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Chem XI Set-2

The document outlines the structure and content of a Chemistry Theory examination for Class XI, session 2024-25, consisting of 33 questions across five sections with varying marks. It includes multiple-choice questions, short answer questions, case-based questions, and long answer questions, covering various chemistry topics. Instructions specify that all questions are compulsory and the use of calculators and log tables is prohibited.

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0% found this document useful (0 votes)
30 views4 pages

Chem XI Set-2

The document outlines the structure and content of a Chemistry Theory examination for Class XI, session 2024-25, consisting of 33 questions across five sections with varying marks. It includes multiple-choice questions, short answer questions, case-based questions, and long answer questions, covering various chemistry topics. Instructions specify that all questions are compulsory and the use of calculators and log tables is prohibited.

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e7076675
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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SESSION ENDING EXAMINATION

SESSION: 2024-25
SUBJECT: CHEMISTRY THEORY
CLASS-XI
MM: 70 Time:3 Hours
Instructions-

1. Read the following instructions carefully.

2. (a) There are 33 questions in this question paper with internal choice.
(b) SECTION A consists of 16 multiple -choice questions carrying 1 mark each.
(c) SECTION B consists of 5 short answer questions carrying 2 marks each.
(d) SECTION C consists of 7 short answer questions carrying 3 marks each.
(e) SECTION D consists of 2 case - based questions carrying 4 marks each.
(f) SECTION E consists of 3 long answer questions carrying 5 marks each.

3. All questions are compulsory.

4. Use of log tables and calculators is not allowed.


____________________________ ____________________________________
SECTION A
1 The number of atoms present in one mole of an element is equal to Avogadro number.
Which of the following element contains the greatest number of atoms?
(a) 4g He (b) 46g Na (c) 0.40g Ca (d) 12g He
2 Which of the following set of quantum numbers is not possible?
(a) n = 3, l = 0, m = 0 (b) n = 3, l = 1, m = -1
(c) n = 2, l = 0, m = -1 (d) n = 2, l = 1, m = 0
3 The ground state electronic configuration of Fe3+ ion is
(a) [Ar] 3d34s2 (b) [Ar] 3d6 4s2 (c) [Ar] 3d5 (d) [Ar] 3d6
4 Whenever a list of radii is given, we find that the size of the noble gases is larger than the
size of their adjacent halogens. The reason is
(a) Noble gases have a complete octet
(b) They have a higher inter electronic repulsion
(c) In halogens it is covalent radii and in noble gases it is Vander walls radii
(d)Noble gases cannot be liquefied
5 The increasing order of effective nuclear charge in Na, Al, Mg and Si atoms
(a) Na < Mg < Si <Al (b) Na < Mg <Al < Si
(c) Mg < Na <Al< Si (d) Na = Mg =Al = Si
6 Find the pair with sp2 hybridisation of the central molecule
(a) NH3 and NO2– (b) BF3 and NH2– (c) BF3 and NO2– (d) NH2– and H2O
7. Thermodynamics is not concerned about.
(a) energy changes involved in a chemical reaction.
(b) the extent to which a chemical reaction proceeds.
(c) the rate at which a reaction proceeds.
(d) the feasibility of a chemical reaction.
8. The spontaneity means, having the potential to proceed without the assistance of external
agency. The processes which occur spontaneously are
(a) flow of heat from colder to warmer body.
(b) gas in a container contracting into one corner.
(c) gas expanding to fill the available volume.
(d) burning carbon in oxygen to give carbon dioxide.
9. In a closed system A(s) ⇌ 4 B(g) + 3C(g)
If partial pressure of C is doubled, then partial pressure of B will be
(a) 12 x (2)1/2 times the original value
(b) ½ times the original value
(c) 2 times the original value
(d) (½) 2 times of the original value
10. H2 + S ⇄ H2S + energy
In this reversible reaction, select the factor which will shift the equilibrium to the right.
(a) adding heat (b) adding H2S
(c) blocking hydrogen gas reaction (d)removing hydrogen sulphide gas
11. One mole of ferrous oxalate requires____ of MnO4– to get oxidised completely in an
acidic medium
(a) 0.6 moles (b) 0.4 moles (c) 0.2 moles (d) 7.5 mole
12. The simplest member with lowest molecular mass of organic compounds is?
(a) Methanol (b) Methane (c) Formaldehyde (d) Formic acid
13. Assertion (A) : The empirical mass of ethene is half of its molecular mass.
Reason (R) : The empirical formula represents the simplest whole number ratio of various
atoms present in a compound.
(a) Both A and R are true and R is the correct explanation of A.
(b) A is true but R is false. (c) A is false but R is true.
(d) Both A and R are false
14. Assertion (A) : The value of electron gain enthalpy decrease while moving left to right in a
period.
Reason (R) : The electron gain enthalpy is the energy which released hence it represented
with negative sign.
(a) Both A and R are true and R is the correct explanation of A.
(b) A is true but R is false. (c) A is false but R is true.
(d) Both A and R are false
15. Assertion (A) : The molecules which have same Hybridization always has the same shape.
Reason (R) : Lone pairs are not included in the shape of the molecule.
(a) Both A and R are true and R is the correct explanation of A.
(b) A is true but R is false. (c) A is false but R is true.
(d) Both A and R are false
16. Assertion (A) : Zinc displaces copper from copper sulphate solution
Reason (R) : The Eo of Zn is -0.76 V and that of Cu is +0.34 V.
(a) Both A and R are true and R is the correct explanation of A.
(b) A is true but R is false. (c) A is false but R is true.
(d) Both A and R are false
Section B
17. Give an example of a molecule in which the ratio of the molecular formula is six times the
empirical formula.
18. Give the electronic configuration of O2- and Na+ ions.
19. Aqueous solution of CuSO4 is Acidic. Why ?
20. Name one compound in which oxidation number of Cl is +4.
OR
Explain Disproportionation reaction with one example
21. Give IUPAC name of (CH3)2-CH-CH=CH2
SECTION C
22. The reactant which is entirely consumed in reaction is known as limiting reagent. In the
reaction 2A + 4B → 3C + 4D, when 5 moles of A react with 6 moles of B, then-
(i) which is the limiting reagent?
(ii) calculate the amount of C formed?
23. Elements A, B, C and D have atomic numbers 12,19, 29, and 36 respectively. On the basis
of electronic configuration, write to which group of the periodic table each element
belongs.
OR
Explain why cations are smaller and anions larger in radii than their parent atoms?
24. Given that ΔH = 0 for mixing of two gases. Explain whether the diffusion of these gases
into each other in a closed container is a spontaneous process or not?
25. The difference between Cp and Cv can be derived using the empirical relation H= U+PV.
Calculate the difference between Cp and Cv for 10 moles of an ideal gas.
26. The following concentration were obtained for the formation of NH3 from N2 and H2 at
equilibrium at 500 K. [N2(g)] = 1.5 x 10-2 M [H2 (g)] = 3.0 x 10-2 M [NH3] = 1.2 x 10-2 M.
Calculate equilibrium constant.
27. Nitric acid is an oxidizing agent which reacts with PbO but not with PbO2. Explain why?
OR
MnO4-2 shows disproportion reaction in acidic medium but MnO4- do not. Give Reason
28. In an estimation of sulphur by carius method 0.468 g of an organic compound gave 0.668
g of barium sulphate. Find the percentage of sulphur in the compound. (atomic Mass of
S=32u, atomic Mass of O=16u and at. Mass of Ba=137u)
SECTION D
29. Read the following passage and answer questions.
Equilibrium Involving Dissolution of Gases in Liquids- When a soda water bottle is
opened, some of The carbon dioxide gas dissolved in it fizzes Out rapidly. The
phenomenon arises due to difference in solubility of carbon dioxide at different pressures.
There is equilibrium between the molecules in the gaseous state and the molecules
dissolved in the liquid under pressure i.e., CO2 (gas) CO2 (in solution).This equilibrium is
governed by Henry’s law, which states that the mass of a gas dissolved in a given mass of
a solvent at any temperature is proportional to the pressure of the gas above the solvent.
This amount decreases with increase of temperature. The soda water bottle is sealed under
pressure of gas when its solubility in water is high. As soon as the bottle is opened, some
of the dissolved carbon dioxide gas escapes to reach a new equilibrium condition required
for the lower pressure, namely its partial pressure in the atmosphere. This is how the soda
water in bottle when left open to the air for some time, turns ‘flat’. It can be generalized
that: For solid liquid equilibrium, there is only one temperature (melting point) at 1 atm
(1.013 bar) at which the two phases can coexist. If there is no exchange of heat with the
surroundings, the mass of the two phases remains constant. For liquid vapour equilibrium,
the vapour pressure is constant at a given temperature. For dissolution of solids in liquids,
the solubility is constant at a given temperature. For dissolution of gases in liquids, the
Concentration of a gas in liquid is Proportional to the pressure (concentration) of the gas
over the liquid
29.(i) Equilibrium is possible only in a ...…….......at a given temperature.
a) open system b) isolated system
c) closed system d) None of above
29.(ii) The value of R= ..........
a) 0.138 bar litre/mol K b) 0.0381 bar litre/mol K
c) 0.318 bar litre/mol K d) 0.0831 bar litre/mol K
29.(iii) The equilibrium involving ions in aqueous solutions which is called as ...
a) static equilibrium b) dynamic equilibrium
c) physical equilibrium d) ionic equilibrium
30. The rotation of carbon-carbon single bond (sigma -bond), due to cylindrical symmetry of
s-MOs (molecular orbitals) long internuclear axis, in alkanes results into different spatial
arrangements of atoms in space, that are interconvertible. These arrangements are called
conformations. However, weak repulsive interaction are present between the adjacent
bonds in alkanes so the rotation of C—C single bond is not completely free and is hindered
by a small energy barriers of 1-20 kJ mol- 1. The repulsive interaction between the
adjacent bond is due to electron cloud. The two types of conformations are very common,
i.e., staggered and eclipsed. The conformation in which the hydrogen atoms attached to the
two carbon atoms are as far apart as possible is called the staggered conformation. The
conformations in which the hydrogen atoms attached to the two carbon atoms are as closed
as possible is called eclipsed conformation. Any intermediate conformation between the
above two is called skew or gauche conformation

30. (i) The electronic distribution of the sigma molecular orbital is symmetrical around the
C-C bond which permits free rotation around C-C bond. Such spatial arrangements of
atoms in which conversion of one another takes place by rotation around C-C bond is
known as
(a) rotamers (b) conformers (c) conformations (d) All of these
30. (ii) The possible rotamers of ethane is/are
(a) 2 (b) 3 (c) 4 (d) ∞
30. (iii) Why do different conformations of ethane cannot be separated and isolated?
30. (iv) Define torsional strain
SECTION E
31. In the Balmer series of atomic spectra of hydrogen atom, a line corresponding to
wavelength 656.4 nm was obtained. Calculate the number of higher orbit from which the
electron drops to produce this line.
32. Discuss the shape of the following molecules using the VSEPR model: BeCl2, BCl3,
SiCl4, AsF5, H2S, PH3
OR
Explain with the help of suitable example polar covalent bond.
33. (i) Which of the following represents the correct IUPAC name for the compounds
concerned?
(a) 2,2-Dimethylpentane or 2-Dimethylpentane (b) But-3-yn-1-ol or But-4-ol-1-yne
(ii) Give condensed and bond line structural formulas and identify the functional group(s)
present, if any, for :
(a) Hexanedial (b) 3- Methyl pentan-2-one

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