1.

For solute which do not undergo any association or dissociation in a solution, the Van’t Hoff factor (i) will be- 1
(a) less than 1 (b) more than 1
(c) equal to 1 (d) zero
2. Isotonic solutions are solutions having the same- 1
(a) surface tension (b) osmotic pressure
(c) vapour pressure (d) viscosity
3. For solution showing negative deviation from Raoult’s law, the value of H is- 1
(a) positive (b) negative
(c) zero (d) none of these
4. Which of the following is not a colligative property? 1
(a) elevation in boiling point (b) depression in freezing point
(c) optical activity (d) relative lowering in vapour pressure
5. The boiling point of a solvent containing a non-volatile solute- 1
(A) is depressed (b) is elevated
(c) does not change (d) None of the above
6. The colligative properties of a dilute solution depend on- 1
(a) the nature of the solute. (b) the nature of the solvent.
(c) the number of particles of solute. (d) the molecular mass of solute.
7. The number of moles of NaCl in 3 litres of 3 M solution is- 1
(a) 1 (b) 3
(c) 9 (d) 27
8. Which of the following solution will have the minimum freezing point? 1
(a) 0.1M FeCl3 (b) 0.1M BaCl2
(c) 0.1M NaCl (d) 0.1M Urea
9. The number of moles of solute dissolved per litre of the solution is 1
(a) Normality (b) Molality
(c) Molarity (d) Formality
10. At higher altitudes, the boiling point of water decreases because- 1
(a) the atmospheric pressure is low (b) the atmospheric pressure is high
(c) the temperature is low (d) the temperature is high
11. Molar solution means 1 mole of solute present in- 1
(a) 1000 g of solvent (b) 1000 g of solution
(c) 1 litre of solvent (d) 1 litre of solution
12. Freezing point of a solvent containing a non-volatile solute- 1
(a) is depressed (b) is elevated
(c) does not change (d) None of these
13. Equimolar solution in the same solvent have- 1
(a) same boiling point but different melting point
(b) same freezing point but different boiling point
(c) same boiling point and same freezing point
(d) different boiling point and different freezing point
14. A colligative property is- 1
(a) Osmotic pressure (b) Boiling point
(c) Vapour pressure (d) Electrical conductivity
15. Which solution does not show positive deviation from Raoult’s law ? 1
(a) Benzene and Acetone (b) Ethanol and Water
(c) Water and HNO3 (d) Acetone and Ethanol
16. Normality of 0.3M phosphorus acid (H3PO3) is - 1
(a) 0.5 (b) 0.6
(c) 0.9 (d) 0.1
17. Constant boiling point mixtures are called - 1
(a) Ideal solution (b) Azeotropes
(c) Isotonic solution (d) Buffers
18 Isotonic solutions have- 1
(a) same boiling point (b) same vapour pressure
(c) same melting point (d) same osmotic pressure
19. For a binary ideal liquid solution, the total pressure of the solution is given as- 1
(a) PTotal=PoA +(PoA-PoB)xA (b) PTotal=PoB +(PoA-PoB)xA
o o o
(c) PTotal=P B +(P B-P A)xA (d) PTotal=PoA +(PoB-PoA)xA
20. What is Reverse Osmosis ? How is it useful ? 2
21. A solution containing 10.2 g of glycerine per litre is found to be isotonic with 2% solution of glucose. Calculate
molar mass of glycerine. (molar mass of glucose = 180) 3
22. Calculate the osmotic pressure at 273K of a 5% solution of compound A. (molecular mass = 60) (Given that R =
0.0821 L atm K-1mol-1) 3
23. The boiling point of water is 100oC. Calculate the boiling point of an aqueous solution containing 0.6 g of Urea
(molar mass=60) in 100 g of water. (kb for water = 0.52kmol-I) 3
24. The boiling point of water is 100oC. Calculate the boiling point of an aqueous solution containing 0.6g of Urea
(molecular mass=60) in 100 g of water. (Kb for water=0.52 K/m) 3
25. 1 g of non-electrolytic solute dissolved in 50 g of benzene lowers the freezing temperature of benzene by 0.40K.
The freezing point depression constant for benzene is 5.12 Kgmol -1. Calculate the molar mass of the solute. 3
24. If 1.71 g of sugar(molar mass=342) are dissolved in 500 cm3 of a solution at 300 K. what will be its osmotic
pressure? (R=0.083 LbarK-1mol-1) 3
25. Urea (molar mass = 60 gmol-1) forms an ideal solution in water. Determine the vapour pressure of an aqueous
solution containing 10 % by mass of urea at 40 oC. (Vapour pressure of pure water at 40 oC = 55.3 mm of Hg)3
26. A solution is made by dissolving 30 g of a non volatile solute in 90g of water. It has a vapour pressure of 2.8 kPa
at 298 K, vapour pressure of pure water is 3.64 kPa. Calculate the molar mass of the solute. 3
27. The vapour pressure of a compound A of molar mass 80 g at 20oC is 2.0 bar. When 4 g of a non-volatile solid is
added to 40 g of compound A in a beaker, the resulting vapour pressure is 1.5 bar. Calculate molar mass of the
non-volatile solid. 3
28. The boiling point of benzene is 353.23K. When 1.8 g of non-volatile solute was dissolved in 90 g of benzene, the
boiling point is raised to 354.11K. Calculate the molar mass of the solute. (Kb for benzene is 2.53K kg/mol) 3
29. 18g of glucose, C6H12O6 (molar mass = 180g mol -I) is dissolved in 1 kg of water in a sauce pan. At what
temperature of this solution boil? (Kb for water = 0.52 k Kg mol -I and boiling point of water = 373.15 K) 3