VJ – 11th CHEMISTRY COMPULSORY QUESTIONS – 2025

COMPULSORY 2 MARKS
1. Which is the suitable method for detection of nitrogen present in food and fertilizers? ( Mar -19)
2. Calculate the orbital angular momentum for d and f orbital. ( June-19)
3. In degenerate orbitals, why do the completely filled and half-filled configurations is more stable than the
partially filled configurations? ( Sep-20)
4. Complete the following : (i) CH3-CH=CH2 + H2 → (ii) CH3MgCl + H2O →(Sep -21)
5. Complete the following reactions (May -22)
(i) C6H5Cl + 2NH3 → (ii) C6H5Cl + 2Na + Cl-C6H5 →
6. If an automobile engine burns petrol at a temperature of 1089 K and if the surrounding temperature is 294 K
, calculate its maximum possible efficiency. (June-22)
7. Calculate the entropy change during the melting of one mole of ice into water at 00 C and 1 atm pressure.
Enthalpy of fusion of ice is 6008 J mol-1. (Mar-23)
8. Complete the following ( June -23)
Conc.H2SO4 HBr
CH3 - CH2 - OH A B
430 - 440K Benzoyl peroxide
9. Calculate the molality of the solution containing 90 g of glucose dissolved in 2 kg of water. (Mar – 24)
10. Complete the following reactions. (i) C6H5Cl + Mg → (ii) CCl4 + H2O → ( June – 24 )
COMPULSORY3 MARKS
1. Give the structural formula for the following compounds. ( Mar -19 , Mar-23 )
a) m-dinitrobenzene b)p-dichlorobenzene c)1,3,5,Tri-methyl Benzene
2. The bond length between all the four carbon atoms is same in 1,3 – butadiene. Explain with reason. (Ju-19)
3. Explain geometrical isomerism in 2-butene. ( Sep-20)
4. Inside a certain automobile engine, the volume of air in a cylinder is 0.375 dm3, when the pressure is
1.05atm. When the gas is compressed to a volume of 0.125 dm3 at the same temperature, what is the
pressure of the compressed air? ( Sep-21)
5. The equilibrium concentrations of NH3 and N2 and H2 are 1.8 x10-2 M, 1.2x10-2M and 3x 10-2 M
respectively. Calculate the equilibrium constant for the formation of NH3 from N2 and H2 . (May -22)
6. Give an example for each of the following type of organic compounds (June-22)
(i) Non-benzonoid aromatic compound (ii) Aromatic heterocyclic compound (iii) Carbocyclic
compound
7. Define : (i) Sigma bond (ii) Pi bond ( June -23)
8. Find A , B and C. (Mar-24)
Alc.KOH NaNH2
CH2 = CH2 + Br2 (A) (B) (C)
9. Draw the M.O diagram for oxygen molecule calculate its bond order and show that O2 is paramagnetic.
( June – 24 )
IMPORTANT QUESTIONS
1. How many moles of ethane is required to produce 44 g of CO2(g) after combustion.
2. Calculate the number of moles present in 9 g of ethane.
3. How many moles of H2 is required to produce 10 moles of NH3?
4. Calculate the amount of H2O produced by combustion of 32 g CH4.
5. How fast must a 54 g tennis ball travel in order to have a de Broglie wavelength that is equal to that of a
photon of green light 5400Å?

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VJ – 11th CHEMISTRY COMPULSORY QUESTIONS – 2025
6. What is the de Broglie wavelength (in cm) of a 160g cricket ball travelling at 140 Km hr-1?
7. What is the de Broglie wave length of an electron, which is accelerated from the rest, through a potential
difference of 100V?
8. Calculate the uncertainty in the position of an electron, if the uncertainty in its velocity is 5.7 × 105 ms-1.
9. Calculate the total number of angular nodes and radial nodes present in 3d and 4f orbitals.
10. How many unpaired electrons are present in the ground state of Fe3+ (z=26), Mn2+ (z=25) and argon (z=18)?
11. Which has the stable electronic configuration? Ni2+ or Fe3+.
12. Find the group number for the following electronic configuration.
(i) ns2 (n-1) d1 (ii) ns2(n-1)d10 (iii) ns2np6
13. Give the IUPAC names of the elements having the following atomic numbers.
(a) 102 (b) 108 (c) 111
14. Write chemical equation for the following reactions.
(i) Reaction of hydrogen with tungsten (VI) oxide WO3 on heating. ii)Hydrogen gas and chlorine gas.
15. Complete the following chemical reactions and classify them in to (a) hydrolysis (b) redox (c) hydration reactions.
1) KMnO4 + H2O2 → 2) CrCl3 + H2O → 3) CaO + H2O →
16. An isotope of hydrogen (A) reacts with diatomic molecule of element which occupies group number 16 and period
number 2 to give compound (B) is used as a modulator in nuclear reaction. (A) adds on to a compound (C), which has
the molecular formula C3H6 to give (D). Identify A, B, C and D.
17. Complete the following reactions.
(i) Al4C3 + D2O → ? (ii) CaC2 + D2O → (iii) Mg3N2 + 6D2O → (iv) Ca3P2 + D2O →
18. Complete the following reactions. (i) Na2O2 + ------- → Na2SO4 + H2O2
19. Write balanced chemical equation for each of the following chemical reactions.
a) Lithium metal with nitrogen gas b) heating solid sodium bicarbonate c) Rubidium with oxygen gas
d) Solid potassium hydroxide with CO2 e) heating calcium carbonate f) heating calcium with oxygen
20. Complete the following reactions? (i) BeO + C +Cl2 → ? (ii) BeCl2+LiAlH4 → ?
21. A sample of gas at 15 °C at 1 atm. has a volume of 2.58 dm3. When the temperature is raised to 38 °C at 1
atm does the volume of the gas increase? If so, calculate the final volume. (June-23)
22. A sample of gas has a volume of 8.5 dm3 at an unknown temperature. When the sample is submerged in ice
water at 0 °C, its volume gets reduced to 6.37 dm3. What is its initial temperature?
23. Argon is an inert gas used in light bulbs to retard the vaporization of the tungsten filament. A certain light
bulb containing argon at 1.2 atm and 18°C is heated to 85°C at constant volume. Calculate its final pressure
in atm.
24. Inside a certain automobile engine, the volume of air in a cylinder is 0.375 dm3, when the pressure is 1.05
atm. When the gas is compressed to a volume of 0.125 dm3 at the same temperature, what is the pressure of
the compressed air? (Sep - 21)
25. A sample of gas has a volume of 3.8 dm3 at an unknown temperature. When the sample is submerged in ice
water at 0°C, its volume gets reduced to 2.27 dm3.What is its initial temperature?
26. Calculate the pressure exerted by 2 moles of sulphur hexafluoride in a steel vessel of volume 6 dm3 at 70 °C
assuming it is an ideal gas.
27. A mixture of gases contains 4.76 mole of Ne, 0.74 mole of Ar and 2.5 mole of Xe. Calculate the partial
pressure of gases, if the total pressure is 2 atm. at a fixed temperature.
28. An unknown gas diffuses at a rate of 0.5 time that of nitrogen at the same temperature and pressure.
Calculate the molar mass of the unknown gas.
29. Write down the Born-Haber cycle for the formation of CaCl2
30. Calculate the work done when 2 moles of an ideal gas expands reversibly and isothermally from a volume
of 500 ml to a volume of 2 L at 25°C and normal pressure.

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VJ – 11th CHEMISTRY COMPULSORY QUESTIONS – 2025
31. Calculate the entropy change in the system, and surroundings, and the total entropy change in the universe
during a process in which 245 J of heat flow out of the system at 77°C to the surrounding at 33°C.
32. 1 mole of an ideal gas, maintained at 4.1 atm and at a certain temperature, absorbs heat 3710J and expands
to 2 litres. Calculate the entropy change in expansion process.
33. 30.4 kJ is required to melt one mole of sodium chloride. The entropy change during melting is 28.4 JK−1
mol−1. Calculate the melting point of sodium chloride.
34. The standard enthalpies of formation of SO2 and SO3 are −297 kJ mol−1 and −396 kJ mol−1 respectively.
Calculate the standard enthalpy of reaction for the reaction: SO2 + 1/2 O2 → SO3
35. For the reaction at 298 K: 2A +B → C. ΔH=400 J mol−1 ; ΔS = 0.2 JK−1 mol−1 Determine the temperature at
which the reaction would be spontaneous.
36. Calculate ∆Hf0 for the reaction CO2(g)+ H2(g) → CO(g)+ H2O(g) given that ∆Hf0 for CO2 (g), CO (g) and
H2O(g) are – 393.5, – 111.31 and – 242 kJ mol–1 respectively.
37. An engine operating between 1270 C and 470 C takes some specified amount of heat from a high
temperature reservoir. Assuming that there are no frictional losses, calculate the percentage efficiency of an
engine. ( June – 24 )
38. Calculate the entropy change when 1 mole of ethanol is evaporated at 351 K. The molar heat of vaporisation
of ethanol is 39.84 kJ mol-1
39. The standard enthalpies of formation of C2H5OH(l), CO2(g) and H2O(l) are - 277,-393.5 and -285.5 kJ mol-1
respectively. Calculate the standard enthalpy change for the reaction C2H5OH(l)+3O2(g)→2CO2(g)+
3H2O(l).The enthalpy of formation of O2(g) in the standard state is Zero, by definition.
40. Calculate the enthalpy of combustion of ethylene at 300 K at constant pressure, if its heat of combustion at
constant volume (ΔU) is −1406 kJ .
41. If an automobile engine burns petrol at a temperature of 816o C (or) 1089K and if the surrounding
temperature is 21o C (or) 294 K , calculate its maximum possible efficiency. (June-22)
42. Calculate the standard entropy change for the following reaction( ΔSf0 ), given the standard entropies of
CO2(g), C(s),O2(g) as 213.6 , 5.740 and 205 JK−1 respectively.
43. Calculate the entropy change during the melting of one mole of ice into water at 00 C and 1 atm pressure.
Enthalpy of fusion of ice is 6008 J mol-1. (Mar-19 , Sep-20 , Mar-23)
44. Show that the reaction CO + ½ O2 → CO2 at 300K is spontaneous. The standard Gibbs free energies of
formation of CO2 and CO are –394.4 and −137.2 kJ mole−1 respectively. (Mar-19)
45. Calculate ΔG0 for conversion of oxygen to ozone 3/2 O2 ⇌ O3(g) at 298 K, if Kp for this conversion is 2.47
x 10−29 in standard pressure units.
46. One mole of PCl5 is heated in one litre closed container. If 0.6 mole of chlorine is found at equilibrium,
calculate the value of equilibrium constant.
47. For the reaction SrCO3(s) ⇌ SrO (s) + CO2(g), the value of equilibrium constant KP =2.2× 10–4 at 1002 K.
Calculate KC for the reaction.
48. At particular temperature KC = 4 × 10–2 for the reaction H2S(g) ⇌ H2(g) + ½ S2(g) Calculate KC for each of
the following reaction
i) 2H2S (g) ⇌ 2H2 (g) + S2 (g) ii) 3H2S (g) ⇌ 3H2 (g) + 3/2 S2(g)
49. The atmospheric oxidation of NO : 2NO(g) + O2(g) ⇌ 2NO2(g), was studied with initial pressure of 1 atm
of NO and 1 atm of O2. At equilibrium, partial pressure of oxygen is 0.52 atm calculate Kp of the reaction.
50. Write the Kp and Kc for the following reactions i). 2SO2(g) + O2(g) ⇌ 2SO3(g) ii). 2CO(g) ⇌ CO2 (g)+ C(s)
51. Consider the following equilibrium reactions and relate their equilibrium constants
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VJ – 11th CHEMISTRY COMPULSORY QUESTIONS – 2025
i) N2 + O2 ⇌ 2NO ; K1 ii) 2NO + O2 ⇌ 2NO2 ; K2 iii) N2 + 2O2 ⇌ 2NO2 ; K3
52. One mole of H2 and one mole of I2 are allowed to attain equilibrium in 1 lit container. If the equilibrium
mixture contains 0.4 mole of HI. Calculate the equilibrium constant.
53. The equilibrium concentrations of NH3, N2 and H2 are 1.8 × 10-2 M, 1.2 × 10-2 M and 3 × 10-2 M
respectively. Calculate the equilibrium constant for the formation of NH3 from N2 and H2.
54. The equilibrium constant at 298 K for a reaction is 100. A + B ⇌ C + D .If the initial concentration of all the
four species is 1 M, the equilibrium concentration of D (in mol lit-1) will be
55. A sample of 12 M concentrated hydrochloric acid has a density 1.2 gL–1 Calculate the molality.
56. A 0.25 M glucose solution at 370.28 K has approximately the pressure as blood does what is the osmotic
pressure of blood?
57. Calculate the molality of a solution containing 7.5 g of glycine (NH2-CH2 -COOH) dissolved in 500 g of
water.
58. Which solution has the lower freezing point? 10 g of methanol (CH3OH) in 100g of water (or) 20 g of
ethanol (C2H5OH) in 200 g of water.
59. How many moles of solute particles are present in one litre of 10-4 M potassium sulphate?
60. The observed depression in freezing point of water for a particular solution is 0.093 0C. Calculate the
concentration of the solution in molality. Given that molal depression constant for water is 1.86 K Kg mol-1.
61. The vapour pressure of pure benzene (C6H6) at a given temperature is 640 mm Hg. 2.2 g of non-volatile
solute is added to 40 g of benzene. The vapour pressure of the solution is 600 mm Hg. Calculate the molar
mass of the solute?
62. The molality of the solution containing 45 g of glucose dissolved in 2 kg of water.
63. 5.845 g of sodium chloride is dissolved in water and the solution was made up to 500 mL using a standard
flask. Calculate the strength of the solution in molarity.
64. 3.15 g of oxalic acid dehydrate, is dissolved in water and the solution was made up to 100 mL using a
standard flask. Calculate the strength of the solution in normality.
65. 5.85g of sodium chloride is dissolved in water and the solution was made up to 500 mL using a standard
flask. Calculate the strength of the solution in formality.
66. Calculate the mole fraction of ethanol and mole fraction of water. When 0.5 mole of ethanol is mixed with
1.5 moles of water. (Sep-20)
67. 50 mL of tincture of benzoin, an antiseptic solution contains 10 mL of benzoin. Calculate the volume
percentage of benzoin.
68. A 60 mL of paracetamol paediatric oral suspension contains 3g of paracetamol. Calculate the mass
percentage of paracetamol.
69. 50 g of tap water contains 20 mg of dissolved solids. What is the TDS value in ppm? ( J-22)
70. What volume of 4M HCl and 2M HCl should be mixed to get 500 mL of 2.5 M HCl?
71. An aqueous solution of 2 % nonvolatile solute exerts a pressure of 1.004 bar at the boiling point of the
solvent. What is the molar mass of the solute when PA0 is 1.013 bar?
72. 0.75 g of an unknown substance is dissolved in 200 g solvent. If the elevation of boiling point is 0.15 K and
molal elevation constant is 7.5 K Kg mol-1 then, calculate the molar mass of unknown substance.
73. At 400K 1.5 g of an unknown substance is dissolved in a solvent and the solution is made to 1.5 L. Its
osmotic pressure is found to be 0.3 bar. Calculate the molar mass of the unknown substance.
74. The depression in freezing point is 0.24K obtained by dissolving 1g NaCl in 200g water. Calculate van’t-
Hoff factor. The molal depression constant is 1.86 KKgmol-1.

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VJ – 11th CHEMISTRY COMPULSORY QUESTIONS – 2025
75. What is the mass of glucose (C6 H12O6) in one litre solution which is isotonic with 6 g L-1 of urea (NH2 CO
NH2) ?
76. 0.2 m aqueous solution of KCl freezes at -0.680C calculate van’t Hoff factor. kf for water is 1.86 K kg mol-1.
77. The antiseptic solution of iodopovidone for the use of external application contains 10 % w/v of
iodopovidone. Calculate the amount of iodopovidone present in a typical dose of 1.5 mL.
78. A litre of sea water weighing about 1.05 kg contains 5 mg of dissolved oxygen (O2). Express the
concentration of dissolved oxygen in ppm.
79. How much volume of 6 M solution of NaOH is required to prepare 500 mL of 0.250 M NaOH solution?
80. Vapour pressure of a pure liquid A is 10.0 torr at 27°C . The vapour pressure is lowered to 9.0 torr on
dissolving one gram of B in 20 g of A. If the molar mass of A is 200 g mol -1 then calculate the molar mass
of B.
81. 2g of a non-electrolyte solute dissolved in 75 g of benzene lowered the freezing point of benzene by 0.20 K.
The freezing point depression constant of benzene is 5.12 K Kg mol-1. Find the molar mass of the solute.
82. What is the mass of glucose (C6 H12O6) in one litre solution which is isotonic with 6 g L-1 of urea (NH2
CO NH2) ?
83. Draw the Lewis structures for the following species. i) NO3– ii) SO42– iii) HNO3 iv) O3 v) Nitrous acid
(HNO2) vi) Phosphoric acid vii) Sulphur trioxide (SO3).
84. Calculate the formal charge on each atom of carbonyl chloride (COCl2)
85. 0.30 g of a substance gives 0.88 g of carbon dioxide and 0.54 g of water calculates the percentage of carbon
and hydrogen in it.
86. 0.32 g of an organic compound, after heating with fuming nitric acid and barium nitrate crystals is a sealed
tube game 0.466 g of barium sulphate. Determine the percentage of sulphur in the compound.
87. 0.24g of an organic compound gave 0.287 g of silver chloride in the carius method. Calculate the percentage
of chlorine in the compound.
88. Give two examples for each of the following type of organic compounds.
(i) non-benzonoid aromatic compound, (ii) aromatic heterocyclic compound,
(iii) alicyclic compound (iv) aliphatic open chain compound (v) Carbocyclic compound
89. Write structural formula for the following compounds
(i) Cyclohexa-1, 4-diene (ii) Ethynyl cyclohexane
90. Give the structural formula of the following compounds (i) 3-cyclohexyl pentan-2-one (ii) 2-ethyl but-3- enoic acid
91. Identify the compound (A) and (B). R – C ≡ N → (A) → (B)
92. Identify the compound (A) and (B). R – Cl → (A) → (B)
93. Identify the compound (A) and (B).
aqueous KOH
(A)
C2H5 - OH
alcoholic KOH (B)

94. Identify the compound (A) and (B).

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VJ – 11th CHEMISTRY COMPULSORY QUESTIONS – 2025
95. Identify the compound (A) and (B).
H2O / H+
(A)
R - C - NH2 LiAlH4
O (B)
ether
96. Complete the following
Conc.H2SO4 HBr
CH3 - CH2 - OH A B
430 - 440K Benzoyl peroxide
97. Complete the following reactions
(i) CH2 = CH2 + H – Br → (ii) CH3 – CHO →

Pt / H2
iii)

98. Draw cis-trans isomers for the following compounds (a) 2- chloro – 2 – butane
(b) CH3 – CH = CH – CH2 – CH3
99. An organic compound (A) on ozonolysis gives only acetaldehyde. (A) reacts with Br2 /CCl4 to give
compound (B) Identify the compound (A) and (B). Write the IUPAC name of (A) and (B). Give the
Geometrical isomers of (A).
100. An organic compound (A) C2H4 decolourises bromine water. (A) on reaction with chlorine gives (B) A
reacts with HBr to give (C).identify (A),(B),(C), Explain the reactions.
101. Write the products A & B for the following reaction.
Cl – CH2 – CH2 – Cl → (A) → (B)
102. Identify the compound (A) and (B). CH ≡ C – CH3 + H2 → A→ B
103. Complete the following reactions?
(a) CH3 – C (CH3) = CH2 → (b) CH3 – CH = CH – CH3 →
104. Complete the following reaction?
(i) CH2 = CH2 + H2 → (ii) CH2 = CH2 + H2O + (O) →
105. Complete the following reaction?
(i) n CH3 – CH = CH2 → ? (ii) CH2 = CH – C6H5 → ?
106. Convert Ethyne to Benzene an name the process
107. Compound C2H6O (A) reacts with (anhydrous ZnCl2 and Con.HCl ) lucas reagent to give compound
(B) and water. Identify compounds A and B.
108. An organic compound (A) of molecular formula C2H6O , on heating with conc.H2SO4 Gives compound
(B). (B) on heating with cold dilute alkaline KMnO4 gives compound (C). Identify (A) ,(B) and (C) and
explain the reactions. ( June -19)
109. A simple aromatic hydrocarbon (A) reacts with chlorine to give compound (B). Compound (B) reacts with
ammonia to give compound (C) which undergoes carbylamines reaction. Identify (A) ,(B) and (C) and explain the
reactions.
110. Identify the compounds X , Y and Z in the following reaction
⁄
C2H6O → X→ Y→ Z

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VJ – 11th CHEMISTRY COMPULSORY QUESTIONS – 2025
111. Write the structure of the following compounds i) 1-Bromo-4-ethyl cyclohexane
ii) 1,4 – Dichlorobut – 2 – ene iii) 2- Chloro – 3- methyl pentane
112. The simple Aromatic Hydrocarbon compound (A) reacts with bromine to give (B). Compound (A) reacts with
Raney Ni and gives (C).Identify (A), (B) and (C).
113. Complete the following reactions

i) CH3 - CH = CH2 + HBr → ii) CH3 - CH2 - Br + NaSH →

iii) CHCl3 + HNO3 → (iv) CCl4 + H2O →

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VJ – 11th CHEMISTRY COMPULSORY QUESTIONS – 2025

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