0 © mananastaa © ott © RANCH the Real Aspirant Central Office = Rangalore, Karnataka Sec: ALL Jr's, Reg, C1208 AIMS "Date; 49-02-2028 | | Time: 02:00 Pat To 5:00 Pn CBSE FINAL ‘Max, Marks: 70M General Instructions: Read the following instructions carefully @) There are 35 questions in this question paper with internal chotce. 4) SECTION A consists of 16 nuiltiple-choice questions carryiate I mark each. jo SECTION B consists of 7. very shore answer questions carrying 2 marks each. d) SECTION C consisis of 5 short answer questions carrying 3. marks each. ©) SECTION D consists of 2 case- based questions carrying 4 marks each. P SECTION E consists of 3 long answer questions carrying 5 marks each. &) All guestions are compulsory Use of log tables and caiculatoryis not allowed "CHEMISTRY SECTION-A 1. The fotlowing questions are muitipte— ehoice questions with one correct answer. this seetion 1x16=16M. Each question earries 1 mark. There is no internal cho 1, The weight percentage of oxygen ta NAOH is . a 40 do 8 20 a 2. 12g oF Me (At Mass 24) will prodice “Mao a) 0.05gm 6) gm c) 40am. a4 em 3. Atomic umber of actinides are . a) S710 71 b) $0 to 103 4) 90.t0 103 4. ‘The Element with highest Electron affinity is a) Fluorine b) Cesium, ¢) Helium, 4) chlorine 5. Hydrogen bonds are formed in many compounds, 4. #0, Els The boiling point o} of hydrogen bond and the such compounds depends to « rder of the beiling poinis'of above number of hydrogen bonds, The correct decreasi compounils is: >HP>H,0 ) Nit, > H0> HE a) HF > H1,0> NU, b) 10> HF > NA, 0) a Page 1Which motecule hues zero dipole rHomen eS ; ) d) HBr javs0 yan0 Sau soon air>0 5 on aul=vand al? =0 spontaneity ai bl eniperatures? a) AH<0.AS<0 b) AU>0;AS<0 ©) AH <0; AS>0 AH>O;AS20 Oxidation numberof Cl in C20CE, 1s ») since it contains ClO~ 8) Zero, Since it contains ©) 44, Sines iveonisins Cl 4) +1 and 1, Since it contains CIO-and CI The funetional group present in Anisole is a) Ketone b)akelyde Amine Sj ether In Duma’s method nitrogen in organic compound is estimated inthe form of a Ny »)NO ©) ME NO, Which one of the following possess the minimum boiling point a)l-Pentyne b) 1 Butyne ) m-Butane _d) Isobutane nfs labelled 4s Assertion (A) and Reason (R). Given below are tyra state Select the most appropriate answer from the options given below: 8) Both A and R are true and R is the correct explanation of A 5) Both Avand R are true but R is not the correct explanation of A ODA is true but R is face GA is false bat R istrve Assertion (A): A mixture of pent pigments can separate by chromatography. Reason (R): Chromatography is used for separation of coloured substances into individual components Assertion (A), Alkenes Reason (R): Double bond is pres olourises bromine in CC? bro ca, in alkenes:Sri Chaitanya Educational Institwdlens, India mm. Ice cacrgy changes of all spontineously occurring R) The stondard ice energies of the elements im their standard states At | ba od) 298 K are taken as ze 9 (A); For any chemical reaction at a particular temperature, the equilibrium constant is fixed and is characteristic property. jum constant is independent of temperature, Section-B ‘This section contains five questions with internal cholee in one question. The Asse Reason (R): Equi following questions are very short answer type und earry two marks cach Sx2=10M. Calculate the molarity of NaOH in the sotution Prepared by dissolving 4g NaOH In enough water to form 250ml of the solution smiodem periodic law b) How docs ionization enthalpy vary across the period and down the group ‘symbol for the element with atomic number 120] a) What would be the IUPAC Name a b) Isoelectronie species have different ionie radii why’? a) On basis of M.0.1 i) Wri lectronic configuration of 0, molecule ii) Calculate it’s Bond order (oR) Draw the shapes of BMO& ABMO formed by the combination of Is &1s atomic Orbital Caleulate the solubility product of calcium hydroxide ifit’s solubility is V5. Seetion—C ‘This section contains seven questions with internal choice in one question. The following questions are short answer (ype and carry three marks each 7x3=21M. Calculate the molar mass of following compounds a) HS, b) Cac, ©) Gla le than P- Nitro plienol. Why? a) O- Nitro phenol is more vi bb) What type of Bonds are Present in. O° Two moles of an ideal gas initially at 27°C and 1 atm pressure is compressed Pages29, 28. a) Write the Newman Projections of ethane Iv. [Sr Ghaitanya Educational stations aaiheoraly andreverbhy ACE india mi ai pressure ot the cea 10 an, Caan We values of a, W and AL! for this process the following thle related to LOW) > steam) at Filip the Blanks in Standard atmospheric pressure iy r a TAS| AG he Ae rou) (Entropy change) (ifee energy) | KJ mol Lmol 1K! KI @_[90_|303.0 | 41.1 = = F118 (i)_[100_ [373.0 | 40.7 109) aS (ii), [110 [383.0 | 40.1 aT = 0979 OR) Calculate enthalpy of formation of C,M,, given enthalpy of combustion of C,H,(2), Gyity(g) and FHy(g) are. ~140 KV/mol, 1530 KJimol and -286 KJémol respectively. 15. Balance the following redox reaction by Hal rection method Fe™* (4g)+CrO(Ay) > FE*(4g) Cr” (gy. (Acid medium) a) In en experiment (36g of an organic compound gave 0.35 g of BaSQ, . Calculate the percentage of Sulphur in the compound. b) Explain homolytic fission. }) Deseribe the mechanismn of addition of HBr to propene in presence of Peroxide Section-D ‘The following questions are case-based questions. Each question has an internal choice and carries Four (I+1+2) marks each. Read the passage carefully and answer the question that follow. 2x4-8M Equilibrium in chemicals is a dynamic process, Even after the equilibrium state is reached, the forward and reverse reactions still take place. At equilibrium, the rates of the reactions remain constant, and the relative concentrations of reactants and products rem: unchanged. The parameters and characteristics of'a system at equilibrium is listed below. (The reaction should be reversible and carried out in closed systent thie process of equilibrium is dynamic) Equal forward and reverse reaction rates are required. The xTeactants ‘lied However, the quan Ferny constant Uni equi hn his Beenivesehed. 88 w longer any change in the eoncentttidm Of the is oF pr, uir will exist betwen the reactants and products Mention any (wo applications n ipplications of chemical eyuilibyium nce Hetweeh a system hit is Feeting 66 sldwly thar ongeniration changes are har cone » changes are hand to ‘nd ie tha as ceachod Chenieal Equitioetumn? ) What do the clative concentrations of the reactants vs the products in & particular equ (i) When K=0.9 ibriuma reaction tell us about each of the Following Values for K? s ii) When K=1,67/s Are reactants or products preferred at equilibrium? (or) arc at equilibrium st 500K and having eoncentration 1.59 M I Ph, and C PCL, 159M \d AT M PCI, Calculate XK; for the reaction, PCI, =* PCL +Cl, 30. James Maxwell (1870) suggested that when electrically charged particle moves under acceleration, alternating electrical and magnetic fields are produced and m of waves called electro: transmitted. These fields are transmitted in the magnetic waves or electromagnetic radiation. These waves do not require any order of medium for their propagation and can move in yacuum. The increasi wavelengths of these radiations is given as below frared rays< Micro Cosmic rays we es AlOy Ni iv) Cy itty + Hey oll ee Vsatm 9 cH 32,4) Calculate i) wave number i) Frequency of yellow radiation having wavelength S800A” ) Give theee differences between orbit and orbitals (or) 8) How many radial nodes and angular nodes are Present in 4d orbitals. b) A golf ball has a mass of 40g and @ speed of 45 ms '. Ifthe speed can measure within accuracy of 2% Calculate the uncertainty in the Position, 33. a) Write IUPAC name of following compounds ay PEREGO ip Chem Cle NN Ott ay bu ° +) What is Positional isomerism? Give an example (OR) ®) Wha is hyper conjugation? IMustrate with an example ») What are Electrophiles? Give Example