NEET ANSWER KEY & SOLUTION
PAPER CODE :- PART TEST-5
CLASS-XII
ANSWER KEY
PHYSICS
1. (A) 2. (A) 3. (C) 4. (B) 5. (B) 6. (D) 7. (C)
8. (B) 9. (C) 10. (C) 11. (A) 12. (B) 13. (A) 14. (A)
15. (B) 16. (A) 17. (B) 18. (D) 19. (D) 20. (D) 21. (C)
22. (C) 23. (A) 24. (B) 25. (D) 26. (B) 27. (A) 28. (C)
29. (B) 30. (A) 31. (B) 32. (C) 33. (B) 34. (B) 35. (C)
36. (B) 37. (B) 38. (D) 39. (A) 40. (A) 41. (C) 42. (A)
43. (B) 44. (A) 45. (A) 46. (D) 47. (A) 48. (B) 49. (B)
50. (C)
CHEMISTRY
51. (C) 52. (C) 53. (D) 54. (A) 55. (C) 56. (A) 57. (D)
58. (A) 59. (B) 60. (B) 61. (D) 62. (B) 63. (D) 64. (A)
65. (B) 66. (A) 67. (A) 68. (D) 69. (A) 70. (C) 71. (C)
72. (C) 73. (C) 74. (A) 75. (B) 76. (A) 77. (D) 78. (A)
79. (B) 80. (D) 81. (A) 82. (A) 83. (A) 84. (C) 85. (A)
86. (C) 87. (B) 88. (A) 89. (A) 90. (D) 91. (D) 92. (B)
93. (C) 94. (C) 95. (B) 96. (D) 97. (C) 98. (B) 99. (C)
100. (D)
BIOLOGY
101. (B) 102. (D) 103. (C) 104. (B) 105. (B) 106. (C) 107. (A)
108. (D) 109. (D) 110. (D) 111. (A) 111. (A) 112. (B) 112. (B)
113. (A) 114. (A) 115. (D) 116. (B) 117. (C) 118. (B) 119. (D)
120. (B) 121. (C) 122. (A) 123. (D) 124. (A) 125. (C) 126. (A)
127. (B) 128. (A) 129. (A) 130. (B) 131. (A) 132. (B) 133. (D)
134. (B) 135. (C) 136. (A) 137. (C) 138. (D) 139. (D) 140. (C)
141. (D) 142. (B) 143. (B) 144. (B) 145. (C) 146. (D) 147. (C)
148. (C) 149. (B) 150. (B) 151. (A) 152. (C) 153. (D) 154. (D)
155. (B) 156. (D) 157. (B) 158. (A) 159. (B) 160. (A) 161. (C)
162. (C) 163. (D) 164. (D) 165. (B) 166. (B) 167. (A) 168. (A)
169. (C) 170. (A) 171. (A) 172. (B) 173. (A) 174. (B) 175. (B)
176. (B) 177. (A) 178. (B) 179. (C) 180. (C) 181. (B) 182. (D)
183. (B) 184. (C) 185. (D) 186. (A) 187. (A) 188. (B) 189. (C)
190. (D) 191. (B) 192. (A) 193. (C) 194. (B) 195. (A) 196. (C)
197. (C) 198. (A) 199. (B) 200. (D)
1
SOLUTIONS
PHYSICS
1. (A) 12. (B)
Sol. For n=1, maximum number of states r n 2 . For ground state n=1 and for first
Sol.
2n 2 2 and for n = 2, 3, 4, maximum
excited state n=2.
number of states would be 8, 18, 32
respectively, Hence number of possible
elements 13. (A)
= 2 + 8 + 18 + 32 = 60.
1 1 1
Sol. R 2 2
2. (A) 1
n n 2
13.6
n=2 E2 3.4 eV 1 1 1 4
2
(2) First condition R 2 2R
1 2 3
Sol.
1 1 1
n=1 E1 13.6 eV Second condition R 2 2
' 1 3
E12 3.4 (13 .6) 10 .2 eV 9 9 27
' '
8R 4 32
8
3
3. (C)
Sol. Lyman series lies in the UV region.
14. (A)
4. (B)
(E n ) He Z2
Sol. The size of the atom is of the order of 1Å = 10 – Sol. En Z 2 He 4
10 (E n ) H Z H2
m.
(En )He 4 (En )H
5. (B)
Sol. Paschen series lies in the infrared region.
15. (B)
6. (D) Sol. P.E. 2 Total energy 2 (13 .6) 27.2 eV
Sol. Lyman series lies in the UV region.
16. (A)
7. (C)
Sol. Wave number 17. (B)
1 1 1 1 1 3R
R 2 2 R
1
n n 2
4 16 16 18. (D)
Sol. In hydrogen, atomic number and mass number
8. (B) are equal.
Sol. Linear momentum
mv 9 .1 10 31 2 .2 10 6 19. (D)
2.0 10 24 kg m / s h
Sol. According to Bohr’s theory mvr n
2
9. (C) h
Circumference 2r n n
Sol. Energy required s mv
10. (C) 20. (D)
Sol. First excited state i.e. second orbit (n = 2)
Sol. Energy / day 200 10 6 24 3600
Second excited state i.e. third orbit (n = 3)
2
2 2.4 3.6 10 12 1728 10 10 J
13 . 6 E 3 9
E 2 2
n E3 2 4 21. (C)
Sol. Nuclear force is stronger than coulomb force.
11. (A)
Sol. Ionization energy = Binding energy. 22. (C)
2
23. (A) 28. (C)
Sol. E1 E2 Sol. Vander Waal force is weak dipole-dipole
1 2 interaction.
n=6
n=5 29. (B)
E2
n=4 Sol. As n increases P.E. increases and K.E.
n=3 decreases.
n=2
E1 30. (A)
n=1
31. (B)
i.e. photons of higher frequency will be
emitted if transition takes place from n = 2 to 32. (C)
1. Sol. For a wide range of values of load resistance,
the current in the zener diode may change but
24. (B)
the voltage across it remains unaffected. Thus
Sol. From diagram
n=4 (– 0.85 the output voltage across the zener diode is a
E3
n=3 (– 1.51 regulated voltage.
E4
n=2 ( –3.4
E1 E2 ) 33. (B)
n=1 (– 13.6
E1 13 .6 (3.4) 10 .2 eV N N
E2 13 .6 (1.51) 12 .09 eV Sol. Forward P reverse
biased biased
E3 1.51 (0.85 ) 0.66 eV
E4 3.4 (1.51) 1.89 eV
E3 is least i.e. frequency is lowest. 34. (B)
Sol. With temperature rise conductivity of
25. (D) semiconductors increases.
81 .2
Sol. For full wave rectifier
rf 35. (C)
1
RL Sol. N-type semiconductors are neutral because
nmax 81 .2% (rf << RL) neutral atoms are added during doping.
36. (B)
26. (B) 0 .96
Sol. =24.
Sol. m1v1 m2 v 2 1 1 0 .96
v1 m2 r23
37. (B)
v 2 m1 r13
Sol. Emitter is heavily doped.
1 1
r1 v 2 3
1 3 1
38. (D)
r2 v1 2 21/3
Trivalent P-type
r1 : r2 1: 21/3 Sol. Ge +
impurity semiconductor
27. (A) 39. (A)
Sol. We know that Sol. In CB amplifier Input and output voltage
1
3
signal are in same phase.
R = R 0A
4 3 4 3 (A)
v R R 0A 40.
3 3
M mA m
41. (C)
v 3 R 3 4 R 3
4 0 3 0 Sol. Phosphorus is pentavalent.
3
42. (A) 46. (D)
Sol. In forward biased PN-junction, external Sol. the deplection layer's consists of Immobile
voltage decreases the potential barrier, so ions
current is maximum. While in reversed biased
47. (A)
PN-junction, external voltage increases the
C.B.
potential barrier, so the current is very small.
Ef Energy gap (Eg)
Sol.
43. (B) V.B.
Sol. In reverse biasing, width of depletion layer
increases.
48. (B)
44. (A)
Sol. At 0K semiconductor behaves as insulator so
Sol. The potential of P-side is more negative that of it's resistance is infinite.
N-side, hence diode is in reverse biasing. In
49. (B)
reverse biasing it acts as open circuit, hence no
Sol. FET is unipolar.
current flows.
50. (C)
45. (A) Sol. P d Transistors are used in oscillators.
Sol. In intrinsic semiconductors, electrons and Q a Diode can act as a rectifier.
holes both are charge carriers. In P-type R b Phosphorus is a pentavalent
impurity.
semiconductors (Extrinsic semiconductors)
S C Bismuth is a trivalent impurity.
holes are majority charge carriers.
CHEMISTRY
51. (C) 54. (A)
Sol. The structure of intermediate acetyl nitrene is Sol. Formaldoxime on reaction with Na/EtOH
gives
CH3 – CO – N. It is formed by the following 1º amine. The reaction is representated as
reaction follows :
H – CH = N – OH
Na / EtOH
4H
CH3NH2 + H2O
Formaldoxime Methylamine
This method is used for the preparation of
primary amines.
52. (C) 55. (C)
Sol. In hypobromite reaction of amide, carbonyl Sol. Primary amine and HNO2 produces nitrogen
gas.
carbon atom is lost as CO3–2 ion. The reaction
RNH2 + HNO2 ROH + N2 + H2O
takes place as follows:
CH3CONH2 + Br2 + 4KOH 56. (A)
Sol. All aldehydes e.g. HCHO, C6H5CHO and
CH3NH2 + 2KBr + K2CO3 + H2O
K2CO3 is an ionic compound and ionizes to CH3CHO on reaction with alkylamine gives
give K+ and CO3–2 ions. schiff’s base
C6H5CHO + H2NCH3
53. (D) Benzaldehyde Methylamine
Sol. Alkyl isocyanide on hydrolysis produces a C6H5CH = N – CH3 + H2O
Schiff’s base
primary amine. The reaction takes place as
follows. 57. (D)
Sol. CH3 CH2 COOH + SOCl2 CH3 CH2COCl
+NH3 CH3CH2CONH2+Br2+KOH
CH3CH2NH2
4
58. (A) 63. (D)
Sol. Alkyl isocyanides on reduction with lithium Sol. All the compounds given above are examples
aluminium hydride forms secondary amines of primary amine.
containing methyl as one of the alkyl groups.
59. (B)
64. (A)
Sol. Sol. For the formation of RNH2 from RCONH2,
NaOH and Br2 are used as reagent. It is called
Hoffmann hypobromite reaction.
65. (B)
Sol. The products of the reaction 1, 2, 3 and 4
respectively are : 1º amine, methyl ketone, 1º
amine and alcohol.
66. (A)
60. (B)
Sol. Gabriel phthalimide reaction is used to prepare
Sol. Secondary amine with (NaNO2 + HCl) gives a primary amine.
nitroso product.
61. (D)
Sol. (i) Presence of electron withdrawing
substituent decreases the basicity while the
presence of electron releasing substituent like,
– CH3, – C2H5 etc. increases the acidity. 67. (A)
(ii) HNO2 converts – NH2 group of aliphatic Sol. The given reaction is represented as :
amine into –OH while that of aromatic amines RCOOH + N3H
Conc.H2 SO4
RNH2
into – N = NCl. + CO2 + N2
Since, phenyl group is a electron withdrawing alkanoic acid hydrazoic acid alkylamine
group, it decreases the basicity. Alkyl group,
on the other hand, being electron releasing, 68. (D)
increases the basicity. Thus, alkyl amines are Sol. Primary and secondary amines react with
more basic as compared to aryl amines as well HNO2,while tertiary amines do not react with
as ammonia. HNO2. Since N, N-Dimethyl ethanamine
R – NH2 HNO2
R – OH
is a tertiary amine,
Thus, HNO2 (nitrous acid) converts alkyl
amines to alcohols. hence it will not react with HNO2.
But C6H5NH2 HNO2
C6H5N NCl
69. (A)
Benzene diazonium chloride
Sol. In the given sequence of reactions, the product
Thus, HNO2 does not convert aryl amines into B, will be ethanol. The reaction takes place as
phenol.
62. (B)
Sol. The reagent which can convert – CONH2
group into – NH2 group is used for this
reaction.
Among the given reagents only NaOH/Br2
converts – CONH3 group to – NH2 group, thus 70. (C)
it is used for converting acetamide to methyl Sol. In Schotten-Baumann reaction a sulphur
amine. This reaction is called Hoffmann compound is not produced with a 1º amine
bromamide reaction. R – NH2 + Cl – CO – C6H5
NaOH
CH3CONH2 + NaOH + Br2 CH3NH2 + R– NHCOC6H5 + HCl
NaBr + Na2CO3 + H2O Alkyl amine Benzoyl chloride
methylamine N-alkyl benzamide
5
71. (C) 80. (D)
Sol. A primary amine condenses with CS2 in the Sol. Methyl -D-glucoside and methyl -D-
presence of HgCl2 to form an alkyl glucoside do not reduce fehling solution and
also do not react with hydrogen cyandide.
isothiocyanate. This compound has a smell
resembling that of mustard oil. It is called as 81. (A)
Hoffmann’s mustard oil reaction. Sol. Due to different spatial arrangement of (–H &
–OH) group at C–1 carbon of glucose form
R – NH2 + S = C = S + HgCl2
R – N =
anomer.
C = S + HgS + 2HCl
Alkyl Amine Alkyl isothiocyanate
82. (A)
72. (C) Sol. RD Haworth
Sol. Triethylamine is tertiary amine. It does not
react with Hinsberg reagent. 83. (A)
Sol. Lactose
73. (C)
Sol. In the 3rd reaction sequence the end product is 84. (C)
a 3º nitro compound. (CH3)3C–NO2 It does not Sol. In maltose two glucose molecule are linked
have hydrogen because of which through –1, 4–glycosidic linkage.
tautomerism is not possible.
85. (A)
74. (A) Sol. Simplest amino acid is glycine (amino
Sol. The acid used is H2PtCl6. It is a solution of acetic acid H2N – CH2 – COOH).
platonic chloride, PtCl4 in con. HCl
86. (C)
2R NH2 H2 [PtCl6 ]
[R NH3 ]2 [PtCl6 ] 2 Sol. The main structural feature of proteins is the
presence of peptide linkage.
Alkylamine platinichloride
87. (B)
Chloroplatinates on ignition leave a residue of
Sol. DNA has nucleotide unit, i.e., Sugar + base +
metallic Pt. This reaction is employed in H3PO4 .
determining molecular weight of amines.
88. (A)
75. (B)
Sol. Biochemical reaction takes place at body Sol.
temperature (37°C) & at pH = 7
76. (A)
Sol. Disaccharides, polysaccharides and starches 89. (A)
Sol. Glucose is monosacchoride
77. (D)
Sol. Glucose on heating with dilute sodium 90. (D)
hydroxide undergoes in a reversible Sol. Secondary structure of protein is regular
isomerisation (known as Lobry de Bruynvan folding pattern of continuous portion of the
Ekenstein rearrangement) and gives D-glucose, polypeptide chain
D-mannose and D-fructose.
91. (D)
78. (A) Sol. End product of protein digestion is –amino
Sol. Change in optical rotation towards an acid because Amino acids are structural unit of
equilibium value is called mutarotation. protein
79. (B) 92. (B)
Sol. Inversion Sol. Cod liver oil is good source of vitamin A & D
6
93. (C) 97. (C)
Sol. Calorific value order is fat > carbohydrate > Sol. Proteins
protein
94. (C) 98. (B)
Sol. Amino acid are linked through peptide linkage Sol. Riboflavin deficiency causes pellagra.
in protein structure.
99. (C)
95. (B) Sol. Acetic acid has the same general formula but
Sol. Isoelectric point is the pH at which structure of not a saccharides.
amino acid has no charge.
100. (D)
96. (D) Sol. Glyptal is a synthetic fibre and used in fabric.
Sol. Essential amino acid
