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Assignment Alcohol, Phenol &ether

The document is an assignment for Class XII Chemistry focusing on alcohols and ethers, covering various topics such as boiling points, acidity, and chemical reactions. It includes questions on the properties of phenols, the reactivity of alcohols, and the synthesis and conversion of compounds. Additionally, it features exercises on distinguishing between different alcohols and ethers, as well as completing chemical reactions.

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70 views3 pages

Assignment Alcohol, Phenol &ether

The document is an assignment for Class XII Chemistry focusing on alcohols and ethers, covering various topics such as boiling points, acidity, and chemical reactions. It includes questions on the properties of phenols, the reactivity of alcohols, and the synthesis and conversion of compounds. Additionally, it features exercises on distinguishing between different alcohols and ethers, as well as completing chemical reactions.

Uploaded by

ohnooohahaha5
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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SESSION 2022-23 CLASS- XII

SUB: CHEMISTRY
ASSIGNMENT
BASS CHEMISTRY- ARCGHOL & ETHERS

Q. 1: Give reasons for


following ;
Boiling points of ethers are lower then their isomeric Alcohols
Anisole reacts with HI to give phenol & CH,I & not iodo- benzene and methyl alcohol.

Phenol is much more acidic then alcohols.

4. Phenol has smaller diploemement then methanol.


Phenols do not give protanations reactions easily.

6. 0-nitrophenol is more acidic then o- methoxyphenol.

7. o-Nitrophenol has lower boiling point than p- Nitrophenol.


than that of n-butyl alcohol
acid catalysed dehydration of tertiary butyl alcohoi is faster

alkenes:
Q2 Write down the product of hyeroboration oxidation of following

Ch3
Cha-Éh=CH

from ethanol.
Q.3: Sodium metal is used to remove last traces of water from ether but not
Why?
chemical reactions;
4: Distinguish betwcen following pairs of compounds by
Q.
Propan 1-ol & Propan -2-ol
See Butyl alcohol &
tert- Butyl alcohol
2.
3 Phenol& Methanol

4. Phenol& Benzoic acid


Phenol& Benzyl alcohol
5.
Ethanol and 1-propanol

Describe the following:


Q. S:
Coupiingreactio
Reimer Tiemann reactioi

Kolbe's reaction
eathers
Williamson's synthesis of

Q.6: Do thefollowing conversiens;


1. Phenol to Aspirin
2 Salicylic acid to Phenol
3 Phenol to Salicylic acid

Phenol to Salicylal dehyde


5. Phenol to Benzene
6. Phenol to Phenolphthalein
7. Isopropyl alcohol to Acetone
8. Ethyl alcohol to Diethyl ether
9. Phenol to Aniline

10 Ethiyl propyl ether to Propan - 1-0r

11. Ethanal to Propan - 2 -0r

12 Ethyl chloride to n- Butyl alcohol


13. Acetone to tert- Butyl alcohol

14. Propene tp Propan 1 -0r


15. Benzene to benzyl alcohol.

Q.7: What is increasing order of;


1. Reactivity of Na- metal with primary, secondary& tertiary alcohol.
2 Reactivity of HCI, HBr & HI with alcohol.

Acidic character of 1°, 2°,3° alcohols.


A. Acidic order of phenol,0-cresol &0- nitro phenol.
5 Boiling points of n-butane, n-butanol, n-butyl chloride, isobutane

Q Arrange the following compounds in decreasing order of solubility and boilingpoint:


(i) CH CH OH, CH CH CH 20H, CH CH 2CH 2CH 2OH,

ci) CH,CH CH CH OH, (CHs)>CH-CH 0H, CH CH 2CH CH 3, (CH,)»-OH


Chi) bulasna 1»*ryt aleatust, 1toprop y alcote
h/hyl elhyl elhu
(v Bulanr-l Aulaw -2 o /co barly t alerhol
Ppaso dielhyt eth
. S:
Expiain the fact thai alcotols act as a
nucicophile as well as an ekecirophile.

Q.9: Why R- O- R
bond angle in ether is nore then H- 0-H bond angle in tH;0, thOugh
oxygen is sp° hybridized in both the cases.
Qi0 Write down the dehydration products of the
following:
CH
CH CH CH
OH
oH OH
() ")
Q11 Completethe following reactions:

aco)o io-eun A

11)
(n) Ch CH- CH-oH Sou
(I
+
OHa

V(iv) 0 o, 1 A
di
4-4 ati

(V)
t CHL+ Naoh A
B
OH
V)

OH
(o
(i)Tmn

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