Sri Chaitanya IIT Academy., India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office, Madhapur – Hyderabad
Sec: Jr.Super60_STERLING BT JEE-ADV_2023-P1 Date: 22-12-2024
Time: 09.00Am to 12.00Noon WTA-22 Max. Marks:180
MATHEMATICS : Global maxima and global minima, Maxima and minima using AM-GM
relation, Applications of maxima and minima in solving equations
PHYSICS : OSCILLATIONS: Simple Pendulum, Physical pendulum, Cumulative problems
in SHM (upto syllabus covered), Liquid in a U-tube, Air chamber with a neck,
Oscillations of a floating cylinder, Balance wheel, Damped, Forced oscillators
(Deleted pertaining to JEE MAINS but still in JEE ADV Syllabus), Miscellaneous
Problems
CHEMISTRY : Hydroxylation reactions; Oxidative cleavage - KMnO4, ozonolysis; allyl
substitution, allyl oxidation; Isomerization; Reaction with carbenes and
carbenoids., Dienes: Preparation and reactions of conjugated dienes, 1-2 and 1-4
addition reaction, ALKYNES: Preparations , Properties- Reduction of alkynes
,cyclic polymerization reaction of alkynes, BENZENE AND EAS: Preparations
of benzene

Name of the Student: ___________________ H.T. NO:

 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P

JEE-ADVANCE-2023-P1-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct
Sec – I(Q.N : 1 – 3) +4 -2 3 12
Choice with partial mark
Questions with Single Correct
Sec – II(Q.N : 4 – 7) +3 -1 4 12
Choice
Sec – III(Q.N : 8 – 13) Questions with Integer Answer Type +4 0 6 24
Sec – IV(Q.N : 14 – 17) Matching Type +3 -1 4 12
Total 17 60

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct
Sec – I(Q.N : 18 – 20) +4 -2 3 12
Choice with partial mark
Questions with Single Correct
Sec – II(Q.N : 21 – 24) +3 -1 4 12
Choice
Sec – III(Q.N : 25 – 30) Questions with Integer Answer Type +4 0 6 24
Sec – IV(Q.N : 31 – 34) Matching Type +3 -1 4 12
Total 17 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct
Sec – I(Q.N : 35 – 37) +4 -2 3 12
Choice with partial mark
Questions with Single Correct
Sec – II(Q.N : 38 – 41) +3 -1 4 12
Choice
Sec – III(Q.N : 42 – 47) Questions with Integer Answer Type +4 0 6 24
Sec – IV(Q.N : 48 – 51) Matching Type +3 -1 4 12
Total 17 60

Sec: Jr.Super60_ STERLING BT Space for rough work Page 2

 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
MATHEMATICS Max Marks: 60

SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

1. The values of parameter a for which the point of minimum of the function
x2  x  2
f ( x)  1  a x  x satisfies the inequality 2
2 3
 0 are
x  5x  6
A) (2 3,3 3) B) (3 3,  2 3) C) ( 2 3,3 3) D) (3 2,2 3)
2. Let f : R  R be a function defined by f ( x)  ( x  3) n1 ( x  5) n2 , n1 , n2  N . Then which
of the following is True ?
A) For n1  3, n 2  4, there exists   (3,5) where f attains local maxima
B) For n1  4, n2  3 , there exists   (3,5) where f attains local minima
C) For n1  3, n2  5, there exists   (3,5) where f attains local maxima
D) For n1  4, n 2  6, there exists   (3,5) where f attains local maxima

   
2 3
3. If the function f ( x )  4  x2  3  4  x2  1 then which of the following
is/are correct ?
A) f ( x) has greatest value 28
B) f ( x) has least value K  [ K ]  9   .  is G .I .F 
C) The slope of the tangent of f ( x) at x  1 equals (8  2 3)
D) f '(2)  0
SECTION – II
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
Sec: Jr.Super60_ STERLING BT Space for rough work Page 3
 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
4. Let f ( x )  2 x  3(1  3a ) x  6(a 2  a ) x  b where a , b  R . Find the smallest integral
3 2

value of ‘a’ for which f ( x) has positive point of local maximum

A) 5 B) 3 C) 2 D) 7
5. Let a  R and f ( x)  2 x  3(a  3) x  6ax  (a  2) then the set of values of a for
3 2

which f has exactly one point of local maxima and one point of local minima is
A) (,1)  (9, ) B) (,1]  [9, ) C) (,1)  [9, ) D) [1,9]
6. Let f ( x)  4 sin 3 x  9cos 2 x  6sin x  3 for 0  x   then the maximum value
of f ( x) occurs at x =
5 
A) 0 B)  C) D)
6 2
7. Let f ( x )  x  1  2  x and g ( x )  x  bx  c are two given functions such that
2

f ( x) and g ( x) attain their maximum and minimum values respectively for same
value of x then the value of b is
A) 2 B) 3 C) 4 D) 5
SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.

8. If f ( x)  x 3  3 x  sin 1 (a 2  3a  2). then the smallest positive integer a for which

f ( x)  0 has three distinct real solutions
9. The smallest positive integer of a for which the function
ax3
f ( x)   ( a  2) x 2  ( a  1) x  2 possesses a negative point of inflection is
3
10. Let f ( x) be a polynomial of degree 3 such that f (1)  10, f (1)  6 . f ( x) has critical
point at x  1 and f '( x) has a critical point at x  1. Then f ( x) has local minima at x =
11. If sin  cos   1, then the minimum value of (1  cos ec )(1  sec ) is
 1
12. The minimum value of the function f ( x)  x 3/2  x 3/2  4  x   for all permissible real
 x
x is k then the value of K  2

13. If M is absolute minimum value of f ( x )  cos  x  10 x  3x 2  x3 ,  2  x  3. Find the

M
value of 
5

Sec: Jr.Super60_ STERLING BT Space for rough work Page 4

 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.
14. Match the following
COLUMN-I COLUMN-II
I) 4 x  x  log e ( a  3a  3),
3 2
if 0  x  3 P) (, 2]  [2, )
f ( x)  
 x  18, if x  3
Then, the complete set of values of ‘a’ such that f ( x)
has a local maxima at x = 3 lie in the interval
II) The equation x  cos x  a has exactly a positive Q) [1, 2]
root, then complete set of values of a lie in the interval
III) 3 | x  k |, xk R) (-20, -16)
 has minimum
f ( x)   2 sin( x  k )
a  2  , x  k
 xk
x = k, then, the complete set of values of ‘a’ lie in the
interval
IV) If f ( x )  x3  9 x 2  24 x  a has 3 real and distinct S) (1, )
roots, then, possible values of a lie in the interval
A) I-S, II-R, III-Q, IV-P B) I-Q, II-S, III-P, IV-R
C) I-S, II-R, III-P, IV-Q D) I-R, II-Q, III-S, IV-P
15. Let the function defined in Column – I have domain (0, / 2) the
COLUMN-I COLUMN-II
I) x  2cos x  2 on (0,   2) has
2 P) Local maximum at
cos 1 (2 / 3)
II) 9 x  4tan x on (0, / 2) has Q) Maximum at x  
2
III) x x
2
R) No local extremum
(1/ 2  x)cos x  sin x 
4
IV) 1  S) Minimum at x  1
  x  cos  ( x  3)  (1/  )sin  ( x  3) on (0,4)
2 
A) I-R, II-P, III-Q, IV-S B) I-R, II-S, III-Q, IV-P
C) I-S, II-R, III-P, IV-Q D) I-R, II-Q, III-S, IV-P
Sec: Jr.Super60_ STERLING BT Space for rough work Page 5
 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
16. Match the following
COLUMN-I COLUMN-II
I) The function f ( x)  ( x  1)  ( x  2)  ( x  3)
2 2 2 P) 0
has a minimum for x 
II) The least value of the function Q) 2
f ( x )  2(3)3 x  32 x.4  2.3x in [ 1,1] is
III) 4 3 R) 8
Let f ( x ) 
x  4 x, 0  x  2, then the global
3 27
minimum value of the function is
IV) Let f ( x)  6  12 x  9 x 2  2 x 3 , x  [1,4] then S) 8

Absolute maximum value of f ( x) is 3
A) I-S, II-R, III-Q, IV-P B) I-R, II-S, III-Q, IV-P
C) I-Q, II-P, III-S, IV-Q D) I-R, II-Q, III-S, IV-P
17. Match the following
COLUMN-I COLUMN-II
I) f ( x)  ( x  1)3 ( x  2)5 P) Has one point of maxima
II) f ( x)  3sin x  4cosx  5 x Q) Has point of minima
III)  x R) Has point of inflection
sin , 0  x 1
f ( x)   2
 x 2  4 x  4, 1  x  2

IV) f ( x)  ( x  1)3/5 S) Has no point of extrema
A) I-S, II-R, III-Q, IV-P B) I-QR, II-RS, III-PR, IV-RS
C) I-S, II-R, III-P, IV-Q D) I-R, II-Q, III-S, IV-P

Sec: Jr.Super60_ STERLING BT Space for rough work Page 6

 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
PHYSICS Max Marks: 60
SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

18. In a linear simple harmonic motion (SHM). Select the correct statement (s)
A) Restoring force is directly proportional to the displacement
B) The acceleration and displacement are opposite in direction
C) The velocity is maximum at mean position
D) The acceleration is minimum at extreme points
19. Three simple harmonic motions in the same direction having the same amplitude and same
period are superposed. If each differ in phase from the next by 45 , then

A) the results amplitude is (1  2 )a

B) the phase of the resultant motion relative to the first is 90

C) the energy associated with the resulting motion is (3  2 2) times the energy
associated with any single motion.
D) the resultant motion is not simple harmonic
20. Two identical blocks P and Q have mass m each. They are attached to two identical springs
having spring constant K each are initially unstretched. Now the left spring (along with P)
A
is compressed by and the right spring (along with Q) is compressed by A. Both the
2
blocks are released simultaneously. They collide perfectly inelastically. Initially time
period of both the blocks was T. Then

Sec: Jr.Super60_ STERLING BT Space for rough work Page 7

 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P

A) the time period of oscillation of combined mass is T

A
B) the amplitude of combined mass is
4
KA2
C) the energy of oscillation of combined mass is
16
3A
D) the amplitude of oscillation of combined mass is
4
SECTION – II
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
21. One end of a long metallic wire of length L is tied to the ceiling. The other end is tied to a
massless spring of spring constant K. A mass m hangs freely from the free end of the spring.
The area of cross-section and the Young’s modulus of the wire are A and Y respectively.
If the mass is slightly pulled down and released, it will oscillate with a time period
T equal to
1/2
m m(YA  KL)
A) 2   B) 2
k YAK
1/2 1/2
 mYA   mL 
C) 2   D) 2  
 KL   YA 

Sec: Jr.Super60_ STERLING BT Space for rough work Page 8

 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
22. A pendulum made of a uniform wire of cross sectional area A has time period T. When an
additional mass M is added to its bob, the time period changes to TM . If the Young’s
1
modulus of the material of the wire is Y then is equal to : (g = gravitational acceleration)
Y
  TM 2  A   T 2  A
A) 1     B) 1    
  T   Mg   M   Mg
T

 TM 2  A  T  2  A
C) 
T   1 Mg D)    1
     TM   Mg

23. When a particle of mass m is attached to a vertical spring of spring constant k and released,
its motion is described by y (t )  y0 sin 2 t , where ‘y’ is measured from the lower end of
unstretched spring. Then  is
1 g g g 2g
A) B) C) D)
2 y0 y0 2 y0 y0
24. The x-t graph of a particle undergoing simple harmonic motion as shown in figure. The
4
acceleration of the particle at t  sec is
3

3 2 2 2 3 2
A)  cms 2 B)  cms 2 C) cms 2 D)   cms 2
32 32 32 32

Sec: Jr.Super60_ STERLING BT Space for rough work Page 9

 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases..
25. A 0.1 kg mass is suspended from a wire of negligible mass. The length of the wire is 1m
and its cross-sectional are is 4.9  107 m2 . If the mass is pulled a little in the vertically
downward direction and released, it performs simple harmonic motion of angular
frequency 140 rads 1 . If the Young’s modulus of the material of the wire is n  109 Nm2
the value of n is
26. The metallic bob of simple pendulum has the relative density 5. The time period of this
pendulum is 10s. If the metallic bob is immersed in water, then the new time period
becomes 5 xs . The value of x will be ……
27. The potential energy of a particle of mass 4kg in motion along the x-axis is given by

U  4(1  cos 4 x) J . The time period of the particle for small oscillation (sin    ) is    s .
K
The value of K is ………
28. A particle of mass 1kg is hanging from a spring of force constant 100 Nm 1 . The mass is
pulled slightly downward and released so that it executes free simple harmonic motion with
time period T. The time when the kinetic energy and potential energy of the system will
T
become equal is . The value of x is
x
29. A particle executes S.H.M with amplitude ‘a’ and time period (T) the displacement of the
1rd 2 2A
particle when its speed is of the maximum speed is then the value of x is
3 x
30. A particle executes simple harmonic motion represented by displacement function
as x(t )  Asin(t   ). If the position and velocity of the particle at t = 0s are 2cm

and 2cms 1 respectively, then its amplitude is x 2cm where the value of x is ____

Sec: Jr.Super60_ STERLING BT Space for rough work Page 10

 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.
31. Two particles ‘A’ and ‘B’ start SHM at t  0. Their positions as function of time are given
by X A  A sin t and X B  A sin(t   / 3)
Column - I Column - II
5
I) minimum time when x is same P)
6

II) minimum time when velocity is same Q)
3

III) minimum time after which v A  0 and vB  0 R)


IV) minimum time after x A  0 and xB  0 S)
2
A) I-Q, II-R, III-S, IV-R B) I-R, II-S, III-Q, IV-P
C) I-S, II-R, III-P, IV-Q D) I-R, II-Q, III-S, IV-P
32. A mass m is subjected to a force F  ( at  bx )iˆ , initially the mass lies at the origin at
rest. Here x refers to the x coordinate of the mass, t refers to the time elapsed. All the values
are in S.I unit (i.e. F , m, t , x, a and b are constants). Now match the column – I with
column – II. (All values in column - II are in S.I units)
Column - I Column - II
I) maximum velocity attained by the mass P) 1
II) average velocity of the particle during the subsequent motion Q) 2
III) average acceleration of the particle during subsequent motion R) 0
 
IV) position of particle at t S) 1
2 2
A) I-R, II-Q, III-S, IV-P B) I-R, II-S, III-Q, IV-P
C) I-S, II-R, III-P, IV-Q D) I-Q, II-P, III-R, IV-S

Sec: Jr.Super60_ STERLING BT Space for rough work Page 11

 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
33. Column – I shows spring block system with a constant force permanently acting on the
block. Match entries of column – I with column – II
Column - I Column – II

m
I. P) time period of ocillation T  2 spring
k
is initially relaxed when force is applied

2mg
II. Q) amplitude of oscillation is A spring is
k
initially relaxed when force is applied

 m
III. R) maximum velocity attained by block is 2 g  .
 k 
Before force is applied block is in equilibrium position

IV. S) maximum magnitude of acceleration of block

is 2g. When force is applied block is in equilibrium
T) velocity of block when spring is in natural length is zero.
If block acquire natural length.
A) I-P,R,S, II-Q,R,T III-P,Q,S, IV-P,Q,R
B) I-P,Q,R,S,T, II-P,Q,R,S,T, III-P,Q,R,S, IV-P,Q,R,S
C) I-P,Q,T, II-Q,R,S,T, III-P,Q,R IV-P,Q,S
D) I-S,T, II-S,T, III-R,S, IV-R,S
Sec: Jr.Super60_ STERLING BT Space for rough work Page 12
 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
34. A simple harmonic oscillator consists of a block attached to a spring with k = 200 N/m.
The block slides on a frictionless horizontal surface, with equilibrium point x  0 . A graph
of the block’s velocity v as a function of time t is shown. Correctly match the required
Information in Column – I with the value given in Column – II (use  2  10 )

Column - I Column - II
I) the block’s mass in kg P) -0.20
II) the block’s displacement at t = 0 in meter Q) -200
III) the block’s acceleration at t = 0.1s in m/s2 R)0.20
IV) the block’s maximum kinetic energy in joule S) 4.0
A) I-S, II-R, III-Q, IV-P B) I-R, II-S, III-Q, IV-P
C) I-R, II-P, III-Q, IV-S D) I-R, II-Q, III-S, IV-P

Sec: Jr.Super60_ STERLING BT Space for rough work Page 13

 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
CHEMISTRY Max Marks: 60
SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

35. The correct statement(s) for the following addition reactions is (are)
H3C H

i) B 
r2/CHCl3
M and N

H CH3

H 3C CH 3

ii) 
Br2 / CHCl3
 O and P

H H
A) (M and O) and (N and P) are two pairs of enantiomers
B)Bromination proceeds through trans-addition in both the reactions
C) O and P are identical molecules
D) (M and O) and (N and P) two pairs of diastereomers
36. Consider the sequence of reacations.
CH 3CH 2  C  C  H i ) NaNH 2
ii ) CH 3CH 2 Br
 X 
H 2 / Pd BaSO4
 Y 
Alkaline KMnO4
Z
Identify the correct statement (s) for above sequence of reactions
A) x is 1-hexyne
B) y is formed by synaddition mechanism from x
C) z is an optically inactive
D) Z is a mesoproduct
Sec: Jr.Super60_ STERLING BT Space for rough work Page 14
 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
37. One mole of a hydrocarbon A reacts with one mole of bromine giving a dibromo
compound, C5 H10 Br2 . Compound A on treatment with cold dilute alkaline potassium
permanganate solution forms a compound, C5 H12O2 . On ozonolysis A gives
equimolarquantities of propanone and ethanal. Correct statements about this is/are
A) A has 9 primary hydrogens
B) Dibromoproduct is a vic-dibromo product
C) After addition of KMnO4 a gem diol is formed
2
D) A has two sp carbons
SECTION – II
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
38. Which compound would give 5-keto-2-methyl hexanal upon ozonolysis ?
CH3 CH3
CH3 CH 3
CH 3
CH3
CH3
A) B) C) CH3 D)
2
39. Ph  C  C  CH 3 
Hg
H
 A; A is
O Ph OH
Ph Ph Ph
O OH
H3C H 3C H3C H3C
A) B) C) D)
40. Hydrogenation of the adjoining compound in the presence of poisoned palladium catalyst
gives
H 3C H
CH 3

H 3C H H
A) an optically active compound B) an optically inactive compound
C) a racemic mixture D) a diastereomeric mixture
Sec: Jr.Super60_ STERLING BT Space for rough work Page 15
 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
41. The number of structural and configurational isomers of a bromo compound, C5 H 9 Br ,
formed by the addition of HBr to 2-pentyne respectively, are
A) 1 and 2 B) 2 and 4 C) 4 and 2 D) 2 and 1
SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.
42. An alkyl halide X, of formula C6 H13Cl on treatment with potassium ter-butoxide gives

two isomeric alkenes Y and Z (C6 H12 ) . Both alkenes on hydrogenation gives
2, 3-dimethyl butane. If z involves reductive ozonolysis, find the number of lone pairs of
electrons in sp 3 hybrid orbitals of organic product
43. Find out the number of stereo isomers formed when cis-2-butene is reacted with bromine
in the presence of CCl4
44. When an aqueous solution of 1 mole of potassium succinate undergoes Kolbe’s
electrolysis to give X lit of CO2 and Y lit of hydro carbon (Assume both are gases) at
STP, find out X  Y (nearest integer)
45. Find out the total number of cyclic isomers possible for a hydrocarbon with the molecular
formulae C4 H 6

46. Consider the reaction C6 H 5  CH  CH 2 

Br2
CCl4
 X 
i ) NaNH 2 (3 eq )
ii ) CH 3I
Y
Find out the number of atoms in same plane of product Y …….. ?
47. Identify the number of compounds which are give positive test for ammonical silver
nitrate solution
i) HC  CH ii) H 3C  C  CH iii) CH 3  C  C  CH 3

HC CH2

iv) Ph  C  C  H v) Ph  HC  CH 2 vi)
vii) Ph  C  C  Ph
Sec: Jr.Super60_ STERLING BT Space for rough work Page 16
 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –1 In all other cases..
48. Consider the sequence of reactions

Br2 CCl4 NaNH 2 Hg / H 2  Zn Hg

  A 
(2 aq )

 B   C 
D
conce.HCl
Identify correct match regarding sequence of reactions from List-I to List – II

COLUMN-I COLUMN-II
I) A is P)

II) B is Q) O

CH 3
III) C is R)

IV) D is S)
Br

Br
A) I-S, II-R, III-Q, IV-P B) I-R, II-S, III-Q, IV-P
C) I-S, II-R, III-P, IV-Q D) I-R, II-Q, III-S, IV-P
Sec: Jr.Super60_ STERLING BT Space for rough work Page 17
 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
49. Match the product from List-II for the reaction given in List-I (Major product only)
COLUMN-I COLUMN-II
I) P) Ph  CH  CH 2
N H 2O2 ,
 
II) ph Q) Ph
N H 2O2 ,
 
III) R) CH 2  CH 2
N H 2O2 ,
 
IV) S)
H 2O2 ,
N  
Ph
A) I-S, II-R, III-Q, IV-P B) I-R, II-S, III-Q, IV-P
C) I-R, II-P, III-S, IV-Q D) I-R, II-Q, III-S, IV-P
50. Consider the sequence of reactions
NaOH Cl2 , h Cl2 , h
CH 3COOH  ( aq )
 A 
Soda lim e

 B  (1 eq )
 C  Na , dry ether
D 
(1 eq )

Br2  CCl4 Fe  tube
E 
Alc . KOH
 F (1 eq )
 G  alK . KOH
NaNH 2
 H  red hot
I
Correct match for List-I to List- II
COLUMN-I COLUMN-II
I) Formation of B P) HCCl3
from A
II) If 2 equivalents of Q) H 2C  CH  Br
Cl2 is added to C gives
III) After addition of alc. R) HC  CH
KOH for G gives
IV) Gives red PPt with S) Decarboxylation
ammonical Cu2Cl2
A) I-S, II-R, III-Q, IV-P B) I-R, II-S, III-Q, IV-P
C) I-R, II-P, III-S, IV-Q D) I-S, II-P, III-Q, IV-R

Sec: Jr.Super60_ STERLING BT Space for rough work Page 18

 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P
51. Match the correct product from List – II to List-I

COLUMN-I COLUMN-II

I) P) gem-dihalide

 Br2
CCl4

II) Q) Acidic strength


 HBr
(2 eq )
III) HC  CH  CH 2  CH 2  CH3  CH3 R) Reddish brown colour

disappears

IV) i ) 2 NaNH Pd  BaSO S) Cis-2-butene

HC  CH 
2  
4
ii ) 2CH 3 I H2

A) I-S, II-R, III-Q, IV-P B) I-R, II-P, III-Q, IV-S

C) I-R, II-P, III-S, IV-Q D) I-R, II-Q, III-S, IV-P

Sec: Jr.Super60_ STERLING BT Space for rough work Page 19

 Sri Chaitanya IIT Academy 22-12-2024_Jr.Super60_STERLING BT_Jee-Adv(2023-P1)_WTA-22_Q.P

Sec: Jr.Super60_ STERLING BT Space for rough work Page 20