solution and
[~] Mo!e fraction of-water Q 26. When is the value of van 't Hoff factor more then one
?
Q 9. The vapour pressure of pure water at 30°C is 3 I.80 mm
of Hg.
d in Q 27. Define Azeotropic Mixture.
How many grams of urea (molar mass 60) should be dissolve
J00 g of water to lower the vapour pressure by 25 mm of Hg ? n
Q28. What is Van 't Hoff factor? How does it modify the equatio
ed for elevation of boiling point?
Q 10. Osmotic pressure of a solution containing 7 g of dissolv Q29.Mention a large scale use of phenomenon called reverse
Hg at body temperature
protein per J00 cm of solution is 25 mm
3
osmosis?
(3 JO K). calculate the molecular mass of the protein (R = 0.08205
1
lit. atm. mol- 1 deg- ) has
Q30.H 2SO4 used in lead storage cell is 38% by mass and
3
density 1.30 g/cm . Calculate its molarity?
Q I J. A solution containing I0.2 g glycerine per litre of a solution
mass
is found to be isotonic with 2.0% solution of glucose(Molar to
molecu lar mass of glycerine. Q3 l. What is the molal elevation constant Kb? How is it related
180). Calculate the solution ?
molality of a
water
Q 12. A solution of 12.5 g of an unknown solute in 170 g of te
mass Q32. The vapour pressure of water is 12.3 Kpa at 300 K. Calcula
give a boiling point elevation of 0.63 K. Calculate the molar pressure of I molar solution of a solute in it.
1 ) vapour
of solute (Kti = 0.52 K/m-
and
g of Q33.State Raoult's law for solutions. Why do water & ethanol
Q 13. The boiling point of a solution containing 1.5 State
I 00 g of benzene was higher by 0.268°C. chlorofonn & acetone solutions deviate from Raoult's law?
dichlorobenzene in
obenzene. the nature of deviation in each and the reason for it?
Calculate the molar mass dichlor
1
(Kb= for benzene= 2.62Km- ) with
Q34. Why does molality of a solution remain unchanged
the 3 change in temperature while the molality changes?
Q 14. The boiling point of water ( I00°C) becomes I00.52. if
solute is dissolved in 20 ml of it. Calculate the
g of non-volatile two
1 Q35. When outer shell of two eggs are removed, one of the
molar mass of the solute (Kb = 0.52 Km- ). Also find freezing in pure water and other is placed in saturated
is o0c eggs is placed
point of this solution given that freezing point of pure water why?
1 solution of NaCl , what will be observed and
and Kr= 1.86 Km· .
e is
0.6 Q36. What is a colligative property? Show that osmosis pressur
Q 15. an aqueous solution of an organic compound containing
water freezes at 272.187- K. If the value of Kr for a colligative property.
g in 2 I. 7 g of
at 273 K, what is the
water is 1.86 deg I molality and it freezes
Q37.On dissolving 3.24 g of sulphur in 40 g of benzene, boiling
molecular mass of the organic compound? Kb for
point of solution was higher than that of benzene by 0.81 K.
2.53 K Kg mol-1. What is the molecu lar formula of
benzene is
sulphur? (Atomic mass of sulphur= 32 g mol-1)
solutions Assignment
A) Which of following form ideal solution:-
Q38. Arrange following solutions in order of increasing boiling
points:- i) Ethanol +water
a) 0.1 M KCl b) 0.1 M Urea ii) Methanol +water
.
c) 0.1 M AlCh d) 0.1 M BaCl2 iii) Benzene + Toluene
Assume I00 % dissociation in which ever case it is possible.
iv) HCl +Water
Q39. Arrange following solutions in order of increasing melting B) What happens in case of negative deviation
points:-
a) 0. I M KCI b) 0.1 M Urea
c) 0.1 M A1Cl 3 d) 0.1 M BaCl2 i) I.M.forces increase on mixing
Assume 100 % dissociation in which ever case it is possible. ii) I.M.forces decrease on mixing
Q40. Arrange following solutions in order of increasing boiling iii) I.M.forces remain same on mixing
points:- iv) I.M.forces have no role
a) 0.2 M KCl b) 0.35 M Urea
c) 0.1 M AlCl 3 d) 0.15 M BaC12
Assume 100 % dissociation in which ever case it is possible. C) Minimum boiling azeotrope is formed by
Q41. Arrange following solutions in order of increasing osmotic
pressure:- i) Ethanol +water
a) 0.2 M KCl b) 0.35 M Urea ii) Methanol +water
d) 0.15 M BaC)i
c) 0.1 M K3[Fe(CN)6] iii) Benzene+ Toluene
Assume I00 % dissociation in which ever case it is possible.
iv) HCl +Water
Q42. Vapor pressure of an ideal liquid mixture of liquids A and B
is given by the formula:- Q2. Some solid substances dissoci~te int? i~ns
p= (140 xA + 60) mm of Hg
Find vapor pressures of pure A and pure B. Also find vapor when dissolved in water .Due to this colhgat1ve
pressure of a mixture containing 1 mol of A and 2 moles of B. properties get changed. Hence we have to apply _a
factor called van't hoff factor(i) . Based on this
Q43. What concentration of nitrogen should be present in a glass of
_ water at room temperature? Assume temp of 25° C ,total pressure information answer the following questions:-
- - -
of I atrn and-mole fraction-of nitrogen in afr as 0.78 l Ki; for
nitrogen =8.42 x 10- M/mm of Hg] [Ans.4.99x10-4M] A) What is relation between van't hoff factor and
7
Q44. Calculate the solubiJity of H2 in water at 25° C if its partial degree of dissociation
pressure above the solution is I Bar.Given that Henry's constant
for H2 in water at 25°C is 71.18 kBar. [Ans. 7. 79X l 0-4M] i-1 i-1
i) (l -1 ii) a=--
n
Q45. Arrange the foJJowing in increasing order of osmotic pressure
--1
n
a)34.2 g/litre sucrose b)60 g/litre Urea i-1 i
c)90 g/litre glucose d)58.5 g/litre NaCl iii) u--- - iv) a. =-
n-1 n
Assume I 00% dissociation in what ever case it is possible.
Q46. Explain why equimolar solutions of sodium chloride and B) What is van't hoff factor if CaCh is 80 %
sodium sulphate are not isotonic?
dissociated.?
Q47. For the electrolyte Ax By derive a relation between degree of
dissociation and Van 't Hoff factor(i). i) 1.6 ii) 2.6
Q48.A solution containing 30 g of a non- volatile solute in 90 g of
water has a vap pressure of 2.8 kPa at 298 K'. When 18 g of water is iii) 2.4 iv) 1.8
added more vap pressure becomes 2.9 kPa .Calculate
a)molar mass of solute
b) Vapour pressure of water at 298 K C) What is degree of dissociation of AlCh if van't
hoff factor is 3.1?
Case study questions
i) 60 % ii) 80 %
Q1. When two liquids are mixed then three types
of solutions are formed. Ideal solutions which iii) 90 % iv) 70 %
obey Raoult' s , non ideal solutions which show
~egative or positive deviations. Based on above
tnfonnation ans\ver the follov.ring questions:-
