SAFETY DATA SHEET
DDP SPECIALTY ELECTRONIC MATERIALS
US 9, LLC
Product name: MOLYKOTE® G-3407 Caliper Pin Grease Issue Date: 11/12/2020
Print Date: 06/22/2023
DDP SPECIALTY ELECTRONIC MATERIALS US 9, LLC encourages and expects you to read and
understand the entire (M)SDS, as there is important information throughout the document. We expect
you to follow the precautions identified in this document unless your use conditions would necessitate
other appropriate methods or actions.
1. IDENTIFICATION
Product name: MOLYKOTE® G-3407 Caliper Pin Grease
Recommended use of the chemical and restrictions on use
Identified uses: Lubricants and lubricant additives
COMPANY IDENTIFICATION
DDP SPECIALTY ELECTRONIC MATERIALS
US 9, LLC
974 Centre Road
Wilmington DE 19805
UNITED STATES
Customer Information Number: 833-338-7668
[email protected]EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact: 1-800-424-9300
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with 29 CFR 1910.1200
Not a hazardous substance or mixture.
Other hazards
No data available
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature: Organic grease
This product is a mixture.
Component CASRN Concentration
® ™ Trademark of affiliates of DuPont de Nemours, Inc. Page 1 of 13
Product name: MOLYKOTE® G-3407 Caliper Pin Grease Issue Date: 11/12/2020
Lithium 12-hydroxyoctadecanoate 7620-77-1 >= 5.0 - <= 10.0 %
Nonanedioic acid, dilithium salt 38900-29-7 >= 1.0 - <= 3.0 %
4. FIRST AID MEASURES
Description of first aid measures
General advice:
First Aid responders should pay attention to self-protection and use the recommended protective
clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section
8 for specific personal protective equipment.
Inhalation: Move person to fresh air; if effects occur, consult a physician.
Skin contact: Wash off with plenty of water.
Eye contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.
Most important symptoms and effects, both acute and delayed:
Aside from the information found under Description of first aid measures (above) and Indication of
immediate medical attention and special treatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology Information.
Indication of any immediate medical attention and special treatment needed
Notes to physician: No specific antidote. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.
5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry
chemical
Unsuitable extinguishing media: None known.
Special hazards arising from the substance or mixture
Hazardous combustion products: Carbon oxides Sulphur oxides Nitrogen oxides (NOx) Metal
oxides
Unusual Fire and Explosion Hazards: Exposure to combustion products may be a hazard to health.
Advice for firefighters
Fire Fighting Procedures: Collect contaminated fire extinguishing water separately. This must not be
discharged into drains. Contain fire water run-off if possible. Fire water run-off, if not contained, may
cause environmental damage.
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Product name: MOLYKOTE® G-3407 Caliper Pin Grease Issue Date: 11/12/2020
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Use water spray to cool unopened containers. Collect contaminated fire extinguishing
water separately. This must not be discharged into drains. Remove undamaged containers from fire
area if it is safe to do so. Evacuate area.
Special protective equipment for firefighters: Wear self-contained breathing apparatus for
firefighting if necessary. Use personal protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Follow safe handling
advice and personal protective equipment recommendations.
Environmental precautions: Do not release the product to the aquatic environment above defined
regulatory levels Prevent further leakage or spillage if safe to do so. Retain and dispose of
contaminated wash water. Local authorities should be advised if significant spillages cannot be
contained.
Methods and materials for containment and cleaning up: Wipe up or scrape up and contain for
salvage or disposal. Local or national regulations may apply to releases and disposal of this material,
as well as those materials and items employed in the cleanup of releases. You will need to determine
which regulations are applicable. For large spills, provide dyking or other appropriate containment to
keep material from spreading. If dyked material can be pumped, Sections 13 and 15 of this SDS
provide information regarding certain local or national requirements.
See sections: 7, 8, 11, 12 and 13.
7. HANDLING AND STORAGE
Precautions for safe handling: Take care to prevent spills, waste and minimize release to the
environment. Handle in accordance with good industrial hygiene and safety practice.
Use only with adequate ventilation. See Engineering measures under EXPOSURE
CONTROLS/PERSONAL PROTECTION section.
Conditions for safe storage: Keep in properly labelled containers. Store in accordance with the
particular national regulations.
Do not store with the following product types: Strong oxidizing agents.
Unsuitable materials for containers: None known.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
If exposure limits exist, they are listed below. If no exposure limits are displayed, then no values are
applicable.
Component Regulation Type of listing Value
Lithium 12- ACGIH TWA Inhalable 10 mg/m3
hydroxyoctadecanoate particulate matter
Further information: LRT irr: Lower Respiratory Tract irritation; J: Does not include
stearates of toxic metals.; A4: Not classifiable as a human carcinogen; varies: varies
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Product name: MOLYKOTE® G-3407 Caliper Pin Grease Issue Date: 11/12/2020
ACGIH TWA Respirable 3 mg/m3
particulate matter
Further information: LRT irr: Lower Respiratory Tract irritation; J: Does not include
stearates of toxic metals.; A4: Not classifiable as a human carcinogen; varies: varies
Exposure controls
Engineering controls: Use local exhaust ventilation, or other engineering controls to maintain
airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure
limit requirements or guidelines, general ventilation should be sufficient for most operations.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Use
good personal hygiene. Do not consume or store food in the work area. Wash hands before smoking
or eating.
Individual protection measures
Eye/face protection: Use safety glasses (with side shields).
Skin protection
Hand protection: Use gloves chemically resistant to this material. NOTICE: The selection of a
specific glove for a particular application and duration of use in a workplace should also take into
account all relevant workplace factors such as, but not limited to: Other chemicals which may be
handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body
reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.
Other protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task.
Respiratory protection: Respiratory protection should be worn when there is a potential to exceed
the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or
guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or
discomfort have been experienced, or where indicated by your risk assessment process. For most
conditions no respiratory protection should be needed; however, if discomfort is experienced, use an
approved air-purifying respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical state Grease
Color green
Odor not significant
Odor Threshold No data available
pH Not applicable
Melting point/range No data available
Freezing point No data available
Boiling point (760 mmHg) Not applicable
Flash point closed cup 188 °C ( 370 °F)
Evaporation Rate (Butyl Acetate Not applicable
= 1)
Flammability (solid, gas) Not classified as a flammability hazard
Lower explosion limit No data available
Upper explosion limit No data available
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Product name: MOLYKOTE® G-3407 Caliper Pin Grease Issue Date: 11/12/2020
Vapor Pressure Not applicable
Relative Vapor Density (air = 1) No data available
Relative Density (water = 1) 1.0
Water solubility No data available
Partition coefficient: n- No data available
octanol/water
Auto-ignition temperature No data available
Decomposition temperature No data available
Dynamic Viscosity Not applicable
Kinematic Viscosity Not applicable
Explosive properties Not explosive
Oxidizing properties The substance or mixture is not classified as oxidizing.
Molecular weight No data available
Particle size No data available
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
10. STABILITY AND REACTIVITY
Reactivity: Not classified as a reactivity hazard.
Chemical stability: Stable under normal conditions.
Possibility of hazardous reactions: Can react with strong oxidizing agents.
Conditions to avoid: None known.
Incompatible materials: Oxidizing agents
Hazardous decomposition products
No hazardous decomposition products are known.
11. TOXICOLOGICAL INFORMATION
Toxicological information appears in this section when such data is available.
Acute toxicity
Acute oral toxicity
Product test data not available. Refer to component data.
Acute dermal toxicity
Product test data not available. Refer to component data.
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Product name: MOLYKOTE® G-3407 Caliper Pin Grease Issue Date: 11/12/2020
Acute inhalation toxicity
Product test data not available. Refer to component data.
Skin corrosion/irritation
Product test data not available. Refer to component data.
Serious eye damage/eye irritation
Product test data not available. Refer to component data.
Sensitization
Product test data not available. Refer to component data.
Specific Target Organ Systemic Toxicity (Single Exposure)
Product test data not available. Refer to component data.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Product test data not available. Refer to component data.
Carcinogenicity
Product test data not available. Refer to component data.
Teratogenicity
Product test data not available. Refer to component data.
Reproductive toxicity
Product test data not available. Refer to component data.
Mutagenicity
Product test data not available. Refer to component data.
Aspiration Hazard
Product test data not available. Refer to component data.
COMPONENTS INFLUENCING TOXICOLOGY:
Lithium 12-hydroxyoctadecanoate
Acute oral toxicity
LD50, Rat, female, > 2,000 mg/kg OECD Test Guideline 420 No deaths occurred at this
concentration.
Acute dermal toxicity
LD50, Rat, male and female, > 2,000 mg/kg OECD Test Guideline 402 No deaths occurred at
this concentration.
Acute inhalation toxicity
The LC50 has not been determined.
Skin corrosion/irritation
Brief contact is essentially nonirritating to skin.
Serious eye damage/eye irritation
May cause slight eye irritation.
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Product name: MOLYKOTE® G-3407 Caliper Pin Grease Issue Date: 11/12/2020
Sensitization
Did not demonstrate the potential for contact allergy in mice.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Carcinogenicity
No relevant data found.
Teratogenicity
Did not cause birth defects in laboratory animals.
Reproductive toxicity
In animal studies, did not interfere with reproduction.
Mutagenicity
In vitro genetic toxicity studies were negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
Nonanedioic acid, dilithium salt
Acute oral toxicity
LD50, Rat, male and female, 300 - 2,000 mg/kg OECD Test Guideline 420
Acute dermal toxicity
For similar material(s): LD50, Rat, male and female, > 2,000 mg/kg No deaths occurred at
this concentration.
Acute inhalation toxicity
The LC50 has not been determined.
Skin corrosion/irritation
Brief contact is essentially nonirritating to skin.
Serious eye damage/eye irritation
May cause slight temporary eye irritation.
Corneal injury is unlikely.
Sensitization
For skin sensitization:
For similar material(s):
Did not demonstrate the potential for contact allergy in mice.
For respiratory sensitization:
No relevant data found.
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Product name: MOLYKOTE® G-3407 Caliper Pin Grease Issue Date: 11/12/2020
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on information for a similar material:
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Carcinogenicity
No relevant data found.
Teratogenicity
Did not cause birth defects or any other fetal effects in laboratory animals.
Reproductive toxicity
For similar material(s): In animal studies, did not interfere with reproduction.
Mutagenicity
For similar material(s): In vitro genetic toxicity studies were negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
12. ECOLOGICAL INFORMATION
Ecotoxicological information appears in this section when such data is available.
Toxicity
Lithium 12-hydroxyoctadecanoate
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), semi-static test, 96 Hour, > 100 mg/l, OECD Test
Guideline 203
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), static test, 48 Hour, > 100 mg/l, OECD Test Guideline
202
Acute toxicity to algae/aquatic plants
EC50, Pseudokirchneriella subcapitata (green algae), static test, 72 Hour, Growth rate, > 160
mg/l, OECD Test Guideline 201
Nonanedioic acid, dilithium salt
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Carp (Cyprinus carpio), Static, 96 Hour, > 100 mg/l, OECD Test Guideline 203
Acute toxicity to aquatic invertebrates
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Product name: MOLYKOTE® G-3407 Caliper Pin Grease Issue Date: 11/12/2020
EC50, Daphnia magna (Water flea), Static, 48 Hour, > 100 mg/l, OECD Test Guideline 202
Acute toxicity to algae/aquatic plants
ErC50, Pseudokirchneriella subcapitata (green algae), Static, 72 Hour, Growth rate, > 100
mg/l
Persistence and degradability
Lithium 12-hydroxyoctadecanoate
Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability.
10-day Window: Pass
Biodegradation: 78 %
Exposure time: 28 d
Method: OECD Test Guideline 301C
Nonanedioic acid, dilithium salt
Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability. Material is ultimately biodegradable (reaches > 70% mineralization in OECD
test(s) for inherent biodegradability).
Based on information for a similar material: 10-day Window: Pass
Biodegradation: > 70 %
Exposure time: 10 d
Method: OECD Test Guideline 301B
Based on information for a similar material: 10-day Window: Not applicable
Biodegradation: 100 %
Exposure time: 4 d
Method: OECD Test Guideline 302B
Bioaccumulative potential
Lithium 12-hydroxyoctadecanoate
Bioaccumulation: No relevant data found.
Nonanedioic acid, dilithium salt
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): -3.53 at 20 °C OECD Test Guideline 107 or
Equivalent
Mobility in soil
Lithium 12-hydroxyoctadecanoate
No relevant data found.
Nonanedioic acid, dilithium salt
No relevant data found.
13. DISPOSAL CONSIDERATIONS
Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
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Product name: MOLYKOTE® G-3407 Caliper Pin Grease Issue Date: 11/12/2020
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Incinerator or other thermal destruction device. For additional information, refer to:
Handling & Storage Information, MSDS Section 7 Stability & Reactivity Information, MSDS Section10
Regulatory Information, MSDS Section 15
Treatment and disposal methods of used packaging: Empty containers should be recycled or
otherwise disposed of by an approved waste management facility. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. Do not re-use
containers for any purpose.
14. TRANSPORT INFORMATION
DOT
Not regulated for transport
Classification for SEA transport (IMO-IMDG):
Not regulated for transport
Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code
Classification for AIR transport (IATA/ICAO):
Not regulated for transport
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
15. REGULATORY INFORMATION
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
No SARA Hazards
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Product name: MOLYKOTE® G-3407 Caliper Pin Grease Issue Date: 11/12/2020
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
Section 103
Calculated RQ exceeds reasonably attainable upper limit.
Components CASRN RQ (RCRA Code)
Ethylbenzene 100-41-4 1000 lbs RQ
Ethylbenzene 100-41-4 100 lbs RQ (F003)
Naphthylamine 91-59-8 10 lbs RQ
Pennsylvania Right To Know
The following chemicals are listed because of the additional requirements of Pennsylvania law:
Components CASRN
Distillates, petroleum, hydrotreated heavy naphthenic 64742-52-5
Pennsylvania Right To Know
The following chemicals are listed because of the additional requirements of Pennsylvania law:
Components CASRN
Polypropylene glycol monobutyl ether 9003-13-8
Lithium 12-hydroxyoctadecanoate 7620-77-1
Methylene bis(dibutylthiocarbamate) 10254-57-6
Distillates, petroleum, hydrotreated heavy naphthenic 64742-52-5
California Prop. 65
WARNING: This product can expose you to chemicals including Naphthylamine, Naphthalenamine,
Aniline, Ethylbenzene, Naphthalene, which is/are known to the State of California to cause cancer. For
more information go to www.P65Warnings.ca.gov.
United States TSCA Inventory (TSCA)
All components of this product are in compliance with the inventory listing requirements of the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
16. OTHER INFORMATION
Hazard Rating System
NFPA
Health Flammability Instability
0 1 0
HMIS
Physical
Health Flammability
Hazard
0/ 1 0
Revision
Identification Number: 4094721 / A776 / Issue Date: 11/12/2020 / Version: 6.0
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Product name: MOLYKOTE® G-3407 Caliper Pin Grease Issue Date: 11/12/2020
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
TWA 8-hour, time-weighted average
Full text of other abbreviations
AICS - Australian Inventory of Chemical Substances; AIIC - Australian Inventory of Industrial
Chemicals; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA -
Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen,
Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT -
Department of Transportation; DSL - Domestic Substances List (Canada); ECx - Concentration
associated with x% response; EHS - Extremely Hazardous Substance; ELx - Loading rate associated
with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances
(Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response
Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous
Materials Identification System; IARC - International Agency for Research on Cancer; IATA -
International Air Transport Association; IBC - International Code for the Construction and Equipment of
Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO -
International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China;
IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL -
Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI -
Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 -
Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for
the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not
Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals;
OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical
Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS -
Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure
Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC)
No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating
Decomposition Temperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety
Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic Substances Control Act
(United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport
of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative
Information Source and References
This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.
DDP SPECIALTY ELECTRONIC MATERIALS US 9, LLC urges each customer or recipient of this
(M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become
aware of and understand the data contained in this (M)SDS and any hazards associated with the
product. The information herein is provided in good faith and believed to be accurate as of the
effective date shown above. However, no warranty, express or implied, is given. Regulatory
requirements are subject to change and may differ between various locations. It is the buyer's/user's
responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The
information presented here pertains only to the product as shipped. Since conditions for use of the
product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the
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Product name: MOLYKOTE® G-3407 Caliper Pin Grease Issue Date: 11/12/2020
conditions necessary for the safe use of this product. Due to the proliferation of sources for
information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for
(M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from
another source or if you are not sure that the (M)SDS you have is current, please contact us for the
most current version.
US
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