TRICHLOROACETIC ACID EXTRA PURE

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Reference number: 06355
Issue date: 14-12-2022 Revision date: 14-12-2022 Supersedes version of: 18-03-2019 Version: 1.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Substance
Trade name : TRICHLOROACETIC ACID EXTRA PURE
EC Index-No. : 607-004-00-7
EC-No. : 200-927-2
CAS-No. : 76-03-9
Product code : 06355
Type of product : Carboxylic acids
Formula : C2HCl3O2
Chemical structure :

Synonyms : Trichloroethanoic acid, TCA

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec : Industrial
For professional use only
Use of the substance/mixture : Laboratory chemicals
Manufacture of substances

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

LOBA CHEMIE PVT.LTD.
107 Wode House Road, Jehangir Villa, Colaba
400005 Mumbai
INDIA
T +91 22 6663 6663 - F +91 22 6663 6699
[email protected] - www.lobachemie.com

1.4. Emergency telephone number

Emergency number : + 91 22 6663 6663 (9:00am - 6:00 pm)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]
Skin corrosion/irritation, Category 1 H314
Specific target organ toxicity – Single exposure, Category 3, Respiratory H335
tract irritation
Hazardous to the aquatic environment – Acute Hazard, Category 1 H400
Hazardous to the aquatic environment – Chronic Hazard, Category 1 H410
Full text of H- and EUH-statements: see section 16

Adverse physicochemical, human health and environmental effects

May cause respiratory irritation. Causes severe skin burns and eye damage. Very toxic to aquatic life with long lasting effects.

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TRICHLOROACETIC ACID EXTRA PURE
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :

GHS05 GHS07 GHS09

Signal word (CLP) : Danger
Hazard statements (CLP) : H314 - Causes severe skin burns and eye damage.
H335 - May cause respiratory irritation.
H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) : P260 - Do not breathe dust/fume/gas/mist/vapours/spray.
P280 - Wear protective clothing, eye protection, face protection, protective gloves.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water .
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.

2.3. Other hazards

Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII

SECTION 3: Composition/information on ingredients

3.1. Substances
Substance type : Mono-constituent
Name : TRICHLOROACETIC ACID
CAS-No. : 76-03-9
EC-No. : 200-927-2
EC Index-No. : 607-004-00-7

3.2. Mixtures
Not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general : Call a physician immediately.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove person to fresh air
and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. Call a
poison center or a doctor if you feel unwell.
First-aid measures after skin contact : Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately
call a POISON CENTER/doctor. Call a physician immediately.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. Immediately call a POISON CENTER/doctor. Call a physician
immediately.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor. Do not
induce vomiting. Call a physician immediately.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects : Causes severe skin burns and eye damage.
Symptoms/effects after inhalation : May cause respiratory irritation.
Symptoms/effects after skin contact : Burns.
Symptoms/effects after eye contact : Serious damage to eyes.
Symptoms/effects after ingestion : Burns.

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TRICHLOROACETIC ACID EXTRA PURE
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). Water spray. Dry
powder. Foam.
Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

Hazardous decomposition products in case of fire : Toxic fumes may be released.

5.3. Advice for firefighters

Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained
breathing apparatus. Complete protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel. Avoid contact with skin and eyes.
Do not breathe dust/fume/gas/mist/vapours/spray.

6.1.2. For emergency responders

Protective equipment : Do not attempt to take action without suitable protective equipment. Use personal protective
equipment as required. For further information refer to section 8: "Exposure
controls/personal protection".
Emergency procedures : Stop release.

6.2. Environmental precautions

Avoid release to the environment. Very toxic to aquatic life with long lasting effects.

6.3. Methods and material for containment and cleaning up

For containment : Collect spillage.
Methods for cleaning up : Mechanically recover the product. Clear up rapidly by scoop or vacuum.
Other information : Dispose of materials or solid residues at an authorized site.

6.4. Reference to other sections

For further information refer to section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while
nursing. Use only outdoors or in a well-ventilated area. Avoid contact with skin and eyes.
Wear personal protective equipment.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Wash contaminated clothing
before reuse. Do not eat, drink or smoke when using this product. Always wash hands after
handling the product.

7.2. Conditions for safe storage, including any incompatibilities

Technical measures : Comply with applicable regulations.

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TRICHLOROACETIC ACID EXTRA PURE
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Storage conditions : Store in original container. Keep container tightly closed. Store in a dry place. Protect from
moisture. Store locked up. Store in a well-ventilated place. Keep cool.

7.3. Specific end use(s)

No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

8.1.1 National occupational exposure and biological limit values
No additional information available

8.1.2. Recommended monitoring procedures

No additional information available

8.1.3. Air contaminants formed

No additional information available

8.1.4. DNEL and PNEC

No additional information available

8.1.5. Control banding

No additional information available

8.2. Exposure controls

8.2.1. Appropriate engineering controls

Appropriate engineering controls:

Ensure good ventilation of the work station.

8.2.2. Personal protection equipment

Personal protective equipment symbol(s):

8.2.2.1. Eye and face protection

Eye protection:
Chemical goggles or face shield

8.2.2.2. Skin protection

Hand protection:
Protective gloves. Nitrile rubber gloves

8.2.2.3. Respiratory protection

Respiratory protection:
Wear appropriate mask

8.2.2.4. Thermal hazards

No additional information available

8.2.3. Environmental exposure controls

Environmental exposure controls:

Avoid release to the environment.

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TRICHLOROACETIC ACID EXTRA PURE
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Solid
Appearance : Deliquescent crystals.
Molecular mass : 163.39 g/mol
Colour : Colourless.
Odour : Pungent.
Odour threshold : No data available
pH : 1.2 (0.1 M Solution)
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 55.5 – 58 °C
Freezing point : Not applicable
Boiling point : 196 – 197 °C
Flash point : > 113 °C
Auto-ignition temperature : Not applicable
Decomposition temperature : No data available
Flammability (solid, gas) : Non flammable.
Vapour pressure : 1 hPa at 51°C
Relative vapour density at 20 °C : 5.64 (Air = 1.0)
Relative density : No data available
Density : 1.63 g/cm³
Solubility : Water: Soluble in water
Partition coefficient n-octanol/water (Log Pow) : 1.33 - Bioaccumulation is not expected.
Viscosity, kinematic : Not applicable
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : Not applicable

9.2. Other information

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
The product is non-reactive under normal conditions of use, storage and transport.

10.2. Chemical stability

Stable under normal conditions of use.

10.3. Possibility of hazardous reactions

No dangerous reactions known under normal conditions of use.

10.4. Conditions to avoid

Direct sunlight. Air contact. Moisture.

10.5. Incompatible materials

No additional information available

10.6. Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

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TRICHLOROACETIC ACID EXTRA PURE
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
Skin corrosion/irritation : Causes severe skin burns.
pH: 1.2 (0.1 M Solution)
Serious eye damage/irritation : Assumed to cause serious eye damage
pH: 1.2 (0.1 M Solution)
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : May cause respiratory irritation.
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified

TRICHLOROACETIC ACID EXTRA PURE (76-03-9)

Viscosity, kinematic Not applicable

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : Very toxic to aquatic life with long lasting effects.
Ecology - water : Very toxic to aquatic life with long lasting effects.
Hazardous to the aquatic environment, short–term : Very toxic to aquatic life.
(acute)
Hazardous to the aquatic environment, long–term : Very toxic to aquatic life with long lasting effects.
(chronic)

12.2. Persistence and degradability

TRICHLOROACETIC ACID EXTRA PURE (76-03-9)

Persistence and degradability May cause long-term adverse effects in the environment.

12.3. Bioaccumulative potential

TRICHLOROACETIC ACID EXTRA PURE (76-03-9)

Partition coefficient n-octanol/water (Log Pow) 1.33 - Bioaccumulation is not expected.

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Product/Packaging disposal recommendations : Dispose of contents/container to a licensed hazardous-waste disposal contractor or

collection site except for empty clean containers which can be disposed of as non-
hazardous waste.

SECTION 14: Transport information

In accordance with ADR / IMDG / IATA / ADN / RID

14.1 UN number
UN-No. (ADR) : UN 1839
UN-No. (IMDG) : UN 1839
UN-No. (IATA) : UN 1839
UN-No. (ADN) : UN 1839
UN-No. (RID) : UN 1839

14.2. UN proper shipping name

Proper Shipping Name (ADR) : TRICHLOROACETIC ACID
Proper Shipping Name (IMDG) : TRICHLOROACETIC ACID, SOLID
Proper Shipping Name (IATA) : Trichloroacetic acid
Proper Shipping Name (ADN) : TRICHLOROACETIC ACID
Proper Shipping Name (RID) : TRICHLOROACETIC ACID
Transport document description (ADR) : UN 1839 TRICHLOROACETIC ACID, 8, II, (E), ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 1839 TRICHLOROACETIC ACID, SOLID, 8, II, MARINE
POLLUTANT/ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 1839 Trichloroacetic acid, 8, II, ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 1839 TRICHLOROACETIC ACID, 8, II, ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 1839 TRICHLOROACETIC ACID, 8, II, ENVIRONMENTALLY HAZARDOUS

14.3. Transport hazard class(es)

ADR
Transport hazard class(es) (ADR) : 8
Danger labels (ADR) : 8
:

IMDG
Transport hazard class(es) (IMDG) : 8
Danger labels (IMDG) : 8
:

IATA
Transport hazard class(es) (IATA) : 8
Danger labels (IATA) : 8
:

ADN
Transport hazard class(es) (ADN) : 8
Danger labels (ADN) : 8

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TRICHLOROACETIC ACID EXTRA PURE
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

RID
Transport hazard class(es) (RID) : 8
Danger labels (RID) : 8
:

14.4. Packing group

Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II

14.5. Environmental hazards

Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available

14.6. Special precautions for user

Overland transport
Classification code (ADR) : C4
Limited quantities (ADR) : 1kg
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P002, IBC08
Special packing provisions (ADR) : B4
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container instructions (ADR) : T3
Portable tank and bulk container special provisions : TP33
(ADR)
Tank code (ADR) : SGAN, L4BN
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Packages (ADR) : V11
Hazard identification number (Kemler No.) : 80
Orange plates :

Tunnel restriction code (ADR) : E

EAC code : 2X

Transport by sea
Limited quantities (IMDG) : 1 kg
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B21, B4
Tank instructions (IMDG) : T3
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : A

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Segregation (IMDG) : SGG1, SG36, SG49

Properties and observations (IMDG) : Colourless, deliquescent crystals. Melting point of the pure substance: 58°C . In the
presence of moisture, corrosive to most metals. Causes burns to skin, eyes and mucous
membranes.
MFAG-No : 153

Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y844
PCA limited quantity max net quantity (IATA) : 5kg
PCA packing instructions (IATA) : 859
PCA max net quantity (IATA) : 15kg
CAO packing instructions (IATA) : 863
CAO max net quantity (IATA) : 50kg
ERG code (IATA) : 8L

Inland waterway transport

Classification code (ADN) : C4
Limited quantities (ADN) : 1 kg
Excepted quantities (ADN) : E2
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0

Rail transport
Classification code (RID) : C4
Limited quantities (RID) : 1kg
Excepted quantities (RID) : E2
Packing instructions (RID) : P002, IBC08
Special packing provisions (RID) : B4
Mixed packing provisions (RID) : MP10
Portable tank and bulk container instructions (RID) : T3
Portable tank and bulk container special provisions : TP33
(RID)
Tank codes for RID tanks (RID) : SGAN, L4BN
Transport category (RID) : 2
Special provisions for carriage – Packages (RID) : W11
Colis express (express parcels) (RID) : CE10
Hazard identification number (RID) : 80

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

REACH Annex XVII (Restriction List)

No REACH Annex XVII restrictions

REACH Annex XIV (Authorisation List)

TRICHLOROACETIC ACID EXTRA PURE is not on the REACH Annex XIV List

REACH Candidate List (SVHC)

TRICHLOROACETIC ACID EXTRA PURE is not on the REACH Candidate List

PIC Regulation (Prior Informed Consent)

TRICHLOROACETIC ACID EXTRA PURE is not subject to Regulation (EU) No 649/2012 of the European Parliament and of the Council of 4 july
2012 concerning the export and import of hazardous chemicals.

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TRICHLOROACETIC ACID EXTRA PURE
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

POP Regulation (Persistent Organic Pollutants)

TRICHLOROACETIC ACID EXTRA PURE is not subject to Regulation (EU) No 2019/1021 of the European Parliament and of the Council of 20
June 2019 on persistent organic pollutants

Ozone Regulation (1005/2009)

TRICHLOROACETIC ACID is not subject to REGULATION (EU) No 1005/2009 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16
September 2009 on substances that deplete the ozone layer.

Explosives Precursors Regulation (2019/1148)

Contains no substance subject to Regulation (EU) 2019/1148 of the European Parliament and of the Council of 20 June 2019 on the marketing and
use of explosives precursors.

Drug Precursors Regulation (273/2004)

Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on drug precursors)

15.1.2. National regulations

Germany
Water hazard class (WGK) : WGK 2, Significantly hazardous to water (Classification according to AwSV; ID No. 197).
Hazardous Incident Ordinance (12. BImSchV) : Is not subject of the Hazardous Incident Ordinance (12. BImSchV)

Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
SZW-lijst van reprotoxische stoffen – Borstvoeding : The substance is not listed
SZW-lijst van reprotoxische stoffen – : The substance is not listed
Vruchtbaarheid
SZW-lijst van reprotoxische stoffen – Ontwikkeling : TRICHLOROACETIC ACID is listed

Denmark
Danish National Regulations : Young people below the age of 18 years are not allowed to use the product

15.2. Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information

Abbreviations and acronyms:

ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways

ADR European Agreement concerning the International Carriage of Dangerous Goods by Road

ATE Acute Toxicity Estimate

BCF Bioconcentration factor

BLV Biological limit value

BOD Biochemical oxygen demand (BOD)

COD Chemical oxygen demand (COD)

DMEL Derived Minimal Effect level

DNEL Derived-No Effect Level

EC-No. European Community number

EC50 Median effective concentration

EN European Standard

IARC International Agency for Research on Cancer

IATA International Air Transport Association

IMDG International Maritime Dangerous Goods

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TRICHLOROACETIC ACID EXTRA PURE
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Abbreviations and acronyms:

LC50 Median lethal concentration

LD50 Median lethal dose

LOAEL Lowest Observed Adverse Effect Level

NOAEC No-Observed Adverse Effect Concentration

NOAEL No-Observed Adverse Effect Level

NOEC No-Observed Effect Concentration

OECD Organisation for Economic Co-operation and Development

OEL Occupational Exposure Limit

PBT Persistent Bioaccumulative Toxic

PNEC Predicted No-Effect Concentration

RID Regulations concerning the International Carriage of Dangerous Goods by Rail

SDS Safety Data Sheet

STP Sewage treatment plant

ThOD Theoretical oxygen demand (ThOD)

TLM Median Tolerance Limit

VOC Volatile Organic Compounds

CAS-No. Chemical Abstract Service number

N.O.S. Not Otherwise Specified

vPvB Very Persistent and Very Bioaccumulative

ED Endocrine disrupting properties

Full text of H- and EUH-statements:

Aquatic Acute 1 Hazardous to the aquatic environment – Acute Hazard, Category 1

Aquatic Chronic 1 Hazardous to the aquatic environment – Chronic Hazard, Category 1

H314 Causes severe skin burns and eye damage.

H335 May cause respiratory irritation.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

Skin Corr. 1 Skin corrosion/irritation, Category 1

STOT SE 3 Specific target organ toxicity – Single exposure, Category 3, Respiratory tract irritation

Safety Data Sheet (SDS), EU

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

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