CHEMISTRY BOARDS IMPORTANT MCQ's
CHEMISTRY BOARDS IMPORTANT MCQ's
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Chapter-2: Solutions
1. Sugar dissolves in water because
(a) sugar is nonpolar (b) water is polar
(c) it forms hydrogen bonding with water (d) sugar and water are both polar
2. The solubility of a gas in water
(a) decreases with increase in temperature (b) increases with increase in temperature
(c) decreases with decrease in temperature (d) is not affected by temperature
3. The units of Henry’s law constant are
(a) bar dm3 mol–1 (b) mol L–1 bar–1 (c) L mol–1 bar–1 (d) bar L–1 mol–1
4. The colligative properties of solutions
(a) depend on nature of solute particles
(b) do not depend on number of solute particles
(c) do not depend on dissociation of solute in solvent
(d) depend on number of solute particles
5. Which of the following solutions /solvent has maximum vapor pressure ?
(a) 1M copper sulphate solution (b) pure solvent water
(c) 0.5M copper sulphate solution (d) 2M copper sulphate solution
6. According to Raoult’s law, relative lowering of vapor pressure of solution containing dissolved non-volatile
solute
(a) is equal to mole fraction of solvent (b) is equal to mole fraction of solute
(c) does not depend on mole fraction of solute (d) is equal to molality of solution
7. Freezing point depression constant of a solvent is
(a) inversely proportional to molality of solution (b) directly proportional to molarity of solution
(c) directly proportional to molality of solution (d) expressed in K kg mol–1
8. Which of the following statements is applicable for 0.1M urea solution and 0.1M sucrose solution?
(a) osmotic pressure of urea solution is greater than that of sucrose solution
(b) osmotic pressure of sucrose solution is greater than that of the urea solution
(c) sucrose solution is not isotonic with urea solution
(d) both the solutions have the same osmotic pressure
9. The Henry’s law constant of a gas is 6.7 × 10–4 mol/(L bar). Its solubility when the partial pressure of the gas at
298 K is 0.65 bar is..
(a) 4.355 × 10 –4 mol/L (b) 4.355 × 10 –2 mol/L
(c) 2.225 × 10 –6 mol/L (d) 2.225 × 10 –2 mol/L
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2.
H3O(aq)
For a reaction HCl(aq) + H2O(1)
Cl((aq)
–)
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6. (d) 7. (b)
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6. (b) 7. (c)
Chapter-05 : Electrochemistry
1. Kohlrausch law is applicable for _______
(a) the solution at infinite dilution (b) a concentrated solution
(c) concentrated as well as dilute solution (d) aqueous solution
2. During electrolysis of molten NaCl, which of the following statement is Incorrect?
(a) a pale green Cl2 gas is released at anode
(b) molten silvery white sodium is deposited at cathode
(c) decomposition of NaCl into Na metal and Cl2 gas
(d) a pale green Cl2 gas is released at anode
3. SI unit of conductivity is ______
(a) Ω–1 m–1 (b) Ω cm–1 (c) Ω m–1 (d) Ω–1 m 2mol–1
4. In case of weak electrolyte the graph /\ vs c is ______
(a) Linear (b) Non linear
(c) Straight line passing from origin (d) Curved
5. In construction of Standard Hydrogen Electrode, platinum acts as _____
(a) inert electrode (b) positive ion producing electrode
(c) negative ion producing electrode (d) donor of electrons
6. For hydrogen gas electrode E H2 is calculated through Nernst equation, where E 0H2 is always
(a) 0V (b) 0.0592V (c) –1.1V (d) 1.1V
7. When molten ionic compound is electrolyzed a metal is formed at _____
(a) Negative electrode (b) Positive electrode (c) Salt bridge (d) Electrolyte
8. The molar conductivity and conductivity of AgNO3 solution are 121.4 Ω cm 2 mol and 2.428 × 10–3 Ω–1 cm–1
–1 –1
9. A cell constituted by two electrodes A ( E 0A /A = 0.35V) and B ( E 0B /B = +0.42V) has value of E 0cell cell equal
to
(a) 0.07V (b) –0.07 V (c) –0.77V (d) 0.77 V
10. Calculate E 0cell cell for galvanic cell with electrodes Co/Co3+, Mn 2+/Mn, E 0Mn = –1.18V, E0Co =1.82 V.
(a) –3.0V (b) + 3.0V (c) 1.36V (d) 0.268V
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6. (c) 7. (a)
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6. (c) 7. (b)
6. (a) 7. (c)
Chapter -12 : Aldehydes, Ketones and carboxylic acids.
1. Which of the following is the product of reaction of ethane nitrile with Grignard reagent followed by acid
hydrolysis?
(a) a ketone (b) an aldehyde (c) an acid (d) an acid chloride
2. ______ reaction is used to synthesize straight alkyl substituted benzenes.
(a) Etard (b) Rosenmund reduction
(c) Stephen reaction (d) Wolf Kishner reduction
3. Ketones can NOT be converted into carboxylic acid using ____.
(a) acidic KMnO4 (b) CrO3
(c) dil.HNO3 (d) Hot and conc. HNO3
4. Correct order of acid strength for
i) acetic acid ii) fluoroacetic acid
iii) 4-Nitrobenzoic acid iv) 4-Methyl benzoic acid is ______
(a) i > ii > iii > iv (b) ii > iii > iv > i (c) iii > iv > i > ii (d) iv > i > ii > iii
5. Addition of sodium bisulphite to ethanol is ______ type of reaction.
(a) electrophilic addition (b) electrophilic substitution
(c) nucleophilic addition (d) nucleophilic substitution
6. The following reactants Can’t be converted into carboxylic acid?
(a) Dry ice (b) Cyclohexane (c) Toluene (d) Cyclohexene
7. The following compounds will give a positive Fehling’s test.
(a) Propandane (b) Pentan-3-one (c) Butanone (d) Butan-2-ol
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6. (b) 7. (d)
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6. (d) 7. (c)
Chapter- 14 : Biomolecules
1. Glucose on oxidation with dilute nitric acid gives ______
(a) saccharic acid (b) oxalic acid (c) gluconic acid (d) malonic acid
2. The glycosidic linkage in maltose is formed between ______
(a) C-1 of α-D glucose and C-2 of α-D glucose (b) C-1 of α-D glucose and C-4 of α-D glucose
(c) C-1 of α-D glucose and C-2 of α-D fructose (d) C-1 of α-D glucose and C-4 of α-D fructose
3. The optically inactive α- amino acid among the following is ______
(a) alanine (b) insulin (c) leucine (d) glycine
4. The sugar component of nucleotide unit in RNA is ______
(a) α- deoxy-D-ribose (b) D-ribose (c) L-ribose (d) 2-deoxy-L-ribose
5. The chemical nature of peptide bond in proteins is ______
(a) primary amide (b) secondary amide (c) tertiary amide (d) an ionic bond
6. In which of the following structure of DNA carries genetic information of the organism
(a) the primary structure of DNA (b) the double helix structure of DNA
(c) complementary base pairing (d) sugar-phosphate backbone
7. In the process of denaturation, there is NO change in the structure following protein
(a) primary (b) secondary (c) tertiary (d) quaternary
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6. (a) 7. (a)
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6. (d) 7. (b)
Chapter-16 : Green Chemistry and Nano-chemistry
1. Bottom ash of thermal power stations can be used as raw material for cement and brick industry. This example
illustrates which of the following principle of green chemistry
(a) Atom economy (b) Designing safer chemicals
(c) Design for energy efficiency (d) Prevention of waste or by products
2. Less hazardous chemical synthesis point of view instead of harmful DDT Now a days ______ is used as
insecticides
(a) Benzene (b) BHC (c) Chlorobenzene (d) Ethanol
3. The concept that aims to maximize efficiency and minimize hazardous effect on human health and environment
was coined by Paul T.Anastas
(a) Green revolution (b) Blue revolution (c) Nano chemistry (d) Green Chemistry
4. Nanorods are the example of ______
(a) One dimensional nanostructure (b) Two Dimensional nanostructure
(c) Three dimensional nanostructure (d) Zero dimensional nanostructure
5. Which nanoparticles act as highly effective bacterial disinfectants, removing E.Coli from water?
(a) Gold nanoparticles (b) Silver nanoparticles (c) TiO2 nanoparticles (d) ZnO nanoparticles
6. Catalyst used for hydrogenation of oil is ______
(a) V2O5 (b) Fe (c) Raney Ni (d) MnO2
7. In green technology developed by Drath and Frost, adipic acid is enzymatically synthesized from
(a) Sucrose (b) lactose (c) maltose (d) glucose
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6. (c) 7. (d)