wi oy ( maniite hes redfny Crp should be mini, | J ae Od be mirrise- dor yy F ene ate nal fitin Tethts blocking the for pant t cei sat i 0 sueet code: BAS PAPER D-311236 ott No: [TTL orc HEMISTRY ENGINEERIN TIME: sHRS__ ait then choke suitably Note: 1, Attn ectons, 1rqulre any missing dt Se all questions in bret [95 sc tS gmat Fasoy meld for pearing ie nanomateria dao shows ersten of 20% wen epl i ell of 25 ei Calculate ts concentation ithe molar absorptivity coelTicint i 12000dm mot em ale the effet of solvent on x + * transition in acetone Cael teen of hcl, ie standard woe al 1.54 V. Wie ‘all reaction [2 zal (024g (00028 fe) a2 <_ Wat oF pan ene ni ze ‘sample of coal contains 60% Carbon, 33% One, 6 07 Fyeopen, 0.5% Supa 0.2% Nitrogen and 0.3% Ash, Calculate ils GCY. 'E | What do you understand by Polymer Blends? 21 erepranVerascupbiertes VG &_] Draw molecular orbital diagram ENO. Caeulae their bond order and opie [7 ‘on their magnetic behaviors. a Verma Gi ibtuing effect involved in NMIR spectroscepy.. take PMR toe coed eis Kean Onpuie empourd (OE a en yi 52¢ Ok eg Fad the structure of compound, Tlustrate the various steps involved during manufacturing of Roland cement with the |7 help of a labelled diagram Give the chemical reactions Ra ‘during setting and ws hardening of cement. Z| Compare merits and demerits of Zeolite and Ton ExepgndeInethod. i Discuss the preparation of Grignard Reagent. P Tinal product obtained when [7 (CoHsMgBr reacts with is l @HCHO (i) CH,CHO {CO _ (iv) COs ‘SECTIONC By Mlustrate the shielding and 3. Attempt any one part ofthe following [a Mnsrate any ive principles of Grgen Chemistry and the give green synthesis method for | 7 preparation of Paracetamol. Fea gid eras on gsi of femperatureand ive Ur ppitions in varios |7 fields. “Attempt any one part of the following: ——Tsymmetrically substituted compounds having even number of cumulative double vos |7 a optialomersm whereas compounds having od mumber of cumulative double bonds exhibit geometrical isomerism. Explain giving proper reasons. | Write short notes on (any TWO) i 7 \ {) UV Shift i) Applications of IR spectoseopy (i Molecule wbraton Attempt any one part of the following: 1[page ‘cqp24nP2_360 | 13-03-2024 08:51:31 | 115.245.130.58 erent® a1g0u ny r MEIN “Horgau opus 099) TTA O19 ta PAH 0. Woy 110 wsyggnt 2219 0 WML r Brnen (SEM 1) THEORY EXAMINATION 2023-24 ENGINEERING CHEMISTRY TIME: 3HRS M.MARKS: 70 a Tiiustrate the working, Gagrammatic representation and call reaction of Lead Acid | 7 storage battery during charging and discharging. | Briefly explain wet corrosion, How corrosion can be prevented by Metallic coating and | 7 using corrosion inhibitors? 6. Attempt any one part of the following: forimeter. A ]7 With the help of @ neat diagram, explain the working of Bomb cal @ sample of coal contain C=89%, H=8% and ash=3%. | ‘The following data were obtained when the above coal was tested in bomb | calorimeter: Weight of coal burnt= 0.85 g; Weight of water taken= 850 g Wotet equivalent of bomb and calorimeter= 3500 g; Rise in temperature= 2.5°Cs Fuse vane correction = 10.0 cal; Acid correction 50.0 cal; Cooling correction= 0.03 °C- ‘Assuming that the latent heat of condensation of steam as 580 cal/em, Calculate gross and net calorific values of the coal. b. Tilustrate the principle of lime soda process. i 30 ppm, HCO;'= 150 ppm, K’ = 68 ppm. Calculate the Lime (87% pure) litre of sample water. 3 7 Atempt any one part of the following) V NS - Classify conducting polymers anda ‘important applications Sy jonomer and polymer), properties & a mas of ‘Analysis of raw water gives the following dat 20 ppm, Mg** = 25 ppm, CO2 = “= 10 ppm. Anal reated water: COs*=45ppm,OH. | >> (91% pure) required to soften WAS b ‘Write the preparation (structure’®! the any THREE polymers: Q yi D \ (i) Buna-S_(ii) Nylon b> Gi Polyester (iv) Kevlar copii NS MeeT PIMP: 31 Note: __|figmre sere ya | F jain he mechanism of Hydrogen evolution and Oxygen absorption with the help Inject Code: BAS202 LLL EGE KOU (SEM H) THEORY EXAMINATION 2023-24 - ENGINEERING CHEMISTRY M.MARKS: 70, 10 0 1 i Rott 1. Attempy all Sections. Ifrequire any mays dat; ehwcve suitably SHOTION A Attenypy of questions in bet 2eTalA 1] Compare and arrange the following, in the increasing order of stability: Os, Ov ,0y | esafen@er oA gare wt athe FE A aged aner A carfeMeL “HE: O2, 07 | ©. } b How nanomaterials are different from bulk materials? | stale tay ara a ier ware fest 8 | [©] What ise seston rae or the molecu to vow NMR spectrum? | oy Gare NMR erga aed ere rar far rar BY all of Explain, whieh one will exhibit Higher value OF Dome in UV/Visible spectra CHCOCH) and CH=CHCOCHS, | i ease AAT AF CHyCOCH: HT CHy=CHCOCH: & UV EIFGA A Pam HT SET are ate seftter tT Calculate the EMF of the Daniel cell at 25°C when the concentration of ZnSO, and x80. are 0.001M and 001M respetney. The nad poeta ofthe el | sec ay saa da A EME sora BE ga ZnS04 3x CuSO4 HY FraaT HART: 0.001M 3 O.OIM RH er AY Ter FAs 1.1 ate Bl | Show with the help of reactions, how seale formation can be prevented by Calgon conditioning? ainiransit & welrar & Rare Per avila asterieiar cant het Prater ST aa der ot weet 8? Classify polymers on the basis of factilty (Stereochemisty). 8 soa reg & sree oe stferent a avigey et! il SECTION B Attempt any tree ofthe following 1x3=21 Fav] What are the Anisotropic enstals How fied on te basis of temperature? | Also give important applications. sifereietttes recor war Reefs Be STEER Gee AN aetteper Rea STAT toga aga sqgiar afr gare b. Explain the Absorption and Intensity shift in the UV speetroscopy and support with | examples. Illustrate, the effect of polar and non-polar solvent on m- x* transition in acetone? adh Reaghewhdh #& arautr athe ata act earEAT we She Sere ener worth ty ache Heat BapaTOT oe ee ate gate Fare Expl metallic lof electrochemical theory of corrosion. jable and sacrificial | coatings for preventing corrosion. Explain00m Sle cate Basan nono: TTT JON 2023-24 TRY (SeM 1) | aero Regeararaiaa Maui A warren A erggtarer Rrasrer atte SHareRra oreettwor oA AemfA AY cares at) are at tana a Fee | seperate fae ng abRtvar sf} exec the principle and working of the Zeollle process. A zeolite sof ed by passing SOL of NaCl solution having, strength of 40% of Na e the hardness of water if 100001, of hard water was softened by using thi d_| Tastee faaterge wither ay Rati afte are ar APT aL SOL, NaCl eet HF 40% (ech) oer arate aireTge etre a fas far sem ae Fe | Ssattarge ar seaiter a 10000, were ret wt area Pere rer at Tet Hr | ater A arora wt | Tilustrate the preparation of Grignard Reagents and predict the final product obtained when C2HsMgBr react with (i) HCHO (ii) CHsCHO (iii) (CHs),CO. faves aftastet fr darft ar avi wt Ste CoHsMgBr (i) HCHO (ii) (CHy),CO & ret wera Fe aT grea aif seare Sr CH;CHO | sxteararoft at 3. Attempt any one part of the followin Txl=7 | (@) | Draw the molecular orbital\diagram of NO and N molecules. Calculate [their bond nRY order and predicts their magnetic behavior. || No ste No arepit a storia safer antes eer) germ ay sear At TTA | at sit sae date caaen & afascarott wt) Discuss any FOUR principles of Green Chemistry. Explain the conventional and Green route synthesis of paracetamol. gita core & Pest on Rapist oe get wt) Saimin ste afta art deasor AY career wt S Aitempt any one part of the following: | (a) | Comment on any TWO of the followi | (i) Lambert- Beer’s Law shielding effect, | favafafa # & Peg ghyae eat wt: (i) Sraé-dra apr fama (ii) HOT AIT (iii) SPeearor Ste Fa-aRRareT gaa) (| WWhy Tetra Methyl Silane is used as an internal indicator in NMIR spectroscopy? A compound have molecular formula CigHu. The H! NMR spectra of the molecule gave | | the following data: A: 5 1.30 (9H, singlet); 6 7.28 (SH, singlet) Giving reasons deduce the structures for the molecule: moa (Molecular vibration (iii)Shielding and de-a | a | BTECH (SEM Il) THEORY EXAMINATION 2023-24 MIE: 3 HRS ENGINEERING CHEMISTRY : M.MARKS: 70 ray ae | ) T renga Pde ar squher wawaane Htacea a safes whee | SoA eat RET rar Rr athe ay aioe YT Coll Bl SOY HH! NMR Sieg & cafatea ser Rar: A: § 1.30 GH, singlet); § 7.28 (SH, singlet) SRO SA BE Oy AY eae a aie att (ii) How many NMR signals are expected in the NMR spectra of ethanol in aqueous condition? Explain their splitting, (i) TaD Hee A star NMR Stag A Prey NMR Bart STA far So sae Reno A carear Afar) 5 Afiempt any one part of the following: Txl=7 — (a) | Diflerentiate between primary and Secondary batteries? Discuss the various reactions involve during the charging and discharging of lead storage battery. greta at efactaw aeftat a dhe afer aerger as wetter Ach & aT ~ Sh Beatie & dha af ah Ret sfefresit we gel Fisch {b) | Describe the various steps involved dufing Portland cement manufacture by rotary kiln method. Explain the settingyand Kardening of cement with relevant chemical reactions involved, C ett acer fie gant ges ete Prater & ehra efter faReet aeih FT aia Ft! unite carafe vfatresit & eer die st Afcer stk qed ae Fr caret 6 Ajiemp! any one part of the following: TxI=7 amount | (2) | Explain the principle of water softening by lime — soda process. Calculate the lime and soda required for 100,000 L of water containing the following salt: Mg"= | 48 ppm, Ca® = 120ppm, FeSO. 7H:0 = 139 pomp, COrB8ppm, NaNOs = 89pm. HCOs = 122 ppm. c arate sir Zann aa wr IG weg Fea ST HAGIEA eaAaTeT lame Wee 100,000 tex or a fale. saves aa ate ett fy ArT FT aorat at Mg’*= 48 drt, Ca =/120 HTH, FeSOs.7H20 = 139 ea, | cor=88 drdtea,, NaNO; = 8.9. STATA, HCOs' = 122 arial 7B) | With the help ofa neat diagram éxplain the working of Bomb calorimeter. A sample | ofcoal contain C=9 1%, H=68%/ N-2% and ash= 1%. The following data were obtained when the above coal was tested in bomb calorimeter: Weight of coal burnt= 0.97 g Weight of water taken= 800 g Water equivalent of bomb and calorimeter= 2100 | Rise in temperature= 2.48°C | Fuse wire correction = 12.0 cal | Acid correction= 58.0 cal Cooling correction= 0.015 °C ‘Assuming that the latent heat of condensation of steam as 587cal/g, Calculate gross and net calorific values of the coal.NA NN a. Roll No: [ ubject Code: BAS202 ie lalgl | | BTECH (SEM nm) THEORY EXAMINATION 2023-24 IME: 3 HRS NGINEERING CHEMISTRY kimi _M.MARK: | WH MTH-QUt ater FH aera B, aa thoithrater At prdsonat y careca | amt) ahaa BH Ua ART A C-91%, H-6%, N=2% BH T=1% Bl aa se | tad ar oheror war Seether A rar aren at fersarferie Ber ot Ee | SANT AT HAS ST TaA= 0.97 AT \ | Sar sa Tel aT AsrA= 800 TT | | ga Bk Helfer F seat Tel= 2100 TT | | argarat & gefa= 248°C | || apr rae gene = 12.0 att | | fas qUR= 58.0 okt | ahaa YUR= 0.015 °C | se mae rare Huet eT Te eT ATTA BT awa ate gee fetta A aera FR | ‘Agiempt any one part of the following: Txi=7 [(@) | Give preparation, properties and Applications Of following polymer: JOG. Neoprene (ii) Terylene Gi) Nylon 6.6. eafafedt agen 4 P| Lat ie sqpeier sage: (i Frais (iy Bret iy ert 66. N We | Classify the Conducting polymers and explain its different types Go| Mention Ws applications also. . 2 ak wags er Fe AT ET A ST | gece arapvaiter oft segaSub Code: BAS 202 rot No. [213161316106 1 Lebor ri B1 B.TECH ORY EXAMINATION 2022-23 FRING CHEMISTRY Printed Pages Paper Id (SEM- 1) THE ENGINE. Time: 3 Hours Total Marks: 70 ea 03 ure got: 70 Note: 1. Attempt all Sections. I? require any missing data; then choose suitably, English Language oF 2. The question paper_may be answered in Hindi Language in the mixed language of Hindi and English, as per convenience, ste 1, ee weet ar were DIET Roel wer oneteery Ber ar weed ot eT ht Ref A quam Ver Gia HPHHY WE) eet TY] 2. eat ay eee BY bey efeeargee Ree rn, rah aaray tera AAT ee atch @) PB arg at vale fra ot wert Bt SECTION A. 2x7=14 1, Attempt aif questions in brief, fret ait weet or sta A sere ATE {Draw the molecular energy level diagram for CO, Calculate its bond order and explain its magnetic behavior co % far sofas sat ax atte gar ah ats arse Ay ro Fe ote ea aaa oraer Ff are Fe Predict the number of signals and their splitting patterns in 'H NMR of CHyCChCH, and CH;OCH;CHs CH,CCI,CH34% CH;OCH;CH3% 'H NMR # aa aft ear ate sae Prats fet 1 aa FEL Two Isomers X and ¥ having molecular formula CHO give IR band near 3550 em” or and 1717 cm’ respectively, Assign structural formula to X and ¥ consistent with their IR absorption band, arofaes = CyHgO aT @ area X ate Y wT: 3550 om" AAC 1717 em afta IR 4 2a BX ote YA SAH IR ait ae age eicarrars a PARE Ft What is electrochemical series? What is the potential of a half cell consisting of zine electrode in 0.01M ZnSO, solution at 25°C. E= 0.763V sarah farat FAT 22 25°C FE 0.01M ZnSO, ste # Farr eeagtS A ae aE ea Ft fart FT ATT? B'= 0.763V WG _ Diferemiate between Gross and Net calorific value ater afte Fe Sei ara ats stare BE Discuss the preparatign and uses of Nylon- 6,6, areratte-6,6 4 are are sort Fs fea ATA Give the structures of FOUR compounds used as initiators in Free Radical (d) ( 4 polymerization. i sft rarer rtrerrestert aroerratalt 567 H aeTT Poe ot are are aa AYyw (a) SECTION B qx3=21 pree of te follow! fre et OT TUR AH | quid crystals. Distinguish ree amportant applications ee Men ey fac FAA AAP afer eaten Pairs Pret between nematic and smectic sos the classification of tid ystals. C piscu Tiquid et fare freee arnt att itr TATE can a a having ever number of curnulative double ssyminetily substi compounds Having ot number of bans eae bonds exlibit geomareal tomers” Wxpluin giving proper emu gare ais Ft aH st sae aa 8, atfecwrr areatitton afta TA ae rer ee a heer ate Ta a mT aredraftor wafita wet 8 “aber arco aT BU ATT EL Define Corrosion. How can corrosion be minimized by sacrificial anodic protection and impressed current cathodic protection: methods? ig fam at Sa ee ohfee aea A impressed Fras afew spre PA rer ere YA PAT TT 2? working of bomb calorimeter. A fed in excess of oxygen using er in calorimeter wiis_2.2°C ‘orintéter is 2000g and water CV of the fuel. (Hydrogen he help of a neat labeled diagram, the 0.85g sample of solid fuel was completely combuste bomb calorimeter. The rise in temperature, of wat Calculate the HCV of the fuel, if water taken -inr vat equivalent of calurimeteris 2200 g, Also calculate the L in fuel ) a tice rach ee et FA aT # AAT aeatttee ovat ck ara 1 af H are fot F085 THT ET eg 8 a TM Seiten Hartt & area 28°C A ge ee daa HCV 41 sora a, afe Scarerftee # ferar war art 2000 are & ate oft ges Heir Tee 2200 are 1 fat Ft LCV a oh aoTaT LI (Cera WATE =2.5) Predict the final product obtained when LiAIH, reacts with: LiAlHa % are Fara TEA TTT Hf Sea AT ATT AE: (i) CH;CHO (ii) CH3CN Gili) CHsCOOC.Hs (iv) CHsCOG:Hs () CH;,COOH Explain with th (vi) CHSN3 (vii) CHsCHCH,O (epoxide) SECTION C Attempt any one part of the following: ann x1=7 Fret Hat fee Go oe oT ee HSE | What are nanomaterials? How the physical and chemical properties of vary with ther size? Write important aplietions of nanomaterials a Sema ae #7 At arate era en 3; TATE ar Seana argc ara fren ate 2 Write a brief note on fullerenes, discussing theit preparation, pr applications. a) aa pede, se ae, et le rat es ve ART Ae FE|. Attempt any one part of the followin a Be eh a ET TTR ATE 4 i 7 clding in NMR _ spectroscopy? a frat is shielding and deshielding in N p D compounds haying ae re the following signals in its HNMR spectra: having ‘molecular formula C4lToBr 51.04 (6H, d) 81.95 (1H, m) 53.33 2H, d) Giving reasons assign the structures for the compound, enmrare airesveanhh a) efee fhe APN er BP aPC Se ar ren afer ama 1H NMR ayaa Peeve Pet fa, 8 1.04 (OH, d) 5195 (1m) 53.3 Qd sarrey aak hfe Fe eae PR A (h) How do Auxochromes inerease the coloring power of Chromophores? afevats apy oh ame a A aT #2? (i) A diene (molecular formula Cyl) shows an intense peak at Pynyx 217 nm while c (molecular formula Csi) shows an intense peak at dow, 175 nm in their UV spectra, Giving proper explanation assign the structures to the two den Ur diene (armf¥n AF C4Hle) AH UV BET A Dae 217 nm tee Aa Pe frarar ® af ga diene (anf zr CsHy) aT UV BPAZT H Pe 175 ne 77 ft frre Reema 1 oP enataree a errattt diene wy AcraTt ee AL (ii) Why the 2 nx for the diene (1) is observed at a lower nm than diene (IT) ? Das iene (1) 3 fe diene (I) 3% nm re ae Ber aTaTe? oF 2), Cas 5. Attempt any one part of the followin; Txt=7 fret 3 2 fey gan we or ene oT fa) Discuss the mechanism of electrochemical corrosion of iron with evolution of hydrogen. What will happen iffa zine rod is vertically half submerged under water? resp i Py ave ia eer rae eon eae aT ea FE 2 er oer ar ea r,t TT WA Discuss the construction and chemisty of charging/discharging of Leud Acid battery, are firs Soft abate feat at eta atte Caer Te Tat ae 6. Attempt any one part of the following: Tx1=7) Pre a Rell ua wer or Gare ARTEL (4) How are scales formed in boilers? Discuss four disadvantages of scale formation in boilers, The hardness of 10,000 litres of water sample was removed by passing it The zeolite softener then required 200 litres of sodium eration, Calculate the through a zeolite softener. chloride solution containing 200 g/L of NaCl for r of water sample. wardness(b), (a) cpr Beg Ae aera? ate aE et Pfr re FTE yr wat #41 10,000 after orf ara char are ieee agree ge ATT TL faraneare ater a aefite & Fre 200 ararfiee NaCl yee 200 oer afRerey ANTES sire Rt aarererrert art a Teh 3 TET AT sate At aera TH Explain briefly the ultimate analysis of coal, A sample of fuel having following 6%, 0 = 4%, N = 3%, S = 3%, ash = 6% and percentage composition C= 70%, H moisture = 8%. Calculate the quantity o} of fuel Shee kf Ron waar Hoare Patera afte ore ar 70%, H = 6%, O = 4%, N ~ 3%, S = 3%, TH = 6% ate a a fare arene ary AL TAT AY TAT HL fair required for complete combustion of | Kg Attempt any one part of the following: fra ae fel vo wer er oan Afere | What are biodegradable polymers? Write a note on: aranfenzact affine sar 2? Fre re om feoroft fer: (i) Polynucleotides (ii) Buna- S Differentiate between Thermoplastic and Thermosetting polymers. Discuss the preparation and uses of Phenol Formaldehyde resin. Fy aR ate seater At Paar FS |